CA2159339C - Improvements relating to soap bars - Google Patents
Improvements relating to soap barsInfo
- Publication number
- CA2159339C CA2159339C CA002159339A CA2159339A CA2159339C CA 2159339 C CA2159339 C CA 2159339C CA 002159339 A CA002159339 A CA 002159339A CA 2159339 A CA2159339 A CA 2159339A CA 2159339 C CA2159339 C CA 2159339C
- Authority
- CA
- Canada
- Prior art keywords
- fatty
- fatty acid
- soap
- mixture
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000344 soap Substances 0.000 title claims abstract description 40
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 48
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 47
- 229930195729 fatty acid Natural products 0.000 claims abstract description 47
- 239000000194 fatty acid Substances 0.000 claims abstract description 47
- -1 isethionate ester Chemical class 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims description 27
- 239000000047 product Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 abstract description 10
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 11
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 5
- 244000060011 Cocos nucifera Species 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011872 intimate mixture Substances 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 241000489477 Chlorogalum Species 0.000 description 2
- 235000007836 Chlorogalum pomeridianum Nutrition 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
- 101100214873 Autographa californica nuclear polyhedrosis virus AC78 gene Proteins 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000014643 Orbignya martiana Nutrition 0.000 description 1
- 244000021150 Orbignya martiana Species 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940079840 cocoyl isethionate Drugs 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid ester group Chemical group C(CCCCCCCCCCC)(=O)O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940045998 sodium isethionate Drugs 0.000 description 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Warehouses Or Storage Devices (AREA)
- Refuse Collection And Transfer (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB939310323A GB9310323D0 (en) | 1993-05-19 | 1993-05-19 | Improvements relating to soap bars |
| GB9310323.2 | 1993-05-19 | ||
| PCT/EP1994/001441 WO1994026866A1 (en) | 1993-05-19 | 1994-04-28 | Improvememts relating to soap bars |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2159339A1 CA2159339A1 (en) | 1994-11-24 |
| CA2159339C true CA2159339C (en) | 1999-07-06 |
Family
ID=10735766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002159339A Expired - Fee Related CA2159339C (en) | 1993-05-19 | 1994-04-28 | Improvements relating to soap bars |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US5482643A (en, 2012) |
| EP (1) | EP0699234B1 (en, 2012) |
| JP (1) | JP2693866B2 (en, 2012) |
| CN (1) | CN1049452C (en, 2012) |
| AU (1) | AU696884B2 (en, 2012) |
| BR (1) | BR9406409A (en, 2012) |
| CA (1) | CA2159339C (en, 2012) |
| CZ (1) | CZ283490B6 (en, 2012) |
| DE (1) | DE69404303T2 (en, 2012) |
| ES (1) | ES2104387T3 (en, 2012) |
| GB (1) | GB9310323D0 (en, 2012) |
| HU (1) | HU217533B (en, 2012) |
| IN (1) | IN181474B (en, 2012) |
| MY (1) | MY131639A (en, 2012) |
| PH (1) | PH31157A (en, 2012) |
| PL (1) | PL178450B1 (en, 2012) |
| SK (1) | SK127695A3 (en, 2012) |
| WO (1) | WO1994026866A1 (en, 2012) |
| ZA (1) | ZA943213B (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19620748A1 (de) * | 1996-05-23 | 1997-11-27 | Hoechst Ag | Tensidmischungen aus Acyloxialkansulfonaten und Fettsäureester |
| DE19620792A1 (de) * | 1996-05-23 | 1997-11-27 | Zschimmer & Schwarz Gmbh & Co | Herstellung und Verwendung gut verarbeitbarer Komponenten für halbsynthetische Toiletteseifen |
| US5965508A (en) * | 1997-10-21 | 1999-10-12 | Stepan Company | Soap bar compositions comprising alpha sulfonated fatty acid alkyl esters and long chain fatty acids |
| US5981451A (en) * | 1998-09-23 | 1999-11-09 | Lever Brothers Company | Non-molten-mix process for making bar comprising acyl isethionate based solids, soap and optional filler |
| JP4452187B2 (ja) * | 2003-05-07 | 2010-04-21 | イーファック・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コンパニー・コマンディートゲゼルシャフト | フレグランスおよびアロマの目標とする放出のための組成 |
| JP2014513076A (ja) | 2011-04-04 | 2014-05-29 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア物品 |
| MX355294B (es) | 2011-08-15 | 2018-04-12 | Procter & Gamble | Artículos para el cuidado personal que tienen composiciones para el cuidado personal que tienen múltiples zonas amoldables. |
| MX2014001896A (es) | 2011-08-15 | 2014-05-27 | Procter & Gamble | Metodos para el cuidado personal. |
| MX355739B (es) | 2013-06-27 | 2018-04-26 | Procter & Gamble | Composiciones y articulos para el cuidado personal. |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2894912A (en) * | 1954-09-21 | 1959-07-14 | Lever Brothers Ltd | Isethionate detergent bar |
| US3376229A (en) * | 1964-12-11 | 1968-04-02 | Lever Brothers Ltd | Synthetic detergent bar |
| GB1294754A (en) * | 1969-12-01 | 1972-11-01 | Unilever Ltd | Synthetic detergent toilet bars |
| GB1381773A (en) * | 1972-05-31 | 1975-01-29 | Unilever Ltd | Detergent bar |
| US3951842A (en) * | 1973-04-02 | 1976-04-20 | Lever Brothers Company | Synthetic detergent bar with antimushing agent |
| US4234464A (en) * | 1979-04-09 | 1980-11-18 | Gaf Corporation | Detergent bar composition and binder therefor |
| US4536338A (en) * | 1983-11-09 | 1985-08-20 | Lever Brothers Company | Process for manufacture of fatty acid esters of hydroxy sulfonates |
| GB8425369D0 (en) * | 1984-10-08 | 1984-11-14 | Unilever Plc | Refining triglyceride oil |
| GB8614462D0 (en) * | 1986-06-13 | 1986-07-16 | Unilever Plc | Cleaning composition |
| GB8708829D0 (en) * | 1987-04-13 | 1987-05-20 | Unilever Plc | Cleaning compositions |
| US5132037A (en) * | 1989-05-05 | 1992-07-21 | Lever Brothers Company, Division Of Conopco, Inc. | Aqueous based personal washing cleanser |
| GB8928902D0 (en) * | 1989-12-21 | 1990-02-28 | Unilever Plc | Detergent bar |
| CA2048408C (en) * | 1990-08-07 | 1996-01-02 | Jeanette Frances Ashley | Acyl isethionate skin cleansing compositions containing selected betaines |
| US5294363A (en) * | 1991-09-23 | 1994-03-15 | The Procter & Gamble Company | Mild personal cleansing bar composition with balanced surfactants, fatty acids, and paraffin wax |
| CA2080154C (en) * | 1991-10-14 | 1999-04-06 | John G. Chambers | Toilet soap bars |
| US5284598A (en) * | 1991-12-04 | 1994-02-08 | Colgate-Palmolive Company | Process for making mild, detergent-soap, toilet bars and the bar resulting therefrom |
-
1993
- 1993-05-19 GB GB939310323A patent/GB9310323D0/en active Pending
-
1994
- 1994-04-28 ES ES94915151T patent/ES2104387T3/es not_active Expired - Lifetime
- 1994-04-28 AU AU66506/94A patent/AU696884B2/en not_active Ceased
- 1994-04-28 CZ CZ953033A patent/CZ283490B6/cs not_active IP Right Cessation
- 1994-04-28 DE DE69404303T patent/DE69404303T2/de not_active Expired - Fee Related
- 1994-04-28 BR BR9406409A patent/BR9406409A/pt not_active IP Right Cessation
- 1994-04-28 CA CA002159339A patent/CA2159339C/en not_active Expired - Fee Related
- 1994-04-28 CN CN94192145A patent/CN1049452C/zh not_active Expired - Fee Related
- 1994-04-28 EP EP94915151A patent/EP0699234B1/en not_active Expired - Lifetime
- 1994-04-28 WO PCT/EP1994/001441 patent/WO1994026866A1/en active IP Right Grant
- 1994-04-28 HU HU9501987A patent/HU217533B/hu not_active IP Right Cessation
- 1994-04-28 PL PL94311672A patent/PL178450B1/pl unknown
- 1994-04-28 SK SK1276-95A patent/SK127695A3/sk unknown
- 1994-04-28 JP JP6524910A patent/JP2693866B2/ja not_active Expired - Lifetime
- 1994-05-09 ZA ZA943213A patent/ZA943213B/xx unknown
- 1994-05-12 PH PH48260A patent/PH31157A/en unknown
- 1994-05-13 IN IN214BO1994 patent/IN181474B/en unknown
- 1994-05-17 MY MYPI94001236A patent/MY131639A/en unknown
- 1994-05-18 US US08/246,047 patent/US5482643A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0699234A1 (en) | 1996-03-06 |
| HU217533B (hu) | 2000-02-28 |
| BR9406409A (pt) | 1995-12-19 |
| MY131639A (en) | 2007-08-30 |
| US5482643A (en) | 1996-01-09 |
| EP0699234B1 (en) | 1997-07-16 |
| PL311672A1 (en) | 1996-03-04 |
| SK127695A3 (en) | 1996-04-03 |
| GB9310323D0 (en) | 1993-06-30 |
| CN1049452C (zh) | 2000-02-16 |
| JPH08510280A (ja) | 1996-10-29 |
| CA2159339A1 (en) | 1994-11-24 |
| HUT72731A (en) | 1996-05-28 |
| CN1123559A (zh) | 1996-05-29 |
| WO1994026866A1 (en) | 1994-11-24 |
| DE69404303T2 (de) | 1997-11-13 |
| IN181474B (en, 2012) | 1998-06-20 |
| AU6650694A (en) | 1994-12-12 |
| PL178450B1 (pl) | 2000-05-31 |
| ES2104387T3 (es) | 1997-10-01 |
| JP2693866B2 (ja) | 1997-12-24 |
| CZ303395A3 (en) | 1996-03-13 |
| CZ283490B6 (cs) | 1998-04-15 |
| AU696884B2 (en) | 1998-09-24 |
| ZA943213B (en) | 1995-11-09 |
| HU9501987D0 (en) | 1995-09-28 |
| PH31157A (en) | 1998-03-20 |
| DE69404303D1 (de) | 1997-08-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |