CA1219995A - Recovery of chlorinated poly(vinyl chloride) - Google Patents
Recovery of chlorinated poly(vinyl chloride)Info
- Publication number
- CA1219995A CA1219995A CA000390134A CA390134A CA1219995A CA 1219995 A CA1219995 A CA 1219995A CA 000390134 A CA000390134 A CA 000390134A CA 390134 A CA390134 A CA 390134A CA 1219995 A CA1219995 A CA 1219995A
- Authority
- CA
- Canada
- Prior art keywords
- cpvc
- liquid
- solution
- vinyl chloride
- chlorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 54
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 52
- -1 poly(vinyl chloride) Polymers 0.000 title claims abstract description 22
- 238000011084 recovery Methods 0.000 title abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 47
- 238000000034 method Methods 0.000 claims abstract description 35
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 27
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 15
- 239000006188 syrup Substances 0.000 claims description 24
- 235000020357 syrup Nutrition 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 230000001376 precipitating effect Effects 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 2
- 238000001914 filtration Methods 0.000 claims 1
- 239000004801 Chlorinated PVC Substances 0.000 abstract description 70
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 abstract description 70
- 239000007788 liquid Substances 0.000 abstract description 67
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 5
- 230000000877 morphologic effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 24
- 238000005660 chlorination reaction Methods 0.000 description 20
- 239000000460 chlorine Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000001556 precipitation Methods 0.000 description 13
- 230000001588 bifunctional effect Effects 0.000 description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 229910052801 chlorine Inorganic materials 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 8
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000000725 suspension Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000004515 macrogranule Substances 0.000 description 3
- 238000005057 refrigeration Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- RFCAUADVODFSLZ-UHFFFAOYSA-N 1-Chloro-1,1,2,2,2-pentafluoroethane Chemical compound FC(F)(F)C(F)(F)Cl RFCAUADVODFSLZ-UHFFFAOYSA-N 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical compound FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 1
- 101100126176 Escherichia coli (strain K12) intQ gene Proteins 0.000 description 1
- GHASVSINZRGABV-UHFFFAOYSA-N Fluorouracil Chemical compound FC1=CNC(=O)NC1=O GHASVSINZRGABV-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229940001981 carac Drugs 0.000 description 1
- 235000019406 chloropentafluoroethane Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/06—Treatment of polymer solutions
- C08F6/12—Separation of polymers from solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/219,650 US4373093A (en) | 1980-12-24 | 1980-12-24 | Recovery of chlorinated poly(vinyl chloride) |
| US219,650 | 1988-07-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1219995A true CA1219995A (en) | 1987-03-31 |
Family
ID=22820153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000390134A Expired CA1219995A (en) | 1980-12-24 | 1981-11-16 | Recovery of chlorinated poly(vinyl chloride) |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4373093A (OSRAM) |
| EP (1) | EP0067209B1 (OSRAM) |
| JP (1) | JPH0145483B2 (OSRAM) |
| AR (1) | AR226930A1 (OSRAM) |
| BR (1) | BR8108928A (OSRAM) |
| CA (1) | CA1219995A (OSRAM) |
| IN (1) | IN155988B (OSRAM) |
| IT (1) | IT1140375B (OSRAM) |
| MX (1) | MX159037A (OSRAM) |
| NO (1) | NO822786L (OSRAM) |
| WO (1) | WO1982002205A1 (OSRAM) |
| ZA (1) | ZA818020B (OSRAM) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5359011A (en) * | 1992-10-14 | 1994-10-25 | The B.F. Goodrich Company | Process for the complete neutralization of chlorinated polyvinyl chloride and product resulting therefrom |
| US7414100B2 (en) * | 2004-06-21 | 2008-08-19 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2006009945A1 (en) | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Impact copolymers |
| US7981984B2 (en) * | 2004-06-21 | 2011-07-19 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| WO2006009951A1 (en) * | 2004-06-21 | 2006-01-26 | Exxonmobil Chemical Patents Inc. | Polymer recovery method |
| US8679341B2 (en) * | 2005-05-06 | 2014-03-25 | Fujifilm Corporation | Method of concentrating nanoparticles and method of deaggregating aggregated nanoparticles |
| JP5118850B2 (ja) * | 2005-05-09 | 2013-01-16 | 富士フイルム株式会社 | 有機顔料分散液の製造方法 |
| TWI428174B (zh) * | 2005-05-09 | 2014-03-01 | Fujifilm Corp | 有機奈米粒子之製法、以其所得到有機奈米粒子、含它之彩色濾光片用噴墨印墨、著色感光性樹脂組成物及感光性樹脂轉印材料、以及使用彼等之彩色濾光片、液晶顯示裝置與ｃｃｄ裝置 |
| US20090045535A1 (en) * | 2005-05-09 | 2009-02-19 | Yousuke Miyashita | Method of producing organic particles and production apparatus usable for the same |
| US7799882B2 (en) * | 2005-06-20 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Polymerization process |
| EP2993192B1 (en) * | 2013-05-02 | 2018-06-20 | Kaneka Corporation | Method for producing chlorinated polyvinyl chloride resin |
| JP6800159B2 (ja) * | 2015-10-15 | 2020-12-16 | 株式会社カネカ | 塩素化塩化ビニル系樹脂の製造方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2571901A (en) * | 1945-12-12 | 1951-10-16 | Niagara Alkali Company | Chlorinating process |
| US2481188A (en) * | 1946-03-30 | 1949-09-06 | Pierce Lab Inc | Chlorination of polyethylene |
| US3062795A (en) * | 1958-04-01 | 1962-11-06 | Exxon Research Engineering Co | Process for preparing halogenated copolymers |
| GB1093850A (en) * | 1965-12-24 | 1967-12-06 | Ici Ltd | Chlorinated polymers |
-
1980
- 1980-12-24 US US06/219,650 patent/US4373093A/en not_active Expired - Fee Related
-
1981
- 1981-11-13 AR AR287432A patent/AR226930A1/es active
- 1981-11-16 CA CA000390134A patent/CA1219995A/en not_active Expired
- 1981-11-19 ZA ZA818020A patent/ZA818020B/xx unknown
- 1981-11-24 IN IN1320/CAL/81A patent/IN155988B/en unknown
- 1981-12-16 JP JP57500389A patent/JPH0145483B2/ja not_active Expired
- 1981-12-16 BR BR8108928A patent/BR8108928A/pt unknown
- 1981-12-16 WO PCT/US1981/001675 patent/WO1982002205A1/en not_active Ceased
- 1981-12-16 EP EP82900440A patent/EP0067209B1/en not_active Expired
- 1981-12-21 IT IT25739/81A patent/IT1140375B/it active
-
1982
- 1982-01-04 MX MX190785A patent/MX159037A/es unknown
- 1982-08-16 NO NO822786A patent/NO822786L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US4373093A (en) | 1983-02-08 |
| EP0067209A4 (en) | 1983-04-06 |
| IN155988B (OSRAM) | 1985-04-20 |
| IT8125739A0 (it) | 1981-12-21 |
| MX159037A (es) | 1989-04-13 |
| EP0067209B1 (en) | 1986-08-20 |
| IT1140375B (it) | 1986-09-24 |
| WO1982002205A1 (en) | 1982-07-08 |
| AR226930A1 (es) | 1982-08-31 |
| NO822786L (no) | 1982-08-16 |
| BR8108928A (pt) | 1982-11-30 |
| EP0067209A1 (en) | 1982-12-22 |
| JPS57502005A (OSRAM) | 1982-11-11 |
| JPH0145483B2 (OSRAM) | 1989-10-03 |
| ZA818020B (en) | 1982-11-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |