CA2163866A1 - Sulfur and mercaptan removal from hydrocarbon streams containing reactive unsaturates - Google Patents
Sulfur and mercaptan removal from hydrocarbon streams containing reactive unsaturatesInfo
- Publication number
- CA2163866A1 CA2163866A1 CA002163866A CA2163866A CA2163866A1 CA 2163866 A1 CA2163866 A1 CA 2163866A1 CA 002163866 A CA002163866 A CA 002163866A CA 2163866 A CA2163866 A CA 2163866A CA 2163866 A1 CA2163866 A1 CA 2163866A1
- Authority
- CA
- Canada
- Prior art keywords
- sulfur
- hydrocarbon streams
- containing reactive
- streams containing
- reactive unsaturates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title abstract 2
- 239000011593 sulfur Substances 0.000 title abstract 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000006384 oligomerization reaction Methods 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Treating Waste Gases (AREA)
Abstract
Sulfur and mercaptans in hydrocarbon streams comprising reactive unsaturates are removed by contacting the hydrocarbon stream at mild temperatures with a hydrogen reduced metal oxide, such as copper, zinc and/or aluminum oxide, without the undesirable byproduct reaction of oligomerization or polymerization of the reactive unsaturates.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6894293A | 1993-05-28 | 1993-05-28 | |
| US068,942 | 1993-05-28 | ||
| PCT/US1994/005994 WO1994028089A1 (en) | 1993-05-28 | 1994-05-27 | Sulfur and mercaptan removal from hydrocarbon streams containing reactive unsaturates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2163866A1 true CA2163866A1 (en) | 1994-12-08 |
| CA2163866C CA2163866C (en) | 2005-03-01 |
Family
ID=22085706
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002163866A Expired - Fee Related CA2163866C (en) | 1993-05-28 | 1994-05-27 | Sulfur and mercaptan removal from hydrocarbon streams containing reactive unsaturates |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0701595B1 (en) |
| JP (1) | JP3637569B2 (en) |
| AU (1) | AU679759B2 (en) |
| CA (1) | CA2163866C (en) |
| DE (1) | DE69426493T2 (en) |
| ES (1) | ES2154678T3 (en) |
| SG (1) | SG49007A1 (en) |
| WO (1) | WO1994028089A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6274533B1 (en) * | 1999-12-14 | 2001-08-14 | Phillips Petroleum Company | Desulfurization process and novel bimetallic sorbent systems for same |
| JP4609961B2 (en) * | 2000-01-28 | 2011-01-12 | Ｊｘ日鉱日石エネルギー株式会社 | Method for removing sulfur compounds |
| DE102013225724A1 (en) * | 2013-12-12 | 2015-06-18 | Evonik Industries Ag | Purification of liquid hydrocarbon streams by means of a copper-containing sorbent |
| SG10201604013RA (en) | 2015-05-28 | 2016-12-29 | Evonik Degussa Gmbh | Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures |
| FR3104459B1 (en) * | 2019-12-17 | 2022-07-01 | Ifp Energies Now | Mass for capturing mercaptans prepared by the molten salt process |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB332910A (en) * | 1929-02-26 | 1930-07-28 | Stadtberger Huette Act Ges | Improvements in or relating to the desulphurisation of liquid hydrocarbons |
| US1904381A (en) * | 1929-11-11 | 1933-04-18 | Universal Oil Prod Co | Refining of hydrocarbon oils |
| GB9116907D0 (en) * | 1991-08-06 | 1991-09-18 | Ici Plc | Sulphur removal process |
-
1994
- 1994-05-27 WO PCT/US1994/005994 patent/WO1994028089A1/en active IP Right Grant
- 1994-05-27 CA CA002163866A patent/CA2163866C/en not_active Expired - Fee Related
- 1994-05-27 SG SG1996005138A patent/SG49007A1/en unknown
- 1994-05-27 DE DE69426493T patent/DE69426493T2/en not_active Expired - Fee Related
- 1994-05-27 JP JP50098295A patent/JP3637569B2/en not_active Expired - Fee Related
- 1994-05-27 EP EP94919268A patent/EP0701595B1/en not_active Expired - Lifetime
- 1994-05-27 AU AU70469/94A patent/AU679759B2/en not_active Ceased
- 1994-05-27 ES ES94919268T patent/ES2154678T3/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08511813A (en) | 1996-12-10 |
| DE69426493D1 (en) | 2001-02-01 |
| EP0701595A1 (en) | 1996-03-20 |
| SG49007A1 (en) | 1998-05-18 |
| DE69426493T2 (en) | 2001-08-09 |
| AU679759B2 (en) | 1997-07-10 |
| ES2154678T3 (en) | 2001-04-16 |
| AU7046994A (en) | 1994-12-20 |
| JP3637569B2 (en) | 2005-04-13 |
| CA2163866C (en) | 2005-03-01 |
| EP0701595B1 (en) | 2000-12-27 |
| WO1994028089A1 (en) | 1994-12-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |