CA1190923A - Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose - Google Patents
Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucoseInfo
- Publication number
- CA1190923A CA1190923A CA000371826A CA371826A CA1190923A CA 1190923 A CA1190923 A CA 1190923A CA 000371826 A CA000371826 A CA 000371826A CA 371826 A CA371826 A CA 371826A CA 1190923 A CA1190923 A CA 1190923A
- Authority
- CA
- Canada
- Prior art keywords
- reaction zone
- continuously
- cellulose
- zone
- dynamic seal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 144
- 239000001913 cellulose Substances 0.000 title claims abstract description 58
- 229920002678 cellulose Polymers 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 39
- 230000008569 process Effects 0.000 title claims abstract description 38
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 title claims abstract description 20
- 239000008103 glucose Substances 0.000 title claims abstract description 20
- 239000002699 waste material Substances 0.000 title claims abstract description 18
- 239000000463 material Substances 0.000 title claims description 46
- 239000000126 substance Substances 0.000 title claims description 7
- 239000002253 acid Substances 0.000 claims abstract description 33
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000007599 discharging Methods 0.000 claims abstract description 12
- 239000003377 acid catalyst Substances 0.000 claims abstract description 7
- 239000002002 slurry Substances 0.000 claims description 25
- 239000000376 reactant Substances 0.000 claims description 18
- 239000002657 fibrous material Substances 0.000 claims description 14
- 238000005903 acid hydrolysis reaction Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 230000004044 response Effects 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 3
- 230000003301 hydrolyzing effect Effects 0.000 claims 5
- 208000036366 Sensation of pressure Diseases 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000001678 irradiating effect Effects 0.000 claims 1
- 235000010980 cellulose Nutrition 0.000 description 37
- 230000007062 hydrolysis Effects 0.000 description 11
- 238000006460 hydrolysis reaction Methods 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000036647 reaction Effects 0.000 description 3
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229940106135 cellulose Drugs 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 230000005865 ionizing radiation Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- 101001121591 Aplysia californica L-amino-acid oxidase Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010907 stover Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 230000029305 taxis Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/131,340 US4316747A (en) | 1980-03-18 | 1980-03-18 | Process for the chemical conversion of cellulose waste to glucose |
| US131,340 | 1980-03-18 | ||
| US131,339 | 1980-03-18 | ||
| US06/131,339 US4316748A (en) | 1980-03-18 | 1980-03-18 | Process for the acid hydrolysis of waste cellulose to glucose |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1190923A true CA1190923A (en) | 1985-07-23 |
Family
ID=26829384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000371826A Expired CA1190923A (en) | 1980-03-18 | 1981-02-26 | Process and apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0037912B1 (ca) |
| AU (1) | AU548717B2 (ca) |
| BR (1) | BR8101561A (ca) |
| CA (1) | CA1190923A (ca) |
| DE (1) | DE3171880D1 (ca) |
| IN (1) | IN153348B (ca) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009076760A1 (en) * | 2007-12-19 | 2009-06-25 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| WO2010009547A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| WO2010009548A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| US8545633B2 (en) | 2009-08-24 | 2013-10-01 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
| US9127325B2 (en) | 2008-07-24 | 2015-09-08 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for treating a cellulosic feedstock |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2525236A1 (fr) * | 1982-04-15 | 1983-10-21 | Creusot Loire | Procede et dispositif d'hydrolyse d'une matiere cellulosique |
| US4728367A (en) * | 1985-01-31 | 1988-03-01 | Wenger Manufacturing, Inc. | Extrusion method and apparatus for acid treatment of cellulosic materials |
| SE501141C2 (sv) * | 1993-04-16 | 1994-11-21 | Regalco Ab | Förfarande för hydrolys av cellulosa- och/eller stärkelsehaltiga material |
| BRPI0613681A2 (pt) * | 2005-07-19 | 2010-07-13 | Holm Christensen Biosystemer A | método e aparelho para conversão de material celulósico para etanol |
| EP2310418B1 (en) | 2008-07-16 | 2016-03-30 | Renmatix, Inc. | Method of extraction of furfural and glucose from biomass using one or more supercritical fluids |
| US8546560B2 (en) | 2008-07-16 | 2013-10-01 | Renmatix, Inc. | Solvo-thermal hydrolysis of cellulose |
| CN102859066B (zh) | 2010-01-19 | 2016-01-13 | 瑞恩麦特克斯股份有限公司 | 使用超临界流体从生物质产生可发酵的糖和木质素 |
| WO2012097781A1 (de) * | 2010-11-25 | 2012-07-26 | Studiengesellschaft Kohle Mbh | Verfahren zur säurekatalysierten depolymerisation von cellulose |
| EP2705111A4 (en) | 2011-05-04 | 2014-11-19 | Renmatix Inc | LIGNINE MANUFACTURE FROM A LIGNOCELLULOSIC BIOMASS |
| US8801859B2 (en) | 2011-05-04 | 2014-08-12 | Renmatix, Inc. | Self-cleaning apparatus and method for thick slurry pressure control |
| US8759498B2 (en) | 2011-12-30 | 2014-06-24 | Renmatix, Inc. | Compositions comprising lignin |
| WO2014143753A1 (en) | 2013-03-15 | 2014-09-18 | Sweetwater Energy, Inc. | Carbon purification of concentrated sugar streams derived from pretreated biomass |
| AU2015320328B2 (en) | 2014-09-26 | 2020-03-05 | Renmatix, Inc. | Cellulose-containing compositions and methods of making same |
| CN107208120B (zh) | 2014-12-09 | 2021-11-23 | 斯威特沃特能源公司 | 快速预处理 |
| US11821047B2 (en) | 2017-02-16 | 2023-11-21 | Apalta Patent OÜ | High pressure zone formation for pretreatment |
| CN207828156U (zh) | 2017-12-06 | 2018-09-07 | 易高环保能源研究院有限公司 | 利用木质纤维素类原料连续水解制糖的装置 |
| US11692000B2 (en) | 2019-12-22 | 2023-07-04 | Apalta Patents OÜ | Methods of making specialized lignin and lignin products from biomass |
| CN115157452B (zh) * | 2022-09-08 | 2022-11-22 | 山西钢建鼎元混凝土制品有限公司 | 一种用于混凝土浇筑加工的上料装置 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2000822B (en) * | 1977-07-11 | 1982-08-11 | Canadian Patents Dev | Method of rendering lignin separable from cellulose and hemicellulose in lignocellulosic material and the product so produced |
-
1981
- 1981-02-26 CA CA000371826A patent/CA1190923A/en not_active Expired
- 1981-03-06 AU AU68126/81A patent/AU548717B2/en not_active Ceased
- 1981-03-16 DE DE8181101951T patent/DE3171880D1/de not_active Expired
- 1981-03-16 EP EP19810101951 patent/EP0037912B1/en not_active Expired
- 1981-03-17 BR BR8101561A patent/BR8101561A/pt unknown
- 1981-03-17 IN IN288/CAL/81A patent/IN153348B/en unknown
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009076760A1 (en) * | 2007-12-19 | 2009-06-25 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| US8283140B2 (en) | 2007-12-19 | 2012-10-09 | Fpinnovations | Conversion of knot rejects from chemical pulping |
| WO2010009547A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| WO2010009548A1 (en) * | 2008-07-24 | 2010-01-28 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| US8449680B2 (en) | 2008-07-24 | 2013-05-28 | Mascoma Canada Inc. | Method and apparatus for treating a cellulosic feedstock |
| US9010522B2 (en) | 2008-07-24 | 2015-04-21 | Abengoa Bioenergy New Technologies, Llc | Method and apparatus for conveying a cellulosic feedstock |
| US9127325B2 (en) | 2008-07-24 | 2015-09-08 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for treating a cellulosic feedstock |
| US8545633B2 (en) | 2009-08-24 | 2013-10-01 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
| US9335043B2 (en) | 2009-08-24 | 2016-05-10 | Abengoa Bioenergy New Technologies, Inc. | Method for producing ethanol and co-products from cellulosic biomass |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0037912A2 (en) | 1981-10-21 |
| EP0037912A3 (en) | 1982-04-21 |
| AU6812681A (en) | 1981-09-24 |
| BR8101561A (pt) | 1981-09-22 |
| EP0037912B1 (en) | 1985-08-21 |
| AU548717B2 (en) | 1986-01-02 |
| DE3171880D1 (en) | 1985-09-26 |
| IN153348B (ca) | 1984-07-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |