CA1250894A - Method for the qualitative and quantitative determination of the hydrogen isotopes, protium, deuterium and tritium, and system for implementing the method - Google Patents
Method for the qualitative and quantitative determination of the hydrogen isotopes, protium, deuterium and tritium, and system for implementing the methodInfo
- Publication number
- CA1250894A CA1250894A CA000505017A CA505017A CA1250894A CA 1250894 A CA1250894 A CA 1250894A CA 000505017 A CA000505017 A CA 000505017A CA 505017 A CA505017 A CA 505017A CA 1250894 A CA1250894 A CA 1250894A
- Authority
- CA
- Canada
- Prior art keywords
- hydrogen
- water
- sample
- isotopes
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 80
- 239000001257 hydrogen Substances 0.000 title claims abstract description 80
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 23
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 title claims abstract description 9
- 229910052805 deuterium Inorganic materials 0.000 title claims abstract description 9
- YZCKVEUIGOORGS-NJFSPNSNSA-N Tritium Chemical compound [3H] YZCKVEUIGOORGS-NJFSPNSNSA-N 0.000 title claims abstract description 8
- 229910052722 tritium Inorganic materials 0.000 title claims abstract description 8
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 title claims abstract description 6
- 241000720974 Protium Species 0.000 title claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 229910001868 water Inorganic materials 0.000 claims abstract description 63
- 238000005259 measurement Methods 0.000 claims abstract description 40
- 238000001228 spectrum Methods 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000002094 microwave spectroscopy Methods 0.000 claims abstract description 14
- 239000007789 gas Substances 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 229910010293 ceramic material Inorganic materials 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000012777 electrically insulating material Substances 0.000 claims description 3
- -1 vapor Substances 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 abstract description 4
- 239000012535 impurity Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 2
- 239000000523 sample Substances 0.000 description 31
- 238000001816 cooling Methods 0.000 description 19
- 241000894007 species Species 0.000 description 9
- 230000000155 isotopic effect Effects 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000001514 detection method Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000002044 microwave spectrum Methods 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 230000003321 amplification Effects 0.000 description 3
- 238000003199 nucleic acid amplification method Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002483 hydrogen compounds Chemical class 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000003868 zero point energy Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N22/00—Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/22—Hydrogen, per se
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- General Health & Medical Sciences (AREA)
- Pathology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Analysing Materials By The Use Of Radiation (AREA)
- Measurement Of Radiation (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Sampling And Sample Adjustment (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3510867.3 | 1985-03-26 | ||
| DE19853510867 DE3510867A1 (de) | 1985-03-26 | 1985-03-26 | Verfahren zur qualitativen und quantitativen bestimmung der wasserstoffisotope protium, deuterium und tritium und anlage zur durchfuehrung des verfahrens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1250894A true CA1250894A (en) | 1989-03-07 |
Family
ID=6266333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000505017A Expired CA1250894A (en) | 1985-03-26 | 1986-03-25 | Method for the qualitative and quantitative determination of the hydrogen isotopes, protium, deuterium and tritium, and system for implementing the method |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4766081A (en, 2012) |
| JP (1) | JPS61230050A (en, 2012) |
| BE (1) | BE903544A (en, 2012) |
| CA (1) | CA1250894A (en, 2012) |
| DE (1) | DE3510867A1 (en, 2012) |
| FR (1) | FR2579751B3 (en, 2012) |
| GB (1) | GB2175093B (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5120659A (en) * | 1989-06-26 | 1992-06-09 | Mine Safety Appliances Company | Deuterated water test method |
| DE4104075C1 (en, 2012) * | 1991-02-11 | 1992-03-19 | Bruker Analytische Messtechnik Gmbh, 7512 Rheinstetten, De | |
| US6159427A (en) * | 1999-04-19 | 2000-12-12 | Ontario Power Generation Inc. | Apparatus for tritium-in-water monitoring |
| DE10163615B4 (de) * | 2001-12-21 | 2004-02-05 | Siemens Ag | Verfahren und Vorrichtung zur Detektion von Leckagen in wassergekühlten elektrischen Maschinen |
| WO2005114176A2 (en) * | 2004-05-19 | 2005-12-01 | University Of Florida | Methods and systems for detecting hydrogen |
| US8597471B2 (en) | 2010-08-19 | 2013-12-03 | Industrial Idea Partners, Inc. | Heat driven concentrator with alternate condensers |
| RU2558433C1 (ru) * | 2014-02-17 | 2015-08-10 | Федеральное государственное бюджетное учреждение науки Южный научный центр Российской академии наук (ЮНЦ РАН) | Способ определения количественного содержания дейтерия в воде и водных растворах |
| DE102014209305B4 (de) * | 2014-05-16 | 2016-04-07 | Umicore Ag & Co. Kg | Methode zur Detektion des Alterungsgrades von Abgaskatalysatoren |
| CN115326962B (zh) * | 2022-08-15 | 2024-04-02 | 中国科学院西北生态环境资源研究院 | 一种天然气中硫化氢的氢同位素测定装置和方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE582035A (en, 2012) * | 1958-08-30 | |||
| DE1077893B (de) * | 1958-12-08 | 1960-03-17 | Linde Eismasch Ag | Verfahren und Vorrichtung zur Bestimmung des Gehaltes an Deuteriumhydrid im Wasserstoff |
| US3208826A (en) * | 1961-02-23 | 1965-09-28 | Edward M Arnett | Method of analyzing water samples for deuterium content |
| DE1209776B (de) * | 1964-06-12 | 1966-01-27 | Dr Helmut F Simon | Verfahren und Vorrichtung zur Messung der Radioaktivitaet C- und/oder H-markierter Verbindungen |
| HU163311B (en, 2012) * | 1972-02-09 | 1973-07-28 | ||
| US4066404A (en) * | 1976-08-02 | 1978-01-03 | Phillips Petroleum Company | Determination of deuterium concentration in water |
| US4464338A (en) * | 1980-10-24 | 1984-08-07 | The United States Of America As Represented By The Secretary Of The Interior | In situ tritium borehole probe for measurement of tritium |
-
1985
- 1985-03-26 DE DE19853510867 patent/DE3510867A1/de active Granted
- 1985-10-23 FR FR8515729A patent/FR2579751B3/fr not_active Expired
- 1985-10-30 BE BE1/011371A patent/BE903544A/fr not_active IP Right Cessation
-
1986
- 1986-02-21 GB GB08604333A patent/GB2175093B/en not_active Expired
- 1986-03-04 US US06/835,989 patent/US4766081A/en not_active Expired - Fee Related
- 1986-03-25 CA CA000505017A patent/CA1250894A/en not_active Expired
- 1986-03-26 JP JP61066097A patent/JPS61230050A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61230050A (ja) | 1986-10-14 |
| GB8604333D0 (en) | 1986-03-26 |
| DE3510867C2 (en, 2012) | 1990-03-08 |
| US4766081A (en) | 1988-08-23 |
| GB2175093A (en) | 1986-11-19 |
| GB2175093B (en) | 1989-01-05 |
| BE903544A (fr) | 1986-02-17 |
| DE3510867A1 (de) | 1986-10-16 |
| FR2579751B3 (fr) | 1987-10-23 |
| FR2579751A1 (fr) | 1986-10-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |