CA2233661C

CA2233661C - Volatile materials treatment system

Info

Publication number: CA2233661C
Application number: CA002233661A
Authority: CA
Inventors: Struan Glen Robertson; Edward Elliott Finsten
Original assignee: Tox Free Systems Inc; Tox Free Systems Ltd
Current assignee: Tox Free Systems Inc; Tox Free Systems Ltd
Priority date: 1995-10-06
Filing date: 1996-10-04
Publication date: 2006-09-12
Anticipated expiration: 2016-10-04
Also published as: CA2233661A1

Abstract

Apparatus for the treatment of volatile material(s) in contaminated material(s) including a retort assembly (10) which includes a rotatable retort (11) disposed at least partially within a combustion chamber (12) with heating means (13) to indirectly heat the contents of the rotatable retort; feeding means (21, 22, 23 ) to feed the contaminated material(s) (20) to the retort. The apparatus further includes means (54) for passing the contaminated material(s) (20) to the retort. The apparatus further includes means (54) for passing the combustion gases from an after burner (50) to the retort assembly to provide additional heat for use in the heating of the contaminated material in the retort. The apparatus further includes a high temperature filter (30) which can filter the volatiles before entering the after burner.

Description

WO 97/13594 PCT/ALJ9G/OOG2ft VOLATILE MATERIALS TREATMENT SYSTEM
This invention relates to the treatment of volatile contaminants. The invention is particularly suitable for, but not limited to, the removal of contaminants from solids and liquids.
S
The contaminants may include, but are not limited to, petroleum products (eg.
petrol, oils, greases); phenols; coaltar; cyanide; pesticides; PCB's; I-iCB's, organochlor-ine pesticides and arsenics.
The treatment of contaminated soils and liquid wastes is a worldwide problem.
Ofi en, the contaminated soils or liquids are simply removed and transferred to a toxic waste dump or pond. This does no more than move the problem. For contaminants such as PCB's, the environmental protection authorities around the world specify strict conditions for their disposal in very high temperature incinerators, eg. found in the vessel "Vulcanus".

International Patent Application No. PCT/AU93/00646 (International Publication No.
WO 94/1S1S0) (Robertson) discloses a stationery retort where toxic waste and other contaminants are removed from soil, the soil being agitated and being brought into contact with the retort walls to cause the wastes and contaminants to be desorbed_ The retort has proved successful in the removal of toxic waste and contaminants from many types of soil.
It is an object of the present invention to provide improved methods and apparatus for use in removing volatile contaminants from solids or liquids.
2S According to one aspect of the present invention there is provided a method for t1e treatment of volatile material (s) in contaminated material (s) including the steps of:
feeding the contaminated material (s) to a retort assembly which includes a rotatable retort at least partially disposed within a combustion chamber which is heated by heating means ;
causing the contaminated material (s) to contact the walls) of the retort to cause the volatile material (s) to be given off as gases;
SUBST)TLTI'E SKEET (Rule 26) VVO 97~z359a z'C'r~AU9G~oaGZs discharging the ueated material from the retort;
uansferring the gases to an afterburner for combustion; and returning the combustion gases from the afterburner to the retort assembly to provide assistance in heating the contaminated materials) being treated in the retort.
S
According to another aspect of the present invention there is provided apparatus for the treatment of volatile material (s) in contaminated material (s) including a retort assembly which includes a rotatable retort disposed at least partially within a combustion chamber with heating means to indirectly heat die rotatable retort; said rotatable retort include a feed end through which the contaminated materials) are fed to the retort and a discharge end from which the materials are discharged from the retort; an afterburner; means to uansfer the volatile materials) given off as gases to the afterburner for combustion; and means for passing d1e combustion gases from the afterburner to the retort assembly to provide additional heat for use in the heating of contaminated material (s) in the retort.
Preferably, the apparatus includes a high temperature filter through which the gaseous volatile material (s) pass after leaving the retort and prior to entering the afterburner.
According to yet another aspect of the present invention there is provided a high temperature filter which is suitable for use.but not limited to the treatment of volatile gaseous contaminated material, the filter including a main body having first and second chambers therein which chambers when the flter is in its operative position include an upper region and a lower region, an opening providing communication between ttze chambers, said opening being' at the lower region of the chambers, an inlet for delivering gaseous contaminated 2S material to the first chamber in the upper region thereof, an outlet for discharging the gaseous material from the second chamber, a solids collection zone adjacent the opening, a solids discharge outlet for discharging solids from the solids collection zone, a baffle opposite to and spaced from the inlet upon which incoming gases impinge and filter means for filtering die gaseous material passing out of the second chamber via the outlet.
SUBSTIT'UZ'E SI~ET (Rule 26) WO 97/I3594 F'CT/ATJ9Cr/OOG28 According to another aspect of the present invention there is provided a retort for use in the treatment of volatile material, the retort including a cylindrical body which is mounted for rotation about its longitudinal axis, said body having an infeed end and an outlet end, a combustion chamber, said cylindrical body being at least partially located within ttie combustion chamber, a plurality of balls or like elements disposed witHin the cylindrical body arranged to interact wide contaminated material when the cylindrical body is rotating to break down the material and dislodge carbonised material which may form on the internal wall of the cylindrical body. The retort is particularly suitable for use in apparatus of the type described herein.
Preferably the retort includes a cage within the cylinder which retains the balls in t1e region of the wall of the cylindrical body. Preferably, the balls are arranged in groups, the groups being at spaced intervals along the interior of the cylindrical body.
The cage includes spaced apart peripherally extending members which arc adapted to assist in retaining the balls in each group at a particular location within the cylindrical body.
Preferably, the balls are made of ceramic material. Preferably, the cage is mounted for rotation in the opposite direction to the cylindrical body.
In one embodiment of the invention the combustion gases are passed through the interior of the reCort. In another embodiment_the combustion gases arc passed to the heating means _ When the contaminated material to be treated is in the form of solids, the solids are preferably passed through a grizzly or sieve prior to entering the retort to remove oversized material. If desired the solids may in addition to or alternatively to the above be passed through a mill prior to entering the retort so as to reduce the particle or granule size of t1e solids.
When the contaminated material is in the form of liquid, floe water content of the liquid is preferably reduced prior to entering the retort. To this end the liquids may be SLJBSTIT'(TI~ SI~ET (Rule 26) 4 PCT/AU9G/()OG28 preheated to boil off the water prior to entering the retort.
Preferably, the rotary retort rotates about an axis inclined at a small angle to the horizontal and is substantially surrounded by a combustion chamber to enable indirect heating of the retort.
Preferably, the combustion gases pass through a scrubber before being released into the atmosphere after passing through the retort. The gases from the high temperature filter may be passed through a condenser, where the condensate contains hydrocarbon fractions such as fuel oil and lubrication oil fractions.
In the high temperature filter according to the invention, the baffle is preferably defined by a wall which separates the said first and second chambers.
Preferably, the wall extends from an upper internal wall of the chambers and terminates at a point spaced from IS a Iower internal wall of the chambers, the space between the free end of the wall and the lower internal wall of the filter defining the opening. The wall may have fins thereon.
Preferably, the discharge outlet comprises a plurality of outlet ports in the upper wall of said second chamber. Preferably, the filter means comprises a plurality of ceramic candles, each ceramic candle being associated with a respect outlet, the ceramic candles extending into the second chamber.
There may further be provided a gas collecting chamber for receiving the gaseous rnai~eriai from tale outlets and a discharge outlet for discharging the gaseous material from the gas collecting chamber. Fan suction means may be provided for drawing t1e gaseous material from the second chamber through the outlets.
The filter may further include pulsing means for delivering a gas under pressure to the filter means in the opposite direction of normal flow for cleaning the filter means.
Preferably, the gas used in the pulsing means is nitrogen.
SUBSTT»'E SHEET (Rule 2b) ..
WO 97/13594 FCT/AU9G/0()C28 A heat jacket is preferably provided which at least partially surrounds the main body of the filter.
A further embodiment of the invention is particularly suited for the treatment of material containing organochlorine pesticides such as DDT, DDE and DDD and various arsenic based compounds. Such material is found in soil from cattle dip sites.
According to this aspect of the present invention there is provided a method for treatment of volatile materials) in contaminated materials) including organochlorine pesticides and arsenic based compounds including the steps of:
feeding the contaminated materials) to a retort assembly which includes a rotatable retort at least partially disposed within a combustion chamber which is heated by heating means;
causing the contaminated materials) to contact the walI(s) of the retort to cause the I S volatile materials) to be given off as gases;
discharging the treated material from the retort into a high temperature filter;
thereafter transferring the gases to an afterburner for combustion and at the same time introducing water vapour into the afterburner.
According to yet another aspect of tly,present invention there is provided apparatus for treatment of volatile materials) in contaminated material (s) including organochlorine pesticides and arsenic based compounds including a retort assembly which includes a rotatable retort having an infeed end through which material is fed to the retort and an outlet, the retort being at least partially disposed within a combustion chamber which is heated by heating means, whereby in use, the contaminated materials) is caused to contact the walls) of the retort to cause the volatile materials) to be given off as gases;
a high temperature filter which receives the material from the retort, an afterburner for combustion of the gases and means for introducing water vapour into the afterburner.
SUBSTITUTE SI~ET (Rule 26) WO 97/I3594 PCT/AU9G/(1OG28 In this particular process the contaminated material is preferably firstly pretreated to remove water from the material. This may be done by the use of a preheater.
The material is then transferred to a retort where the contaminant compounds are vaporised.
The contaminarits in the gas stream so formed are then transferred to a high temperature filter which may be of die type described earlier where further particulate matter is separated from the gas. The remaining gaseous component is transferred to an afterburner. The afterburner thermally destructs the organochlorine pesticides to produce simple products of combustion and hydrogen chloride gas. The arsenic component of the gas will pass through the afterburner primarily as arsenic trioxide.
If desired water vapour which may be conveniently drawn from the preheater is fed into the afterburner. The introduction of the water vapour causes a water/gas reaction which assists in the production of hydrogen chloride and arsenates.
The gas stream then passes to a condenser wherein the gas is rapidly cooled so as to condense the arsenates for collection as particulate matter. After the gas stream leaves the condenser calcium carbonate can be added to the stream to neutralise the hydrogen chloride.
The gas can be finally passed tlmough a dust collector device whereafter the gas can pass to atmosphere.
As mentioned earlier the gases leaving the afterburner are cooled so as sublimate (condense) the arsenic and arsenic trioxide. Two alternative systems are envisaged I. indirect air cooled; or 2. evaporative cooling through injection of water into the gas stream.
The gas stxeam leaving the afterburner is cooled to preferably about 110°C in the condenser and then may be dosed with calcium carbonate (CaC03) (lime). The calcium SUBSTITUTE SKEET (Rule 26) carbonate reacts with the constituents ofthe gas stream to neutralise the hydrochloric acid and absorb moisture in the gas stream . The lime assists in minimizing moisture problems on the filter bags, and can be collected in a dust collection bin.
The dust collector which may be in the form of a baghouse will remove the particulate arsenic trioxide which condenses below at approximately 120 ° C and collects on the filter media. The gas stream will exit the baghouse at approximately 100 ° C and be vented to atmosphere. An auxiliary fan on the baghouse will be used in conjunction with the high temperature filter fan in order to overcome the additional pressure loss in the system. The fans will be balanced using dampers in the system. The contaminated particulate (arsenic trioxide, spent lime) can be collected in plastic lined 200 L drums for disposal at authorized landfills.
In a broad aspect, then, the present invention relates to a high temperature filter for use in the treatment of volatile gaseous contaminated material, the filter including a main body having an internal space therein which internal space includes an upper region and a lower region, said internal space being separated into first and second chambers, an opening providing communication between the chambers, said opening being at the lower region of the internal space, an inlet for delivering the gaseous contaminated material to the first chamber in the upper region of the internal space, an outlet for discharging the gaseous material from the second chamber in the upper region of the internal space, a solids collection zone adjacent the opening, a solids discharge outlet for discharging solids from the solids collection zone, a baffle directly opposite to and spaced from the inlet upon which incoming gases impinge so as to separate the solids from the gaseous material, filter means for filtering the gaseous material passing out ofthe second chamber via the outlet and a heat jacket which at least partially surrounds the main body of the filter.
To enable the invention to be fully understood, preferred embodiments ofthe invention in its various aspects will now be described with reference to the accompanying drawings in which:

-7a-Figure 1 is a schematic circuit diagram of a first embodiment for the treatment of contaminated solids;
Figure 2 is a schematic view of the retort of the first embodiment;
Figure 3 is a more detailed schematic view of the retort of the first embodiment;
Figure 4 si a schematic sectional side view of a high temperature filter according to the present invention;
Figure 5 is a schematic side view of an afterburner for use in the present invention;
Figure 6 is a schematic view of a second embodiment for the treatment of WO 97/13594 i'CT/AU9G100G28 _g_ contaminated liquids;
Figure 7 is a schematic view of a third embodiment for the treatment of contaminated liquids;
Figure 8 is a schematic view of a further embodiment particularly suited for the treatment of organochlorine pesticides and arsenic compounds;
Figure 9 is a schematic side elevation of a part of a high temperature filter according to another form of the invention;
Figure 10 is a side elevation of a manifold as shown in Figure 9;
Figure I I is a schematic side elevation of one form of condenser which can be used in the embodiment of Figure 8;
Figure 12 is a schematic side elevation of another form of condenser 4vhich can be used in the embodiment of Figure 8;
Figure I3 is a sectional view of a retort according to one embodiment of the invention;
and Figure 14 is a modified form of the retort shown in Figure 13.
Referring to Figures 1-3, die rotary retort 10 has a cytindricai retort wall 1 1 rotatably journal led within a combustion chamber I2 heated by a plurality of burners 13 to provide indirect heating to the interior of the retort 10.
Ceramic seals form an airproof seal between the moving retort wall I 1 and the fixed ends of the combustion chamber 12 (or of a support structure for the retort), and also act as SUBST)TLJT'E SFWET (Rule 2fi) an explosion vent in case of a volatile mix release caused by oxygen in the retort. (Preferably, a nitrogen purge is provided for the retort to prevent the oxygen levels becoming dangerous.) As shown in Figure 3, fins, blades or the like 14 are provided on the inner face of the retort wall 11 to increase the agitation of materials passing through the retort and to improve the heat transfer from the retort wall 1 1 to the materials.
Contaminated solids 20 are transferred via conveyor 21 to a grizzly 22 where oversized particles are removed. The acceptable particles are fed to the interior of the retort IO via a rotary valve 23. As the contaminated solids move through tte retort I0, volatile contaminants are given off as gases and are transferred via a gas line 15 to a high temperature filter 30 to be hereinafter described in more detail. The high temperature filter 30 is heated by the combustion gases from the combustion chamber 12 (being transferred via a line 1G).
A rotary valve I7 discharges the treated solids to a product in I8 and a conveyor 19 may be provided to transfer the treated solids from the product bin 18 to a dump pile 19A.
Referring now to Figure 4, the high temperature filter 30 is maintained above 500°C
above the combustion gases from the retort being fed via line 1G to a heat jacket 31 to prevent ' 20 condensation of the volatile gases 32. The volatile gases enter a first chamber 33 and impinge on a wall 34 which acts as a baffle and separates the first chamber 33 from a second chamber 35. The wall 34 may have fins or plates thereon for the transfer of heat as well as to slow the gas stream down. As the volatile gases 32 sharply change path when passing from the first -L-~L~__'7'1 ~ .t__ J 1.
~mamu~r » ~o me secona cnamber 35, most of tile particuiates 3G in tile voiatiie gases 32 collect at the bottom of the high temperature filter 30 and can be selectively discharged by a rotary valve 37 and line 38 to the product bin 18. The combustion gases 32 then pass through ceramic candles 39 which capture particles down to -1 micron. The interiors of the ceramic candles 39 are connected to a pIenum or chamber 40 and the volatile gases 32 are drawn from the plenum by a suction fan 41. The suction fan generates a partial vacuum in the high temperature filter 30 (and the retort IO) and assists in causing the ceramic seals to SLJBSTITUT73 5F-~ET (Rule 2G) seal against the ends of the retort wall I I . An explosion vent in the form of a door 63 may be provided in the wall of the filter the door being arranged to open in the event of an explosion.
S To prevent the oxygen level in the high temperature filter 30 reaching dangerous levels, sensor means (not shown) monitor the oxygen levels and if required, nitrogen from a supply tank 42 is injected into die line IS via one or more nozzles connected to a valve 43.
To remove the particulates 36 which tend to coat the exterior of the ceramic candles 39, an air compressor 44 is connected to a manifold 4S via a valve 46. A
