CA1197831A - Catalyst components for the polymerization of alpha- olefins and catalysts obtained therefrom - Google Patents
Catalyst components for the polymerization of alpha- olefins and catalysts obtained therefromInfo
- Publication number
- CA1197831A CA1197831A CA000418216A CA418216A CA1197831A CA 1197831 A CA1197831 A CA 1197831A CA 000418216 A CA000418216 A CA 000418216A CA 418216 A CA418216 A CA 418216A CA 1197831 A CA1197831 A CA 1197831A
- Authority
- CA
- Canada
- Prior art keywords
- compound
- solid catalyst
- halide
- component according
- catalyst component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 27
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 18
- 239000004711 α-olefin Substances 0.000 title abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 32
- 239000007788 liquid Substances 0.000 claims abstract description 29
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000007791 liquid phase Substances 0.000 claims abstract description 14
- 239000006185 dispersion Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 11
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 239000002243 precursor Substances 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 13
- -1 alkaryl alcohol Chemical compound 0.000 claims description 9
- 230000009466 transformation Effects 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 8
- 229910010066 TiC14 Inorganic materials 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000007790 solid phase Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 18
- 239000011949 solid catalyst Substances 0.000 claims 13
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 9
- 239000005977 Ethylene Substances 0.000 abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 3
- 239000007792 gaseous phase Substances 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 description 18
- 150000004820 halides Chemical class 0.000 description 15
- 239000010936 titanium Substances 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000725 suspension Substances 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 150000003609 titanium compounds Chemical class 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012967 coordination catalyst Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical group CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000001502 aryl halides Chemical class 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Glass Compositions (AREA)
- Control Of Throttle Valves Provided In The Intake System Or In The Exhaust System (AREA)
- Air Bags (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25841/81A IT1169292B (it) | 1981-12-24 | 1981-12-24 | Componenti di catalizzatori per la polimerizzazione delle alfa olefine e i catalizzatori da essi ottenuti |
| IT25841A/81 | 1981-12-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1197831A true CA1197831A (en) | 1985-12-10 |
Family
ID=11217892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000418216A Expired CA1197831A (en) | 1981-12-24 | 1982-12-21 | Catalyst components for the polymerization of alpha- olefins and catalysts obtained therefrom |
Country Status (14)
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU542963B2 (en) * | 1982-08-20 | 1985-03-28 | Phillips Petroleum Co. | Polymerisation catalyst for olefins |
| EP1270610B8 (en) * | 2001-06-20 | 2006-09-27 | Borealis Technology Oy | Preparation of olefin polymerisation catalyst component |
| DE60120389T2 (de) | 2001-06-20 | 2007-06-14 | Borealis Technology Oy | Herstellung eines Katalysatorbestandteils zur Olefinpolymerisation |
| EP1375528A1 (en) | 2002-06-18 | 2004-01-02 | Borealis Polymers Oy | Method for the preparation of olefin polymerisation catalysts |
| EP1403292B1 (en) | 2002-09-30 | 2016-04-13 | Borealis Polymers Oy | Process for preparing an olefin polymerisation catalyst component with improved high temperature activity |
| EP2845868A1 (en) | 2006-05-31 | 2015-03-11 | Borealis Technology Oy | Oxidation state of Ti as means for increasing catalyst activity |
| EP1939227B1 (en) | 2006-12-28 | 2013-10-30 | Borealis Technology Oy | Catalyst preparation with phosphorous compound |
| ES2393382T3 (es) | 2008-06-26 | 2012-12-20 | Borealis Ag | Preparación de catalizador usando H2 |
| ES2541701T3 (es) | 2010-07-13 | 2015-07-23 | Borealis Ag | Componente de catalizador |
| EP2570438A3 (en) | 2010-07-13 | 2013-12-25 | Borealis AG | Catalyst component |
| EP2960257B1 (en) | 2014-06-27 | 2022-09-28 | Borealis AG | Improved process for preparing a particulate olefin polymerisation catalyst component |
| ES2676219T3 (es) | 2014-06-27 | 2018-07-17 | Borealis Ag | Componente de catalizador para la preparación de poliolefinas nucleadas |
| CN107810205B (zh) | 2015-07-16 | 2020-05-19 | 博里利斯股份公司 | 催化剂组分 |
| JP2024536444A (ja) | 2021-10-14 | 2024-10-04 | ボレアリス エージー | チーグラー・ナッタ触媒成分を形成するプロセス |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3953414A (en) * | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| IT1078995B (it) * | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
| JPS54158489A (en) * | 1978-06-05 | 1979-12-14 | Mitsubishi Petrochem Co Ltd | Polymerization of olefin |
| DE3065499D1 (en) * | 1979-04-11 | 1983-12-15 | Mitsui Petrochemical Ind | Process for producing spherical carrier particles for olefin polymerisation catalyst, catalyst comprising such carrier particles, and use of such catalyst in olefin polymerisation |
-
1981
- 1981-12-24 IT IT25841/81A patent/IT1169292B/it active
-
1982
- 1982-12-15 NO NO824221A patent/NO162563C/no unknown
- 1982-12-17 KR KR8205664A patent/KR890003625B1/ko not_active Expired
- 1982-12-17 ZA ZA829296A patent/ZA829296B/xx unknown
- 1982-12-20 AU AU91692/82A patent/AU564286B2/en not_active Expired
- 1982-12-21 CA CA000418216A patent/CA1197831A/en not_active Expired
- 1982-12-22 AT AT82111903T patent/ATE47403T1/de not_active IP Right Cessation
- 1982-12-22 GR GR70148A patent/GR78406B/el unknown
- 1982-12-22 JP JP57224078A patent/JPS58111809A/ja active Pending
- 1982-12-22 DE DE8282111903T patent/DE3279986D1/de not_active Expired
- 1982-12-22 BR BR8207450A patent/BR8207450A/pt not_active IP Right Cessation
- 1982-12-22 EP EP82111903A patent/EP0083073B1/en not_active Expired
- 1982-12-23 IN IN1480/CAL/82A patent/IN158357B/en unknown
- 1982-12-23 ES ES518516A patent/ES8500964A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ATE47403T1 (de) | 1989-11-15 |
| NO824221L (no) | 1983-06-27 |
| EP0083073A1 (en) | 1983-07-06 |
| ZA829296B (en) | 1983-09-28 |
| KR890003625B1 (ko) | 1989-09-28 |
| ES518516A0 (es) | 1984-12-01 |
| IT8125841A0 (it) | 1981-12-24 |
| IT1169292B (it) | 1987-05-27 |
| GR78406B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-09-27 |
| KR840002856A (ko) | 1984-07-21 |
| NO162563B (no) | 1989-10-09 |
| DE3279986D1 (en) | 1989-11-23 |
| EP0083073B1 (en) | 1989-10-18 |
| NO162563C (no) | 1990-01-17 |
| IN158357B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-10-25 |
| JPS58111809A (ja) | 1983-07-04 |
| AU564286B2 (en) | 1987-08-06 |
| BR8207450A (pt) | 1983-10-18 |
| AU9169282A (en) | 1983-06-30 |
| ES8500964A1 (es) | 1984-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEC | Expiry (correction) | ||
| MKEX | Expiry |