CA2167203C - Process for the conditioning of radioactive waste using phosphosilicated apatites as the confinement matrix - Google Patents

Process for the conditioning of radioactive waste using phosphosilicated apatites as the confinement matrix Download PDF

Info

Publication number
CA2167203C
CA2167203C CA002167203A CA2167203A CA2167203C CA 2167203 C CA2167203 C CA 2167203C CA 002167203 A CA002167203 A CA 002167203A CA 2167203 A CA2167203 A CA 2167203A CA 2167203 C CA2167203 C CA 2167203C
Authority
CA
Canada
Prior art keywords
apatite
phosphosilicated
actinides
formula
lanthanides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002167203A
Other languages
English (en)
French (fr)
Other versions
CA2167203A1 (en
Inventor
Joelle Carpena
Jean-Louis Lacout
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat à l'Énergie Atomique et Aux Énergies Alternatives
Original Assignee
Commissariat a lEnergie Atomique CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA filed Critical Commissariat a lEnergie Atomique CEA
Publication of CA2167203A1 publication Critical patent/CA2167203A1/en
Application granted granted Critical
Publication of CA2167203C publication Critical patent/CA2167203C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/30—Processing
    • G21F9/301—Processing by fixation in stable solid media
    • G21F9/302—Processing by fixation in stable solid media in an inorganic matrix
    • G21F9/304—Cement or cement-like matrix
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/28—Treating solids
    • G21F9/34—Disposal of solid waste

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Processing Of Solid Wastes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Oxide Ceramics (AREA)
CA002167203A 1993-07-15 1994-07-12 Process for the conditioning of radioactive waste using phosphosilicated apatites as the confinement matrix Expired - Fee Related CA2167203C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9308676A FR2712726B1 (fr) 1993-07-15 1993-07-15 Procédé de conditionnement de déchets radioactifs utilisant des apatites silicatées comme matrice de confinement.
FR93/08676 1993-07-15
PCT/FR1994/000873 WO1995002886A1 (fr) 1993-07-15 1994-07-12 Procede de conditionnement de dechets radioactifs utilisant des apatites phosphosilicatees comme matrice de confinement

Publications (2)

Publication Number Publication Date
CA2167203A1 CA2167203A1 (en) 1995-01-26
CA2167203C true CA2167203C (en) 2004-06-29

Family

ID=9449257

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002167203A Expired - Fee Related CA2167203C (en) 1993-07-15 1994-07-12 Process for the conditioning of radioactive waste using phosphosilicated apatites as the confinement matrix

Country Status (9)

Country Link
US (1) US5771472A (enExample)
EP (1) EP0708969B1 (enExample)
JP (1) JPH09500212A (enExample)
CA (1) CA2167203C (enExample)
DE (1) DE69405872T2 (enExample)
ES (1) ES2109714T3 (enExample)
FR (1) FR2712726B1 (enExample)
TW (1) TW269042B (enExample)
WO (1) WO1995002886A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2728099B1 (fr) * 1994-12-07 1997-01-10 Commissariat Energie Atomique Procede de conditionnement d'iode radioactif, en particulier d'iode 129, utilisant une apatite comme matrice de confinement
FR2741339B1 (fr) * 1995-11-20 1997-12-12 Commissariat Energie Atomique Procede de fabrication de composes de type monazite dopes ou non en actinides et application au conditionnement des dechets radioactifs riches en actinides et en lanthanides
GB2316940A (en) * 1996-08-30 1998-03-11 Queen Mary & Westfield College Silicon-substituted hydroxyapatite
FR2772651B1 (fr) * 1997-12-23 2000-01-28 Commissariat Energie Atomique Procede de conditionnement de dechets industriels, notamment radioactifs, dans des ceramiques apatitiques
EP1053764A4 (en) * 1998-02-05 2006-11-22 Morishige Fumie THERAPEUTIC INSTRUMENT FOR TREATING OR HEALING PSORIASIS, CONSTITUTIONAL ECZEMA, JOINT RHEUMATISMS AND / OR CANCER OR PREVENTING THE PROGRESSION OF SUCH DISEASES AND METHOD OF USING THE SAME
AU2776299A (en) * 1998-02-18 1999-09-06 Rocky Mountain Remediation Services, L.L.C. Method for treating wastes and preparing construction materials from waste
US6204430B1 (en) * 1998-02-18 2001-03-20 Rocky Mountain Remediation Services Llc Hexametaphosphate as an agent for treating wastes, preparing construction materials and stabilizing soils
US6217775B1 (en) 1998-03-20 2001-04-17 James L. Conca Treatment of metal-contaminated leachates utilizing fish bones and fish hard parts
FR2784091B1 (fr) * 1998-09-11 2000-11-10 Commissariat Energie Atomique Procede pour confiner le plutonium dans des ceramiques apatitiques et produits obtenus par ce procede
FR2786478B1 (fr) * 1998-11-30 2000-12-22 Commissariat Energie Atomique Confinement du cesium et/ou du rubidium dans des ceramiques apatitiques
JP4672962B2 (ja) * 2000-06-12 2011-04-20 ジオマトリクス ソリューションズ，インコーポレイテッド 放射性及び有害廃棄物の処理方法並びに封入廃棄品
IL136685A0 (en) * 2000-06-12 2001-06-14 Gribbitz Arthur Process for treatment of radioactive waste
JP4690347B2 (ja) * 2004-02-23 2011-06-01 ジオマトリクス ソリューションズ，インコーポレイテッド 放射性および有害廃棄物のホウケイ酸ガラス固定化の方法および組成物
US7550645B2 (en) * 2004-02-23 2009-06-23 Geomatrix Solutions, Inc. Process and composition for the immobilization of radioactive and hazardous wastes in borosilicate glass
JP5002002B2 (ja) * 2006-03-20 2012-08-15 ジオマトリックス ソリューションズ インコーポレーテッド 高アルカリ性放射性廃棄物および有害廃棄物をシリケート系ガラスの中に固定化するためのプロセスおよび組成物
GB0900269D0 (en) * 2009-01-08 2009-02-11 Univ Aberdeen Silicate-substituted hydroxyapatite

