CA2028512A1 - Hard-surface cleaning compositions - Google Patents
Hard-surface cleaning compositionsInfo
- Publication number
- CA2028512A1 CA2028512A1 CA 2028512 CA2028512A CA2028512A1 CA 2028512 A1 CA2028512 A1 CA 2028512A1 CA 2028512 CA2028512 CA 2028512 CA 2028512 A CA2028512 A CA 2028512A CA 2028512 A1 CA2028512 A1 CA 2028512A1
- Authority
- CA
- Canada
- Prior art keywords
- surface cleaning
- hard surface
- compositions
- composition
- cleaning composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Abstract Liquid hard surface cleaning composition as described which comprises anionic surfactant ammonium salts, ethanol, n-butoxypropanol and a primary or secondary alcohol having a C5 alkyl branched or linear.
The composition which may also comprise ammonium and n-propoxypropanol are especially suitable for use as a spray composition.
The composition which may also comprise ammonium and n-propoxypropanol are especially suitable for use as a spray composition.
Description
2 ~ 3 l ~ C~
HARD~SURFACE CLE~NING COMPOSITIONS
I. Co~N
J. DE WAELE.
M. EVERS
A. KOENIG
Technical field m e invention rela~es to a hard surface cleaning composition which provides at the same time good cleaning performance and good shine. The compositions of ~he invention are especially suitable ~or use as a spray cleaning composition.
~q~
Hard surface cleaning compositions are well known in ~he art and their cleaning performances have been well improved over the years. ~hile focusing on cleaning performances, a ne~ pro~lem has been encountered in that good shine results were not obtained with these compositions, unles~ the surface which had been cleaned had also been rinsed afterwards, i.e., that good shine per~ormance was incompatible wi~h good cleaning per~ormance, in a non rinse-~ype hard surfac~ clean~r~ Indeed, when used, most :.' . , ' .
.
, . . , - , , ~ . . .
compositions leave str~aking traces and/or a residual film on the cleaned surfaces which, as a consequence, do not have a good appearance.
Such problem is particularly a nuisance when the hard surface cleaner is used to clean windows or mirrors, because the residual film i5 even more apparent.
As far as windows are concerned, compositions have be~n formulated which yield "volatile" cleaners, which deal efficiently with this problem; such composi~ions, however, may not be used to clean all surfaces because they often contain solvents which tend to dissolve some materials.
Additio~ally, these compositions have other negatives such as inflam~ability and noxious odor.
US Patent 3,591,510 discloses hard surface cleaners which contain surfactants possibly in the form of their ammonium salt, a solvent mi~ture, and a water soluble builder.
US Patent 3,591,509 discloses compositions containing surfactants possibly present in the form of their ammonium salt, a solvent mixture, a water soluble builder and a water soluble carboxymethylcellulose.
British Patent 2160 887 discloses a composition containing an anionic surfactant, water soluble and water insoluble alcohols and an organic solvent.
Japanese Patent Publication 6203499~ discloses compositions containing an anionic surfactant salt, a water soluble solvent, sodium or potassium hydroxide, and monoethanolamine.
~ ' - - . . .-, - . :: : . . .:
.: :. - . - ~ :. . . .. .
- . . . . . .
: - ~ , ,, : ., :
HARD~SURFACE CLE~NING COMPOSITIONS
I. Co~N
J. DE WAELE.
M. EVERS
A. KOENIG
Technical field m e invention rela~es to a hard surface cleaning composition which provides at the same time good cleaning performance and good shine. The compositions of ~he invention are especially suitable ~or use as a spray cleaning composition.
~q~
Hard surface cleaning compositions are well known in ~he art and their cleaning performances have been well improved over the years. ~hile focusing on cleaning performances, a ne~ pro~lem has been encountered in that good shine results were not obtained with these compositions, unles~ the surface which had been cleaned had also been rinsed afterwards, i.e., that good shine per~ormance was incompatible wi~h good cleaning per~ormance, in a non rinse-~ype hard surfac~ clean~r~ Indeed, when used, most :.' . , ' .
.
, . . , - , , ~ . . .
compositions leave str~aking traces and/or a residual film on the cleaned surfaces which, as a consequence, do not have a good appearance.
Such problem is particularly a nuisance when the hard surface cleaner is used to clean windows or mirrors, because the residual film i5 even more apparent.
As far as windows are concerned, compositions have be~n formulated which yield "volatile" cleaners, which deal efficiently with this problem; such composi~ions, however, may not be used to clean all surfaces because they often contain solvents which tend to dissolve some materials.
Additio~ally, these compositions have other negatives such as inflam~ability and noxious odor.
US Patent 3,591,510 discloses hard surface cleaners which contain surfactants possibly in the form of their ammonium salt, a solvent mi~ture, and a water soluble builder.
US Patent 3,591,509 discloses compositions containing surfactants possibly present in the form of their ammonium salt, a solvent mixture, a water soluble builder and a water soluble carboxymethylcellulose.
British Patent 2160 887 discloses a composition containing an anionic surfactant, water soluble and water insoluble alcohols and an organic solvent.
Japanese Patent Publication 6203499~ discloses compositions containing an anionic surfactant salt, a water soluble solvent, sodium or potassium hydroxide, and monoethanolamine.
~ ' - - . . .-, - . :: : . . .:
.: :. - . - ~ :. . . .. .
- . . . . . .
: - ~ , ,, : ., :
Japanese :Patent Publication 58101198 discloses compositions containing alkanolamine, a mixture of anionic and nonionic surfactant and polypropylene glycol.
It is an object of the present invention to provide liquid, hard surface cleaning compositions which have good cleaning performance as well as good shine performance, i.e. which are suitable on a non-rinse use.
It is another object of the present invention to provide liquid, hard surface cleaning compositions which can be used on all surfaces, and which are especially efficient on glass.
It is still another object of the invention to provide a hard surface cleaner which is suitable for use with any dispensing means, especially with a spray dispenser.
Other objects and advantages of the present invention will appear from the following description.
I
Summarv of the invention The invention provides hard surface cleaning compositions which have a pH of in the range of from 6 to 11 and which comprise - from 0.04% to 0.6% by weight of the total composition of anionic surfactants ammonium salts, , .- . ~ .
. . ..
.. ~' , - ' . ~
., - . . . .
~ ' . : ' ' :
- : , ' , . .
- : . .~...... . , .:
~,. "
:
S~ 3 ~3 ~J, ~
- from o% to 0.5% by weight of the total composition of aTmnonia, - from 1% to 9% by weight of the total compositiort of ethanol, - from 0.5~ to 3~ by weight of ~he total composition of n-butoxypropanol, - from 0~ to 3~ by weight of the total composition of n-propoxypropanol, - from 0.5~ to 3% of a primary or secondary monoalcohol having a C5 unsubstituted alkyl branched OTt linear chain, or mixtures thereof.
~te compositions are substantially free of monoe~hanolamine, diethanolamine, triethanolamine or mixtures ~tereof.
Detailed description of the invention The compositions of ~te invention contain anionic surfactants ammonium salts, at a level ranging from 0.04%
to 0.6%, preferably from 0.07% to 0.45% by weight of the total composition.
The anionic surfactants for use herein include alkyl benzene sulfonates or sulfates, paraffin sulfonates, olefin sulfonates, sulfonates of fatty acids and of fatty acid esters and the like whtch are well known in the detergency art.` Also suitable are e~toxylated species such as alkyl polyethoxy sulfates and sulfosuccinates.
Preferred surfactants for use herein are C8-C18 alkyl benzene sulfonates and C8-C18 alkyl polye~toxy sulfates.
Most preferred for the working of the invention, is a mixture of C8-C18 linear alkyl benzene sulphonate and a 3 times ethoxylated C8~C18 alkyl sul~ate.
- .. . . .
.. ..
.
: :
.
2 ~ ?~
All anionic surfactants are present in the composition in tha form of their ammonium salts.
The compositions of the invention also further contain a specific solvent mixture which consists of ~rom 1% to 9%
by weight of the total composition, preferably from 8% to 9%, o~ ethanol, from 0.5% to 3% by weight of the kotal composition, pre~erably from 1.5% to 2%, of n-butoxypropanol, and from 0.5% to 3% by weight of the total composition, preferably from 1.5% to 2%, of a primary or secondary monoalcohol having a C5 alkyl unsubstituted linear or branched chain, or mixt~lres thereof.
This definition comprises l-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, neopentyl alcohol, 3-methyl-2-butanol, and isoamyl alcohol.
Preferably, this alcohol is selected from 2-pentanol, n-pentanol, and isoamylalcohol. Highly preferred for use in the present compositions is 2-pentanol.
Importantly, the tertiary alcohol according to this formula (tertiary amyl alcohol) is not suitable for use in the compositions of the invention.
m e solvent system of the present invention may additionally comprise n-propoxypropanol, up to 3~ by weight of the total composition.
The composition o~ the invention preferably contains ammonia, in amounts up to 0.5% by weight of the total composition.
Depending on presence of ammonia, the compositions of the invention have a pH which is in the range of ~rom 9 to 11 :. . : , : .
.
. - . . . ~ .
- . , .. : .. . . .
- . . . . : .. ,: , ~ , (if the composition contains ammonia), or in the range of from 6 to 9 (if the compositions are free of ammonia).
The compositions of the invention are substantially free of monoethanolamine, diethanolamine, triethanolamine and mixtures thereof.
The compositions of the invention may additionally contain very low amounts, specifically ~elow 0.2%, of builders such as nitrilotriacetates, polycarboxylates, nitrates, water soluble phosphates, silicates, ethylene diamine tetraacetate (EDTA), amino polyphosphonates, phospates and mixtures thereof.
The compositions of the invention are obtained by mixing all the ingredients together; the hard surface clean rs thus obtained are suitable for use in any dispensing means currently used in this technological field, but preferably, they will be used as spray cleaners.
These compositions are suitable for use on all surfaces, especially on windows or any glass material.
The composition of the invention may contain optionals at conventional lavels; such optionals include perfumes, dyes, optical brighteners, thickeners, soil suspending agents, enzymes, freeze thaw, bactericides and preservatives.
ExamPle 1 The following composition according to the invention is prepared ~y mixing all ingredients (percentages are by weight of total composition) 0.15% Linear alkyl benzene sulfonate ammonium salt . .
.
. , , ' ', ' '.' ~
.
.
.
1.5% n~butoxy propanol 1% ethanol 1.5~ 2-pentanol O.1% ammonia up to 100% water and miscellaneous the compositions of the invention have a p~ of 10 m is composition was compared to a reference compositions of the following formula, as a representative of the prior art:
0.15% Linear alkyl benzen~ sulfonate ammonium salt 9% e~hanol 1.5% n-butoxy propanol 0.75~ n-propoxy propanol up to 100% water and minors m es~ two compositions wsre compared for their shine performance ~on mirrors) as well as ~or their cleaning performance.
The cleaning performance was evaluated on synthetic soils as described in the following :
KD soil : is compose~ of 2S% HS ~ soil with carbon black (2), 37.5~ CriscoR (1) oil, 37,5% PuritanR (1) oil.
This soil is rolled onto stainless steel plates (beforehand cleaned with a detergent and then wi~h alcohal) using a paint roller. A very thin uniform layer is needed since the soil is difficult to cure. The plates are placed in the oven at 115~C ~"soft soil") or 170C
("hard soil") ~or 2 h~urs ~nd then allowed to age at least 1 dayO
~1) commercial cooking oil sold by The Procter ~ Gamble Company (2) commercial soil sold by Chem Pack Xnc., U.S.A.
: ~ ' . ~ ' .
- . . ~ .
' " ,, ' ., , ~ ~ ~ 'S'~
The test conditions were as follows :
All tests were run with the aid of an Erichsen washability machine. A sponge of approximately 9,5 x 5 x ~ cm was used after being carefully washed under hot running water and squeezed through drying rolls. 5g. of the undiluted cleanser to ~e tested on spread cver one side of the sponge. ~he number of strokes of the cleaning machine needed to clean the plates were coun~ed.
The cleaning performance testing r~sults are the following :
¦ Hard ¦ Soft ¦
I soil I soil I t# strokes) - I
Reference ¦ 110 ¦ 34 Invention ¦ 30 ¦ 2 m e shine performance was evaluated on mirrors; using ths compositions either in "sp-;ay mcde", or in "~oam-mode"; the spray mode refers to the use of a conventional spray dispenser, wherea~ the foam mode refers to the use of a spra~
dispenser equipped with a sieve, i.e. a foaming de~ice.
The composition on the mirror is then wiped, using three different cloths :
Xitchen = dry cotton towel Cif Ballerina R twet cloth), commercially available Domex R paper towel, commercially available .. : . ,.
.
me degree of filming/streaking ic visually evaluated by 3 judges working independently using a 0-4 scale, whereby 0 = no difference and 4 = great difference.
The results are :
PSU Grades ¦ Spray ¦ Foam I
Xitchen ¦ + 0,25 ¦ 0 1- . I I
Cif Ballerina ¦ + 0,08 ¦ + 0,41 - I I I
Domex I O ¦ + 1,17 The above results show that the composition of the invention exhibit outstanding cleaning performance, and at least as good shine results as ~he reference compositions.
.
.: ~
2 ~
. -- 10 --Examples no. 2 no. 3 no. 4 no. 5 % by weight of the total composition NH4 Linear alkyl 0.1 0.2 0.15 0.2 ~en2ene sulphonate Ammonia 0.2 0.1 0 0.15 Ethanol 8 9 7 ~ .
n-Butoxypropanol 1.5 1 3 2 n-propoxypropanol 0 0.5 1 1.5 Primary or secondary 2 1O5 2 1.5 monoalcohol ha~ing (2-pen~anol)(1-pentanol)(isoaryl (2-me~hyl-a C5 alkyl alcohol) l-~ytoxy) unsubstituted linear or branched chain Water and minors up to 100
It is an object of the present invention to provide liquid, hard surface cleaning compositions which have good cleaning performance as well as good shine performance, i.e. which are suitable on a non-rinse use.
It is another object of the present invention to provide liquid, hard surface cleaning compositions which can be used on all surfaces, and which are especially efficient on glass.
It is still another object of the invention to provide a hard surface cleaner which is suitable for use with any dispensing means, especially with a spray dispenser.
Other objects and advantages of the present invention will appear from the following description.
I
Summarv of the invention The invention provides hard surface cleaning compositions which have a pH of in the range of from 6 to 11 and which comprise - from 0.04% to 0.6% by weight of the total composition of anionic surfactants ammonium salts, , .- . ~ .
. . ..
.. ~' , - ' . ~
., - . . . .
~ ' . : ' ' :
- : , ' , . .
- : . .~...... . , .:
~,. "
:
S~ 3 ~3 ~J, ~
- from o% to 0.5% by weight of the total composition of aTmnonia, - from 1% to 9% by weight of the total compositiort of ethanol, - from 0.5~ to 3~ by weight of ~he total composition of n-butoxypropanol, - from 0~ to 3~ by weight of the total composition of n-propoxypropanol, - from 0.5~ to 3% of a primary or secondary monoalcohol having a C5 unsubstituted alkyl branched OTt linear chain, or mixtures thereof.
~te compositions are substantially free of monoe~hanolamine, diethanolamine, triethanolamine or mixtures ~tereof.
Detailed description of the invention The compositions of ~te invention contain anionic surfactants ammonium salts, at a level ranging from 0.04%
to 0.6%, preferably from 0.07% to 0.45% by weight of the total composition.
The anionic surfactants for use herein include alkyl benzene sulfonates or sulfates, paraffin sulfonates, olefin sulfonates, sulfonates of fatty acids and of fatty acid esters and the like whtch are well known in the detergency art.` Also suitable are e~toxylated species such as alkyl polyethoxy sulfates and sulfosuccinates.
Preferred surfactants for use herein are C8-C18 alkyl benzene sulfonates and C8-C18 alkyl polye~toxy sulfates.
Most preferred for the working of the invention, is a mixture of C8-C18 linear alkyl benzene sulphonate and a 3 times ethoxylated C8~C18 alkyl sul~ate.
- .. . . .
.. ..
.
: :
.
2 ~ ?~
All anionic surfactants are present in the composition in tha form of their ammonium salts.
The compositions of the invention also further contain a specific solvent mixture which consists of ~rom 1% to 9%
by weight of the total composition, preferably from 8% to 9%, o~ ethanol, from 0.5% to 3% by weight of the kotal composition, pre~erably from 1.5% to 2%, of n-butoxypropanol, and from 0.5% to 3% by weight of the total composition, preferably from 1.5% to 2%, of a primary or secondary monoalcohol having a C5 alkyl unsubstituted linear or branched chain, or mixt~lres thereof.
This definition comprises l-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, neopentyl alcohol, 3-methyl-2-butanol, and isoamyl alcohol.
Preferably, this alcohol is selected from 2-pentanol, n-pentanol, and isoamylalcohol. Highly preferred for use in the present compositions is 2-pentanol.
Importantly, the tertiary alcohol according to this formula (tertiary amyl alcohol) is not suitable for use in the compositions of the invention.
m e solvent system of the present invention may additionally comprise n-propoxypropanol, up to 3~ by weight of the total composition.
The composition o~ the invention preferably contains ammonia, in amounts up to 0.5% by weight of the total composition.
Depending on presence of ammonia, the compositions of the invention have a pH which is in the range of ~rom 9 to 11 :. . : , : .
.
. - . . . ~ .
- . , .. : .. . . .
- . . . . : .. ,: , ~ , (if the composition contains ammonia), or in the range of from 6 to 9 (if the compositions are free of ammonia).
The compositions of the invention are substantially free of monoethanolamine, diethanolamine, triethanolamine and mixtures thereof.
The compositions of the invention may additionally contain very low amounts, specifically ~elow 0.2%, of builders such as nitrilotriacetates, polycarboxylates, nitrates, water soluble phosphates, silicates, ethylene diamine tetraacetate (EDTA), amino polyphosphonates, phospates and mixtures thereof.
The compositions of the invention are obtained by mixing all the ingredients together; the hard surface clean rs thus obtained are suitable for use in any dispensing means currently used in this technological field, but preferably, they will be used as spray cleaners.
These compositions are suitable for use on all surfaces, especially on windows or any glass material.
The composition of the invention may contain optionals at conventional lavels; such optionals include perfumes, dyes, optical brighteners, thickeners, soil suspending agents, enzymes, freeze thaw, bactericides and preservatives.
ExamPle 1 The following composition according to the invention is prepared ~y mixing all ingredients (percentages are by weight of total composition) 0.15% Linear alkyl benzene sulfonate ammonium salt . .
.
. , , ' ', ' '.' ~
.
.
.
1.5% n~butoxy propanol 1% ethanol 1.5~ 2-pentanol O.1% ammonia up to 100% water and miscellaneous the compositions of the invention have a p~ of 10 m is composition was compared to a reference compositions of the following formula, as a representative of the prior art:
0.15% Linear alkyl benzen~ sulfonate ammonium salt 9% e~hanol 1.5% n-butoxy propanol 0.75~ n-propoxy propanol up to 100% water and minors m es~ two compositions wsre compared for their shine performance ~on mirrors) as well as ~or their cleaning performance.
The cleaning performance was evaluated on synthetic soils as described in the following :
KD soil : is compose~ of 2S% HS ~ soil with carbon black (2), 37.5~ CriscoR (1) oil, 37,5% PuritanR (1) oil.
This soil is rolled onto stainless steel plates (beforehand cleaned with a detergent and then wi~h alcohal) using a paint roller. A very thin uniform layer is needed since the soil is difficult to cure. The plates are placed in the oven at 115~C ~"soft soil") or 170C
("hard soil") ~or 2 h~urs ~nd then allowed to age at least 1 dayO
~1) commercial cooking oil sold by The Procter ~ Gamble Company (2) commercial soil sold by Chem Pack Xnc., U.S.A.
: ~ ' . ~ ' .
- . . ~ .
' " ,, ' ., , ~ ~ ~ 'S'~
The test conditions were as follows :
All tests were run with the aid of an Erichsen washability machine. A sponge of approximately 9,5 x 5 x ~ cm was used after being carefully washed under hot running water and squeezed through drying rolls. 5g. of the undiluted cleanser to ~e tested on spread cver one side of the sponge. ~he number of strokes of the cleaning machine needed to clean the plates were coun~ed.
The cleaning performance testing r~sults are the following :
¦ Hard ¦ Soft ¦
I soil I soil I t# strokes) - I
Reference ¦ 110 ¦ 34 Invention ¦ 30 ¦ 2 m e shine performance was evaluated on mirrors; using ths compositions either in "sp-;ay mcde", or in "~oam-mode"; the spray mode refers to the use of a conventional spray dispenser, wherea~ the foam mode refers to the use of a spra~
dispenser equipped with a sieve, i.e. a foaming de~ice.
The composition on the mirror is then wiped, using three different cloths :
Xitchen = dry cotton towel Cif Ballerina R twet cloth), commercially available Domex R paper towel, commercially available .. : . ,.
.
me degree of filming/streaking ic visually evaluated by 3 judges working independently using a 0-4 scale, whereby 0 = no difference and 4 = great difference.
The results are :
PSU Grades ¦ Spray ¦ Foam I
Xitchen ¦ + 0,25 ¦ 0 1- . I I
Cif Ballerina ¦ + 0,08 ¦ + 0,41 - I I I
Domex I O ¦ + 1,17 The above results show that the composition of the invention exhibit outstanding cleaning performance, and at least as good shine results as ~he reference compositions.
.
.: ~
2 ~
. -- 10 --Examples no. 2 no. 3 no. 4 no. 5 % by weight of the total composition NH4 Linear alkyl 0.1 0.2 0.15 0.2 ~en2ene sulphonate Ammonia 0.2 0.1 0 0.15 Ethanol 8 9 7 ~ .
n-Butoxypropanol 1.5 1 3 2 n-propoxypropanol 0 0.5 1 1.5 Primary or secondary 2 1O5 2 1.5 monoalcohol ha~ing (2-pen~anol)(1-pentanol)(isoaryl (2-me~hyl-a C5 alkyl alcohol) l-~ytoxy) unsubstituted linear or branched chain Water and minors up to 100
Claims (8)
1. A hard surface cleaning composition which is substantially free of monoethanolamine, diethanolamine and triethanolamine comprising - from 0.04% to 0.6% of the total composition of anionic surfactant ammonium salt, - from 0% to 0.5% of ammonia - from 1% to 9% ethanol - from 0.5% to 3% of n-butoxypropanol - from 0% to 3% of n-propoxypropanol - from 0.5% to 3% of a primary or secondary monoalcohol having a C5 alkyl branched or linear chain, or mixtures thereof.
2. A hard surface cleaning composition according to Claim 1, which comprises - from 0.1% to 0.2% of the total composition of anionic surfactant ammonium salt, - from 0.1% to 0.2% of ammonia - from 8% to 9% ethanol - from 1.5% to 2% n-butoxypropanol - from 1.5% to 2% of a C5 branched or linear monoalcohol
3. A hard surface cleaning composition according to Claim 1 wherein the monoalcohol having a C5 alkyl branched or linear chain is 2-pentanol.
4. A hard surface cleaning composition according to Claim 2 wherein the monoalcohol having a C5 alkyl branched or linear chain is 2-pentanol.
5. A hard surface cleaning composition according to Claim 1, 2, 3, or 4 characterized in that it has a pH in the range of from 6 to 11.
6. A hard surface cleaning composition according to Claim 1, 2, 3 or 4, characterized in that it has a pH in the range of from 6 to 9, and it is substantially free of ammonia.
7. A hard surface cleaning composition according to Claim 1, 2, 3 or 4 characterized in that it has a pH in the range of from above 9 to 11, and it contains ammonia.
8. The use of the hard surface cleaning compositions according to Claim 1, 2, 3 or 4 as a spray composition
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP89870186.7 | 1989-11-23 | ||
| EP89870186A EP0428816A1 (en) | 1989-11-23 | 1989-11-23 | Hard-surface cleaning compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2028512A1 true CA2028512A1 (en) | 1991-05-24 |
Family
ID=8203293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2028512 Abandoned CA2028512A1 (en) | 1989-11-23 | 1990-10-25 | Hard-surface cleaning compositions |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0428816A1 (en) |
| JP (1) | JPH03199297A (en) |
| AR (1) | AR245203A1 (en) |
| AU (1) | AU647053B2 (en) |
| BR (1) | BR9005912A (en) |
| CA (1) | CA2028512A1 (en) |
| IE (1) | IE904232A1 (en) |
| MX (1) | MX172523B (en) |
| NZ (1) | NZ236187A (en) |
| PE (1) | PE17800890A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5817615A (en) * | 1992-02-07 | 1998-10-06 | The Clorox Company | Reduced residue hard surface cleaner |
| US5252245A (en) * | 1992-02-07 | 1993-10-12 | The Clorox Company | Reduced residue hard surface cleaner |
| US5523024A (en) * | 1992-02-07 | 1996-06-04 | The Clorox Company | Reduced residue hard surface cleaner |
| US5585342A (en) * | 1995-03-24 | 1996-12-17 | The Clorox Company | Reduced residue hard surface cleaner |
| US5468423A (en) * | 1992-02-07 | 1995-11-21 | The Clorox Company | Reduced residue hard surface cleaner |
| BR9306574A (en) * | 1992-06-18 | 1998-12-08 | Unilever Nv | Homogeneous aqueous cleaning composition comprising surfactant and solvent and cleaning process |
| ES2229226T3 (en) | 1994-07-07 | 2005-04-16 | The Clorox Company | ANTIMICROBIAL CLEANING PRODUCT FOR HARD SURFACES. |
| GB2319179A (en) * | 1996-11-12 | 1998-05-20 | Reckitt & Colman Inc | Cleaning and disinfecting compositions |
| JP2002226898A (en) * | 1999-01-13 | 2002-08-14 | Nisshin Kagaku Kk | Cleaning agent for spray |
| EP3170883B1 (en) * | 2015-11-20 | 2021-08-11 | The Procter & Gamble Company | Cleaning product |
| CA3077837A1 (en) | 2020-04-03 | 2021-10-03 | Fluid Energy Group Ltd. | Hard surface cleaner |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4152306A (en) * | 1976-02-26 | 1979-05-01 | LDMJ Limited | Windshield cleaning solvent |
| EP0261874A3 (en) * | 1986-09-22 | 1989-01-25 | The Procter & Gamble Company | Concentrated hard-surface cleaning compositions |
| DE3713962A1 (en) * | 1987-04-25 | 1988-11-10 | Henkel Kgaa | LAUNDRY TREATMENT AGENTS FOR OIL AND FAT SOILS |
-
1989
- 1989-11-23 EP EP89870186A patent/EP0428816A1/en not_active Withdrawn
-
1990
- 1990-10-25 CA CA 2028512 patent/CA2028512A1/en not_active Abandoned
- 1990-11-19 AR AR31841490A patent/AR245203A1/en active
- 1990-11-22 NZ NZ23618790A patent/NZ236187A/en unknown
- 1990-11-22 BR BR909005912A patent/BR9005912A/en not_active Application Discontinuation
- 1990-11-22 AU AU66886/90A patent/AU647053B2/en not_active Ceased
- 1990-11-22 PE PE1990178008A patent/PE17800890A1/en unknown
- 1990-11-22 IE IE423290A patent/IE904232A1/en unknown
- 1990-11-23 MX MX2345490A patent/MX172523B/en unknown
- 1990-11-26 JP JP32222790A patent/JPH03199297A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AR245203A1 (en) | 1993-12-30 |
| MX172523B (en) | 1993-12-17 |
| IE904232A1 (en) | 1991-06-05 |
| NZ236187A (en) | 1992-05-26 |
| BR9005912A (en) | 1991-09-24 |
| AU6688690A (en) | 1991-05-30 |
| PE17800890A1 (en) | 1991-03-16 |
| JPH03199297A (en) | 1991-08-30 |
| EP0428816A1 (en) | 1991-05-29 |
| AU647053B2 (en) | 1994-03-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU641643B2 (en) | Hard-surface cleaning compositions | |
| US3591510A (en) | Liquid hard surface cleaning compositions | |
| US4690779A (en) | Hard surface cleaning composition | |
| US6440924B1 (en) | Aqueous multiphase detergents with immiscible phases | |
| US4676920A (en) | Creamy scouring compositions | |
| US6521584B1 (en) | Liquid multiphase detergents | |
| NO970432L (en) | Glass cleaning composition | |
| EP0261718B1 (en) | Creamy scouring compositions | |
| CA2028512A1 (en) | Hard-surface cleaning compositions | |
| WO1997029173A1 (en) | Glass cleaner with enhanced anti-streaking properties | |
| AU695680B2 (en) | Concentrated cleaning compositions | |
| EP1021400B1 (en) | Low streaking and filming hard surface cleaners | |
| US5753604A (en) | Water-containing floor cleaning composition | |
| EP0261874A2 (en) | Concentrated hard-surface cleaning compositions | |
| EP0879226B1 (en) | Low sudsing, low streaking and filming hard surface cleaners | |
| CA2127917A1 (en) | Stable microemulsion cleaning composition | |
| US20090143274A1 (en) | Surfactant Reduction Enabled by Use of Isopropylnaphthalene Sulfonate Linker | |
| SK110295A3 (en) | Floor-cleaning agents | |
| EP0442251A1 (en) | Hard surface cleaning compositions | |
| US5683975A (en) | Floor wiping composition | |
| CA1224373A (en) | Hard surface cleaning composition | |
| JPH0813990B2 (en) | Creamy polishing composition | |
| CN108384650B (en) | Surfactant composition | |
| Andree et al. | Alkyl polyglycosides in hard surface cleaners and laundry detergents | |
| WO1997041198A1 (en) | Process for cleaning plastic surfaces and means for carrying out the process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Dead |