CA2180308A1 - Method of removing volatile metals from slag using an acid wash - Google Patents

Method of removing volatile metals from slag using an acid wash

Info

Publication number
CA2180308A1
CA2180308A1 CA 2180308 CA2180308A CA2180308A1 CA 2180308 A1 CA2180308 A1 CA 2180308A1 CA 2180308 CA2180308 CA 2180308 CA 2180308 A CA2180308 A CA 2180308A CA 2180308 A1 CA2180308 A1 CA 2180308A1
Authority
CA
Canada
Prior art keywords
volatile
acid
volatile metals
slag
metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA 2180308
Other languages
English (en)
French (fr)
Inventor
John Duckett Winter
John Saunders Stevenson
Jerrold Samuel Kassman
Harry Clarence Wiese
George Neal Richter
Lisa Marie Kocsis
Rinaldo Ibbarola Salveleon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of CA2180308A1 publication Critical patent/CA2180308A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/485Entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/52Ash-removing devices
    • C10J3/526Ash-removing devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845Quench rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • C10K1/028Dust removal by electrostatic precipitation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/102Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids containing free acid
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/20Obtaining zinc otherwise than by distilling
    • C22B19/22Obtaining zinc otherwise than by distilling with leaching with acids
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006Wet processes
    • C22B7/007Wet processes by acid leaching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/02Working-up flue dust
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/18Electrolytic production, recovery or refining of metals by electrolysis of solutions of lead
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1223Heating the gasifier by burners
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1625Integration of gasification processes with another plant or parts within the plant with solids treatment
    • C10J2300/1628Ash post-treatment
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/169Integration of gasification processes with another plant or parts within the plant with water treatments
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1846Partial oxidation, i.e. injection of air or oxygen only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/01Recirculation of gases produced to lower part of fuel bed
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/02Slagging producer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)
  • Electrolytic Production Of Metals (AREA)
CA 2180308 1995-09-26 1996-07-02 Method of removing volatile metals from slag using an acid wash Abandoned CA2180308A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/533,703 US5647876A (en) 1995-09-26 1995-09-26 Method of removing volatile metals from slag using an acid wash
US08/533,703 1995-09-26

Publications (1)

Publication Number Publication Date
CA2180308A1 true CA2180308A1 (en) 1997-03-27

Family

ID=24127097

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2180308 Abandoned CA2180308A1 (en) 1995-09-26 1996-07-02 Method of removing volatile metals from slag using an acid wash

Country Status (10)

Country Link
US (1) US5647876A (enExample)
EP (1) EP0765944B1 (enExample)
JP (1) JP4001399B2 (enExample)
KR (1) KR970015791A (enExample)
CA (1) CA2180308A1 (enExample)
DE (1) DE69606597T2 (enExample)
DK (1) DK0765944T3 (enExample)
ES (1) ES2144702T3 (enExample)
IN (1) IN189415B (enExample)
TW (1) TW419525B (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8142528B2 (en) * 2005-11-30 2012-03-27 General Electric Company Methods and systems of reducing viscosity of gasification system slag
DE102008005704A1 (de) * 2008-01-24 2009-07-30 Uhde Gmbh Verfahren und Anlage zur Entfernung insbesondere bei der Synthesegas-Gewinnung anfallenden Schlacken aus einem Schlackebad-Behälter
US9381446B2 (en) 2012-01-18 2016-07-05 General Electric Company System for deaeration in a flash vessel
KR101405013B1 (ko) * 2012-09-20 2014-06-10 한국전력공사 분류층 가스화 장치
US20150159097A1 (en) * 2013-12-11 2015-06-11 General Electric Company System and method for continuous slag handling with direct cooling
US9464244B2 (en) * 2014-02-26 2016-10-11 General Electric Company System and method for black water removal
CN114350965B (zh) * 2021-11-30 2024-02-23 攀钢集团研究院有限公司 钒渣钙化焙烧熟料提取钒、锰和废水循环利用的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE240366C (enExample) * 1900-01-01
US3971652A (en) * 1972-02-21 1976-07-27 Metallurgical Development Company Ammoniacal extraction of copper from metallic materials
US4057512A (en) * 1975-09-29 1977-11-08 Exxon Research & Engineering Co. Alkali metal catalyst recovery system
DD232250A1 (de) * 1984-07-19 1986-01-22 Leuna Werke Veb Verfahren zur herstellung von kornaktivkohle aus asche der braunkohlenschwelkoksvergasung
US4614543A (en) * 1985-01-31 1986-09-30 Amax Inc. Mixed lixiviant for separate recovery of zinc and lead from iron-containing waste materials
US4705537A (en) * 1985-12-02 1987-11-10 Texaco Inc. Process for separating clarified water from an aqueous dispersion of ash, slag and char particulate matter
IT1262923B (it) * 1992-01-10 1996-07-22 Marco Olper Procedimento per il recupero dello zinco e del piombo dai fumi dell' acciaieria elettrica e per il riciclo al forno degli stessi depurati ed impianto per attuarlo
US5344479A (en) * 1992-03-13 1994-09-06 Sherritt Gordon Limited Upgrading copper sulphide residues containing nickel and arsenic

Also Published As

Publication number Publication date
DE69606597T2 (de) 2000-07-06
TW419525B (en) 2001-01-21
US5647876A (en) 1997-07-15
DK0765944T3 (da) 2000-05-15
EP0765944B1 (en) 2000-02-09
JP4001399B2 (ja) 2007-10-31
DE69606597D1 (de) 2000-03-16
EP0765944A1 (en) 1997-04-02
JPH09125167A (ja) 1997-05-13
ES2144702T3 (es) 2000-06-16
IN189415B (enExample) 2003-02-22
KR970015791A (ko) 1997-04-28

Similar Documents

Publication Publication Date Title
US4668428A (en) Partial oxidation process
US4436531A (en) Synthesis gas from slurries of solid carbonaceous fuels
EP0113469B1 (en) A method for removal of sour water from coal gasification slag
AU2006201144A1 (en) Method and device for producing synthesis gases by partial oxidation of slurries made from fuels containing ash with partial quenching and waste heat recovery
CZ14799A3 (cs) Způsob snížení tvorby depozitů ve formě šupin v odparce na nejmenší míru a izolace solí během zplyňovacího procesu
EP0145806B1 (en) Environmentally safe process for disposing of toxic inorganic cn-containing sludge
EP0290689A1 (en) Partial oxidation process
EP0551155A1 (en) Process for recovering zinc and lead from flue dusts from electrical steel works and for recycling said purified metals to the furnace, and installation for implementing said process
US5647876A (en) Method of removing volatile metals from slag using an acid wash
JP3129711B2 (ja) 石炭のコークス化と、塩素含有樹脂または塩素含有有機化合物、あるいはそれらを含む廃プラスチックの処理を並行して行う方法
US4654164A (en) Partial oxidation process
US4952380A (en) Partial oxidation process
EP0386352B1 (en) Partial oxidation process
Aziz et al. Waste Treatment and Management in Chlor-Alkali Industries
US4826627A (en) Partial oxidation process
US4957544A (en) Partial oxidation process including the concentration of vanadium and nickel in separate slag phases
US4857229A (en) Partial oxidation process of sulfur, nickel, and vanadium-containing fuels
JP4118240B2 (ja) 廃棄物からの鉛の回収方法
US4889658A (en) Partial oxidation process
US4488950A (en) Heavy metal separation from copper-bearing wastes
EP0209261B1 (en) Partial oxidation process
EP0148542B1 (en) Synthesis gas from slurries of solid, carbonaceous fuels
US4788003A (en) Partial oxidation of ash-containing liquid hydrocarbonaceous and solid carbonaceous
Boerrigter et al. Implementation of Thermal Processes for Feedstock Recycling of Bromine, with Energy Recovery, from Plastic Waste of Electrical and Electronic Equipment (WEEE)–Phase 1: Literature survey/status update, evaluation, and ranking of combustion, gasification, and pyrolysis based technologies
CA1255505A (en) Partial oxidation process

Legal Events

Date Code Title Description
FZDE Dead

Effective date: 20060704