CA1241181A - Method of separating and purifying hydrogen - Google Patents
Method of separating and purifying hydrogenInfo
- Publication number
- CA1241181A CA1241181A CA000443888A CA443888A CA1241181A CA 1241181 A CA1241181 A CA 1241181A CA 000443888 A CA000443888 A CA 000443888A CA 443888 A CA443888 A CA 443888A CA 1241181 A CA1241181 A CA 1241181A
- Authority
- CA
- Canada
- Prior art keywords
- magnesium
- hydrogen
- transition metal
- hydride
- active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 76
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 76
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 238000000034 method Methods 0.000 title claims abstract description 32
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 88
- 239000011777 magnesium Substances 0.000 claims abstract description 58
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 54
- 229910012375 magnesium hydride Inorganic materials 0.000 claims abstract description 45
- 239000007789 gas Substances 0.000 claims abstract description 38
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052756 noble gas Inorganic materials 0.000 claims abstract description 6
- 150000002835 noble gases Chemical class 0.000 claims abstract description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 25
- 150000003624 transition metals Chemical class 0.000 claims description 25
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 230000000737 periodic effect Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 3
- 235000001055 magnesium Nutrition 0.000 claims 18
- 229940091250 magnesium supplement Drugs 0.000 claims 18
- 239000002244 precipitate Substances 0.000 claims 3
- 239000003960 organic solvent Substances 0.000 claims 2
- 238000003795 desorption Methods 0.000 claims 1
- 150000004678 hydrides Chemical class 0.000 abstract description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- 238000006356 dehydrogenation reaction Methods 0.000 description 14
- 238000004949 mass spectrometry Methods 0.000 description 10
- -1 polycyclic aromatic compound Chemical class 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 229910000765 intermetallic Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 241000220317 Rosa Species 0.000 description 2
- 229910010066 TiC14 Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 229910052987 metal hydride Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- JRTIUDXYIUKIIE-KZUMESAESA-N (1z,5z)-cycloocta-1,5-diene;nickel Chemical compound [Ni].C\1C\C=C/CC\C=C/1.C\1C\C=C/CC\C=C/1 JRTIUDXYIUKIIE-KZUMESAESA-N 0.000 description 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical class CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 206010008631 Cholera Diseases 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910005438 FeTi Inorganic materials 0.000 description 1
- 229910002335 LaNi5 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- BMGNSKKZFQMGDH-FDGPNNRMSA-L nickel(2+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ni+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O BMGNSKKZFQMGDH-FDGPNNRMSA-L 0.000 description 1
- VOKXPKSMYJLAIW-UHFFFAOYSA-N nickel;phosphane Chemical class P.[Ni] VOKXPKSMYJLAIW-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- AEGVXRFFNDYKDD-UHFFFAOYSA-N palladium;phosphane Chemical class P.P.[Pd] AEGVXRFFNDYKDD-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/508—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by selective and reversible uptake by an appropriate medium, i.e. the uptake being based on physical or chemical sorption phenomena or on reversible chemical reactions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19823247361 DE3247361A1 (de) | 1982-12-22 | 1982-12-22 | Verfahren zur abtrennung und reinigung von wasserstoff |
| DEP3247361.3 | 1982-12-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1241181A true CA1241181A (en) | 1988-08-30 |
Family
ID=6181323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000443888A Expired CA1241181A (en) | 1982-12-22 | 1983-12-21 | Method of separating and purifying hydrogen |
Country Status (10)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3247360A1 (de) * | 1982-12-22 | 1984-07-05 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur herstellung aktiver magnetsiumhdrid-magnesium-wasserstoffspeichersysteme |
| DE3340492A1 (de) * | 1983-11-09 | 1985-05-15 | Studiengesellschaft Kohle mbH, 4330 Mülheim | Verfahren zur herstellung von feinverteiltem, hochreaktivem magnesium und dessen verwendung |
| US5199972A (en) * | 1982-12-22 | 1993-04-06 | Studiengesellschaft Kohle G.M.B.H. | Method of preparing active magnesium-hydride or magnesium hydrogen-storer systems |
| DE3639545C1 (de) * | 1986-11-20 | 1988-06-01 | Studiengesellschaft Kohle Mbh | Verfahren zur Waermespeicherung und -transformation sowie Kaelteerzeugung |
| US5211923A (en) * | 1991-08-01 | 1993-05-18 | University Of Chicago | Hydrogen and sulfur recovery from hydrogen sulfide wastes |
| US5262127A (en) * | 1992-02-12 | 1993-11-16 | The Regents Of The University Of Michigan | Solid state chemical micro-reservoirs |
| US6342195B1 (en) * | 1993-10-01 | 2002-01-29 | The Penn State Research Foundation | Method for synthesizing solids such as diamond and products produced thereby |
| DE4419456A1 (de) * | 1994-06-03 | 1995-12-07 | Goldschmidt Ag Th | Verfahren zur Herstellung von Magnesiumhydrid |
| US5843395A (en) * | 1997-03-17 | 1998-12-01 | Wang; Chi S. | Process for hydrogen production from hydrogen sulfide dissociation |
| DE50004040D1 (de) * | 1999-02-24 | 2003-11-20 | Goldschmidt Ag Th | Aktiviertes Magnesiummetall |
| NO328522B1 (no) * | 2007-03-19 | 2010-03-08 | Statoil Asa | Fremgangsmate for produksjon av hydrogen, hydrogenproduksjonsanlegg, en vann-gassskift-reaktor samt en fremgangsmate for fremstilling av hydrogen fra syngass. |
| CN102020246B (zh) * | 2010-12-23 | 2013-01-23 | 苏州市创新净化有限公司 | 氢气纯化回收系统及工艺方法 |
| RU2686898C1 (ru) * | 2018-05-30 | 2019-05-06 | Общество с ограниченной ответственностью "ХитЛаб" | Способ изготовления гидрида магния для химического генератора водорода |
| CN112225176B (zh) * | 2020-10-12 | 2023-05-09 | 艾氢技术(苏州)有限公司 | 一种固体氢放氢纯化系统 |
| CN114477089B (zh) * | 2020-10-26 | 2023-10-27 | 中国石油化工股份有限公司 | 一种低温脱除微量co的方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1911780A (en) * | 1930-03-24 | 1933-05-30 | Standard Oil Dev Co | Process for purifying gases |
| GB634799A (en) * | 1946-06-08 | 1950-03-29 | American Electro Metal Corp | Methods of and plant for producing magnesium powder or powder metal mixtures containing magnesium |
| US3485585A (en) * | 1964-09-01 | 1969-12-23 | Hercules Inc | Preparation of metal hydrides |
| US3479165A (en) * | 1966-06-28 | 1969-11-18 | Exxon Research Engineering Co | Hydrogen storage system |
| US3666416A (en) * | 1970-11-25 | 1972-05-30 | Shell Oil Co | Magnesium hydride production |
| SU628180A1 (ru) * | 1975-12-29 | 1978-10-15 | Государственный проектный и научно-исследовательский институт "Гипроникель" | Аппарат дл производства металлических порошков из металлоорганических соединений |
| FR2407169A1 (fr) * | 1977-10-27 | 1979-05-25 | Raffinage Cie Francaise | Procede de preparation d'une reserve d'hydrogene et applications de ce procede. |
| FR2407170A1 (fr) * | 1977-10-27 | 1979-05-25 | Raffinage Cie Francaise | Procede combine de stockage et de production d'hydrogene et applications de ce procede |
| US4216198A (en) * | 1977-12-19 | 1980-08-05 | Billings Energy Corporation | Self-regenerating method and system of removing oxygen and water impurities from hydrogen gas |
| DE2804445A1 (de) * | 1978-02-02 | 1979-08-09 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von magnesiumhydriden |
| CH634015A5 (fr) * | 1978-11-14 | 1983-01-14 | Battelle Memorial Institute | Composition a base de magnesium pour le stockage de l'hydrogene et procede de preparation de cette composition. |
| DE2908928A1 (de) * | 1979-03-07 | 1980-09-18 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von organolithiumverbindungen neben lithiumhydrid |
| US4300946A (en) * | 1979-05-17 | 1981-11-17 | Billings Energy Corporation | Granulating and activating metal to form metal hydride |
| US4389326A (en) * | 1979-08-27 | 1983-06-21 | Agence Nationale De Valorization De La Recherche | Method of storing hydrogen in intimate mixtures of hydrides of magnesium and other metals or alloys |
| US4383837A (en) * | 1979-12-28 | 1983-05-17 | Atlantic Richfield Company | Efficient methane production with metal hydrides |
| US4360505A (en) * | 1981-07-02 | 1982-11-23 | Air Products And Chemicals, Inc. | Recovering hydrogen from gas stream using metal hydride |
| US4431561A (en) * | 1982-04-28 | 1984-02-14 | Energy Conversion Devices, Inc. | Hydrogen storage materials and method of making same |
| DE3536797A1 (de) * | 1985-10-16 | 1987-04-16 | Studiengesellschaft Kohle Mbh | Verfahren zur herstellung von halogen-magnesium-alanat und dessen verwendung |
| JP3093166B2 (ja) * | 1997-06-16 | 2000-10-03 | 鹿島建設株式会社 | 円形レールを用いたクレーンの旋回構造 |
-
1982
- 1982-12-22 DE DE19823247361 patent/DE3247361A1/de not_active Withdrawn
-
1983
- 1983-12-20 EP EP83112796A patent/EP0111923B1/de not_active Expired
- 1983-12-20 AT AT83112796T patent/ATE40667T1/de not_active IP Right Cessation
- 1983-12-20 DE DE8383112796T patent/DE3379164D1/de not_active Expired
- 1983-12-21 JP JP58243065A patent/JPS59131503A/ja active Granted
- 1983-12-21 DK DK590483A patent/DK162634C/da not_active IP Right Cessation
- 1983-12-21 IE IE3017/83A patent/IE56386B1/en not_active IP Right Cessation
- 1983-12-21 CA CA000443888A patent/CA1241181A/en not_active Expired
- 1983-12-21 ES ES528245A patent/ES528245A0/es active Granted
- 1983-12-21 AU AU22756/83A patent/AU574056B2/en not_active Ceased
-
1985
- 1985-06-03 US US06/740,698 patent/US4695446A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3379164D1 (en) | 1989-03-16 |
| DK162634B (da) | 1991-11-25 |
| EP0111923A2 (de) | 1984-06-27 |
| AU2275683A (en) | 1984-06-28 |
| JPS59131503A (ja) | 1984-07-28 |
| DK590483A (da) | 1984-06-23 |
| US4695446A (en) | 1987-09-22 |
| ATE40667T1 (de) | 1989-02-15 |
| JPH059364B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-04 |
| DK162634C (da) | 1992-04-13 |
| AU574056B2 (en) | 1988-06-30 |
| EP0111923A3 (en) | 1986-07-23 |
| IE56386B1 (en) | 1991-07-17 |
| IE833017L (en) | 1984-06-22 |
| EP0111923B1 (de) | 1989-02-08 |
| DE3247361A1 (de) | 1984-06-28 |
| ES8406372A1 (es) | 1984-08-01 |
| DK590483D0 (da) | 1983-12-21 |
| ES528245A0 (es) | 1984-08-01 |
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