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5182418A (en) * 1965-06-21 1993-01-26 The United States Of America As Represented By The Secretary Of The Navy Aimable warhead
US3960085A (en) * 1967-05-25 1976-06-01 The United States Of America As Represented By The Secretary Of The Navy Variable geometry warhead
US4026213A (en) * 1971-06-17 1977-05-31 The United States Of America As Represented By The Secretary Of The Navy Selectively aimable warhead
GB1422133A (en) * 1972-08-25 1976-01-21 Plessey Co Ltd Ceramic materials
US3959172A (en) * 1973-09-26 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Process for encapsulating radionuclides
US4028265A (en) * 1974-04-02 1977-06-07 The United States Of America As Represented By The United States Energy Research And Development Administration Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products
US4442028A (en) * 1982-07-08 1984-04-10 The United States Of America As Represented By The United States Department Of Energy Method for incorporating radioactive phosphoric acid solutions in concrete
FR2704052B1 (fr) * 1993-04-14 1995-05-24 Thomson Brandt Armements Charge formée multiamorçable.

Also Published As

Publication number Publication date
EP0708969A1 (fr) 1996-05-01
JPH09500212A (ja) 1997-01-07
DE69405872T2 (de) 1998-04-02
DE69405872D1 (de) 1997-10-30
WO1995002886A1 (fr) 1995-01-26
FR2712726B1 (fr) 1995-12-15
CA2167203A1 (en) 1995-01-26
EP0708969B1 (fr) 1997-09-24
ES2109714T3 (es) 1998-01-16
TW269042B (enExample) 1996-01-21
US5771472A (en) 1998-06-23
FR2712726A1 (fr) 1995-05-24

Similar Documents

Publication Publication Date Title
US5771472A (en) Process for the conditioning of radioactive waste using phosphosilicated apatites as the confinement matrix
Pan et al. Compositions of the apatite-group minerals: substitution mechanisms and controlling factors
US6459010B1 (en) Method for packaging industrial, in particular radioactive, waste in apatite ceramics
RU2446490C2 (ru) Химически связанный керамический радиационно-защитный материал и способ его подготовки
AU2023206234B2 (en) Composition and method for the processing of hazardous sludges and ion exchange media
JPH0452917B2 (enExample)
US6023006A (en) Method of manufacturing compounds of the monazite type, doped or not doped with actinides and application to the packaging of radioactive waste high in actinides and in lanthanides
Jeong et al. Cementing the gap between ceramics, cements, and polymers
Hikichi et al. Thermal reactions of hydrated hexagonal RPO4· nH2O (R= Tb or Dy, n= 0.5 to 1)
Yudintsev A structural-chemical approach to selecting crystalline matrices for actinide immobilization
Fong et al. Development of a glass-encapsulated calcium phosphate wasteform for the immobilization of actinide and halide containing radioactive wastes from the pyrochemical reprocessing of plutonium metal
Carpena et al. Apatitic waste forms: process overview
US6489531B1 (en) Confinement of caesium and/or rubidium in apatitic ceramics
Veilleux et al. Synthesis of new apatite phases by spray pyrolysis and their characterization
Ptáček Rare-earth element-bearing apatites and oxyapatites
Donald et al. A glass-encapsulated ceramic wasteform for the immobilization of chloride-containing ILW: Formation of halite crystals by reaction between the glass encapsulant and ceramic host
Hirose et al. An alternative process to immobilize intermediate wastes from LWR fuel reprocessing
Bamberger Preparation of metal phosphates by metathesis reaction with BPO4
Orlova et al. Anhydrous Lanthanide and Actinide (III) and (IV) Orthophosphates Mem (PO4) n. Synthesis, Crystallization, Structure, and Properties
KR100852383B1 (ko) 실리카 함유 무기물을 이용한 방사성 폐용융염의고화처리방법
Senamaud et al. Synthesis and characterization of Cs-bearing apatites
JP4294222B2 (ja) アパタイト焼結体にプルトニウムを閉じ込める方法及び該方法を用いて得た生成物
Alekseeva et al. Chemical Stability of the CsZr2 (PO4) 3 Phosphate with the Kosnarite Structure in Various Environments
JP3309796B2 (ja) 核燃料再処理廃棄物の処理方法
Stewart et al. Waste form strategies for Mo-rich radioactive waste

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed