CA2124601C - Hydrogen fractionation by adsorbent membranes - Google Patents
Hydrogen fractionation by adsorbent membranesInfo
- Publication number
- CA2124601C CA2124601C CA002124601A CA2124601A CA2124601C CA 2124601 C CA2124601 C CA 2124601C CA 002124601 A CA002124601 A CA 002124601A CA 2124601 A CA2124601 A CA 2124601A CA 2124601 C CA2124601 C CA 2124601C
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- stream
- permeate
- components
- secondary components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 197
- 239000003463 adsorbent Substances 0.000 title claims abstract description 66
- 239000001257 hydrogen Substances 0.000 title claims description 31
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 25
- 238000005194 fractionation Methods 0.000 title description 9
- 239000012466 permeate Substances 0.000 claims abstract description 88
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 239000000047 product Substances 0.000 claims abstract description 58
- 238000000034 method Methods 0.000 claims abstract description 53
- 239000000463 material Substances 0.000 claims abstract description 27
- 238000001179 sorption measurement Methods 0.000 claims abstract description 26
- 239000007789 gas Substances 0.000 claims description 72
- 229930195733 hydrocarbon Natural products 0.000 claims description 33
- 150000002430 hydrocarbons Chemical class 0.000 claims description 33
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 238000009792 diffusion process Methods 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 6
- 239000001307 helium Substances 0.000 claims description 6
- 229910052734 helium Inorganic materials 0.000 claims description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 230000000274 adsorptive effect Effects 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 32
- 238000011084 recovery Methods 0.000 abstract description 27
- 230000001965 increasing effect Effects 0.000 abstract description 5
- 230000010354 integration Effects 0.000 abstract 1
- 239000000306 component Substances 0.000 description 113
- 230000008569 process Effects 0.000 description 22
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
- 239000004215 Carbon black (E152) Substances 0.000 description 15
- 238000005057 refrigeration Methods 0.000 description 13
- 239000000758 substrate Substances 0.000 description 12
- 239000001273 butane Substances 0.000 description 10
- 230000006835 compression Effects 0.000 description 10
- 238000007906 compression Methods 0.000 description 10
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 9
- 230000035699 permeability Effects 0.000 description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- 239000001294 propane Substances 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000012263 liquid product Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- NPSSWQJHYLDCNV-UHFFFAOYSA-N prop-2-enoic acid;hydrochloride Chemical compound Cl.OC(=O)C=C NPSSWQJHYLDCNV-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005373 porous glass Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/225—Multiple stage diffusion
- B01D53/226—Multiple stage diffusion in serial connexion
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Separation Of Gases By Adsorption (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/098,654 US5332424A (en) | 1993-07-28 | 1993-07-28 | Hydrocarbon fractionation by adsorbent membranes |
| US08/098654 | 1993-07-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2124601A1 CA2124601A1 (en) | 1995-01-29 |
| CA2124601C true CA2124601C (en) | 1999-12-28 |
Family
ID=22270331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002124601A Expired - Fee Related CA2124601C (en) | 1993-07-28 | 1994-05-26 | Hydrogen fractionation by adsorbent membranes |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5332424A (en:Method) |
| EP (1) | EP0636400B1 (en:Method) |
| AU (1) | AU658095B2 (en:Method) |
| CA (1) | CA2124601C (en:Method) |
| DE (1) | DE69413472T2 (en:Method) |
| MY (1) | MY130050A (en:Method) |
| TW (1) | TW264403B (en:Method) |
Families Citing this family (89)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5507856A (en) * | 1989-11-14 | 1996-04-16 | Air Products And Chemicals, Inc. | Hydrogen recovery by adsorbent membranes |
| US5558698A (en) * | 1993-10-25 | 1996-09-24 | Membrane Technology And Research, Inc. | Acid gas fractionation process |
| US5407467A (en) * | 1993-10-25 | 1995-04-18 | Membrane Technology And Research, Inc. | Sour gas treatment process |
| US5407466A (en) * | 1993-10-25 | 1995-04-18 | Membrane Technology And Research, Inc. | Sour gas treatment process including membrane and non-membrane treatment steps |
| US5556449A (en) * | 1993-10-25 | 1996-09-17 | Membrane Technology And Research, Inc. | Acid gas fractionation process for fossil fuel gasifiers |
| US5401300A (en) * | 1993-10-25 | 1995-03-28 | Membrane Technology And Research, Inc. | Sour gas treatment process including dehydration of the gas stream |
| US5435836A (en) * | 1993-12-23 | 1995-07-25 | Air Products And Chemicals, Inc. | Hydrogen recovery by adsorbent membranes |
| US5912048A (en) * | 1994-08-25 | 1999-06-15 | Air Products And Chemicals, Inc. | Passivation carbonaceous adsorptive membranes |
| AU690723B2 (en) * | 1994-09-14 | 1998-04-30 | Bend Research, Inc. | Organic and inorganic vapor permeation by countercurrent condensable sweep |
| US5792239A (en) * | 1994-10-21 | 1998-08-11 | Nitrotec Corporation | Separation of gases by pressure swing adsorption |
| US5632803A (en) * | 1994-10-21 | 1997-05-27 | Nitrotec Corporation | Enhanced helium recovery |
| US5707425A (en) * | 1994-10-21 | 1998-01-13 | Nitrotec Corporation | Helium recovery from higher helium content streams |
| US5557030A (en) * | 1995-03-23 | 1996-09-17 | Uop | Process for rejecting heavy hydrocarbons from light hydrocarbons gases |
| US5841021A (en) * | 1995-09-05 | 1998-11-24 | De Castro; Emory S. | Solid state gas sensor and filter assembly |
| AU714275B2 (en) * | 1996-01-25 | 1999-12-23 | Exxon Research And Engineering Company | Separation process in which a membrane is used |
| US5647227A (en) * | 1996-02-29 | 1997-07-15 | Membrane Technology And Research, Inc. | Membrane-augmented cryogenic methane/nitrogen separation |
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| US5753011A (en) * | 1997-01-17 | 1998-05-19 | Air Products And Chemicals, Inc. | Operation of staged adsorbent membranes |
| US5769926A (en) * | 1997-01-24 | 1998-06-23 | Membrane Technology And Research, Inc. | Membrane separation of associated gas |
| US6159272A (en) * | 1997-01-24 | 2000-12-12 | Membrane Technology And Research, Inc. | Hydrogen recovery process |
| US5861049A (en) * | 1997-01-24 | 1999-01-19 | Membrane Technology And Research, Inc. | Chlorine separation process combining condensation, membrane separation and flash evaporation |
| US5772733A (en) * | 1997-01-24 | 1998-06-30 | Membrane Technology And Research, Inc. | Natural gas liquids (NGL) stabilization process |
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| US6117210A (en) * | 1997-04-29 | 2000-09-12 | Praxair Technology, Inc. | Solid electrolyte systems for producing controlled purity oxygen |
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| US5928409A (en) * | 1997-11-12 | 1999-07-27 | New Jersey Institute Of Technology | Method and apparatus for gas removal by cyclic flow swing membrane permeation |
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| US6085549A (en) * | 1998-04-08 | 2000-07-11 | Messer Griesheim Industries, Inc. | Membrane process for producing carbon dioxide |
| US6187077B1 (en) * | 1998-04-17 | 2001-02-13 | American Air Liquide Inc. | Separation of CF4 and C2F6 from a perfluorocompound mixture |
| US6065306A (en) * | 1998-05-19 | 2000-05-23 | The Boc Group, Inc. | Method and apparatus for purifying ammonia |
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| DE10007440A1 (de) * | 2000-02-18 | 2001-08-23 | Linde Ag | Verfahren zum Abtrennen einer Helium-reichen Fraktion aus einem wenigstens Methan, Stickstoff und Helium enthaltenden Strom |
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| US7252702B2 (en) * | 2003-07-25 | 2007-08-07 | Saudi Arabian Oil Company | Hydrogen purification optimization system |
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| US20060213757A1 (en) * | 2005-03-23 | 2006-09-28 | The Regents Of The University Of California | Porous membrane materials as structured packing for distillation |
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| US7938893B2 (en) * | 2006-04-18 | 2011-05-10 | Gas Technology Institute | Membrane reactor for H2S, CO2 and H2 separation |
| KR100711237B1 (ko) | 2006-06-09 | 2007-04-25 | 한국에너지기술연구원 | 흡착제가 충진된 분리막 및 이를 이용한 이산화탄소 분리방법 |
| US7811359B2 (en) * | 2007-01-18 | 2010-10-12 | General Electric Company | Composite membrane for separation of carbon dioxide |
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| AU2009203714B2 (en) * | 2008-01-08 | 2011-11-17 | Shell Internationale Research Maatschappij B.V. | Multi - stage membrane separation process |
| RU2489197C2 (ru) * | 2008-05-12 | 2013-08-10 | Мембране Текнолоджи Энд Ресерч, Инк. | Способ разделения газов с применением мембран с продувкой пермеата для удаления co2 из продуктов сжигания |
| US8495882B2 (en) * | 2009-08-10 | 2013-07-30 | General Electric Company | Syngas cleanup section with carbon capture and hydrogen-selective membrane |
| US20110283737A1 (en) * | 2010-05-20 | 2011-11-24 | Siemens Medical Solutions Usa, Inc. | Process for separating gases at cryogenic temperatures |
| US8388732B2 (en) * | 2010-06-25 | 2013-03-05 | Uop Llc | Integrated membrane and adsorption system for carbon dioxide removal from natural gas |
| JP2014502212A (ja) * | 2010-11-18 | 2014-01-30 | クローズド・ジョイント・ストック・カンパニー・“グラシス” | 高圧の炭化水素ガス混合物の精製方法およびその実施のための装置 |
| US8568512B2 (en) | 2011-04-29 | 2013-10-29 | A.R.C. Technologies Corporation | Method and system for methane separation and purification from a biogas |
| US8882886B2 (en) * | 2012-10-31 | 2014-11-11 | The Boeing Company | Aircraft fuel tank flammability reduction methods and systems and air separation methods using membranes |
| EP2961684A2 (en) * | 2013-02-28 | 2016-01-06 | Air Products and Chemicals, Inc. | Process and apparatus for producing oxygen and nitrogen using ion transport membranes |
| EP3114193B1 (en) * | 2014-03-07 | 2021-02-24 | Watt Fuel Cell Corp. | Active filtration systems and methods for hydrocarbon fuels |
| US9387430B2 (en) | 2014-11-19 | 2016-07-12 | Apache Corporation | Methods and systems of enhanced carbon dioxide recovery |
| CN106979665B (zh) * | 2017-04-13 | 2023-03-24 | 成都赛普瑞兴科技有限公司 | 一种提纯合成气的方法及其设备 |
| US20220205717A1 (en) * | 2020-12-31 | 2022-06-30 | Saudi Arabian Oil Company | Recovery of noncondensable gas components from a gaseous mixture |
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| DE3315930A1 (de) * | 1982-07-29 | 1984-03-01 | Linde Ag, 6200 Wiesbaden | Verfahren und vorrichtung zur zerlegung eines gasgemisches |
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-
1993
- 1993-07-28 US US08/098,654 patent/US5332424A/en not_active Expired - Lifetime
-
1994
- 1994-05-24 TW TW083104679A patent/TW264403B/zh active
- 1994-05-26 CA CA002124601A patent/CA2124601C/en not_active Expired - Fee Related
- 1994-06-02 MY MYPI94001395A patent/MY130050A/en unknown
- 1994-06-02 AU AU64511/94A patent/AU658095B2/en not_active Ceased
- 1994-06-07 DE DE69413472T patent/DE69413472T2/de not_active Expired - Fee Related
- 1994-06-07 EP EP94108718A patent/EP0636400B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| TW264403B (en:Method) | 1995-12-01 |
| EP0636400B1 (en) | 1998-09-23 |
| AU6451194A (en) | 1995-02-16 |
| US5332424A (en) | 1994-07-26 |
| CA2124601A1 (en) | 1995-01-29 |
| DE69413472D1 (de) | 1998-10-29 |
| EP0636400A1 (en) | 1995-02-01 |
| AU658095B2 (en) | 1995-03-30 |
| DE69413472T2 (de) | 1999-02-18 |
| MY130050A (en) | 2007-05-31 |
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| EEER | Examination request | ||
| MKLA | Lapsed | ||
| MKLA | Lapsed |
Effective date: 20090526 |