CA2001682C

CA2001682C - Thin film transistor having memory function and method for using thin film transistor as memory element

Info

Publication number: CA2001682C
Application number: CA002001682A
Authority: CA
Inventors: Hiroshi Matsumoto; Hiroyasu Yamada; Nobuyuki Yamamura; Shinichi Shimomaki; Naohiro Konya; Kyuya Baba
Original assignee: Casio Computer Co Ltd
Current assignee: Casio Computer Co Ltd
Priority date: 1988-10-28
Filing date: 1989-10-27
Publication date: 1994-05-03
Anticipated expiration: 2009-10-27
Also published as: DE68912071D1; KR930003556B1; EP0366146B1; DE68912071T2; CA2001682A1; EP0366146A3; KR900007075A; EP0366146A2

Abstract

A memory element is formed of a thin film tran-sistor. The thin film transistor has a semiconductor layer, a source electrode electrically connected to the semiconductor layer, a drain electrode electrically con-nected to the semiconductor layer and formed separately from the source electrode, a gate electrode for control-ling formation of a channel of the semiconductor layer, and a gate insulation film for isolating the gate elec-trode and the semiconductor layer from each other and causing a hysteresis in the relation between the drain current and the gate circuit. The insulation film is a silicon nitride film whose composition ratio of silicon to nitrogen is in a range of approx. 0.85 to 1.1.
According to this invention, the relation between the gate voltage and the drain current can be set to have a hysteresis. Therefore, the thin film transistor can be used as a memory element. Further, according to this invention, data can be written, erased and read out by selectively applying an electric field to the gate insu-lation film. Therefore, the thin film transistor can be used as a memory element.

Description

- 2~2 This invention relates to a thin film transistor having a memory function and a method for using a thin film transistor as a memory element.
As is well known in the art, a thin film transistor includes a gate electrode, a gate insulation film, a semiconductor layer and source and drain electrodes which are formed in a laminated structure. The stagger type, inverted stagger type, coplanar type and inverted coplanar type structures are known as the thin film transistor.
The conventional thin film transistor has no memory function. Further, a method of using the thin film transistor as a memory element is not known in the prior art. However, it is extremely convenient if the thin film transistor has a memory function.
This invention has been made in view of the above fact, and an object of this invention is to provide a thin film transistor having a memory function and a method for using a thin film transistor as a memory element.
The above object can be attained by a memory ele-ment comprising a thin film transistor having a semicon-ductor layer-~4t; a source electrode-(G~-electrically connected to the semiconductor layer; a drain electrode -~t electrically connected to the semiconductor layer and formed separately from the source electrode; a gate electrode (2) for controlling formation of a channel;

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and insulation film means (3) for isolating the gate ,., electrode ~ from the semiconductor layer t~t~and caus-ing a hysteresis in the relation between the drain cur-rent and the gate voltage.
The insulation film means includes an SiN film having a composition ratio Si/N of silicon atoms Si to nitrogen atoms N which lies in a range between approx.
0.85 and 1.1.
According to this invention, the gate insulation film means causes a hysteresis in the gate voltage-drain current relation. The thin film transistor may have a memory function due to the hysteresis of the gate voltage-drain current relation and as a result the thin film transistor can be used as a memory element.
Further, the above object can be attained by a method for using a thin film transistor as a memory element comprising the steps of preparing a thin film transistor having a semiconductor layer ~, a source electrode t~t, a drain electrode -~7~, a gate electrode ^~ and a gate insulation film; writing first data into the thin film transistor by applying a first voltage to the gate insulation film; writing second data different from the first data by applying a second voltage of a polarity opposite to that of the first voltage to the gate insulation film; and reading data stored in the thin film transistor according to a current which flows in the channel and whose level is changed by a difference in the voltages applied to the gate insula-tion film.
According to this invention, data can be written into the thin film transistor by applying an adequate voltage to the gate insulation film and then the data can be read out from the thin film transistor. That is, the thin film transistor can be used as a memory element.
This invention can be more fully understood from the following detailed description when taken in con-junction with the accompanying drawings, in which:
Fig. lA is a cross sectional view of a thin film transistor having a memory function according to a first embodiment of this invention;
Fig. lB is a plan view of the thin film transistor according to the first embodiment;
Figs. 2A and 2B are cross sectional views showing the manufacturing process of the thin film transistor according to the first embodiment;
Figs. 3A to 3D are graphs showing the relation between the VG-ID characteristic and the composition ratio of Si/N of the gate insulation film of the thin film transistor with the thickness of the gate insula-tion film set at 2000 angstrom;
Figs. 4A to 4D are graphs showing the relation between the VG-ID characteristic and the composition ratio of Si/N of the gate insulation film of the thin ~Z~i~32 film transistor with the thickness of the gate insulation film set at 3000 angstrom;
Fig. 5 shows the relation between the degree of hysteresis and the composition ratio of Si/N of the gate insulation film of each of the thin film transistors in a case where the gate insulation films are formed to have thicknesses of 2000 and 3000 angstrom;
Figs. 6 to 8 are cross sectional views showing the structures of applications of the thin film transistor used for a memory and according to the first embodiment;
Fig. 9 is a cross sectional view showing the struc-ture of a thin film transistor constituting a memory and according to a second embodiment of this invention;
Figs. 10 and ll are graphs respectively showing the relation between the film thickness of a non-memory insulation film of the thin film transistor of Fig. lO
and the leak current and that between the film thickness and the hysteresis width;
Fig. 12 is a cross sectional view showing the struc-ture of a thin film transistor having a memory functionaccording to a third embodiment of this invention;
Figs. 13 to 15 are cross sectional views of appli-cations of the third embodiment of this invention;
Fig. 16 is a cross sectional view showing the structure of a thin film transistor having a memory function according to a fourth embodiment of this invention;

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Fig. 17 is a graph showing the characteristic of the thin film transistor with the memory function according to the fourth embodiment;
Fig. 18 is a cross sectional view showing the structure of a thin film transistor having a memory function according to a fifth embodiment of this invention;
Fig. l9A is a cross sectional view of a thin film transistor according to a sixth embodiment of this invention;
Fig. l9B is a plan view of the thin film transistor of the sixth embodiment;
Fig. 20 is a view showing a model of the structure of a gate insulation film of the thin film transistor according to the sixth embodiment;
Figs. 21A to 21D are cross sectional diagrams showing the manufacturing process of the thin film transistor according to the sixth embodiment;
Fig. 22 shows the relation between the flow rate ratio of silane gas SiH4 to ammonia gas HN3 and the composition ratio (Si/N) of silicon atoms Si to nitrogen atoms N in the deposited silicon nitride film.
Fig. 23 is a diagram showing the characteristic of the thin film transistor according to the sixth embodiment; and Figs. 24 and 25 are circuit diagrams of examples of memory circuits using the memory element of this invention.
There will now be described a first embodiment of this invention with reference to the accompanying drawings.
Fig. lA is a cross sectional view of a thin film transistor having a memory function according to the first embodiment and Fig. lB is a plan view of the thin film transistor shown in Fig. lA. Fig. lA corresponds to a cross sectional view taken along line A-A of Fig. lB. In Fig. lB, only main portions are shown for easy understanding the positional relation thereof.
In the first embodiment, the thin film transistor with the memory function has an inverted stagger type structure. The basic structure of the thin film tran-sistor with the memory function is the same as that of the conventional inverted stagger type thin film tran-sistor. However, the film quality (composition) of the gate insulation film of the thin film transistor of this embodiment is different from that of the gate insulation film of the conventional thin film transistor.
The structure of the thin film transistor with the memory function is now explained with reference to Figs. lA and lB. A gate electrode 2 of chromium, Al or the like is formed on an insulation substrate 1 of glass, for example. A gate insulation film 3 is formed on the gate electrode 2. A semiconductor layer 4 of i (intrinsic)-a (amorphous)-Si (silicon) structure with a thickness of approx. 300 to 600 angstrom is formed on the gate insulation film 3. The semiconductor layer may be formed of polycrystalline silicon, monocrystalline silicon or compound semiconductor, for example.
Further, n+-a-Si contact layers 5 of N-type high impu-rity concentration are formed on the semiconductor layer 4 and source electrode 6 and drain electrode 7 are formed on the n+-a-Si contact layers 5. The presence of the contact layer 5 permits an ohmic contact to be obtained between the semiconductor layer 4 and the source and drain electrodes 6 and 7.
The gate insulation film 3 is formed of an SiN film having a hysteresis characteristic. More specifically, the gate insulation film 3 is formed of an SiN film with the composition ratio Si/N of silicon atoms Si to nitro-gen atoms N which is set larger than the stoichiometric ratio (Si/N=0.75). In this embodiment, the film thick-ness of the gate insulation film 3 is set at approx.
2000 angstrom and the composition ratio thereof is set at 0.85 to 1.1.
Now, the manufacturing process of the thin film transistor with the memory function is explained with reference to Figs. 2A and 2B. First, a metal film MF1 is formed to a thickness of approx. 500 angstrom on the insulation substrate 1 by the sputtering or CVD method.
After this, a photoresist film is formed on the metal film MFl which is then etched out as shown in Fig. 2A.

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The film MFl is patterned with the remaining photoresist film REl used as a mask so as to form a gate electrode.
Then, an SiN film constituting the gate insulation film 3, i-a-Si semiconductor layer 4 and n+-a-Si contact layer 5 are sequentially formed on the resultant struc-ture by the plasma CVD method. Further, a metal film or photoresist film MF2 is formed on the resultant struc-ture and a photoresist film is formed on the film MF2.
The photoresist film is etched out as shown in Fig. 2B.
The film MF2 is patterned with the remaining photoresist film RE2 used as a mask so as to form a source electrode 6 and a drain electrode 7. Further, that portion (channel portion) of the contact layer 5 which lies between the source electrode 6 and the drain electrode 7 is etched out with the photoresist film RE2 used as a mask. As the result of this, the structure shown in Fig. lA is obtained.
Formation of the SiN film constituting the gate insulation film 3 by use of the plasma CVD method is effected by selectively setting the flow rate ratio of SiH4 to NH3 used as the main component gases in the process such that the composition ratio Si/N of an SiN
film to be formed can be set within the range of 0.85 to 1.1. For example, the flow rate ratio of SiH4 to NH3 is set to 42:48. The gate insulation film (SiN film)- 3 has a sufficiently large hysteresis characteristic.
Figs. 3A to 3D show the result of measurement made 2~D0~8;~

for the VG-ID characteristic (the relation between the gate voltage VG and the drain current ID) of the thin film transistor with the film thickness of the gate insulation film (SiN film) 3 set at 2000 angstrom in a case where the composition ratio of Si/N of the gate insulation film 2 is changed.
Fig. 3A shows the VG-ID characteristic in a case where the composition ratio Si/N is set at 0.75 (which is the composltion ratio of Si to N when the gate insu-lation film of the conventional thin film transistor is formed of Si3 N4), Fig. 3B shows the VG-ID characteris-tic in the case of Si/N=0.85, Fig. 3C shows the VG-ID
characteristic in the case of Si/N=l.0 and Fig. 3D shows the VG-ID characteristic in the case of Si/N=l.l.
Figs. 3A to 3D show the result of measurement of variation in the drain current (current flowing in the channel between the source electrode and the drain electrode) ID with respect to the gate voltage VG with the drain voltage VD set at 10 V.
AS is clearly understood from Figs. 3A to 3D, the VG-ID characteristic of the thin film transistor in which the gate insulation film is formed of the SiN film having the composition ratio of Si to N of 0.75 displays little hysteresis.
In contrast, each of the characteristics of the thin film transistor in which the gate insulation film is formed of the SiN film having the composition ratio ~o~
-of Si to N of 0.85 to 1.1 displays a relatively large hysteresis as shown in Figs. 3B to 3D.
In Figs. 3A to 3D, the degree of delta vth of the hysteresis is defined as a difference between the gate voltage VG at which the drain current ID becomes 1 nA
when the gate voltage vG is gradually changed from a negative value to +40 v and the gate voltage vG at which the drain current ID becomes 1 nA when the gate voltage VG is gradually decreased from +40 V. delta Vth=2 v in Fig. 3A, delta vth=14 v in Fig. 3B, delta Vth=28 v in Fig. 3C, and delta Vth=20 V in Fig. 3D.
As described above, the VG-ID characteristic has a relatively large hysteresis characteristic as shown in Figs. 3B to 3D, and this means that the thin film tran-sistors have the memory function in which charge can bestored in the gate insulation film 3. Therefore, the thin film transistor whose gate insulation film 3 is formed of an SiN film having the composition ratio of Si to N of 0.85 to 1.1 can be used as a memory element in which data can be written or read out by controlling a voltage applied to the gate electrode 2. Further, the thin film transistor with the memory function maintains the influence by a voltage which is finally applied to the gate electrode 2. Therefore, the thin film transis-tor can be used as a memory element such as an E 2 PROM.

