CA1246375A - Disintegration of wood - Google Patents

Disintegration of wood

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Publication number
CA1246375A
CA1246375A CA000486990A CA486990A CA1246375A CA 1246375 A CA1246375 A CA 1246375A CA 000486990 A CA000486990 A CA 000486990A CA 486990 A CA486990 A CA 486990A CA 1246375 A CA1246375 A CA 1246375A
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Canada
Prior art keywords
log
liquid
wood
jet
nozzle
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Expired
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CA000486990A
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French (fr)
Inventor
Marian Mazurkiewicz
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University of Missouri System
Original Assignee
University of Missouri System
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Priority to CA000486990A priority Critical patent/CA1246375A/en
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Abstract

Abstract of the Disclosure Disintegration of wood especially for production of wood pulp for making paper, involving subjecting a body of wood, more particularly a debarked log, to liquid jet action with the energy of the liquid as it impacts on the body such as to effect disintegration of the body into particles.

Description

~sdpd UMO 1303 , I
~ ~24~3t7~ j D I S I NTEGRAT I ON OF WOOD
Background of the Invention This invention relates to the disintegration of wood, and more particularly ~o methods of and apparatus for reducing a body of wood to a multiplicity of particles.
The invention is especially concerned with the dis-in~egration of bodies of wood, and more particularly debarked logs, to produce wood particles ~or production of wood pulp for making paper.
~eretofore, generally standard practice for making wood pulp for paper production has involved the m~chanical comminution of debarked logs, utilizing knives for chippin~
the logs, or grinding wheels or grindstones for grinding the logs. In either case, relatively high initîal equipment cost and relatively high energy (power) consum~tion are involved, and the knives need sharpening and the grindstones need dressing, which is time-consuming and costly. Not only that, cutting and grinding may produce crushed fibers, which may be detrimental to the p-oduction of good quality pulp.
It is understood that much of the newsprint cur-rently used is made from a mixture of 70% to 80% ground wood and the remainder unbleached sulphite or semi-bleached sul-phate pulp. While ground wood pulp is of lower cost than chemical pulp, the cost of ground wood pulp is still rela-tively high because the grinding operatian involves relatively high power consu~p~ion. Use o~ ground wood pulp may also have the disadvantage that paper containing a high percentage of ground wood is adve~sely affected as to color and strength qualities by exposure to sunlight, heat and air, and, is therefore less desirable for use in making newsprint, which must be capable of being fed through modern high speed presses without web breakage, and also capable of accepting inks with good printability.
~, ,~,,
- 2 - 64725-409 ~2~ 75 With regard to energy consumption involved in grinding wood, energy is usually expressed in terms of horsepower/tons per day of air-dried pulp produced, i.e. horsepower input divided by the tons of pulp produced per day. The energy supplied to the grindstone is consumed in overcoming the friction between the stone and the surface of the wood being ground, and it is believed that almost all of it is transmitted to sensible heat in the water which is sprayed on the stone, and that only a small amount of the energy is absorbed in forming new surfaces as particles (fibers) separate from the wood. For example, in "Wood Machining Processes", by Peter Koch, published by Ronald Press Company, New York, N.Y.
1964, the average power requirement to yield ninety to ninety-five percent fiber from the original log volume is stated as 65 to 75 horsepower per day per ton (on an oven dry basis). According -to "Pulp and Paper", by James P. Casey, published by Inter-Science Publisher, Inc., New York, N.Y. 1952, at a grinding pressure of 20 psi, the power consumption for a number of species of wood is as follows:
Spruce70 hp/day~ton Hemlock108 hp/day/ton Jack Pine105 hp/day/ton Shortleaf Pine125 hp/day/ton Poplar140 hp/day/ton Cottonwood215 hp/day/ton Summary of the Invention Among the several objects of the invention may be noted the provision of improved methods of more economically reducing a body of wood, and more particularly a log, to particles B
- 3 ~ 64725-409 ~637S

especially for making wood pulp, although possibly useful for producing particles for other purposes; the provision of such methods which may attain improved economy by reduction of initial equipment cost, reduction of power consumption, and elimination of sharpening and dressing; and the provision of such methods which, in addition to the stated economic advantage, produce particles, and especially wood fibers, of requisite quality for making good quality pulp for good quality paper production.
In general, the method of this inventioninvolves reducing a body of wood having a length and girth to a multiplicity of wood fibers of lengths suitable for use in the manufacture of paper.
The method comprises the steps subjecting the body of wood to liquid jet means comprising at least one substantially coherent continuous stream of liquid at a delivery pressure of from about
4,000 psi to about 60,000 psi, and effecting relative movement of said jet means and the body so that the liquid as it impacts on the body traverses a path on the body at a relatively low velocity of less than about fifteen feet per minute whereby the energy of the liquid as it impacts on the body is sufficiently concentrated and of sufficient duration to efEect disintegration of the body of wood into said multiplicity of wood fibers, said disintegration involving separation of the wood fibers in the body of wood without substantial damage to the fibers, said traversal path followed by the impacting liquid comprising a plurality of closely spaced reaches disposed over at least a substantial portion of the entire outer surface of the body whereby the body is substantially completely disintegrated over a relatively large area e~tending both girthwise and lengthwise ~ 3a - 64725-409 ~2~i3~

with respect to the body.
Other objects and features will be in part apparent and in part pointed out hereinafter.
Brief Description of the Drawin~~
Figure 1 is a perspective, with parts broken away and shown in section, of a first embodiment of apparatus of this invention;
Figure 2 is a detail, partly in section, showing the tip of a nozzle of the Figure 1 embodiment;
Figure 3 is a view illustrating a second embodiment of the apparatus;
Figure 4 is a detail, partly in section, showing the tip of a nozzle of the Figure 3 embodiment, the nozzle here being a rotary dual-orifice nozzle;
Figure 5 is a view illustrating a third embodi.ment of the apparatus;
Figure 6 is a view illustrating the trajectory on a log of a jet from a nozzle of the first embodiment as the log is fed past the nozzle at a relatively fast speed;
Figure 7 is a view illustrating the trajectory on a log of a jet from a nozzle of the first embodi.ment as the log is fed past the nozzle at a relatively slow speed;

~' 2sdpd UMO 1303 .
,. I
4 ~2~6~75 Fig. 8 is a YieW illustrating the trajectory on a log of a jet from a rotary nozzle of the Fig. 3 embodiment as the log is fed past the nozzle at relatvely slow speed and the nozzle is rotated at relatively slow speed;
Fig. 9 is a view illustrating the trajectory on a log of jets from a rotary nozzle of the Fig. 3 embodiment as the log is fed past the nozzle at relatvely fast speed and the nozzle is rotated at relatively fast speed;
Fig. 10 is a chart showing flow rate/pressure rela-10 tionships for nozzle orifices of different sizes, the nozzle orifice size being expressed in inches, also showing the horse power requirements;
Fig. 11 is a chart showing depth of removal/pressure relationships on a test in which a rotary nozzle was moved along the work 1.27 cm (0.5 in) from the work;
Fig. 12 is a chart showing depth of removal/pressure relationships on a test in which a rotary nozzle was moved y along the work L5.24 cm (6 in) from the work; and Fig 13 is a chart showing depth of removalJpressure 20 relationships on a tes~ in which the work was turned in a lathe and a non-rotary nozzle was moved along the work.
Corresponding reference characters indicate corre-sponding parts throu~hou~ the several views of the drawings.
.
Description of the Preferred Embodiments Referring to Fig. 1 of the drawings, a first embodi-ment of apparatus of this invention for carrying out the meth-od of this invention i5 shown basically to comprise means gen-erally indicated at 1 for subjecting a body of wood, which is to be reduced to a multiplicity of particles, to liquid jet 30 action with the energy of the liquid as it impacts on the body such as to effect disintegration of the body into particles.
Generally the liquid is water, although for wood pulping it ~A6~3~75 may be a chemical pulping liquid. The water may be at ambient temperature, or may be heated for wood pulping. Thus, it may be at a temperature in the range from about ~0C. to about 180C. The apparatus has means as will appear, generally in-dicated at 3, for effecting relative movement between the body of wood and the liquid such that the liquid impacts on the body in a trajectory having a longitudinal and a transverse component relative to the body. Typical trajectories are il-lustrated in Figs. 6 and 7. The apparatus is adapted for re-ducing a log L, more particularly an already debarked log, toa multiplicity of particles wherein the means 1 for subjecting the log to liquid jet action comprises a plurality of nozzles, each designated 5, for directing jets radially inwardly on the log. The jets are preferably coherent jets, but it is contem-plated that they may he fan, cavitated or pulsed jets. The means 3 for effecting the stated relative movement between the log and the nozzles effects this movement endwise and circum-ferentially of the log so that each jet impacts on the log in the stated trajectory having a longitudinal and girthwise com-ponent relative to the log.
More particularly, the Fig. 1 apparatus, as shown,comprises nozzle-holding means 7 in the form of an annular open-ended drum or cylinder suitably mounted as indicated at 9 for oscillation on its axis, which may be more or less hori-zontal, and preferably slightly inclined from one end of the drum, constituting the entrance end for a log, which is its left end as illustrated in Fig. 1, to its other (right) end.
The nozzles 5 are mounted in the cylindrical wall of the drum extending generally radially thereof, each nczzle generally comprising a tubular body 9 with a nozzle orifice member or tip 11 at its inner end (see Fig. 2). In the tip is the noz-zle orifice 13. Brass, sapphire and carbide tips have been used in preliminary tests. The nozzles may be mounted in the wall of the drum for radial adjustment in and out relative to 2sdpd UMO 1303 6 ~ 37~

the drum, being slidably adjustable in radial openings 15 in the wall, for example. As appears in F~g. 1, the nozzles may be arranged in a number of circular series spaced lengthwise of the drum, with the nozzles extending progressively farther inward in the successive circular series 15 to take into ac-count the progressive disintegration of the log as it is fed forward. Three such series are shown, the nozzles also being arranged in rows extending lengthwise of the d`rum.
At 17 is indica~ed a roller conveyor for supporting a log L in position for feeding the log endwise through the drum 7 from the entrance (left) end of the drum, enabling movement of the log 2~ by manually pushing it endwise through the drum for impact a~ jets of liquid from the no2zles 5 on the log as it passes ~hrough the drum. Obviouslyt the endwise feed of the log may be a suitably powered feed, as by use of a hydraulic pusher means or a chain puller means~ At 19 is gen-erally indicated means for effecting oscillation of the drum ~and hence the nozzl-s) through a selected arc and at a se- i lected rate so that each jet of liquid impacts on the log in the stated trajectory having a longi~udinal component and a transverse or girthwise component relative to~the log. The _ nozzles are supplied with liquid under relatively high pres-sure via flexible high-pressure sùpply lines as indicated at 21 supplied with the liquid from a high-pressure pump (not shown). The flexible supply lines permit the oscillation of drum and the nozzles.
In the operation of the apparatus, a debarked log is fed through the drum generally at a predetermined rate. As the log is fed through the drum, it is subjected to the liquid jet açtion of the jets of liquid directed radially inwardly on the log all around the log by the oscillating nozzles 5. The oscillation of the drum through an arc in conjunction with the axial feed of the log causes each jet to impact on the log in a trajectory having the desired longitudinal and girthwi~e 7 ~6~

trajectory relative to the log. Liquid is delivered from the nozzles 5 at such high pressure that the energy of the liquid as it impacts on the log is such as to effect disintegration of the log into particles. The pressure (hence the energy) and the trajectory may be controlled for control over the characteristics of the particles, as will be described later.
Generally, the log is completely disintegrated into particles by the jets, although it is intended that less than complete disintegration is within the scope of the invention. It will be observed that the inward stepping of the nozzles from the first to the third circular series of nozzles may be such that the standoff distance of the nozzle tips from the log passing through the drum is about the same for the successive series.
The drum 7 with its nozzles 5 is housed in a suitable shroud or housing such as indicated at 23 for collection of particles from the disintegration of the log and carrying the particles away by the liquid which effected the disintegration.
Figs. 6 and 7 illustrates the jet trajectories ob-tained by feeding logs through the drum at different rates.
In each case, the trajectory (i.e., the path of the jet where it impacts on the log) is generally sinusoidal on the curved surface of the log, extending lengthwise of the log, with the amplitude (representing the transverse component of the wave form) corresponding to the arc of oscillation of the jet and the pitch (frequency) determined by the log speed. Fig. 6 il-lustrates the wave form for a relatively fast moving log and Fig. 7 the wave form for a relatively slow moving log. Gen-erally, the particle size is directly proportional to the log speed, the faster the speed (Fig. 6) the larger the particles, and vice versa (Fig. 7). It will be understood that the num-ber and arrangement of nozzles is such that the jet trajecto-ries generally cover the entire surface of the log for com-plete disintegration of the log.

~`

8 ~ i3~7~

For the requisite energy of the liquid (e.g. water) as it impacts on the log to effect disintegration of the log into particles, the jet diameter (nozzle orifice diameter) may range from about 0.1 mm to about 5.0 mm and the liquid pres-sure as supplied to the nozzles should be above about ~,000 psi. For disintegration of the log into chips, the nozzle orifice diameter may be about 0.4 mm and the pressure about 20,000 psi. For disintegration of the log into fibers, the nozzle orifice diameter may be about 0.6 mm and the pressure about 10,000 psi. For disintegration of the log into powder, the nozzle orifice may be about 1.0 mm and the pressure about 60,000 psi.
Fig. 3 illustrates a second embodiment of the inven-tion generally corresponding to the Fig. 1 embodiment with the principal difference that each nozzle, here designated 5a, is a multi-orifice nozzle and is rotated around an axis extending generally radially with respect to the log. The rotation of the nozzles is indicated by the arrows Al. Fig. 4 illustrates a dual-jet nozzle 5a, having a tip 25 with two orifices each designated 27 therein, these orifices being angled at 15, for example, to the nozzle axis so that they diverge at an angle of 30 toward the exit. The nozzles may be mounted in a drum 7a similar to the drum 7 shown in Fig. 1, the drum 7a being oscillable like drum 7 as indicated by the arrow A2, and the nozzles being adjustable in and out as indicated by the arrow A3. Each nozzle may be rotated by suitable drive means such as indicated at 29 in Fig. 3.
Figs. 8 and 9 illustrate (enlarged), a small span of the jet trajectories obtained by feeding a log past a rotary nozzle, the latter rotating at different rates. In each case, the trajectory is generally cycloidal on the curved surface of the log, extending lengthwise sinusoidally of the log. Fig. 8 illustrates a small part o the cycloidal trajectory for a relatively slow moving log and relatively slow nozzle rotation 2sdpd UMO 1303 g ~ 637~

rate (e.g. 10 inches per minute log speed and 60 rpm nozzle rotation rate) and Fig. 9 illustrates a small part of the cy-cloidal trajectory for a relatively fast moving log and rela-tively high nozzle rotation rate (e.g. 15 inches per minute log speed and 220 rpm nozzle rotation rate~. The particle lengths derived by these trajectories are indicated at 33 and 35 in Figs. 8 and 9. Generally, it may be said that the length of the particles is in direct relationship to the log feed and in inverse relationship to the nozzle speed. In the case of a log fed through drum 7a, which is oscillating, the trajectories would be cycloidal and sinusoidal. I
Fig. 5 illust-rates a third embodiment of the inven-tion comprising a nozzle 5 operable by a robotic apparatus 37 in cooperation with the feed of the log L on conveyor 17 past the nozzle to generate the desired jet trajectory.
It is to be noted that the liquid jet is generated by a potential energy build-up prior to the liquid exiting the nozzles. The nozzle tr-ansforms this energy into kinetic ener-gy. According to ths Bernoulli equations, the jet velocity becomes:
._ ~ .
v=
.
where:
v = jet velocity p = pressure p = liquid density.
The flow rate of the jet stream eqUates to the cross-sectional area of stream multiplied by this stream velocity.
The cross-sectional area of the jet is related to the nozzle orifice cross-section area and the discharge coefficient~
which depends on the nozzle geometry and the quality of manu;-facture.

2sdpd UMO 1303 ~2~i375 The power required to produce the flow i5 given by the equation:

~ ~ Cd D4 ~ ~ p3/~

In this equation:
d = nozzle discharge coefficient D - nozzle orifice diameter p c fluid density p - generating pressure.
The impact C~ the jet on the body of wood separates 10 wood particles from tne body, the separating action generally ¦
increasing wi~h the energy impact per unit length of impact, and depending on the jet pressure, diameter, standoff distance of the nozzle from the work and the feed rate velocity. Gen-erally the separating ability increases with the energy input per unit length of cut.
The standor distance is belie~ed to be an important factor in the process. With a relatively small distance be-tween the nozzle and the work the jet has a good action At -greater distances, the jet action is adversely affected.
When the motîon of a regular coherent jet is abruptly stopped by a solid body, a very high pressure is created around the contact area. This approximates the water hammer pressure at the instant of impact and then decays to the hydrodynamic sta~nation pr-essure, which for incompressible f~ow is given by:
.
: p _ 1 p 0 V2 where:
p = the density of incompressible flow v = the normal component of the collision velocity.

'~

2sdpd UM0 1303 6375i During this impact a high velocity lateral flow is created. The velocity of this flow is several times larger than that o~ the iniet flow and is highly destructive tG
structural material such as wood.
Because of the strong wood anisotropy, it is diffi-cult to develop, from a theoretical aspect, the relationship - between water jet parameters and particle separation ability.
To obtain these, certain experiments were ca~ried out~ speci-fically in two groups: first with a rotary nozzle moved along the work with the work stationary, and second with a non-rotary nozzle moved along the work being turned in a lathe.
The cycloi~ nozzle experiment utilized a water jet nozzle having two closely spaced 1 mm diameter (0.04 in.) noz-zle ori~ices with an ~ncluded angle of 30 and were carried out on a test rig in which the nozzle was traversed along the work. The feed ra~e o~ the nozzle along the work was varied at levels of 30.48 cm/min (1 ft/min), 91.~ cm/min (3 ft/min), 152.2 cm/min (5 ft/min), and 304.8 cm/min (10 ft/min). The nozzle was rotated at a constant speed of 120 rpm. The experi-ment was carried out at pressures of 35 MPa (5000 psi), 70 MPa (10,000 psi), and 105 MPa (15,000 psi), and at standoff dis-tances of 1~27 cm (D.5 in.) and 15.24 cm (6 in.) from the work. As a sample~ a dried red oak log was used measuring - 30.48 cm x 30.48 cm x 244 cm ~12 in. x 12 in. x 8 ~t.)~ The traiectory developed by the je~s on the sample log are simple cycloids similar to those shown in Figs. 8 and 9. The para-metric equations of these curves are:

X. = vL t + r cos ~t Y~ = r sin ~t 2sdpd UMO 1303 37~

where:
r - radius o~ circle of impact VL = feed rate . t = time The size o~ the particles will be governed by the linear feed rate and the nozzle rQtational speed~ and can be furthe~ controlled by adding nozzles to the sxstem. Thus;
practically any wood particle length can be achieved by ad-justing the relationship be~ween the feed rate and the nozzle rpm. These two parameters and the jet radius control the vel-ocity of the point.o~ jet impact which can be found from the equation:

Vc = vL ~ ~2x - 2~ r vL sin ~t where:
VL = fe~d rate r = radius of circle of impact ~ = angular nozzle velocity t = time Following the tests carried out, as described ear- -`20 lier, the particles were collected and the depth of particleremoval was measured. This data was used to develop the rela-tionship between the depth of particle removal, the jet pres-, sure and the different ~eed rates and standoff distances.Such plots are shown in Fiss. 11 and 12 with remarks concern-ing the ~olume ~f wood removed and the specific energy in-volvqd. Figs. 11 and 12 confirmed the theoretical expecta-tions. The depth of particle removal increases with jet pres-sure and decreases with feed rate. The relationship between said depth and feed rate is not as yet completely clear, how-ever.
Over the range of feed rates examined to date, as the Vc equation demonstrates, the jet traverse velocity is 3~

controlled by the work feed rate and the jet radius. Thus~
increasing the radius of the circle of impact from 1.9 cm (0.75 in.) to 12.7 cm (5 in.) and 25.4 cm (10 in.) will in-crease jet traverse velocity at a feed rate of 304.8 cm/min (10 ft/min) at 120 rpm from about 304.0 cm/min (120 in/min) to 309.9 cm/min (122 in/min) then to 439.4 cm/min (173 in/min).
Then if the experiment is carried out for example, at a radius of the circle of impact of 10 cm (4 in) the depth of particle removal should be in the same range. This means that the power consumption will drop significantly from 163.3 KWh per 1 m3 of solid red oak pulped to around 16.3 KWh per 1 m3 of pulp produced.
The second test was carried out on a lathe rotating at 120 rpm using a dried red oak cylindrical sample measuring 13.3 diameter x 43.2 cm (5 1/4 diameter x 17 in) at a feed rate of 0.38 mm/min (0.01574 in/min). A nozzle with a 0.2 mm (0.008 in) orifice and a nozzle with a 0.75 mm (0.030 in) ori-fice were used. The standoff distance was 1.6 mm (1/16 in).
The tests were run at jet pressures of 35 MPa (5,000 psi) 70 MPa (10,000 psi) and 105 MPa (15,000 psi). The results of these tests are presented in E`ig. 13.
The quality of the fibers removed as a product of the operation are an important feature of the pulping process, and are the measure of the success of the operation. The de-gree of damage to the fiber walls is especially important in the case of hardwood cutting. For this reason a series of scanning microscope photographs were taken of the material produced in the tests. Upon careful study of the photographs, it appeared that smashed fibers occurred only rarely. It also appeared that the fibers were very effectively separated, by the jet, without noticeable damage.
In view of the above, it will be seen that the sev-eral objects of the invention are achieved and other advan-tageous results attained.

2sdpd UMO 1303 ~2~6375 . As various changes could be made in the above con-structions and methods without departing from the scope of the invention, it is intended that all matter contained in the above descriptio~ or shown in the accompanying drawing5 shall be interpreted as ~llustrative and not in a limiting~sense.

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. . .

P

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Claims (11)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. The method of reducing a body of wood having a length and girth to a multiplicity of wood fibers of lengths suitable for use in the manufacture of paper, comprising subjecting the body of wood to liquid jet means comprising at least one substantially coherent continuous stream of liquid at a delivery pressure of from about 4,000 psi to about 60,000 psi, and effecting relative movment of said jet means and the body so that the liquid as it impacts on the body traverses a path on the body at a relatively low velocity of less than about fifteen feet per minute whereby the energy of the liquid as it impacts on the body is sufficiently concentrated and of sufficient duration to effect disintegration of the body of wood into said multiplicity of wood fibers, said disintegration involving separation of the wood fibers in the body of wood without substantial damage to the fibers, said traversal path followed by the impacting liquid comprising a plurality of closely spaced reaches disposed over at least a substantial portion of the entire outer surface of the body whereby the body is substantially completely disintegrated over a relatively large area extending both girthwise and lengthwise with respect to the body.
2. The method of claim 1 wherein relative movement is effected between the body and the liquid such that the liquid impacts on the body in a trajectory having a longitudinal and a girthwise component relative to the body.
3. The method of claim 2 wherein the trajectory is sinusoidal.
4. The method of claim 2 wherein the trajectory is cycloidal.
5. The method of claim 4 wherein the body of wood is a debarked log, said method comprising subjecting the log to a purality of liquid jets directed generally radially inwardly on the log.
6. The method of claim 5 wherein relative movement is effected between the log and the jets endwise and circumferentially of the log so that each jet impacts on the log in a trajectory having a longitudinal and a girthwise component relative to the log.
7. The method of claim 6 wherein the jets are oscillated in a generally fixed plane normal to the log as the log moves endwise past the jets.
8. The method of claim 7 wherein each jet is rotated around an axis extending generally radially with respect to the log.
9. The method of claim 8 utilizing multi-orifice nozzles and wherein each nozzle is rotated around an axis extending generally radially with respect to the log.
10. The method of claim 9 wherein each jet is delivered through an orifice having a diameter from about 0.1 mm to about 5 mm.
11. The method of reducing a debarked log to a multiplicity of particles suitable for the manufacture of paper, comprising feeding the log forward in the direction of its length at a relatively low velocity of less than about fifteen feet per minute, and, as it is fed forward, subjecting it to the action of a plurality of jets of liquid directed generally radially inwardly on the log all around the log, each jet comprising a substantially coherent continuous stream of liquid wherein the delivery pressure of the liquid is from about 4,000 psi to about 60,000 psi and wherein each jet is delivered through an orifice having a diameter of from about 0.1 mm. to about 5 mm., the energy of the liquid as it impacts on the log thus being sufficiently concentrated and of sufficient duration as to effect substantially complete disintegraiton of the log into said particles over a relatively large area extending both girthwise and lengthwise with respect to the log.
CA000486990A 1985-07-17 1985-07-17 Disintegration of wood Expired CA1246375A (en)

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Application Number Priority Date Filing Date Title
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