respective pipe 47 extends from the manifold 4S into the interior of each ceramic candle 39 and sensor means (not shown) which monitor the gas flow through the ceramic candles, operate t1e valve 46 so that a blast of air is injected into the interior of the ceramic candles, via the pipes 47 to cause a countercurrent flow to die flow of the volatile gases 32 to dislodge the particulates 1 S from the candles for collection in the bottom of the high temperature filter 30.
Figures 9 and 10 show a modified form of apparatus for introducing nitrogen into the high temperature filter as well as for removing the particles from the candles. In the apparatus as shown nitrogen is fed from a manifold 401 having a plurality of outlets 402 to 406_ Each outlet is connected to a transfer tube 407 which extends into the filter at a position above the candles 39. The tube has a series of downwardly facing holes 408 each hole being associated with a respective candle. T7ie arrangement is such that a blast of nitrogen can tie directed downwardly to clear the candles and at the same time deliver nitrogen to the f-tlter_ The volatile gases 32 are conveyed via a line 48 to an afterburner SO (see Figure S) in which combustion air is injected via a number of inclined injection pipes 51 to create a vortex for efficient combustion of the volatile gases. In one embodiment the combustion gases 52 from the afterburner pass through a plenum S3 to a line S4 which is connected to a pipe or conduit SS extending through the interior of the retort 10. In another embodiment the SLTBSTTZ'UZ'E SI~ET (Rule 26) ' ~ w0 97/I3594 t'CT/AU9G/OOG28 gases can pass along line 54 and instead of passing through the retort can be fed to the burners I3 as shown by dash line 62 in Figure I.
The pipe 55 has a plurality of helical flytes 56 to further promote the agitation of the laminated solids 50 in the retort I0, and to promote the transfer of heat from die combustion gases to the solids. /~s shown in Figure I , the flow of the combustion gases 52 from the afterburner is concurrent with the flow of solids through the retort IO and the heat from the combustion gases 52 reduces the heat requirements for the retort provided by the burners I5, thereby reducing the input energy demand and cost. (This means flat the volatile contaminants in the soil are used to provide a portion of the energy demands for the treatment of the soil and so the volatile materials, which normally have a highly negative economic value, are given at least a partial positive economic value.) From the pipe 55, a line 57 transfers the combustion gases 52 to a scrubber 58 and thereby to the end stack 59 for release to the atmosphere.
IS
Referring now to a second embodiment of Figure 6, liquid contaminants from a pond I20 are fed to a concentrator 12I where the water content of the liquids is minimised and the concentrated contaminated liquid is transferred to a tank 122. The contaminated liquid is pumped via a pump I22a to spray nozzles I23 which inject the contaminated liquid into the retort 10. The contaminated liquid comes into contact with the interior of the retort wall 11 and the conduit SS to cause the volatile contaminants to be given off as gases as hereinbefore described and any non-volatile solids are discharged via rotary valve 17 to the product bin I8.
It will be noted that line 54 connects the afterburner 50 to the conduit 55 so that t1e 2S flow of combustion gases 52 from the afterburner is countercurrent to the flow of the contaminated liquids through t1e retort 10.
In the embodiment of Figure 7, which is particularly suitable for the treatment of refinery tank bottoms, the contaminated refinery products containing, eg. 50-80 % water, is pumped from a refinery tank 220 to a preheater 222 where the water and light hydrocarbon SUBSTTTUTB SF~ET (Rule 26) T
' WO 97/I3594 ~ I'CT/AU9G/OOG28 fractions) are boiled off at, eg. 120°C plus and fed by line 260 to the afterburner S0. A hot filtering device 261 removes particulates from the water/gas stream and feeds them to the high temperature filter 30 via a rotary valve 262_ The concentrated liquid from the preheater 222 is sprayed into the retort IO as hereinbefore described. The preheater I22 is heated by S combustion gases from the retort IO via line 223.
From the retort, the non-volatile solids are discharged via rotary valve I7 to the bin I8, and the volatile gases are transferred to the high temperature filter 30.
The volatile gases are transferred from the filter 30 to a condenser 270 via line 27I at a temperature of, eg.
S00°C. The gases are cooled and the condensate is collected as fuel oil, which is drawn off to tank 272 via line 273. By arranging the Condenser 270 as a "fractional distillation unit", the condensate may be separated into a lubrication oil component (drawn off at, eg.
300-500°C) to tank 274 via line 275, and a diesel substitute component (at, eg. 200-300°C) via line 273 to tank 272.

The remaining volatiles from the condenser 270 are fed to the afterburner SO
via line 48. These voIatiles, and the 222 water/light 1vC fraction from the preheater, may be burnt at, eg. 1200°C with a residence time of, eg. 20 seconds. The energy from the afterburner SO
is recycled to heat the preheater 223 and die high temperature filter 30. The high temperature filter and pre-treatment feed and product lines.are surrounded by a heating jacket to maintain temperature and the heat is sourced from the combustion chamber excess gases.
This method markedly reduces the costs of treating the refinery tac~lc bottoms, and the ~oto .rr~ ..FF....~ h.. r1... _ _r .a -~~~w me wmc~ uy 1.11C: Lel:VVery oc me vaiuabie eondensates(s).

Figure 8 shows a further embodiment of the invention which is particularly suited for the treatment of material containing organochlorine pesticides such as DDT, DDE and DDD
and various arsenic based compounds. Such material is found in soil from cattle dip sites.
In this particular arrangement die contaminated material is preferably firstly pretreated SU13STT'f(JT'E SFiF~T (Rule 2G) WO 97/13594 PCT/Atl9G/OOG28 to remove water from the material. This may be done by the use of a preheater 501. The material is then transferred to retort 503 where the contaminant compounds are vaporised.
The contaminants in the gas stream so formed are then transferred to high temperature filter 504 which may be which may be of the type described earlier where further particulate matter is separated from the gas. The remaining gaseous component is transferred to afterburner 506. The afterburner thermally destructs the organochlorine pesticides to produce simple products of combustion and hydrogen chloride gas. The arsenic component of the gas will pass through the after burner primarily as arsenic trioxide.
If desired water vapour which may be conveniently drawn from the preheater 501 is fed into the afterburner 506 via line 510. The introduction of the water vapour causes a water/gas reaction which assisu in the production of hydrogen chloride and arsenates.
The gas stream then passes to condenser 512 wherein the gas is rapidly cooled so as to condense the arsenates for collection as particulate matter at vessel 514.
After the gas stream leaves the condenser SI2 calcium carbonate can be added to t1e stream via hopper 516 to neutralise the hydrogen chloride.
The gas can be finally passed through a dUSt collector device 518 whereafter the gas can pass to atmosphere. The dust collector 518 which may be in the form of a baghouse will remove the particulate arsenic trioxide which condenses below at approximately 120°C and collects on the filter media. The gas stream will exit the baghouse at approximately 100°C
and be vented to atmosphere. An auxiliary fan on the baghouse will be used in conjunction with the high temperature filter fan in order to overcome the additional pressure loss in the system_ The fans will be balanced using dampers in the system. The contaminated particulate (arsenic trioxide, spent lime) will be collected in plastic lined 200 L drums for disposal at authorised landfills.
Two examples of condensers which can be used are shown in Figures 1 l and 12.
Figure 1 1 shows an evaporate cooling arrangement wherein the gases leave the afterburner SUBSTTTUTE SHEET (Rule 26) ' ~ WO 97/13594 PCT/AU9G/OOG28 and travel along an inverted U-tube 601. Water spray a fed from reservoir 602 to spray heads 603 by pump 604 so as to rapidly cool the gas before it leaves the condenser.
Figure 12 shows an indirect air cooled arrangement where gases enter die top of the condenser 700. A series of fans 701 create an air flow across the condenser thereby cooling the gases before they exit at the bottom.
Figures 13 and 14 show two arrangements of a retort which is suitable for use in various forms of apparatus described herein. Referring to the drawings the retort 800 includes a cylindrical body 80I which is mounted for rotation about its central axis for example on shaft 810. The retort 800 is disposed within a combustion chamber (not shown) the ends being sealed by ceramic seals (not shown). The retort has an infeed end 802 through contaminated material is fed into the retort and an outlet 803. A
plurality of flytes 808 are formed on the internal wall of the cylindrical body 801 the flytes preferably having a 5° pitch.
The retort 800 further includes a cage 815 which is mounted within the cylindrical body 801. The cage 815 comprises a series of horizontal elements or rods 816 and a series of circumferential elements 817 connected together to form a unitary structure. The circumferentiaI elements 817 are arranged in pairs on the region of the space between adjacent flytes 808. The cross-sectional diameter of the cage 8I5 is less than that of the internal cross-sectional diameter of cylindrical body 801 thereby forming an annular space 818 between the cylindrical body 801 and the cage 815.
The cage 8I5 is mounted for rotation and preferably is arranged to rotate in the opposite direction to flat of the cylindrical body.
A plurality of balls 806 or like elements are disposed in the space 818 and are arranged to interact with contaminated material when the parts are rotating to break down the material and dislodge carbonised material which may form on the internal wall of the SUBSTrI UTE 5F1~T {Rulc 26) WO 97/13s94 PC'I'/A119G/OOG28 cylindrical body 801. The balls 806 are arranged in groups disposed at spaced intervals along the cylindrical body and are retained in position by respective pairs of circumferential elements 817 In the embodiment shown in Figure 14 there is further provided a series of arms 820 which can assist in moving the balls during rotation of the parts. The arms 820 can either rotate with the cage on shaft 8I0 or can be fixed to tte internal wall of the cylindrical body 801.
The balls are arranged in groups each group which are held in place by the cage 815 and more particularly by the element 817 projecting into space 818. The groups of balls are being disposed at spaced intervals along the cylindrical body.
NB: For both contaminated solids or liquids, the flow of the combustion gases through the retort may be eidter concurrent or countercurrent to the flow of the contaminated materials.
The recycling of the afterburner gases back into the retort 10 via the tube, pipe or conduit 55 minimises the energy input to the retort by the burners.
The provision of the heat fins or flytes 56 on the pipe or conduit 55 not only increases the radiant surface area of die retort, but also assists in breaking up any large particles. In addition, the recycling pipe or conduit also helps create a convection environment with improves the volatile removal process, ttie convection improvement being created by the moving retort wall and by rotation of the pipe or conduit 55.
The energy sources for the burners 13 may include liquid petroleum gas, propane, natural gas, recycled hydrocarbons or other readily available energy sources.
The volatiles which may be treated by the method and apparatus of the present SUBSTT»I~ SHEET (Rule 26) w0 97/I3594 PCT/AU9C/OOG28 invention include hydrocarbons, organo-chlorides, arsenics, hydrogenated hydrocarbons, PCB's, coaltars and the like.
The operating temperature in the retort will be dependent on t1e volatile contaminants being treated and the retort may be operated at different temperatures to enable different volatiles to be treated on a fractional basis.
Various changes and modifications may be made to the embodiments described without departing from the present invention.
SUBSTITUI~ SF~ET (Rule 26)

Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. ~A high temperature filter for use in the treatment of volatile gaseous contaminated material, the filter including a main body having an internal space therein which internal space includes an upper region and a lower region, said internal space being separated into first and second chambers, an opening providing communication between the chambers, said opening being at the lower region of the internal space, an inlet for delivering the gaseous contaminated material to the first chamber in the upper region of the internal space, an outlet for discharging the gaseous material from the second chamber in the upper region of the internal space, a solids collection zone adjacent the opening, a solids discharge outlet for discharging solids from the solids collection zone, a baffle directly opposite to and spaced from the inlet upon which incoming gases impinge so as to separate the solids from the gaseous material, filter means for filtering the gaseous material passing out of the second chamber via the outlet and a heat jacket which at least partially surrounds the main body of the filter.

2. ~A high temperature filter according to claim 1 wherein said baffle is defined by a wall which separates said first and second chambers.

3. ~A high temperature filter according to claim 2 wherein said wall extends from an upper internal wall of the chambers and terminates at a point spaced from a lower internal wall of said chambers, the space between the wall and the lower internal wall defining said opening.

4. ~A high temperature filter according to any one of claims 1 to 3 wherein said discharge outlet comprises a plurality of outlet ports in the upper wall of said second chamber.

5. ~A high temperature filter according to claim 4 wherein said filter means comprises a plurality of ceramic candles, each ceramic candle being associated with a respective outlet port, said ceramic candles extending into said second chamber.

6. A high temperature filter according to claim 4 including a gas collecting chamber for receiving the gaseous material from the outlet ports and a discharge outlet for discharging the gaseous material from the gas collecting chamber.

7. A high temperature filter according to claim 4 further including a fan suction means for drawing the gaseous material from the second chamber through the outlet ports.

8. A high temperature filter according to any one of claims 1 to 3 further including pulsing means for delivering a gas pressure to the filter means in the opposite direction of normal flow for cleaning the filter means.

9. A high temperature filter according to claim 8 wherein the gas used in the pulsing means is nitrogen.

10. A high temperature filter according to any one of claims 1 to 3 including plates on said baffle for the transfer of heat and for slowing the passage of the gaseous stream down through the first chamber.