In the above explanation, delta Vth is called "thedegree of hysteresis", but delta vth may be called "the size of hysteresis", "hysteresis width" or "memory width".
Further, in the above explanation, the film thick-ness of the SiN film used as the gate insulation film 3 is set at 2000 angstrom. However, the film thickness of the SiN film can be selectively set in a range of 500 to 4000 angstrom. It is preferable to set the film thick-ness in a range of 2000 to 3000 angstrom (which is the thickness of the gate insulation film of the ordinary thin film transistor). In a case where the film thick-ness of the SiN film is made larger, it becomes neces-sary to make the range of the Si/N composition ratio narrower than that (Si/N=O. 85 to 1.1) set in the case of the film thickness of 2000 angstrom.
Figs. 4A to 4D show the result of measurement (made by setting the drain voltage VD at 10 V and the source voltage Vs at 0 V) of the VG-ID characteristic of the thin film transistor with the film thickness of the gate insulation film 3 set at 3000 angstrom in a case where the SiN composition ratio of the gate insulation film 3 is changed. Fig. 4A shows the characteristic in the case of Si/N=0.75, Fig. 4B shows the characteristic in the case of Si/N=O. 85, Fig. 4C shows the characteristic in the case of Si/N=l.O and Fig. 4D shows the character-istic in the case of Si/N=l.l.
As shown in Figs. 4A to 4D, the degree of delta vthof the hysteresis of the VG-ID characteristic in the case of the gate insulation film having the film thick-ness of 3000 angstrom is smaller than that of the VG-ID
characteristic in the case of the gate insulation film having the film thickness of 2000 angstrom shown in Figs. 3A to 3D even if the composition ratio of Si to N
is set at any value. However, if the Si/N composition ratio is set at 1.0, a large hysteresis as shown in Fig. 4C can be attained even when the film thickness is set at 3000 angstrom. The degree of delta Vth of the hysteresis shown in Fig. 4C is 16 V. If the degree of delta Vth of the hysteresis is not less than 15 V, the thin film transistor can have a practically sufficient memory function. Therefore, the thin film transistor having the film thickness of 3000 angstrom and the SiN
composition ratio of 1.0 can be used as a memory element such as an E2PROM. Delta Vth=0.5 V in Fig. 4A, delta Vth=2 V in Fig. 4B and delta Vth=12 v in Fig. 4D. The degree of the hysteresis of Fig. 4D is relatively large.
Fig. 5 shows the relation between the SiN composi-tion ratio of the SiN film and the degree of delta Vthof the hysteresis in cases where the film thickness of the gate insulation film (SiN film) 3 is set at 2000 and 3000 angstrom. Fig. 5 shows the result of measurement of delta Vth at which a circuit of 1 nA flows between the source and drain when the gate voltage VG is set at + 40 V, the drain voltage is set at lO V and the source voltage is set at 0 V. As is understood from Fig. 5, 2~ 8~

the hysteresis becomes largest when the composition ratio of Si to N is set at or near l.0 irrespective of whether the film thickness of the SiN film 3 is set at 2000 or 3000 angstrom. As described before, when the degree of delta Vth of the hysteresis is larger than 15 V, the thin film transistor can have a practically sufficient memory function. Therefore, if the film thickness of the SiN film is set at 2000 angstrom, the composition ratio of Si to N may be set between approx. 0.85 and 1.1. Further, if the film thickness of the SiN film is set at 3000 angstrom, the composition ratio of Si to N may be set at approx. 1Ø
If the film thickness of the gate insulation film (SiN film) 3 is set to be less than 2000 angstrom, the range of the composition ratio of Si to N can be set wider than that of approx. 0.85 to 1.1. However, if the film thickness of the gate insulation film 3 is set to be less than 2000 angstrom, the withstanding voltage of the insulation film is lowered. Therefore, it is pref-erable to set the film thickness of the gate insulationfilm 3 within the range of 2000 to 3000 angstrom.
In the above embodiment, the inverted stagger type thin film transistor is explained. This invention can also be applied to the stagger type, coplanar type and the inverted coplanar type thin film transistor.
In this case, if the ratio of Si to N of the gate insu-lation film 3 is set in the range of approx. 0.85 to 1.1 and the film thickness of the gate insulation film (SiN
film) 3 is set such that the degree of delta Vth of the hysteresis is more than 15 V, then the thin film tran-sistor may have the memory function.
Fig. 6 shows an embodiment in which this invention is applied to a stagger type thin film transistor, Fig. 7 shows an embodiment in which this invention is applied to an inverted coplanar type thin film transis-tor and Fig. 8 shows an embodiment in which this inven-tion is applied to a coplanar type thin film transistor.
The thin film transistors shown in Figs. 6 to 8 are similar to the inverted stagger type thin film transis-tor shown in Fig. lA except the laminated structure of the respective layers constituting the transistor.
Therefore, the same reference numerals are attached to corresponding portions of the transistors and the expla-nation for the structure of Figs. 6 to 8 is omitted.
As described above, the thin film transistors of the above embodiments can be used as a memory element since the gate insulation film is formed of an SiN film with the composition ratio Si/N of silicon atoms Si to nitrogen atoms N lying in the range of approx. 0.85 to 1 .1 .
In a case where the semiconductor layer 4 is formed of intrinsic silicon, the transistor is operated in a p-channel operation mode when a negative voltage of approx. -15 V to -17 v is applied to the gate electrode Q~8~

2, and the drain current ID abruptly increases as shown in Figs. 2A to 2D and Figs. 3A to 3D.
In order to solve the above problem, a small amount of impurity may be doped into the semiconductor layer 4.
With this structure, the gate voltage which may cause the thin film transistor to be operated in the p-or n-channel operation mode can be shifted. In this way, the thin film transistor with the memory function can be easily controlled.
The semiconductor layer 4 is not necessarily formed of amorphous silicon and can be formed of the other sem-iconductor material such as polycrystalline silicon, monocrystalline silicon or germanium.
Second Embodiment In the thin film memory element of the first embodiment, the gate insulation film 3 is formed of an SiN film having the ratio Si/N =0.85 to 1.15. However, the SiN film having Si/N=0.85 to 1.15 has an electrical resistance lower than that of the SiN film having the stoichiometric ratio of Si/N (Si/N=0.75). For this reason, a leak current may easily flow between the the gate electrode 2 and the source and drain electrodes 6 and 7 of the thin film memory element in the first embodiment. Further, charges injected from the semicon-ductor layer 4 into the gate insulation film 3 and trapped therein may tend to be discharged into the gate electrode 2. In this embodiment, a memory element is ~o~

constituted by a thin film transistor in which the degree of delta Vth of the hysteresis is increased and a leak current between the gate electrode and the source and drain electrodes is suppressed to a small value.
In this embodiment, the gate insulation film is formed with two-layered structure. The two-layered film includes a non-memory insulation film having no charge storage function provided on the gate electrode and a memory insulation film having a charge storage function provided on the semiconductor layer.
Now, the second embodiment is explained in detail with reference to Figs. 9 to 11.
Fig. 9 is a cross sectional view of a thin film memory element utilizing an inverted stagger type thin film transistor of this embodiment. The thin film mem-ory element is formed of an inverted stagger type thin film transistor having the memory function and formed on an insulation substrate 11 formed of glass or the like.
The inverted stagger type thin film transistor includes a gate electrode 12 formed on the insulation substrate 11, a gate insulation film 13 of SiN formed with two-layered structure and formed on the gate insulation film 12, a semiconductor layer 14 of i-a-Si formed on the gate insulation film 13, an n-type a-Si layer 15 formed on the semiconductor layer 14, and source and drain electrodes 16 and 17 formed on the n-type a-Si layer 15.
Unlike the structure shown in Fig. lA, in the structure shown in Fig. 9, the peripheral portion of the semiconductor layer 14 is formed flush with the electrodes 16 and 17. The gate electrode 12 and the source and drain electrodes 16 and 17 are connected to wirings (not shown).
The gate insulation film 13 is formed of a two-layered film including a non-memory insulation film 13a having no charge storage function and a memory insulation film 13b having a charge storage function and formed on the insulation film 13a. The non-memory insulation film 13a is formed of an SiN film having the composition ratio Si/N of silicon atoms Si to nitrogen atoms N set near the stoichiometric ratio [Si/N=o.75]~ or more generally in 15 the range 0.1 to 0.8, and the memory insulation film 13b is formed of an SiN film having the composition ratio Si/N=0.85 to 1.15. The film thickness of the insulation film 13a is set to 2000 angstrom and that of the insulation film 13b is set to 100 angstrom.
The above thin film memory element is formed as follows. First, metal film of chromium (Cr) or the like is formed to a thickness of 1000 angstrom on the insulation substrate 11 and is patterned by the photoetching process (PEP), for example, so as to form a gate electrode 12. Then, a non-memory insulation film 13a, a memory insulation film 13b, an i-type a-Si semiconductor layer 14 and an n-type a-Si layer 15 are sequentially deposited on the resultant structure. The i-type a-Si ,~

semiconductor layer 14 is formed with a thickness of approx. 1500 angstrom and the n-type a-Si layer 15 is formed with a thickness of approx. 250 angstrom. The deposition of the insulation films 13a and 13b, i-type a-Si layer 14 and n-type a-Si layer 15 is effected by use of the plasma CVD mèthod. The deposition of the insulation film 13a is effected by selectively setting the flow rate ratio of SiH4 to NH3 used as the main component gases in the process such that the composition ratio Si/N of the SiN film to be deposited on the substrate 11 is set near the stoichiometric ratio (Si/N=0.75). The deposition of the insulation film 13b is effected by selectively setting the flow rate ratio of SiH4 to NH3 such that the composition ratio Si/N of the SiN film to be deposited is set in the composition ratio range of 0.85 to 1.15. Further, the deposition of the i-type a-Si semiconductor layer 14 is effected by using SiH4 as the main component gas and the n-type a-Si layer 15 is deposited by introducing PH3 as n-type impurity gas into the SiH4 gas at a predetermined flow rate. Then, a metal film of Cr or the like is deposited on the n-type a-Si layer 15 to a thickness of approx.
500 angstrom by the sputtering method or the like.
The metal film is patterned by the PEP method to form source and drain electrodes 16 and 17. Then, the n-type a-Si layer 15 is etched out with the source and drain electrodes 16 and 17 used as a mask. Further, the peripheral portion of the i-type a-Si semiconductor layer 14 is patterned to be flush with source and drain electrodes 16 and 17, thus completing a thin film memory element.
In the thin film memory element, charges are trapped in an interface of the gate insulation film 13 and the semiconductor layer 14 or in the gate insulation film 13 by an electric field from the gate electrode 12.
Therefore, even when the gate insulation film 13 is formed with the two-layered structure as described above, the thin film transistor may have the memory function (hysteresis characteristic) if the semiconduc-tor layer 14 is formed in contact with the memory insulation film 13b. Further, in Fig. 9, the memory insulation film 13a is formed to be thicker than the memory insulation film 13b. As a result, the degree of delta Vth of the hysteresis can be increased and a leak current can be reduced.
This effect is explained with reference to Figs. 10 and 11. Figs. 10 and 11 show the result of measuring the leak current and the hysteresis widths when the thickness of the gate insulation film 13 (the sum of the thicknesses of the insulation films 13a and 13b) is kept constant and the ratio of the thickness of the memory insulation film 13b to the thickness of the gate insula-tion film 13 is changed. In the thin film memory ele-ment having a gate insulation film (the gate insulation film only of the memory insulation film 13b) in which the ratio of the film thickness of the non-memory insu-lation film 13a is 0 %, a leak current is large and the hysteresis width is small. On the other hand, the leak current becomes smaller as shown in Fig. 10 and hyster-esis width becomes larger as shown in Fig. 11 as the film thickness ratio of the non-memory insulation film 13a becomes larger. Further, if the memory insulation film 13b is removed and the film thickness ratio of the non-memory insulation film 13a is set to 100 %, then the hysteresis width delta Vth becomes substantially 0, preventing the transistor from operating as a memory.
Therefore, if the non-memory insulation film 13a is formed to be thicker than the memory insulation film 13b, it becomes possible to reduce the leak current and increase the hysteresis width. For example, if the film thickness of the non-memory insulation film 13a is set to 2000 angstrom and the film thickness of the memory insulation film 13b is set to 100 angstrom as in the above embodiment, a thin film memory in which substan-tially no leak current flows and the hysteresis width is sufficiently large can be obtained.
Third Embodiment In the above embodiments, the composition ratio Si/N of the gate insulation film 3 is set to 0.85 to 1.1. However, even if the composition ratio Si/N is less than 0.85, for example, 0.75, the electric field applied to the gate insulation film 3 becomes larger when the film thickness is made smaller so that the gate insulation film 3 may have a function of trapping charge. In this way, the degree of delta Vth of the hysteresis can be increased. However, if the gate insu-lation film 3 is made thin, the withstanding voltage of the gate insulation film 3 is lowered and the transistor may be broken down.
In this embodiment, a thin film transistor having lo an excellent memory function without lowering the withstanding voltage of the gate insulation film can be provided. The gate insulation film of the thin film transistor of this embodiment is formed of a ferroelectric film formed in contact with the gate elec-trode and a silicon nitride film formed in contact withthe semiconductor layer.
Now, the third embodiment is explained in detail with reference to Fig. 12.
Fig. 12 is a cross sectional view showing an exam-ple of the thin film transistor with the memory functionof this embodiment. In Fig. 12, a gate electrode 12 of chromium (Cr) or the like is formed on an insulation substrate 11 of glass, for example. A gate insulation film 23 is formed on the gate electrode 12. A semicon-ductor layer 14 formed of i-type amorphous silicon (i-a-si) and further, n+-type semiconductor layers 15 are formed on the i-type semiconductor layer 14. The channel portion of the n-type semiconductor layer 15 is removed. Source and drain electrodes 16 and 17 of chro-mium or the like are formed on the n+-type semiconductor layers 15. The gate electrode 12, and the source and drain electrodes 16 and 17 are connected to wirings (not shown).
The gate insulation film 23 is formed of a ferroelectric film 23a formed in contact with the gate electrode 12 and a silicon nitride (SiN) film 23b formed in contact with the semiconductor layer 14. The ferroelectric film 23a is formed of a dielectric mate-rial such as tantalum oxide (TaOx) having a dielectric constant not less than 10. In this embodiment, Ta2O3 is used as the tantalum oxide and a Ta2O3 film with a thickness of 3000 angstrom is formed. The dielectric constant of Ta2O3 is approx. 25. The silicon nitride film 23b is formed of silicon nitride (Si3N4) having the composition ratio Si/N of silicon atoms Si to nitrogen atoms N substantially equal to the stoichiometric ratio (Si/N=0.75). Further, the silicon nitride film 23b is formed to a thickness of 250 angstrom. The dielectric constant of the silicon nitride film 23b is 7.1.
Now, the operation of the thin film transistor of this embodiment is explained. In a thin film tran-sistor having a gate insulation film formed of a single film of silicon nitride, the intensity of an electric field applied to the gate insulation film when the f2'~

gate voltage VG is 40 V is 1.3 MV/cm (in this case, the film thickness of the gate insulation film is 3000 angstrom). However, in the thin film transistor of this embodiment, the intensity of an electric field applied to the gate insulation film 23b when the gate voltage VG is 40 V is 3.5 MV/cm.
The degree of delta Vth of the hysteresis increases with an increase in the intensity of the electric field applied to the silicon nitride film 23b. Therefore, according to the thin film transistor with the memory function of this embodiment, the operation margin or delta vth can be increased without raising the gate voltage VG.
In the above explanation, the ferroelectric film (Ta2o3) 23a is formed to a thickness of 3000 angstrom.
However, if the ferroelectric film 23a is formed thinner, the intensity of the electric field applied to the silicon nitride film 23b can be increased.
In this case, if the ferroelectric film 23a is made too thin, the withstanding voltage of the transistor is lowered. In contrast, if the ferroelectric film 23a is made too thick, then the electric field applied to the sillcon nitride film 23b becomes weak. Therefore, it is preferable to set the film thickness of the ferroelectric film 23a in a range of 1000 to 3000 angstrom. Further, the ferroelectric film 23a is not limited to tantalum oxide but can be formed of any dielectric material having a dielectric constant equal to or larger than 10. In this embodiment, the film thickness of the silicon nitride film 23b is set to 250 angstrom, but can be selected from a range of 50 to 2000 angstrom (preferably 50 to 1000 angstrom). When the film thickness of the silicon nitride film 23b is set in the above range, the silicon nitride film 23b may have a sufficiently large charge trapping ability and can be used as a memory element.
With the construction of this embodiment, a rela-tively strong electric field is applied to the silicon nitride, and therefore it is not necessary to set the composition ratio Si/N of the silicon nitride film 23b in a range of 0.85 to 1.1. However, if the composition ratio Si/N of the silicon nitride film 23b is set in the range of 0.85 to 1.1, a more effective memory function can be attained.
The construction of this embodiment can also be applied to the stagger type, inverted coplanar type and coplanar type thin film transistors. In this case, the gate insulation film is formed with a two-layered film having a ferroelectric film provided on the gate electrode and a silicon nitride film provided on the semiconductor layer. Fig. 13 shows an example in which this embodiment is applied to the stagger type thin film transistor, Fig. 14 shows an example in which this embodiment is applied to the inverted coplanar type thin film transistor, and Fig. 15 shows an example in which this embodiment is applied to the coplanar type thin film transistor. The thin film transistors with the memory function shown in Figs. 13 to 15 are similar in the basic construction to the thin film transistor of Fig. 12 except the laminated structure of the layers constituting the transistor, and therefore, the same reference numerals are attached to corresponding por-tions of the transistors and the explanation for the structure of Figs. 13 to 15 is omitted.
As described above, in this embodiment, the silicon nitride film 23b is made thin and is formed to have a charge trapping function and the ferroelectric film 23a is formed to provide a high withstanding voltage for the gate insulation film 23. In this way, the operation margin of the memory element can be increased without lowering the withstanding voltage of the gate insulation film 23. For example, if the ferro-electric film is formed with a film thickness of 1000 to 5000 angstrom and a dielectric constant of not less than 10, a sufficiently high withstanding voltage can be attained by the ferroelectric film. Further, if the silicon nitride film is formed with a film thickness of 50 to 2000 angstrom, then the silicon nitride film can have a sufficiently large charge trapping ability and can be used as a memory element. For example, the ferr-oelectric film can be formed of tantalum oxide. Since the dielectric constant of tantalum oxide is large, it becomes easy to obtain a high withstanding voltage for the gate insulation film.
Fourth Embodiment In this embodiment, a thin film transistor in which the degree of delta Vth of the hysteresis is large and which can be preferably used as a memory element is provided.
In this embodiment, a semiconductor layer is dis-posed between the gate electrode and the gate insulation film of the thin film transistor.
Now, the construction of the thin film transistor according to this embodiment is explained with reference to Figs. 16 and 17.
Fig. 16 is a cross sectional view of the thin film transistor according to this embodiment. The construc-tion of Fig. 16 is similar to that of Fig. lA except that a second semiconductor layer 18 is disposed between the gate electrode 2 and the gate insulation film 3.
The semiconductor layer 18 is formed as follows. First, a metal layer is formed on the substrate 1 and a semi-conductor layer of amorphous or polycrystalline silicon is formed to a thickness of 200 angstrom by the plasma CVD method. The metal layer and semiconductor layer are etched out by the photoetching process with the same photoresist film used as a mask so as to form the gate electrode and second semiconductor layer 18.

- ~oo~

Fig. 17 shows the VG-ID characteristic of the thin film transistor with the construction of Fig. 16. As shown in Fig. 17, the degree of delta Vth of the hyste-resis in the VG-ID characteristic of the thin film tran-sistor according to this embodiment is extremely large.
The possible reason for the increased degree of delta Vth is that charges are stored in the interface between the gate insulation film 3 and the second semiconductor layer 18 so as to enhance the charge storing ability of the thin film transistor.
As described above, in this embodiment, the hys-teresis of the VG-ID characteristic can be made larger and the thin film transistor can be used as a memory element.
The thin film transistor of Fig. 16 is formed with the inverted stagger structure, but this embodiment can be applied to the inverted coplanar type, coplanar type and stagger type thin film transistors. Further, the semiconductor layer 18 can be formed of amorphous silicon, polycrystalline silicon or monocrystalline silicon.
Fifth Embodiment In the embodiment of Fig. 16, a single semiconduc-tor layer is additionally provided. However, this invention is not limited to this. For example, it is possible to additionally provide a plurality of semicon-ductor layers in the thin film transistor as shown in Fig. 18.
In Fig. 18, a gate electrode 2 of metal such as chromium is formed to a thickness of 1000 angstrom on an insulation substrate 1. A gate insulation layer 33 is formed to a thickness of 2500 angstrom on the gate elec-trode 2 so as to insulatively cover the gate electrode 2. The insulation layer 33 is formed with a laminated structure of silicon nitride films 34A to 34C and amor-phous silicon (semiconductor) films 35A and 35B which are alternately arranged. Each of the films is formed to a thickness of approx. 500 angstrom by the plasma CVD method or the like. The lamination order can be reversed and the number of laminated films is not limited to 5. A semiconductor layer 4, n-type semicon-ductor layer 5, and source and drain electrodes 6 and 7are formed on the gate insulation layer 33. As in the case of the embodiment of Fig. 17, the degree of delta Vth of the hysteresis in the VG-ID characteristic of the thin film transistor according to this embodiment is enoughly large. Therefore, the thin film transistor of this embodiment can be used as a memory element.
The same effect can be attained by using polycr-ystalline silicon layers or monocrystalline silicon layers instead of the amorphous silicon layers 35A and 35B. In the above embodiment, the inverted stagger type thin film transistor is shown, but this embodiment can also be applied to inverted coplanar type, coplanar type and stagger type thin film transistors.
Sixth Embodiment When the gate insulation film 3 is formed by the CVD method, the composition ratio (Si/N) of deposited silicon nitride may vary depending on variation in the interface condition of the deposited surface (the sur-face of the substrate 1 and the surface of the gate electrode 2) of silicon nitride and variation in the substrate temperature. For this reason, the charge trapping abilities of different portions of the gate insulation film thus formed may vary from each other, causing variation in the memory characteristic of the transistor.
In this embodiment, a thin film transistor having an adequate (little variation) charge trapping function is provided. In this embodiment, the composition ratio of silicon atoms to nitrogen atoms of the gate insulation film is changed in a thickness direction thereof and the composition ratio Si/N of a partial area of the gate insulation film in the thickness direction is set to 1Ø
Now, the thin film transistor with the memory func-tion is explained in detail with reference to Figs. 19A
to 22.
Fig. l9A and l9B are cross sectional and plan views of the thin film transistor with the memory func-tion according to this embodiment. In order to attain the thin film transistor of this construction, a gate 8~

electrode 2 is formed on an insulation substrate 1 of glass, for example. Then, a gate insulation film 43 is formed on the gate electrode 2 and an i-type amor-phous silicon layer 4 is formed on the gate insulation film 43. An n-type amorphous silicon layer 5 and source and drain electrodes 6 and 7 are formed on the i-type semiconductor layer 4. As shown in Fig. 19B, the gate electrode 2 is connected to a gate line 2a and the source and drain electrodes 6 and 7 are respectively connected to source and drain lines 6a and 7a.
The gate insulation film 43 is formed of silicon nitride (SiN) and with a film thickness of approx.
2000 angstrom. The composition ratio (Si/N) of silicon atoms Si to nitrogen atoms N varies in a direction of the gate insulation film 3 and the composition ratio Si/N of a partial area (layer) of the gate insulation film 43 is set to 1Ø
Fig. 20 is a model diagram showing the distribution of silicon atoms Si and nitrogen atoms N of the gate insulation film 43. The composition ratio Si/N of sili-con atoms Si to nitrogen atoms N of the gate insulation film 43 varies from approx. 0.75 to 1.15 in a direction from the gate electrode 2 (lower side in Fig. 20) to the i-type semiconductor layer 4 (upper side in Fig. 20).
The area in which Si/N=1.0 lies in a position slightly deviated from the central position to the i-type semi-conductor layer 4.

Figs. 21A to 21D show the manufacturing process of the thin film transistor with the memory function according to this embodiment. The manufacturing process is explained below.
As shown in Fig. 21A, the gate electrode 2 and gate line 2a are formed on the insulation substrate 1. The gate electrode 2 and gate line 2a are formed by deposit-ing metal such as chromium (Cr) on the substrate 1 to a thickness of 1000 angstrom by the vapor deposition lo method, sputtering method or the like and then pattern-ing the metal film by the photolithographic method.
After this, the gate insulation film 43 of silicon nitride is formed to a thickness of 2000 angstrom on the resultant structure. Then, the semiconductor layer 4 is formed to a thickness of 1500 angstrom on the gate insu-lation film 43, thus completing the semiconductor struc-ture shown in Fig. 21B.
The deposition of silicon nitride by the CVD method is effected while the flow rate of silicon gas SiH4 is continuously increased and the flow rate of ammonia gas NH3 iS continuously decreased with the total sum of the flow rate of silane gas SiH4 and ammonia gas NH3 kept constant. In this case, the flow rate of silane gas SiH4 (SiH4 [SCCM] (Standard Cubic Centimeter per Minute)) and the flow rate of ammonia gas NH3 (NH3 [SCCM]) are so selected that the ratio of SiH4 [SCCM] to NH3 [SCCM] will be set to substantially 1:2 in the ;~0~1~82 initial period of deposition of silicon nitride and the ratio of SiH4 [SCCM] to NH3 [SCCM] will be set to sub-stantially 1:1 in the end of the deposition.
When silicon nitride is deposited while the flow rate ratio (SiH4 [SCCM]/NH3 [SCCM]) of silane gas SiH4 to ammonia gas NH3 iS continuously changed with time, the composition ratio of silicon atoms Si to nitrogen atoms N in a film thickness direction of the gate insu-lation film 43 formed by the deposition is continuously changed. Further, the composition ratio Si/N of the initially deposited SiN is approx. 0.75 and the composi-tion ratio Si/N of the finally deposited SiN is approx.
1.15. As a result, a layer (area) whose composition ratio Si/N is 1.0 is provided in part of the film.
Fig. 22 shows the result of measurement of the relation between the flow rate ratio ( SiH4 [SCCM]/NH3 [SCCM]) of silane gas SiH4 to ammonia gas NH3 and the composition ratio ( Si/N) of silicon atoms Si to nitrogen atoms N in the deposited silicon nitride film. Fig. 22 shows the measurement result obtained when silicon nitride is deposited under a condition that the sub-strate temperature is set at 250 C, the pressure is set at 0.5 Torr, the flow rate of nitrogen gas N2 which is an atmospheric gas is set at 390 [SCCM] (constant), and the total flow rate of silane gas SiH4 and ammonia gas NH3 iS set at 90 [ SCCM] ( constant).
As is clearly seen from Fig. 22, the composition ;~

ratio Si/N of the silicon nitride deposited under a con-dition that the flow rate ratio SiH4 [SCCM]/NH3 [SCCM]
of silane gas SiH4 to ammonia gas NH 3 is set to approx. 30/60 (SiH4 [SCCM] : NH3 [SCCM] = 1:2) is approx. O. 75. The composition ratio Si/N of the silicon nitride deposited under a condition that SiH4 [SCCM]/NH3 [SCCM] is set to approx. 45/45 (SiH4 [SCCM] : NH3 [SCCM]
= 1:1) is approx. O. 75. Further, the composition ratio Si/N of the silicon nitride deposited under a con-dition that the flow rate SiH4 [SCCM]/NH3 [SCCM] iS setto approx. 42/48 is approx. 1Ø
Therefore, if silicon nitride is deposited while the flow rate of silane gas SiH4 to ammonia gas NH3 is changed from approx. 1: 2 to approx. 1:1, the composition ratio Si/N of a partial area (layer) of the gate insula-tion film 43 can be set to 1.0 irrespective of variation in the substrate temperature and variation in the inter-face condition on which silicon nitride is deposited.
The semiconductor layer 4 is formed by deposition after the deposition of the gate insulation film 43 by using a mixed gas of silane and hydrogen by the plasma CVD method.
After the semiconductor layer 4 is formed, it is patterned into a shape of the element region by the photolithographic method. Then, an amorphous silicon - layer 5 having n-type impurity such as phosphorus (P) doped therein and a metal film 8 of chromium (Cr) or the like which is used as source and drain electrodes are deposited on the resultant structure, thus forming a structure as shown in Fig. 21B. Further, the n-type semiconductor layer 5 is deposited to a thickness of 250 angstrom by using a mixed gas of silane, phosphine and hydrogen by the plasma CVD method, and the metal film 8 is deposited to a thickness of 1000 angstrom by the vapor deposition method or sputtering method.
The metal film 8 and n-type semiconductor layer 5 are patterned by the photolithographic method to form the source electrode 6, source line 6a, drain electrode 7 and drain line 7a as shown in Fig. 21D. In this way, a thin film transistor with the memory function as shown in Figs. 19A and 19B is completed.
In this embodiment, the composition ratio of sili-con atoms to nitrogen atoms of the gate insulation film 43 changes in the film thickness direction. Therefore, the composition ratio of a partial layer of the gate insulation film 43 is set to 1Ø The gate insulation film 43 formed of silicon nitride has an optimum charge trapping function in the area whose composition ratio Si/N is set at or near 1Ø Therefore, the thin film transistor of this embodiment has a stable memory function.
In this embodiment, the composition ratio of the area near the gate electrode 2 of the gate insula-tion film 43 is set near the stoichiometric ratio 2~0~8~

(Si/N=0.75). The silicon nitride film having Si/N
of 0.75 has a high insulation property. That is, in this embodiment, the withstanding voltage of the gate insulation film 43 is high and a leak current flowing between the gate electrode 2 and the source and drain electrodes 6 and 7 is small. Further, if that area of the gate insulation film 43 whose composition ratio Si/N
is 1.0 is made thin, the hysteresis of the vG-ID chara-cteristic becomes large, enhancing the memory function.
Fig. 23 shows the gate voltage VG-drain current ID
characteristic of the thin film transistor according to this embodiment. The degree of delta Vth of the hyst-eresis of the thin film transistor with the memory func-tion is as large as approx. 40 v.
In the above explanation, the composition ratio Si/N is changed from 0.75 to 1.15, but it can be changed from 1.15 to 0.75. Further, it is possible to use another composition ratio range such as a range of 0.9 to 1.1.
In the above embodiment, the inverted stagger type thin film transistor with the memory function is explained. However, this embodiment can also be applied to the inverted coplanar type and coplanar type thin film transistors with the memory function.
In the above explanation, each embodiment is sepa-rately explained for easy understanding. However, the above embodiments can be combined. For example, the 2~0~

gate insulation film 3 of the thin film transistor of the fourth embodiment shown in Fig. 16 can be formed such that the composition ratio thereof can be continu-ously changed in the same manner as in the case of the insulation film 43 shown in Fig. 20. Further, the other embodiments can be variously combined.
Next, the construction and operation of a memory circuit using the thin film transistor with the memory function of the above construction is explained with reference to Fig. 24. As shown in Fig. 24, the current path of a transistor TM used as a memory element is series-connected to the current path of a selection transistor TS to form a transistor pair. The selection transistor TS is turned on when a voltage having an absolute value larger than a predetermined value (for example, higher than +10 v or lower than -10 v) is applied to the gate electrode thereof. A plurality of pairs of the transistors TM and TS are arranged in a matrix form. The gates of the transistors TM and TS on the same row are commonly connected to a corresponding one of gate lines (word line) GL. The current paths of the selection transistors TS on the same column are com-monly connected at one end to a corresponding one of drain lines DL. Further, the current paths of the mem-ory transistors TM on the same column are commonly con-nected at one end to a corresponding one of source lines (bit line) SL.

8~

The gate lines GL are connected to a row decoder RD. The drain lines DL and source lines SL are con-nected to a column decoder CD. The source lines SL are also connected to a sense amplifier SA. The sense amplifier SA is connected to a reference voltage generating circuit RG. The row decoder RD is supplied with a row address, write-in control signal, readout control signal and erasing command signal. The column decoder CD is supplied with a column address, write-in control signal, readout control signal and erasing com-mand signal.
A) A data write-in process (writing data of logic "l") with the above construction is explained below.
First, a row address and a column address for specifying one of the memory transistors TM into which data is written are supplied to the row decoder RD and the column decoder CD and the write-in signal is set to an active level. The row decoder RD sets the voltage of the gate line GL on the row which is specified by an input signal to Vp/2, for example, and sets voltages of the other gate lines to 0 V. For example, in a case where the gate voltage can be changed in a range of +40 V to -40 V, Vp/2 is set to 20 V, for example. The column decoder CD sets the voltages of the drain line DL
and source line SL on the column selected by the input signal to -Vp/2 (-20 v)~ for example, and sets the volt-ages of the other drain lines and source lines to o v.

2~

The selection transistor TS is turned on in response to the gate voltage and a voltage of -Vp/2 is applied to the source and drain electrodes of the memory tran-sistor. Therefore, a voltage vp or 40 V is applied between the gate and drain, that is, across the gate insulation film of the memory transistor TM. As a result, charges are trapped in the gate insulation film of the selected memory transistor, thereby complet-ing the operation of writing data "1".
B) Next, the data erasing (writing data of logic "0") method is explained below.
First, a row address and a column address for specifying one of the memory transistors TM having data to be erased are supplied to the row decoder RD and the column decoder CD and the erasing signal is set to an active level. The row decoder RD sets the voltage of the gate line GL on the row which is specified by an input signal to -Vp/2, for example, and sets voltages of the other gate lines to 0 V. The column decoder CD sets the voltages of the drain line DL and source line SL on the column selected by the input signal to +vp/2, for example, and sets the voltages of the other drain lines and source lines to 0 v. The selection transistor TS is turned on in response to the gate voltage and a voltage of +vp/2 is applied to the source and drain electrodes of the memory transistor. Therefore, a voltage -vp is applied between the gate and drain of the memory transistor TM. As a result, charges are trapped in the gate insulation film of the selected memory transistor, thereby completing the operation of writing data "O".
C) The operation of reading out data from the mem-ory element is explained below.
First, a row address and a column address for specifying one of the memory transistors TM from which data is read out are supplied to the row decoder RD and the column decoder CD and the readout signal is set to an active level. The row decoder RD sets the voltage of the gate line GL on the row which is specified by an input signal to VON (for example +10 V) and sets volt-ages of the other gate lines to 0 V. The column decoder CD sets the voltage of the drain line DL on the column selected by the input signal to VD (for example, 10 v) and sets the source line SL on the selected column into the electrically floating state. The selected transis-tors TS and TM are turned on in response to the gate voltage and a current ID flows from the activated drain line into the sense amplifier SA via the transistors TS
and TM and the source line SL. The sense amplifier SA
compares a voltage caused on the source line SL by the current ID with a reference voltage from the reference voltage generating circuit RG. The level of the current ID is highly dependent on the polarity of the charge trapped in the memory transistor TM, that is, data stored in the memory transistor TM. As a result, the 2~0~

voltage of the source line SL varies widely depending on data stored in the memory transistor TM. Therefore, the sense amplifier SA determines data corresponding to the charge trapped in the gate insulation film of the memory transistor TM based on the comparison result and outputs the data.
Next, another example of the memory circuit is explained with reference to Fig. 25.
As shown in Fig. 25, the current path of a transis-tor TM used as a memory element is series-connected to the current path of a selection transistor TS to form a transistor pair. For example, the selection transistor TS is formed of an N-channel MOS transistor. A plural-ity of pairs of the transistors TS and TM are arranged in a matrix form. The gates of the memory transistors TM on the same row are commonly connected to a first gate line GLl and the gates of the selection transistors TS on the same row are commonly connected to a second gate line GL2. The current paths of the selection tran-sistors TS on the same column are commonly connected atone end to a drain line DL. The current paths of the memory transistors TM on the same column are commonly connected at one end to a source line SL. The gate lines GLl and GL2 are connected to a row decoder RD.
The drain lines DL and source lines SL are connected to a column decoder CD. The source lines SL are also con-nected to a sense amplifier SA. The sense amplifier SA

is connected to a reference generating circuit RG. The row decoder RD is supplied with a row address, write-in control signal, readout control signal and erasing com-mand signal, and the column decoder CD is supplied with a column address, write-in control signal, readout control signal and erasing command signal.
Now, the operation of the memory circuit shown in Fig. 25 is explained.
A) A data write-in operation (writing data of logic "1") is explained below.
First, a row address and a column address for specifying one of the memory transistors TM into which data is written are supplied to the row decoder RD and the column decoder CD and the write-in signal is set to an active level. The row decoder RD sets the voltage of the first gate line GLl on the row which is specified by an input signal to Vp/2 (20 V), for example, sets the voltage of the second gate line GL2 on the selected row to VON (10 V) and sets voltages of the other gate lines to 0 V. The column decoder CD sets the voltages of the drain line DL and source line SL on the column selected by the input signal to - Vp/2 (-20 V), for example. The selection transistor TS is turned on in response to the voltage VON, causing the voltage Vp to be applied across the gate insulation film of the selected memory transis-tor TM. As a result, charges are trapped in the gate insulation film of the selected memory transistor, thereby completing the operation of writing data "1".
B) Next, the data erasing operation (writing data of logic "0") is explained below.
First,-a row address and a column address for specifying one of the memory transistors TM having data to be erased are supplied to the row decoder RD and the column decoder CD and the erasing signal is set to an active level. The row decoder RD sets the voltage of the first gate line GLl on the row which is specified by an input signal to -Vp/2, for example, sets the voltage of the second gate line GL2 to VON and sets voltages of the other gate lines to 0 V. The column decoder CD sets the voltages of the drain line DL and source line SL on the column selected by the input signal to +vp/2, for example, and sets the voltages of the other drain and source lines to 0 V. The selection transistor TS is turned on in response to the voltage VON. Therefore, a voltage -Vp is applied across the gate insulation film of the selected memory transistor TM. As a result, charges are trapped in the gate insulation film of the selected memory transistor, thereby completing the operation of writing data "0".
C) The operation of reading out data from the memory element is explained below.
First, a row address and a column address for specifying one of the memory transistors TM from which data is read out are supplied to the row decoder RD and 201~

the column decoder CD and the readout signal is set to an active level. The row decoder RD sets the voltage of the first gate line GL on the row which is specified by an input signal to VSELECT (O V), sets the voltage of the second gate line GL2 on the selected row to VON and sets voltages of the other gate lines to 0 V. The column decoder CD sets the voltage of the drain line DL
on the column selected by the input signal to VD ( for example, 10 V) and sets the source line SL on the selected column into the electrically floating state.
The selected transistors TS and TM are turned on in response to the gate voltages VSELECT and VON and a cur-rent ID flows from the activated drain line DL into the sense amplifier SA via the transistors TS and TM and the source line SL. The level of the current ID iS highly dependent on the contents of data stored in the memory transistor TM. As a result, the voltage of the source line SL varies depending on data stored in the memory transistor TM. The sense amplifier SA compares a volt-age caused on the source line SL by the current ID withthe reference voltage from the reference voltage gene-rating circuit RG. The sense amplifier SA determines data corresponding to the charge trapped in the gate insulation film of the memory transistor TM based on the comparison result and outputs the data.
The above-described circuit construction and volt-age relation are explained only as one example. For - 2~0~82 example, the relation between the voltage used for the write-in operation and that used for the erasing opera-tion can be reversed. Further, the voltage applied between the gate electrode and the source and drain electrodes to write data can be set to 10 V, 20 V or 30 v, for example.
As described above, according to this invention, a memory function can be added to the conventional thin film transistor and the property thereof can be enhanced.

Claims

1. A memory element comprising:
a thin film transistor;
a semiconductor layer;
a source electrode electrically connected to said semiconductor layer;
a drain electrode electrically connected to said semiconductor layer and formed separately from said source electrode;
a gate electrode for controlling formation of a channel in said semiconductor layer; and insulation film means for isolating said gate electrode from said semiconductor layer and causing a hysteresis in the relation between the drain current and gate voltage, said insulation film means including a silicon nitride film whose composition ratio Si/N of silicon to nitride lies within a range of 0.85 to 1.1.

2. A memory element according to claim 1, wherein said insulation film means includes a first silicon nitride film (13b) having a function of trapping charges, and a second silicon nitride film (13a) of a composition different from that of said silicon nitride film.

3. A memory element according to claim 2, wherein said insulation film means includes said silicon nitride film (13b) whose composition ratio Si/N lies in a range of 0.85 to 1.1, and said silicon nitride film (13a) whose composition ratio Si/N lies in a range of 0.7 to 0.8.

4. A memory element according to claim 1, wherein said insulation film means includes a silicon nitride film (23b) and a film (23a) formed of ferroelectrical material.

5. A memory element according to claim 1, wherein said insulation film means is constituted by a laminated structure of at least one insulation layer (3) and at least one semiconductor layer (18).

6. A memory element according to claim 1, wherein said insulation film means includes a silicon nitride film (22A) whose composition ratio Si/N varies in the thickness direction thereof and which has an area having a composition ratio of 1Ø

7. A memory element according to claim 1, wherein said memory element comprises means for writing data into said memory element, means for erasing data stored in said memory element, and means for reading out data stored in said memory element.

8. A memory element according to claim 1, wherein said memory element further includes a glass substrate (1), and said thin film transistor is formed on the glass substrate (1).

9. A memory element according to claim 1, wherein said memory element comprises thin film transistors (TM) in a matrix form.

10. A memory element according to claim 9, wherein said memory element further comprises means (TS, RD, CD) for selecting at least one of the thin film transistors (TM), and means (TS, RD, CD, RG) for writing data into a selected thin film transistor, erasing data stored in a selected thin film transistor, and reading data stored in a selected thin film transistor.

11. A method for using a thin film transistor memory element as claimed in claim 1, comprising the steps of:
preparing a thin film transistor having a semiconductor layer (4), a source (6), a drain (7), a gate (2) and a gate insulation film;
writing first data into said thin film transistor by applying a first voltage to said gate insulation film;

writing second data, different from the first data, by applying a second voltage, different from that of the first voltage, to said gate insulation film; and reading data stored in said thin film transistor according to a current which flows in said channel and whose level is changed by differences in the voltages applied to gate insulation film.

12. A method according to claim 11, wherein said first and second voltages are of opposite polarities.

13. A method according to claim 11, wherein said method further includes the steps of arranging said thin film transistors in a matrix form and selecting a desired one of said thin film transistors, and said steps of writing the first data and writing and reading out the second data are effected with respect to said selected thin film transistor.