CA2011316A1 - Prevailingly liquid detergent and/or bleaching compositions containing low molecular weight tertiary amines in the form of n-oxide - Google Patents
Prevailingly liquid detergent and/or bleaching compositions containing low molecular weight tertiary amines in the form of n-oxideInfo
- Publication number
- CA2011316A1 CA2011316A1 CA002011316A CA2011316A CA2011316A1 CA 2011316 A1 CA2011316 A1 CA 2011316A1 CA 002011316 A CA002011316 A CA 002011316A CA 2011316 A CA2011316 A CA 2011316A CA 2011316 A1 CA2011316 A1 CA 2011316A1
- Authority
- CA
- Canada
- Prior art keywords
- oxide
- tea
- tertiary amine
- bleaching
- liquid detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 238000004061 bleaching Methods 0.000 title claims abstract description 35
- 239000007788 liquid Substances 0.000 title claims abstract description 32
- 150000003512 tertiary amines Chemical class 0.000 title claims abstract description 16
- 150000001204 N-oxides Chemical class 0.000 claims abstract description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 229910001868 water Inorganic materials 0.000 claims description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 15
- 238000005406 washing Methods 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylene diamine Substances C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 230000007547 defect Effects 0.000 claims description 3
- -1 triethylenediamine N-oxide Chemical class 0.000 claims description 3
- VTGXVUQXDHXADV-UHFFFAOYSA-N 1-methyl-1-oxidopiperidin-1-ium Chemical compound C[N+]1([O-])CCCCC1 VTGXVUQXDHXADV-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 2
- 125000005270 trialkylamine group Chemical group 0.000 claims description 2
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 claims 2
- DDNBPWZIXPAKRN-UHFFFAOYSA-N 2-hydroxy-n,n-bis(2-hydroxyethyl)ethanamine oxide Chemical compound OCC[N+]([O-])(CCO)CCO DDNBPWZIXPAKRN-UHFFFAOYSA-N 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- LFMTUFVYMCDPGY-UHFFFAOYSA-N n,n-diethylethanamine oxide Chemical compound CC[N+]([O-])(CC)CC LFMTUFVYMCDPGY-UHFFFAOYSA-N 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 91
- 239000000047 product Substances 0.000 description 28
- 238000012360 testing method Methods 0.000 description 18
- 239000000654 additive Substances 0.000 description 12
- 239000007844 bleaching agent Substances 0.000 description 10
- 230000000875 corresponding effect Effects 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 8
- 239000000306 component Substances 0.000 description 8
- 229960004418 trolamine Drugs 0.000 description 8
- 235000019641 whiteness Nutrition 0.000 description 8
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229960002163 hydrogen peroxide Drugs 0.000 description 5
- 241000219146 Gossypium Species 0.000 description 4
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 4
- 238000004453 electron probe microanalysis Methods 0.000 description 4
- UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 235000020095 red wine Nutrition 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000013065 commercial product Substances 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 101150034533 ATIC gene Proteins 0.000 description 1
- 101000714952 Hololena curta Mu-agatoxin-Hc1c Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229940061319 ovide Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT8919708A IT1229564B (it) | 1989-03-09 | 1989-03-09 | Composizioni detergenti e/o sbiancanti prevalentemente liquide contenenti ammine terziarie a basso peso molecolare in forma di n ossido. |
| IT19708A/89 | 1989-03-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2011316A1 true CA2011316A1 (en) | 1990-09-09 |
Family
ID=11160559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002011316A Abandoned CA2011316A1 (en) | 1989-03-09 | 1990-03-07 | Prevailingly liquid detergent and/or bleaching compositions containing low molecular weight tertiary amines in the form of n-oxide |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0387049A3 (it) |
| JP (1) | JPH02272099A (it) |
| CA (1) | CA2011316A1 (it) |
| IT (1) | IT1229564B (it) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298195A (en) * | 1992-03-09 | 1994-03-29 | Amway Corporation | Liquid dishwashing detergent |
| US8871807B2 (en) | 2008-03-28 | 2014-10-28 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
| US8809392B2 (en) | 2008-03-28 | 2014-08-19 | Ecolab Usa Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
| BRPI0907918B1 (pt) | 2008-03-28 | 2018-07-24 | Ecolab Inc. | Ácidos sulfoperoxicarboxílicos, sua preparação e métodos de utilizção como agentes alvejantes e antimicrobianos |
| US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| US9926214B2 (en) | 2012-03-30 | 2018-03-27 | Ecolab Usa Inc. | Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water |
| US8822719B1 (en) | 2013-03-05 | 2014-09-02 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
| US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US20140256811A1 (en) | 2013-03-05 | 2014-09-11 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| ITUB20150389A1 (it) * | 2015-04-23 | 2016-10-23 | Chimec Spa | Composizione comprendente una ammina ossido e un tensioattivo e suo uso in ambito petrolifero |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5024576A (it) * | 1973-07-05 | 1975-03-15 | ||
| DE2365172A1 (de) * | 1973-12-29 | 1975-07-10 | Hoechst Ag | Bleichmittel fuer wasch- und reinigungsmittel |
| LU71985A1 (it) * | 1975-03-06 | 1977-01-28 | ||
| US4298492A (en) * | 1979-06-21 | 1981-11-03 | Lever Brothers Company | Built liquid detergent composition |
| AU604263B2 (en) * | 1986-11-06 | 1990-12-13 | Clorox Company, The | Acyloxynitrogen peracid precursors |
| JPH0633422B2 (ja) * | 1987-05-22 | 1994-05-02 | 燐化学工業株式会社 | 洗浄剤 |
-
1989
- 1989-03-09 IT IT8919708A patent/IT1229564B/it active
-
1990
- 1990-03-07 CA CA002011316A patent/CA2011316A1/en not_active Abandoned
- 1990-03-08 EP EP19900302462 patent/EP0387049A3/en not_active Withdrawn
- 1990-03-09 JP JP2059799A patent/JPH02272099A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02272099A (ja) | 1990-11-06 |
| IT8919708A0 (it) | 1989-03-09 |
| EP0387049A2 (en) | 1990-09-12 |
| IT1229564B (it) | 1991-09-04 |
| EP0387049A3 (en) | 1991-09-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3755435A (en) | N-(2-hydroxy-higher hydrocarbyl)-n-lower hydrocarbyl-aminocarboxylates | |
| US3324183A (en) | Terg-o-tometee test results | |
| FI96776C (fi) | Pesuainekoostumuksia, jotka sisältävät orgaanista pinta-aktiivista ainetta ja smektiittityyppistä savea | |
| CA1080744A (en) | Monoesters derived from ethoxylated higher alcohols and thiodisuccinic acid as detergent builders | |
| DE69019781T2 (de) | Bleichmittelzusammensetzung. | |
| US6602441B1 (en) | Bleaching-active metal complexes | |
| US4497725A (en) | Aqueous bleach compositions | |
| US4820437A (en) | Bleaching composition | |
| CA2011316A1 (en) | Prevailingly liquid detergent and/or bleaching compositions containing low molecular weight tertiary amines in the form of n-oxide | |
| US5998645A (en) | Bleaching-active metal complexes | |
| FR2459279A1 (fr) | Composition detergente liquide contenant un systeme adjuvant actif | |
| US3979312A (en) | Detergent composition containing novel bleaching agent | |
| GB2072643A (en) | Aqueous H2O2 bleach compositions | |
| US2362401A (en) | Detergent compositions | |
| GB2110259A (en) | Peroxyacid bleaching and laundering composition | |
| JPS6212791B2 (it) | ||
| EP0249474B1 (en) | Cleaning compositions | |
| JPH01501154A (ja) | 改善された洗浄力および繊維製品柔軟仕上げ性を有するビルダー塩無含有液体洗剤 | |
| US2119523A (en) | Pyrophosphate ester bleaching agent | |
| CA2236524C (en) | Liquid laundry detergent product | |
| EP0433257B1 (en) | A process for enhancing the bleaching effect at washing and use of certain amphoteric compounds in a detergent composition for enhancing the bleaching effect | |
| CH678678B5 (it) | ||
| JPH0813996B2 (ja) | 漂白剤組成物 | |
| JP3354760B2 (ja) | 液体漂白剤組成物 | |
| JP3382338B2 (ja) | 液体漂白剤組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 19930907 |