CA2262599C - Process and reactor for carrying out an exothermic reaction - Google Patents
Process and reactor for carrying out an exothermic reaction Download PDFInfo
- Publication number
- CA2262599C CA2262599C CA002262599A CA2262599A CA2262599C CA 2262599 C CA2262599 C CA 2262599C CA 002262599 A CA002262599 A CA 002262599A CA 2262599 A CA2262599 A CA 2262599A CA 2262599 C CA2262599 C CA 2262599C
- Authority
- CA
- Canada
- Prior art keywords
- zone
- slurry
- catalyst particles
- freeboard
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000002002 slurry Substances 0.000 claims abstract description 105
- 239000003054 catalyst Substances 0.000 claims abstract description 84
- 239000002245 particle Substances 0.000 claims abstract description 84
- 239000007788 liquid Substances 0.000 claims abstract description 55
- 238000010992 reflux Methods 0.000 claims abstract description 32
- 239000000725 suspension Substances 0.000 claims abstract description 9
- 239000011949 solid catalyst Substances 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 47
- 238000001816 cooling Methods 0.000 claims description 38
- 238000003786 synthesis reaction Methods 0.000 claims description 13
- 239000000376 reactant Substances 0.000 claims description 9
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 238000004064 recycling Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 14
- 239000002826 coolant Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 229910017052 cobalt Inorganic materials 0.000 description 7
- 239000010941 cobalt Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 238000004891 communication Methods 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- -1 aromatic urethanes Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0065—Separating solid material from the gas/liquid stream by impingement against stationary members
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00141—Coils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96202235 | 1996-08-08 | ||
| EP96202235.6 | 1996-08-08 | ||
| PCT/EP1997/004404 WO1998006487A1 (en) | 1996-08-08 | 1997-08-07 | Process and reactor for carrying out an exothermic reaction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2262599A1 CA2262599A1 (en) | 1998-02-19 |
| CA2262599C true CA2262599C (en) | 2005-11-22 |
Family
ID=8224267
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002262599A Expired - Fee Related CA2262599C (en) | 1996-08-08 | 1997-08-07 | Process and reactor for carrying out an exothermic reaction |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6322755B1 (de) |
| EP (1) | EP0949961B2 (de) |
| JP (1) | JP4100711B2 (de) |
| AU (1) | AU710780B2 (de) |
| CA (1) | CA2262599C (de) |
| DE (1) | DE69704718T3 (de) |
| DZ (1) | DZ2288A1 (de) |
| ID (1) | ID17986A (de) |
| MY (1) | MY116410A (de) |
| NO (1) | NO318961B1 (de) |
| SA (1) | SA97180494B1 (de) |
| WO (1) | WO1998006487A1 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6160026A (en) * | 1997-09-24 | 2000-12-12 | Texaco Inc. | Process for optimizing hydrocarbon synthesis |
| JP4351805B2 (ja) † | 1997-10-07 | 2009-10-28 | サソール テクノロジー（プロプライエタリー）リミテッド | ガス状反応物から液体生成物、場合によりガス状生成物を製造する方法 |
| US6080301A (en) | 1998-09-04 | 2000-06-27 | Exxonmobil Research And Engineering Company | Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins |
| US7096931B2 (en) * | 2001-06-08 | 2006-08-29 | Exxonmobil Research And Engineering Company | Increased heat exchange in two or three phase slurry |
| US8394154B2 (en) * | 2007-12-28 | 2013-03-12 | Texaco Inc. | Counter-current oxidation and steam methane reforming process and reactor therefor |
| US20090165368A1 (en) * | 2007-12-28 | 2009-07-02 | Yunquan Liu | Process and apparatus for reforming gaseous and liquid fuels |
| US20090170967A1 (en) * | 2007-12-28 | 2009-07-02 | Lixin You | Concurrent oxidation and steam methane reforming process and reactor therefor |
| US7989511B2 (en) * | 2008-05-21 | 2011-08-02 | Texaco Inc. | Process and apparatus for synthesis gas and hydrocarbon production |
| EA021337B1 (ru) * | 2008-09-30 | 2015-05-29 | Джэпэн Ойл, Гэз Энд Металз Нэшнл Корпорейшн | Реактор в виде барботажной колонны и способ управления реактором в виде барботажной колонны |
| JP5808559B2 (ja) | 2011-03-31 | 2015-11-10 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素油の製造方法、フィッシャー・トロプシュ合成反応装置及び炭化水素油の製造システム |
| JP5878809B2 (ja) * | 2012-03-28 | 2016-03-08 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 炭化水素合成用反応器 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2159077A (en) † | 1935-11-18 | 1939-05-23 | Ig Farbenindustrie Ag | Production of valuable hydrocarbons and their derivatives containing oxygen |
| US2567259A (en) | 1946-03-07 | 1951-09-11 | Texas Co | Catalytic conversion with a fluidized solid catalyst |
| US2584391A (en) † | 1947-03-29 | 1952-02-05 | Universal Oil Prod Co | Apparatus for effecting fluidized contact between solid particles and fluid mediums |
| US2581118A (en) | 1947-05-09 | 1952-01-01 | Standard Oil Dev Co | Method of controlling temperatures in a fluidized catalyst hydrocarbon synthesis process |
| US2775512A (en) † | 1953-03-02 | 1956-12-25 | Koppers Co Inc | Apparatus for the production of hydrocarbons |
| US3565589A (en) * | 1968-10-28 | 1971-02-23 | Cities Service Res & Dev Co | Upflow catalytic hydrotreating reactor |
| JPS5740196B2 (de) * | 1973-11-13 | 1982-08-25 | ||
| US4204847A (en) * | 1978-06-05 | 1980-05-27 | American Air Filter Company, Inc. | Mist eliminator device for a wet scrubber apparatus |
| JPS56110701A (en) † | 1980-02-07 | 1981-09-02 | Sumitomo Chem Co Ltd | Method and apparatus for removal of heat from polymerizer |
| EP0396650B2 (de) * | 1988-09-02 | 1995-04-12 | GebràDer Sulzer Aktiengesellschaft | Vorrichtung zur durchführung katalysierter reaktionen |
| CA2038772C (en) | 1990-04-04 | 2001-12-25 | Eric Herbolzheimer | Catalyst fluidization improvements |
| DE4119216C2 (de) * | 1991-06-11 | 1994-09-22 | Wurz Dieter | Tropfenabscheider |
| GB9203959D0 (en) † | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Method of conducting catalytic converter multi-phase reaction |
| GB9203958D0 (en) † | 1992-02-25 | 1992-04-08 | Norske Stats Oljeselskap | Catalytic multi-phase reactor |
| DE4314015A1 (de) * | 1993-04-23 | 1994-10-27 | Auf Adlershofer Umweltschutzte | Vorrichtung zur Abtrennung von Feststoffpartikeln aus Suspensionsreaktoren |
| US5512250A (en) * | 1994-03-02 | 1996-04-30 | Catalytica, Inc. | Catalyst structure employing integral heat exchange |
| US5464459A (en) * | 1994-06-06 | 1995-11-07 | Koch Engineering Company, Inc. | Chevron type mist eliminator and system |
-
1997
- 1997-08-06 DZ DZ970138A patent/DZ2288A1/fr active
- 1997-08-06 US US08/906,740 patent/US6322755B1/en not_active Expired - Lifetime
- 1997-08-06 MY MYPI97003597A patent/MY116410A/en unknown
- 1997-08-07 CA CA002262599A patent/CA2262599C/en not_active Expired - Fee Related
- 1997-08-07 WO PCT/EP1997/004404 patent/WO1998006487A1/en not_active Ceased
- 1997-08-07 JP JP50940898A patent/JP4100711B2/ja not_active Expired - Fee Related
- 1997-08-07 AU AU40152/97A patent/AU710780B2/en not_active Ceased
- 1997-08-07 EP EP97937577A patent/EP0949961B2/de not_active Expired - Lifetime
- 1997-08-07 DE DE69704718T patent/DE69704718T3/de not_active Expired - Lifetime
- 1997-08-07 ID IDP972741A patent/ID17986A/id unknown
- 1997-10-14 SA SA97180494A patent/SA97180494B1/ar unknown
-
1999
- 1999-02-05 NO NO19990556A patent/NO318961B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU710780B2 (en) | 1999-09-30 |
| JP4100711B2 (ja) | 2008-06-11 |
| JP2000516139A (ja) | 2000-12-05 |
| DZ2288A1 (fr) | 2002-12-25 |
| US6322755B1 (en) | 2001-11-27 |
| EP0949961B1 (de) | 2001-05-02 |
| ID17986A (id) | 1998-02-12 |
| DE69704718D1 (de) | 2001-06-07 |
| NO318961B1 (no) | 2005-05-30 |
| DE69704718T3 (de) | 2010-12-23 |
| MY116410A (en) | 2004-01-31 |
| AU4015297A (en) | 1998-03-06 |
| WO1998006487A1 (en) | 1998-02-19 |
| EP0949961B2 (de) | 2010-06-09 |
| EP0949961A1 (de) | 1999-10-20 |
| CA2262599A1 (en) | 1998-02-19 |
| NO990556L (no) | 1999-03-26 |
| DE69704718T2 (de) | 2001-09-20 |
| NO990556D0 (no) | 1999-02-05 |
| SA97180494B1 (ar) | 2006-03-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |