CA2008167C - Method and apparatus for manufacturing high-grade nickel matte - Google Patents

Method and apparatus for manufacturing high-grade nickel matte

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Publication number
CA2008167C
CA2008167C CA 2008167 CA2008167A CA2008167C CA 2008167 C CA2008167 C CA 2008167C CA 2008167 CA2008167 CA 2008167 CA 2008167 A CA2008167 A CA 2008167A CA 2008167 C CA2008167 C CA 2008167C
Authority
CA
Canada
Prior art keywords
suspension smelting
furnace
smelting furnace
matte
electric furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA 2008167
Other languages
French (fr)
Other versions
CA2008167A1 (en
Inventor
Pekka Hanniala
Jussi Asteljoki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Outokumpu Oyj
Original Assignee
Outokumpu Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Outokumpu Oyj filed Critical Outokumpu Oyj
Publication of CA2008167A1 publication Critical patent/CA2008167A1/en
Application granted granted Critical
Publication of CA2008167C publication Critical patent/CA2008167C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention relates to a method and apparatus for manufacturing high-grade nickel matte. In the method of the invention comprises, a concentrate under treatment, together with flux, recirculated flue dust and oxidizing gas is fed into a suspension smelting furnace. In the suspension smelting furnace there is formed slag and high-grade nickel matte. At least the slag from the suspension furnace is conducted into an electric furnace where it is reduced, in the presence of a reducing agent so that the electric furnace slag and metallicized matte are formed and at least part of the metallicized matte from the electric furnace is returned as feed to the suspension smelting furnace. The apparatus for carrying out the method of the invention comprises a suspension smelting furnace and an electric furnace.

Description

200816~

The present invention relates to a method and apparatus for manufacturing high-grade nickel matte in a combination of suspension smelting furnace and electric furnace .
Conventionally high-grade nickel matte i8 manufactured from sulphidic concentrates as follows: first the concentrate is dried and smelted in a suspension smelting furnace to form nickel matte. The nickel matte thus obtained i6 further converted to high-grade nickel matte, where the c~ ' in~d content of nickel and copper is 72-75% by weight, for instance in a Pierce-Smith type converter. In addition to this, the slag from both the suspension smelting furnace and the converter is cleaned in an electric furnace, from which the obtained matte is le~uLlle-l as feed to the converter. The gases created in the process, both from the suspension smelting furnace and from the converter, are collected and used in the production of sulphuric acid.
The above described conventional method for manufacturing high-grade nickel matte is reliable and has been tried and found adequate, but it also has some drawbacks. Such drawbacks are for instance its high investment costs. Iqoreover, the process forms two different gas flows, of which one (the converter gas flow based on the blasting technique) is highly variable in quantity, which makes the gas treatment and sulphuric acid production expensive. The use of the converter also leads to problems with smoke in the working areas, because the converter hood must be shi~ted at different stages of the converting process. Furthermore, the process requires shifting of the molten material from the suspension smelting furnace into the converter, and from the converter to the electric furnace as well as from the electric furnace to the converter. For the above described reasons, the process results in a large amount of intD ~ te *
;.
, . , , . ....... ,,, , _ _ _ _ _ 2 ~0~8~67 products, which again cause expenses in their treatment, smelting and cleaning.
An obj ect of the present invention is to eliminate some of the drawbacks of the prior art and to provide a better and simpler method for manufacturing high-grade nickel matte, as well as an apparatus suited for the method .
Accordingly, one aspect of the invention provides a method for manufacturing high-grade nickel matte, which comprise6: a) feeding a concentrate under treatment, together with flux, recirculated flue dust and oxidizing gas into a suspension smelting furnace, b) forming a slag and high-grade nickel matte in the suspension smelting furnace, c) conducting at least the slag from the suspension smelting furnace into an electric furnace, where it is reduced, in the presence of a reducing agent, so as to form electric furnace slag and metallicized matte, and d) returning at least part of the metallicized matte from the electric furnace as feed to the suspension smelting furnace.
A further aspect of the invention provides an apparatus for carrying out the method, which comprises a suspension smelting furnace for smelting the material and an electric furnace for treating the molten material.
In the manufacturing method of high-grade nickel matte according to the present invention, there is produced high-grade nickel matte in a suspension smelting furnace, such as a flash smelting furnace. As a result of the high nickel content of the high-grade matte, and the high oxygen potential of the furnace, the nickel content of the slag from the suspension smelting furnace is also high. the slag from the suspension smelting furnace is reduced in an electric furnace, which is either separate or connected to the suspension smelting furnace by a special separating member. If desired, at least part of the high-grade nickel matte can also be fed into the electric furnace. The matte . .
_ _ _ _ _ _ , . . .. .. . .. .
3 2~81B7 created in the electric furnace is at least partly recirculated back to the suspension smelting furnace. The recirculated matte, which is fed into the suspension smelting furnace either as a granulated product or molten, further reduces the slag from the suspension smelting furnace, and simultAneollqly ~limin;~h~ the amount of the recirculated material. Thus, the method and apparatus of the present invention for manufacturing high-grade nickel matte make it possible to eliminate the use of the converter as one process stage.
Conc~ ntly, the method for manufacturing high-grade nickel matte of the present invention leads to remarkable advantages in comparison with conventional technique. While using granulated matte from an electric furnace as the feed for the suspension smelting furnace, it is unnecessary to shift molten materials in the manufacturing method of the present invention, and as a result smoke problems in the working area are essentially reduced. Accordingly, there are essentially no into ~ te products ~ormed in connection with the manufacture of high-grade nickel matte. Furth,~ e, according to the invention there is created only one essentially even gas flow, which lowers the cost of sulphuric acid production and of gas treatment.
While applying the method and apparatus for manufacturing high-grade nickel matte of the present invention in a new production unit, the space and other facilities required by the converter can be excluded from the very beginning. This makes the production unit more compact and essentially cheaper in investment costs, as compared to the prior art equipment. Accordingly, the demand for labour is reduced owing to the manufacturing method of high-grade nickel matte of the present invention.
The manufacture of high-grade nickel matte according to the present invention can also be applied to an existing production unit, because the technology used in , ~
,:
_ .. , , . , . , ,, , . .. _, ... . ... . ..
the method i6 known as such. However, in the manufacturing method of high-grade nickel matte of the present invention, both the coupling of the equipment together and the method for running the high-grade nickel matte production are 5 essentially different from those of the prior art.
r ~ ?nts of the invention will be described in more detail below, with reference to the appended drawings, in which:
Figure 1 is an illustration of a preferred 10 embodiment of the invention, seen in a side-view cross-section, and Figure 2 is an illustration of another preferred embodiment of the invention, seen in a side-view cross-section .
According to Figure 1, into the reaction shaft 2 of a suspension smelting furnace 1, there is fed oxidizing gas 3, flux 4, concentrate 5 and matte 6 formed in an electric furnace, as well as flue dust 7 obtained from the cooling 21 of exhaust gases. The gases created in the suspension smelting furnace 1 are removed through uptake shaft 8 to gas treatment in a gas cooling system 21. Slag 9 from the suspension smelting furnace 1 and produced high-grade nickel matte 10 are removed from settler 11 respectively through discharge hatches 19 and 20.
The slag 9 from the suspension smelting furnace is further conveyed to an electric furnace 12, where the 61ag 9 is reduced by means of coke 13 used as the reducing agent. As a result of the reduction process, there is created slag 14 and metallicized matte 15, which are removed from the electric furnace 12 respectively through the discharge hatches 16 and 17. The metallicized matte 15 is subjected to granulation 18 after removal from the furnace. The granulated matte 6 is returned as feed to the suspension smelting furnace, for the production of further high-grade nickel matte.
4_: .

According to Figure 2, the suspension smelting furnace 1 and an electric furnace 22 are interconnected so that in between the suspension smelting furnace 1 and the electric furnace 22 there is installed a partition wall 23, which prevents the molten high-grade nickel matte 10 produced in the suspension smelting furnace 1 from flowing into the electric furnace 22, but allows the slag 9 from the suspension smelting furnace to flow as an overflow into the electric furnace. The partition wall 23 can be formed of one piece, in which case the wall 23 is common for both the suspension smelting furnace 1 and the electric furnace 22, or alternatively of two pieces, in which case the sections of the wall 23 adjacent the suspension smelting furnace 1 and the electric furnace 22 are separate, and there is formed a connecting duct 24 in between the walls.
The following Example illustrates the invention.
Exam~le The method of the invention was applied to a sulphide concentrate, which contained 6.9~6 by weight nickel, 1.2% by weight copper, 36.3% by weight iron, 26.5%
by weigh sulphur and 11. 5% by weight silicon oxide. The concentrate was fed into the reaction shaft of a flash smelting furnace, and for each ton of concentrate there is also fed 82 kg of matte from an electric furnace, 230 kg of flux, and 98 kg of flue dust separated from the exhaust gases from the flash smelting furnace. In addition to this, there was fed 320 Nm of oxidizing gas with an oxygen enrichment degree of 80% into the reaction shaft per ton of concentrate fed therein.
The product obtained from the settler of the flash smelting furnace was high-grade nickel matte containing 65% by weight of nickel, 10% by weight of copper and 22% by weight of sulphur. Moreover, from the settler of the flash smelting furnace there was obtained slag containing 3% by weigh of nickel, 0.6% by weight of sulphur and 30% by weight of silicon oxide.
~ .

200816~
The slag from the flash smelting furnace was further cu..v~yed to an electric furnace, where the slag was reduced by means of coke. In the reduction there was formed a slag phase and a metallicized matte phase, which 5 in connection with the removal from the electric furnace was granulated and returned as feed to the flash smelting furnace. On the basis of the slag from the electric furnace, which contained 0.1596 by weight nickel and 0.17%
by weight copper, it was observed that, with the method of 10 the present invention, the obtained recovery rate of the nickel that was fed in the concentrate was 97 . 996 .

Claims (10)

1. A method for manufacturing high-grade nickel matte, which comprises:
a) feeding a concentrate under treatment, together with flux, recirculated flue dust and oxidizing gas into a suspension smelting furnace, b) forming a slag and high-grade nickel matte in the suspension smelting furnace, c) conducting at least the slag from the suspension smelting furnace into an electric furnace, where it is reduced, in the presence of a reducing agent, so as to form electric furnace slag and metallicized matte, and d) returning at least part of the metallicized matte from the electric furnace as feed to the suspension smelting furnace.
2. A method according to claim 1, wherein the slag from the suspension smelting furnace is fed into the electric furnace.
3. A method according to claim 1, wherein the slag from the suspension smelting furnace and part of the matte from the suspension smelting furnace are fed into the electric furnace.
4. A method according to claim 1, 2 or 3, wherein the matte obtained from the electric furnace is granulated on removal from the electric furnace.
5. A method according to claim 1, 2 or 3, wherein the matte returned to the suspension smelting furnace is fed to the suspension smelting furnace in a molten state.
6. An apparatus for carrying out the method of claim 1, wherein the apparatus comprises a suspension smelting furnace for smelting the material and an electric furnace for treating the molten material.
7. An apparatus according to claim 6, wherein the suspension smelting furnace and the electric furnace are separated from each other.
8. An apparatus according to claim 6, wherein a separating member is disposed between the suspension smelting furnace and the electric furnace.
9. An apparatus according to claim 8, wherein the separating member is a partition wall.
10. An apparatus according to claim 8, wherein the separating member is a connecting duct.
CA 2008167 1989-01-27 1990-01-19 Method and apparatus for manufacturing high-grade nickel matte Expired - Lifetime CA2008167C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI890395 1989-01-27
FI890395A FI84368B (en) 1989-01-27 1989-01-27 Process and equipment for producing nickel fine matte

Publications (2)

Publication Number Publication Date
CA2008167A1 CA2008167A1 (en) 1990-07-27
CA2008167C true CA2008167C (en) 1996-12-03

Family

ID=8527788

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2008167 Expired - Lifetime CA2008167C (en) 1989-01-27 1990-01-19 Method and apparatus for manufacturing high-grade nickel matte

Country Status (8)

Country Link
CN (1) CN1027978C (en)
AU (1) AU623969B2 (en)
BR (1) BR9000366A (en)
CA (1) CA2008167C (en)
FI (1) FI84368B (en)
RU (1) RU2102509C1 (en)
UA (1) UA27218C2 (en)
ZA (1) ZA90500B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4320319C2 (en) * 1992-06-18 2003-11-20 Outokumpu Harjavalta Metals Oy Process for the production of a highly enriched nickel stone and metallized sulfide stone

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI97396C (en) * 1993-12-10 1996-12-10 Outokumpu Eng Contract Method for the production of nickel fine stone from nickel-containing raw materials at least partially pyrometallurgically processed
FI98380C (en) * 1994-02-17 1997-06-10 Outokumpu Eng Contract Method and apparatus for suspension melting
FI114808B (en) * 2002-05-03 2004-12-31 Outokumpu Oy Process for the processing of precious metal
CN1311090C (en) * 2005-08-23 2007-04-18 云锡元江镍业有限责任公司 Bessemer matte production method using nickel sulfide materials
US8016912B2 (en) 2007-09-14 2011-09-13 Barrick Gold Corporation Process for recovering platinum group metals using reductants
FI20110279A0 (en) 2011-08-29 2011-08-29 Outotec Oyj A method for recovering metals from material containing them
CN102605191B (en) 2012-04-16 2013-12-25 阳谷祥光铜业有限公司 Method for directly producing row copper by copper concentrate
FI124912B (en) 2012-04-16 2015-03-31 Outotec Oyj A method for treating metallurgical slags of non-ferrous metals
FI124028B (en) * 2012-06-13 2014-02-14 Outotec Oyj Process and arrangement for refining copper concentrate
CN104451195B (en) * 2014-11-21 2016-05-18 邱江波 The flash smelting method of lateritic nickel ore
CN104880073B (en) * 2015-06-23 2016-11-23 邹镇 An a kind of step meltblown smelting device
CN112030006B (en) * 2020-07-17 2022-05-31 中国恩菲工程技术有限公司 Furnace screening method suitable for nickel matte converting reduction furnace

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5143015B2 (en) * 1972-05-04 1976-11-19
AU521924B2 (en) * 1978-12-06 1982-05-06 Moskovsky Ins Stali Pyrometallurgical processing of nonferrous materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4320319C2 (en) * 1992-06-18 2003-11-20 Outokumpu Harjavalta Metals Oy Process for the production of a highly enriched nickel stone and metallized sulfide stone

Also Published As

Publication number Publication date
AU4860690A (en) 1990-08-02
FI890395A0 (en) 1989-01-27
BR9000366A (en) 1990-12-04
CA2008167A1 (en) 1990-07-27
FI84368B (en) 1991-08-15
FI890395A (en) 1990-07-28
CN1027978C (en) 1995-03-22
CN1044501A (en) 1990-08-08
AU623969B2 (en) 1992-05-28
RU2102509C1 (en) 1998-01-20
UA27218C2 (en) 2000-08-15
ZA90500B (en) 1990-10-31

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