CA1189669A - Process for the preparation of polymer melts which are substantially free of volatile components - Google Patents
Process for the preparation of polymer melts which are substantially free of volatile componentsInfo
- Publication number
- CA1189669A CA1189669A CA000405303A CA405303A CA1189669A CA 1189669 A CA1189669 A CA 1189669A CA 000405303 A CA000405303 A CA 000405303A CA 405303 A CA405303 A CA 405303A CA 1189669 A CA1189669 A CA 1189669A
- Authority
- CA
- Canada
- Prior art keywords
- melt
- extruder
- degasification
- zone
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 63
- 239000000155 melt Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 238000007872 degassing Methods 0.000 claims abstract description 68
- 238000001816 cooling Methods 0.000 claims abstract description 31
- 150000001336 alkenes Chemical class 0.000 claims abstract description 17
- 238000004898 kneading Methods 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 229920000098 polyolefin Polymers 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 208000036366 Sensation of pressure Diseases 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 3
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 3
- 239000000306 component Substances 0.000 description 20
- 238000012545 processing Methods 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- -1 polyethylene Polymers 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- ZRQLTXQMULNPJC-UHFFFAOYSA-N hexane oct-1-ene Chemical compound CCCCCC.CCCCCCC=C ZRQLTXQMULNPJC-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000001609 comparable effect Effects 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/26—Treatment of polymers prepared in bulk also solid polymers or polymer melts
- C08F6/28—Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8102930 | 1981-06-17 | ||
| NL8102930A NL8102930A (nl) | 1981-06-17 | 1981-06-17 | Werkwijze voor het bereiden van polymeersmelten die vrijwel vrij zijn van vluchtige bestanddelen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1189669A true CA1189669A (en) | 1985-07-02 |
Family
ID=19837655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000405303A Expired CA1189669A (en) | 1981-06-17 | 1982-06-16 | Process for the preparation of polymer melts which are substantially free of volatile components |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4452977A (enExample) |
| EP (1) | EP0068561B1 (enExample) |
| JP (1) | JPS583845A (enExample) |
| AU (1) | AU553321B2 (enExample) |
| CA (1) | CA1189669A (enExample) |
| DE (1) | DE3266024D1 (enExample) |
| ES (2) | ES8400451A1 (enExample) |
| IN (1) | IN158001B (enExample) |
| NL (1) | NL8102930A (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8203281A (nl) * | 1982-08-21 | 1984-03-16 | Stamicarbon | Inrichting en werkwijze voor het winnen van polymeer uit een oplossing. |
| DE3310676A1 (de) * | 1983-03-24 | 1984-09-27 | Basf Ag, 6700 Ludwigshafen | Verfahren und vorrichtung zum entfernen von fluechtigen anteilen aus polymerenschmelzen oder paste |
| NL8600144A (nl) * | 1986-01-23 | 1987-08-17 | Stamicarbon | Werkwijze voor het zuiveren van een thermoplastisch polymeer. |
| JP2760499B2 (ja) * | 1986-11-05 | 1998-05-28 | 三菱レイヨン 株式会社 | トナー用樹脂及びその製造法 |
| LU86810A1 (fr) * | 1987-03-16 | 1988-11-17 | Labofina Sa | Procede pour enlever le solvant d'une solution de polymere |
| US4958006A (en) * | 1988-06-28 | 1990-09-18 | Union Carbide Chemicals And Plastics Inc. | Fluidized bed product discharge process |
| JPH0286604A (ja) * | 1988-09-22 | 1990-03-27 | Toyo Eng Corp | 重合体の精製方法 |
| DE3840293A1 (de) * | 1988-11-30 | 1990-05-31 | Werner & Pfleiderer | Verfahren zum entfernen von verunreinigungen aus polymeren kunststoffen und vorrichtung zur durchfuehrung des verfahrens |
| WO1991001865A1 (en) * | 1989-07-27 | 1991-02-21 | Wenger Manufacturing, Inc. | Inlet for twin screw extruder |
| US4983114A (en) * | 1989-07-27 | 1991-01-08 | Wenger Manufacturing, Inc. | Inlet for twin screw extruder |
| DE4021751A1 (de) * | 1990-07-07 | 1992-01-16 | Berstorff Gmbh Masch Hermann | Entgasungsextruder |
| JP2591526Y2 (ja) * | 1991-08-26 | 1999-03-03 | 本田技研工業株式会社 | サッシュレスドア車用ルーフキャリア |
| KR0184275B1 (ko) * | 1993-06-08 | 1999-05-15 | 바케르 헬무트 | 열 가소성 물질의 가스 제거 장치 |
| DE4437994C1 (de) * | 1994-10-25 | 1996-07-04 | Hoechst Ag | Entgasungsvorrichtung und ihre Verwendung |
| US5541285A (en) * | 1995-01-13 | 1996-07-30 | Exxon Chemical Patents Inc. | Method to process narrow molecular weight distribution polyolefins |
| JP3016711B2 (ja) * | 1995-04-17 | 2000-03-06 | 株式会社日本製鋼所 | 押出成形における脱気方法および押出機のベント装置 |
| ES2162532B1 (es) * | 1998-05-27 | 2002-08-01 | Serveis De Produccio Empresari | Perfeccionamientos en los sistemas de refrigeracion de lineas de extrusion. |
| DE102004011324B4 (de) * | 2004-03-09 | 2023-10-19 | Coperion Gmbh | Verfahren und Anlage zum Entgasen von Restmonomere enthaltendem Polyolefin-Granulat |
| US8273831B2 (en) | 2006-07-20 | 2012-09-25 | Albemarle Corporation | Process technology for recovering brominated styrenic polymers from reaction mixtures in which they are formed and/or converting such mixtures into pellets or into granules or pastilles |
| DE102013108369A1 (de) * | 2013-04-11 | 2014-10-16 | Mondi Gronau Gmbh | Verfahren zur Herstellung einer elastischen Folie für Einweg-Hygieneprodukte |
| US10730032B2 (en) | 2018-05-16 | 2020-08-04 | Chevron Phillips Chemical Company Lp | Polymer flake degassing system and methods |
| CN114410004B (zh) * | 2022-01-27 | 2023-05-23 | 杭州聚丰新材料有限公司 | 一种低气味高熔指聚丙烯及其制备方法 |
| US12421329B1 (en) * | 2024-12-23 | 2025-09-23 | Useon Technology Limited | Continuous dynamic and efficient devolatilization method for polymer/volatile system based on high mass transfer interfaces |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL101818C (enExample) * | 1955-05-18 | 1900-01-01 | ||
| US3476736A (en) * | 1966-04-14 | 1969-11-04 | Phillips Petroleum Co | Solvent removal from polyolefin in vented extruder with water addition |
| DE1529882A1 (de) * | 1966-06-18 | 1969-10-30 | Dynamit Nobel Ag | Schneckenspritzgiessmaschine |
| US3874090A (en) * | 1972-09-15 | 1975-04-01 | Polysar Ltd | Method and apparatus for drying polymeric materials |
| US4186047A (en) * | 1977-02-02 | 1980-01-29 | Phillips Petroleum Company | Solvent removal from polymer solutions |
-
1981
- 1981-06-17 NL NL8102930A patent/NL8102930A/nl not_active Application Discontinuation
-
1982
- 1982-06-08 US US06/386,314 patent/US4452977A/en not_active Expired - Fee Related
- 1982-06-09 AU AU84710/82A patent/AU553321B2/en not_active Ceased
- 1982-06-15 DE DE8282200741T patent/DE3266024D1/de not_active Expired
- 1982-06-15 EP EP82200741A patent/EP0068561B1/en not_active Expired
- 1982-06-16 CA CA000405303A patent/CA1189669A/en not_active Expired
- 1982-06-16 ES ES513154A patent/ES8400451A1/es not_active Expired
- 1982-06-16 ES ES513151A patent/ES513151A0/es active Granted
- 1982-06-17 JP JP57104656A patent/JPS583845A/ja active Granted
- 1982-06-28 IN IN756/CAL/82A patent/IN158001B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN158001B (enExample) | 1986-08-16 |
| ES513154A0 (es) | 1983-10-16 |
| ES8305006A1 (es) | 1983-03-16 |
| EP0068561B1 (en) | 1985-09-04 |
| AU8471082A (en) | 1982-12-16 |
| ES513151A0 (es) | 1983-03-16 |
| DE3266024D1 (en) | 1985-10-10 |
| AU553321B2 (en) | 1986-07-10 |
| US4452977A (en) | 1984-06-05 |
| EP0068561A1 (en) | 1983-01-05 |
| JPS583845A (ja) | 1983-01-10 |
| ES8400451A1 (es) | 1983-10-16 |
| JPH0212166B2 (enExample) | 1990-03-19 |
| NL8102930A (nl) | 1983-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |