CA2199422A1 - Alkylesters de l'acide phenylacetiques - Google Patents

Alkylesters de l'acide phenylacetiques

Info

Publication number
CA2199422A1
CA2199422A1 CA002199422A CA2199422A CA2199422A1 CA 2199422 A1 CA2199422 A1 CA 2199422A1 CA 002199422 A CA002199422 A CA 002199422A CA 2199422 A CA2199422 A CA 2199422A CA 2199422 A1 CA2199422 A1 CA 2199422A1
Authority
CA
Canada
Prior art keywords
methoxy
bond
radical
riii
general formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002199422A
Other languages
English (en)
Inventor
Klaus Oberdorf
Hubert Sauter
Hartmann Konig
Albrecht Harreus
Bernd Muller
Reinhard Kirstgen
Wassilios Grammenos
Herbert Bayer
Franz Rohl
Gisela Lorenz
Eberhard Ammermann
Volker Harries
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2199422A1 publication Critical patent/CA2199422A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5456—Arylalkanephosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/32—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C07C235/34—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton containing six-membered aromatic rings having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C239/00—Compounds containing nitrogen-to-halogen bonds; Hydroxylamino compounds or ethers or esters thereof
    • C07C239/08—Hydroxylamino compounds or their ethers or esters
    • C07C239/20—Hydroxylamino compounds or their ethers or esters having oxygen atoms of hydroxylamino groups etherified
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/60—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/56—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734—Ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/734—Ethers
    • C07C69/736—Ethers the hydroxy group of the ester being etherified with a hydroxy compound having the hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/34—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/52—Two oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D249/12—Oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/34—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4056—Esters of arylalkanephosphonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

L'invention concerne des alkylesters de l'acide phénylacétique de formule (I), dans laquelle l'indice et les substituants ont les significations suivantes: R' est un formyle, alkylcarbonyle ou alkyle; R'' est un alkyle; U désigne -O-, -S-, -NH- ou -NHO-; V désigne -O-, -S- ou -NH-; X est un cyano, nitro, halogène, alkyle, halogéno-alkyle, alcoxy, halogéno-alcoxy, alkyltio ou, dans le cas où n > 1, un alkylène éventuellement substitué, un alcénylène, oxyalkylène, oxyalkylènoxy, oxyalcénylène, oxyalcénylènoxy ou un butadiènediyle; n = 0, 1, 2 ou 3; R est un halogène, hydroxy, mercapto, amino, carboxyle, carbonylamino ou un radical organique, qui est lié directement, ou par l'intermédiaire d'un groupe oxy, mercapto, amino, carboxyle ou carbonylamino, ou forme, conjointement avec un groupe X et le noyau phényle auquel ces groupes sont liés, un système bicyclique éventuellement substitué, partiellement ou complètement insaturé. L'invention se rapporte également à des procédés et à des produits intermédiaires permettant la fabrication de ces alkylesters, ainsi qu'à leur utilisation.
CA002199422A 1994-09-10 1995-08-30 Alkylesters de l'acide phenylacetiques Abandoned CA2199422A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4432336 1994-09-10
DEP4432336.0 1994-09-10

Publications (1)

Publication Number Publication Date
CA2199422A1 true CA2199422A1 (fr) 1996-03-14

Family

ID=6527949

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002199422A Abandoned CA2199422A1 (fr) 1994-09-10 1995-08-30 Alkylesters de l'acide phenylacetiques

Country Status (8)

Country Link
EP (1) EP0781266A1 (fr)
JP (1) JPH10505596A (fr)
AU (1) AU3387895A (fr)
BR (1) BR9509004A (fr)
CA (1) CA2199422A1 (fr)
IL (1) IL115158A0 (fr)
WO (1) WO1996007633A1 (fr)
ZA (1) ZA957545B (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6255352B1 (en) * 1997-05-28 2001-07-03 Basf Aktiengesellschaft Method for combating harmful fungi
US8293681B2 (en) 2008-09-19 2012-10-23 Sumitomo Chemical Company, Ltd. Seed treatment agent and method for protecting plant
US8871762B2 (en) 2010-03-03 2014-10-28 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8916595B2 (en) 2010-03-03 2014-12-23 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8940717B2 (en) 2010-03-03 2015-01-27 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8940795B2 (en) 2010-03-03 2015-01-27 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8946298B2 (en) 2010-03-03 2015-02-03 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US9107408B2 (en) 2010-03-03 2015-08-18 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US10051860B2 (en) 2010-03-03 2018-08-21 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease

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ES2152396T3 (es) * 1994-04-06 2001-02-01 Shionogi & Co Derivado del acido fenilacetico con sustitucion en gamma, su procedimiento de obtencion y bactericida agricola que lo contiene.
US5849758A (en) * 1995-05-30 1998-12-15 American Cyanamid Company Herbicidal 2, 6-disubstituted pyridines and 2, 4-disubstituted pyrimidines
CN1078202C (zh) * 1995-04-08 2002-01-23 巴斯福股份公司 基本上异构体纯的α－双肟的制备方法
WO1997009302A1 (fr) * 1995-09-08 1997-03-13 Shionogi & Co., Ltd. DERIVES DE L'ACIDE α-ALCOXYPHENYLACETIQUE, INTERMEDIAIRE UTILISE POUR SA PRODUCTION, ET PESTICIDE LE CONTENANT
AU2712097A (en) * 1996-05-13 1997-12-05 Shionogi & Co., Ltd. Alpha-substituted benzyl ether derivatives and pesticides comprising the same as active ingredients
EP2094662B1 (fr) * 2006-12-14 2012-04-11 Astellas Pharma Inc. Composés acide polycyclique utiles comme antagonistes crth2 et agents antiallergiques
BRPI0911134B1 (pt) 2008-03-21 2017-01-17 Sumitomo Chemical Co composição de controle de doenças de plantas, método de controle de doenças de plantas, e uso
CN103641731B (zh) * 2009-02-16 2015-10-28 住友化学株式会社 苯基乙酰胺化合物的制造方法
JP5326891B2 (ja) * 2009-07-14 2013-10-30 住友化学株式会社 シバ病害の防除方法
JP2011201852A (ja) * 2010-03-03 2011-10-13 Sumitomo Chemical Co Ltd 植物病害防除組成物及び植物病害防除方法
JP2011201857A (ja) * 2010-03-03 2011-10-13 Sumitomo Chemical Co Ltd 植物病害防除組成物及び植物病害防除方法
JP2012097063A (ja) * 2010-10-07 2012-05-24 Sumitomo Chemical Co Ltd 植物病害防除組成物及び植物病害防除方法
JP5793896B2 (ja) * 2010-10-07 2015-10-14 住友化学株式会社 植物病害防除組成物及び植物病害防除方法
JP2012102075A (ja) * 2010-10-14 2012-05-31 Sumitomo Chemical Co Ltd 有害生物防除用組成物及び有害生物防除方法
JP2012102076A (ja) * 2010-10-14 2012-05-31 Sumitomo Chemical Co Ltd 有害生物防除用組成物及び有害生物防除方法
JP2012136503A (ja) * 2010-10-14 2012-07-19 Sumitomo Chemical Co Ltd 有害生物防除用組成物及び有害生物防除方法
JP2012102074A (ja) * 2010-10-14 2012-05-31 Sumitomo Chemical Co Ltd 有害生物防除用組成物及び有害生物防除方法
JP2012106984A (ja) * 2010-10-28 2012-06-07 Sumitomo Chemical Co Ltd 有害生物防除用組成物及び有害生物防除方法
JP2012206990A (ja) * 2011-03-30 2012-10-25 Sumitomo Chemical Co Ltd 植物の生長を促進する方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1274127B (de) * 1965-10-26 1968-08-01 Akad Wissenschaften Ddr Verfahren zur Herstellung von ª‡-Alkoxyarylessigsaeurealkylestern

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6255352B1 (en) * 1997-05-28 2001-07-03 Basf Aktiengesellschaft Method for combating harmful fungi
US8293681B2 (en) 2008-09-19 2012-10-23 Sumitomo Chemical Company, Ltd. Seed treatment agent and method for protecting plant
US8871762B2 (en) 2010-03-03 2014-10-28 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8916595B2 (en) 2010-03-03 2014-12-23 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8940717B2 (en) 2010-03-03 2015-01-27 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8940795B2 (en) 2010-03-03 2015-01-27 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US8946298B2 (en) 2010-03-03 2015-02-03 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US9107408B2 (en) 2010-03-03 2015-08-18 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease
US10051860B2 (en) 2010-03-03 2018-08-21 Sumitomo Chemical Company, Limited Plant disease controlling composition and method for controlling plant disease

Also Published As

Publication number Publication date
JPH10505596A (ja) 1998-06-02
AU3387895A (en) 1996-03-27
WO1996007633A1 (fr) 1996-03-14
ZA957545B (en) 1997-03-10
BR9509004A (pt) 1998-06-02
EP0781266A1 (fr) 1997-07-02
IL115158A0 (en) 1995-12-31

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Legal Events

Date Code Title Description
FZDE Discontinued