CA1207978A - Sodium tripolyphosphate with a high rate of hydration and a sprayable slurry containing same - Google Patents
Sodium tripolyphosphate with a high rate of hydration and a sprayable slurry containing sameInfo
- Publication number
- CA1207978A CA1207978A CA000433179A CA433179A CA1207978A CA 1207978 A CA1207978 A CA 1207978A CA 000433179 A CA000433179 A CA 000433179A CA 433179 A CA433179 A CA 433179A CA 1207978 A CA1207978 A CA 1207978A
- Authority
- CA
- Canada
- Prior art keywords
- tpp
- sodium tripolyphosphate
- thermal treatment
- orthophosphates
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000019832 sodium triphosphate Nutrition 0.000 title claims abstract description 91
- 239000002002 slurry Substances 0.000 title claims description 25
- 230000036571 hydration Effects 0.000 title abstract description 22
- 238000006703 hydration reaction Methods 0.000 title abstract description 22
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 75
- 238000011282 treatment Methods 0.000 claims abstract description 17
- 239000007792 gaseous phase Substances 0.000 claims abstract description 13
- 238000007669 thermal treatment Methods 0.000 claims abstract description 13
- 230000000295 complement effect Effects 0.000 claims abstract description 12
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 238000009987 spinning Methods 0.000 claims abstract description 8
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 16
- 239000003599 detergent Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 229910021536 Zeolite Inorganic materials 0.000 claims description 9
- 239000010457 zeolite Substances 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 8
- 239000007791 liquid phase Substances 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims 4
- 239000012071 phase Substances 0.000 description 22
- 239000000203 mixture Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
- 238000000889 atomisation Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000007832 Na2SO4 Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/40—Polyphosphates
- C01B25/41—Polyphosphates of alkali metals
- C01B25/412—Preparation from alkali metal orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
- C11D3/062—Special methods concerning phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR82.13065 | 1982-07-27 | ||
| FR8213065A FR2531059A1 (fr) | 1982-07-27 | 1982-07-27 | Tripolyphosphate de sodium a vitesse d'hydratation elevee |
| FR83.07006 | 1983-04-28 | ||
| FR8307006A FR2545097B3 (fr) | 1983-04-28 | 1983-04-28 | Composition lessivielle conduisant a une bouillie a faible viscosite, a base de tripolyphosphate de sodium, a vitesse d'hydratation elevee et renfermant un tensio-actif non-ionique |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1207978A true CA1207978A (en) | 1986-07-22 |
Family
ID=26223013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000433179A Expired CA1207978A (en) | 1982-07-27 | 1983-07-26 | Sodium tripolyphosphate with a high rate of hydration and a sprayable slurry containing same |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4671948A (enExample) |
| EP (1) | EP0101347B1 (enExample) |
| AU (1) | AU1734383A (enExample) |
| BR (1) | BR8303970A (enExample) |
| CA (1) | CA1207978A (enExample) |
| DE (1) | DE3366455D1 (enExample) |
| DK (1) | DK341783A (enExample) |
| ES (1) | ES524428A0 (enExample) |
| FI (1) | FI832695A7 (enExample) |
| GR (1) | GR77555B (enExample) |
| IL (1) | IL69315A (enExample) |
| OA (1) | OA07504A (enExample) |
| PT (1) | PT77103B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2257326B1 (enExample) * | 1973-06-19 | 1976-05-28 | Rhone Progil | |
| AU575613B2 (en) * | 1984-01-25 | 1988-08-04 | Griffith Thomas | Phosphates for use in detergents |
| FR2571712B1 (fr) * | 1984-10-15 | 1987-01-09 | Rhone Poulenc Chim Base | Tripolyphosphate de sodium a vitesse d'hydratation elevee, son procede de preparation et son application en detergence |
| US5232620A (en) * | 1991-02-28 | 1993-08-03 | Fmc Corporation | Sodium tripolyphosphate composition and method of producing it |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB799429A (en) * | 1954-03-08 | 1958-08-06 | Knapsack Ag | Manufacture of alkali metal phosphates |
| DE1604790A1 (de) * | 1965-11-22 | 1971-01-14 | Albright & Wilson Australia | Verfahren und Vorrichtung zur Beseitigung von Wasser aus waessrigen Loesungen von Feststoffen |
| FR2257326B1 (enExample) * | 1973-06-19 | 1976-05-28 | Rhone Progil | |
| FR2396250A1 (fr) * | 1977-07-01 | 1979-01-26 | Rhone Poulenc Ind | Nouveau procede pour le traitement de matieres thermosensibles |
| FR2419754A1 (fr) * | 1978-03-14 | 1979-10-12 | Rhone Poulenc Ind | Dispositif pour la mise en contact de substances se presentant sous au moins deux phases differentes |
| FR2431321A1 (fr) * | 1978-07-21 | 1980-02-15 | Rhone Poulenc Ind | Procede de traitement de substances se presentant sous des phases differentes, tel que traitement de substances sous forme liquide, semi-liquide, ou pateuse, par une autre phase notamment gazeuse |
| FR2508887A1 (fr) * | 1981-07-06 | 1983-01-07 | Rhone Poulenc Chim Base | Nouveau tripolyphosphate de sodium, procede pour l'obtenir et applications |
| FR2508818A1 (fr) * | 1981-07-06 | 1983-01-07 | Rhone Poulenc Chim Base | Procede de traitement thermique et/ou chimique homogene d'un fluide, et application aux polyphosphates |
-
1983
- 1983-07-18 EP EP83401467A patent/EP0101347B1/fr not_active Expired
- 1983-07-18 DE DE8383401467T patent/DE3366455D1/de not_active Expired
- 1983-07-24 IL IL69315A patent/IL69315A/xx unknown
- 1983-07-25 GR GR72025A patent/GR77555B/el unknown
- 1983-07-26 FI FI832695A patent/FI832695A7/fi not_active Application Discontinuation
- 1983-07-26 PT PT77103A patent/PT77103B/pt unknown
- 1983-07-26 BR BR8303970A patent/BR8303970A/pt unknown
- 1983-07-26 DK DK341783A patent/DK341783A/da not_active Application Discontinuation
- 1983-07-26 ES ES524428A patent/ES524428A0/es active Granted
- 1983-07-26 OA OA58071A patent/OA07504A/xx unknown
- 1983-07-26 CA CA000433179A patent/CA1207978A/en not_active Expired
- 1983-07-27 AU AU17343/83A patent/AU1734383A/en not_active Abandoned
-
1986
- 1986-01-24 US US06/822,243 patent/US4671948A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3366455D1 (en) | 1986-10-30 |
| EP0101347B1 (fr) | 1986-09-24 |
| ES8404403A1 (es) | 1984-04-16 |
| US4671948A (en) | 1987-06-09 |
| AU1734383A (en) | 1984-02-02 |
| ES524428A0 (es) | 1984-04-16 |
| BR8303970A (pt) | 1984-04-24 |
| IL69315A0 (en) | 1983-11-30 |
| GR77555B (enExample) | 1984-09-24 |
| IL69315A (en) | 1986-08-31 |
| DK341783D0 (da) | 1983-07-26 |
| EP0101347A1 (fr) | 1984-02-22 |
| FI832695A0 (fi) | 1983-07-26 |
| PT77103B (fr) | 1986-01-27 |
| PT77103A (fr) | 1983-08-01 |
| DK341783A (da) | 1984-01-28 |
| FI832695A7 (fi) | 1984-01-28 |
| OA07504A (fr) | 1985-03-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |