CA1169716A

CA1169716A - Self-agitated development process

Info

Publication number: CA1169716A
Application number: CA000377464A
Authority: CA
Inventors: Dan A. Hays
Original assignee: Xerox Corp
Current assignee: Xerox Corp
Priority date: 1980-06-02
Filing date: 1981-05-13
Publication date: 1984-06-26
Also published as: BR8103447A; EP0041399B1; EP0041399A3; ES519510A0; ES8405167A1; AU7117181A; AU547726B2; MX153982A; ES502718A0; EP0041399A2; ES8304674A1; DE3168598D1

Abstract

ABSTRACT OF THE DISCLOSURE
This invention is directed to a process and apparatus for causing the development of electrostatic latent images, the process residing in the provision of a development zone, encompassed by a flexible imaging member moving at a speed of from about 5 cm/sec to about 50 cm/sec, and a transporting member moving at a speed of from about 6 cm/sec to about 100 cm/sec, the flexible imaging member and transporting member having a distance therebetween of from about 0.05 millimeters to about 1.5 milli-meters, the movement of said members causing a shearing action in said development zone, (2) adding an insulating developer composition to the development zone, the developer composition being comprised of insulating toner particles and insulating magnetic carrier particles, (3) introducing a high electric field in the development zone, (4) the insulating toner particles being caused to migrate from one layer of carrier particles to another layer of carrier particles contained in the development zone as a result of said shearing action, and said high electric field, the carrier particles rotating inone direction, then subsequently in an opposite direction, wherein said carrier particles are continuously made available immediately adjacent to the flexible imaging member.

Description

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The present invention is generally directed to an improved apparatus and an improved proeess for causing the development of images in an electrostatographic imaging system. More specifically, the present invention is directed to an improved self-agitated development apparatus 5 and development process wherein a two component insulating developer composition is contained and transported in a highly agitated development zone encompassed by an imaging member and a transporting member, thereby allowing for the continual development of high quality images, including the efficient development of solid areas.
10The development of images by electrostatographic means is well known, including the development of latent images employing toner parti-cles, as described for example in U. S. Patent 3,618,552, cascade develop-ment; U. S. Patents 2,874,063, 3,251,70~, and 3,357,402 magnetic brush development, U. S. 2,217,776 on powder cloud development, and U.S.
153,166,432 on touchdown development. In one magnetic brush system developer material comprised of toner and magnetic carrier partieles, is transported by a magnet, which magnet is the source of a magnetic field that causes alignment of the magnetic carrier into a brush like configura-tion. The resulting magnetic brush is brought into close proximity to the 20 electrostatic latent image bearing surface causing the toner particles to be attracted from the brush to the electrostatic latent image by electrostatic attraction.
While many processes are in existence for causing the develop-ment of images, difficulties continue to be encountered in the design of a 25 simple, inexpensive and reliable two-component insulative developer system, which provides a high solid area development rate, low background deposi-tion and long term stability. Thus for example, the present magnetic brush systems are sometimes inefficient since only a small fraction of the toner transported through the development zone is accessible for deposition onto 30 the image bearing member. ~or insulative developer, the solid area deposition is limited by a layer of net charged carrier particles resulting from toner deposition on a precharged imaging member. Since the develop-er entering the development zone has a neutral charge, deposition of charged toner onto the imaging member produces a layer of oppositely 35 charged developer which opposes further toner deposition. The net electr~
static force due to the charged image member and the net-charged _ `:

developer layer becomes zero for that toner between the developer and the electrostatic latent image of the imaging member. The collapse in the electrostatic force, or the electric field acting on the charged toner, occurs even though the toner charge deposited on the photoreceptor does not 5 neutralize the image charge. Image field neutrali~ation can occur, however, if there is a sufficiently high developer flow rate and multiple development rollers. Image field neutralization is herein defined to occur when the potential due to a layer of charged toner deposited on the imaging member is equal but opposite to the potential due to the charged imaging member.
10 In the absence of a bias on the development roller, image neutralization produces a zero development electric field. Since a toner layer is of finite thickness, the charge density of the toner layer is less than the image charge density for the condition of image field neutrali~ation. The difference in charge density depends on the relative thicknesses of the 15 imaging member and toner layer. If the thickness of the charged toner layer is much less than the imaging member, image field neutralization occurs when the toner charge density neutralizes the image charge density.
When magnetic brush development is accomplished with conduc-tive developer materials, the solid area deposition is not limited by a layer 20 of net-charged developer near the imaging member, since this charge is dissipated by conduction ~o the development roller. The solid area deposi-tion is, however, limited by image field neutralization, provided there is sufficient toner available at the ends of the developer brush, while the toner supply is limited to the ends or tips of the bristles, since toner cannot be 25 extracted from the bullc of the developer where the high developer conduc-tivity collapses the electric field within the developer, at any location, and confines it to the region between the latent image and the developer. For either insulative or conductive developer, the solid area deposition is limited by toner supply at low toner concentrations. The toner supply is limited to a 30 layer of carrier material adjacent to the image bearing member since the magnetic field stifens the developer and hinders developer mixing in the development zone.
Numerous improved types of toner materials, apparatus, and processes have been envisioned for the purpose of producing line copies of 35 high resolution, however, difficulties continue to be encountered in produc-ing consistently high quality copies of line and solid areas, in view of for '3'7~

example the breakdown in the trihoelectric relationship between the carrier particles and the toner particles, inefficient and incomplete removal of sufficient toner from the carrier particles, the inability of the toner particles to transfer from one carrier bead to another carrier bead in the 5 development zone, thereby depleting the amount of toner available at the surface of the image to be developed; and the like. While many of the electrophotographic machines now currently in use employ two-component developer mixtures of toner and carrier materials, solid area development is limited, particularly with magnetic brush systems utilizing insulative devel-10 oper materials, by for example, either electric field eollapse or inadequatetoner supply as explained hereinbefore.
There continues to be a need for apparatus and processes which will improve the quality of images produced, particularly in electrophoto-graphic systems, such as xerographic imaging systems, which are simple and 15 economical to operate; and which result in reproducible high quality images including both line copy quality and solid area image development. Addi-tionally, it would be desirable to provide an apparatus and a process where background development is substantially eliminated, and where the life of the developer is increased. In the systems discussed hereinbefore, there 20 continues to exist the problem of achieving uniform development for both the fine line image areas as well as the larger solid areas of the electrostatic latent image, while maintaining a minimum background densi-ty.
In accordance with the present invention there is provided an 25 improved apparatus and an improved development process wherein toner particles are made continuously available immediately adjacent to a flexible imaging surface, in that toner particles transfer from one layer of carrier particles to another layer of carrier particles in a development zone, thereby increasing the amount of toner available at the surface of the image 30 bearing member. In accordance with the present invention, this is generally accomplished by establishin~ a develop~.ent zone encompassed by a transport-ing member or development roll and a flexible image bearing member the distance between the members being from about 0.05 millimeters to about 1.5 millimeters, and preferably from about 0.4 millimeters to about 1.0 35 millimeters, the development zone containing therein insulating toner particles and insulating carrier particles. The toner migration rate depends yeneral-ly on the amount of developer agitation, the magnitude of the elec~rical ~ield applied to the development zone, the lengkh o~ the develcpment zone, and/or the amount or degree of deflection of the flexible imaging member.
5 The magnitude of the electric field is inversely proportional to the develop-er thickness, and directly proportion~l to the difference in potential between the charged imaging member and the bias on the development roller. Thus for example, for a typical image potential of about 400 volts, a background potential of about 50 volts, and a roll bias of about 100 volts to 10 suppress background deposition, the electric field potential is about 300 ` volts across the developer layer. For a preferred thickness of 0.5 mm (millimeters), the development electric field is 300 volts across 0.5 mm; i.e., 600 V/mm. Also the degree of developer agitation is proportional to the shear rate and development time, thus for a particular process speed and 15 development roll speed, increased developer agitation is obtained when the developer layer is thin, for example, one layer of toner particles and the development zone is long, which length ranges from 0.5 cm to 5 cm with a preferred length being between 1 cm and 2 cm. However, lengths outside these ranges may be used providing the objectives of the present invention 20 are accomplished.
Improved developer agitation and hence solid area development is obtained with the improved apparatus, and improved process of the present invention when a low magnetic field is present in the development zone, since with such a field, the developer does not stiffen but is fluid-like 25 under agitation and/or shearing. The magnetic field is generally less than 150 gauss and preferably less than 20 gauss. If desired, ferromagnetic material such as steel can be used to shape and reduce the magnetic field in the development zone.
A development system based on a self-agitated development 30 zone has a number of advantages over conventional systems, for example, solid area and line development is at its maximum, since the toner charge neutralizes the fields from the image charge; and development, limited by image field neutralization enables the present system to develop in one embodiment low voltage images associated with thin image bearing mem-35 bers. For a particular image potential the amount of toner deposited on theimaging bearing member is substantially independent of the spacing between the development roll, and the image bearing member, within the range of 0.05 millimeters to 1.5 millimeters.
In one specific preferred embodiment, the present invention is directed to an apparatus and a process for causing the development of 5 electrostatic latent images on a flexible imaging member, characterized in that the improvement resides in the provision of a development zone, encompassed by a flexible imaging member moving at a speed of from about 5 cm/sec to about 50 cm/sec, and a transporting member, moving at a speed of from about 6 cm/sec to about lOO cm/sec, the imaging member and 10 transporting member having a distance therebetween of from about O.OS
millimeters to about 1.5 millimeters, the movement of said members causing a shearing action in said development zone, adding an insulating developer composition to the development zone, the developer composition being comprised of insulating toner particles and insulating magnetic carrier 15 particles, introducing a high electric field in the development zone, the insulating toner particles being caused to migrate from one layer of carrier particles to another layer of carrier particles contained in the development zone as a result of said shearing action, and said high electric field, the carrier particles rotating in one direction than subsequently in an opposite 20 direction, wherein the toner particles are continuously made available i~-diately adjacent the imaging member~ While developer agitation occurs in the presence of a small magnetic field, the absence of a magnetic field is preferred. As indicated, for example, with reference to Figure 5, the flexible imaging member is deflected in an arc by the developing composi-25 tion, which deflection acts as a pressure force so as to cause agitation ofthe developer particles..
The process of the present invention is particularly adaptable in an electrophotographic imaging apparatus which comprises another feature of the present invention, the apparatus containing an imaging means, a 30 charging means, an exposure means, a development means, a transfer means, and a fusing means, characterized in that the improvement resides in the development means consisting essentially of a transporting means moving at a speed of from about 6 cm/sec to about 100 cm/sec, a flexible imaging means moving at a speed of from about S cm/sec to about 50 35 cm/sec, said transporting means and said flexible imaging means having a distance therebetween of from about 0.05 millimeters to about 1.5 milli-.

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meters, said movement causing a shearing action which in combination with a high electrical field causes insulating toner particles contained in the development means to migrate from the insulating carrier particles contained in the development means, migration being in the direction of the flexible imaging means, said migration resulting from the rotation of carrier particles in one direction and subsequently in an opposite direction as a result of said shearing action and said electric field wherein said toner particles are made continuously available immediately adjacent to the imaging means.
Various aspects of the invention thus can be listed as follows:
An improved process for causing the development of electrostatic latent images on an imaying member, - comprising providing a development zone ranging in length of from about 0.5 centimeters to about 5 centimeters, which development zone is encompassed by a tensioned deflected flexible imaging member and a transporting member wherein the flexible imaging member is comprised of a supporting substrate, a : photogenerating layer, and a transport layer, causing the deflected flexible imaging member to move at a speed of from about 5 cm/sec to about 50 cm/sec, causing the transporting member to move at a speed of from about 6 cm/sec to about 100 cm/sec, said deflected flexible imaging member and said transporting member moving at different speeds, the ratio of the velocity of the transporting member to the flexible imaging member being greater than zero and less than 1, maintaining a distance between the flexible imaging member and the transporting member of from about 0.05 millimeters to about 1.5 millimeters, adding insulating developer particles to the development zone, which particles are comprised of electrically insulating toner particles, and electrically insulating magnetic carrier particles, the flexible imaging member being deflected by the electrically insulating developer E

-6a-particles, wherein the deflection of the flexible imaging member caused by the insulating developer particles contained in the development zone is in the form of an arc, introducing a high electric field in the development zone, wherein the developer particles contained in the development zone are agitated, and the insulating toner particles migrate from one layer of carrier particles to another layer of carrier particles in the development zone, the carrier particles rotating in one direction and subsequently in another direction whereby toner particles are continuously made available immediately adjacent the deflected flexible imaging member, said process being accomplished in the absence of a magnetic field.
lS An electrostatographic imaging apparatus comprised of an imaging means, a charging means, an exposure means, a development means, and a fixing means, the improvement residing in the development means comprising in operative relationship a tensioned deflected flexible imaging means; a transporting means;
a development zone situated between the imaging means and the transporting means; the development zone containing therein electrically insulating toner particles, and electrically insulating magnetic carrier particles, means for causing the flexible imaging means to move at a speed of from about 5 cm/sec, to about 50 cm/sec, means for causing the transporting means to move at a speed of from about 6 cm/sec to about 100 cm/sec, the means for imaging and the means for transporting moving at different speeds; and the means for imaging and the means for tran.sporting having a distance therebetween of from about 0~05 millimeters to about 1.5 millimeters.
An electrostatographic imaging apparatus comprised in operative relationship of a tensioned deflected flexible imaging member, a transporting roller means containing magnets therein attached to the transporting roIler core, said roller containing thereon insulative developer particles comprised of electrically ~ .

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-6b-insulating toner particles, and electrically insulating magnetic carrier particles, whereby toner particles are transferred to the deflected flexible imaging member with the further provision that there is provided a low magnetic field means in a developmen-t zone encompassed by the deflected flexible imaging member, and the transporting roller means, and high magnetic fields at the entrance and exit regions of said development zone.
An electrostatographic imaging method which comprises forming an electrostatic image on a tensioned deflected flexible imaging member contained in an electrostatographic imaging apparatus comprised of an imaging means, a charging means, an exposure means, a development means, a transfer means, and a fixing means, the improvement residing in the development means comprised in operative relationship of a deflected.flexible imaging means, and a transporting means, means for causing the transporting means to move at a speed of from about 6 cmtsec to about lO0 cm/sec, means for causing the deflected flexible imaging member means to move at a speed of from about 5 cm/sec to about 50 cm/sec, the means for transporting and the means for imaging moving at different speeds, said deflected flexible imaging member means and said transporting means having a distance therebetween of from about 0.05 millimeters to about 1.5 millimeters, the deflection of the flexible imaging member means caused by electrically insulating developer particles comprised of electrically insulating toner particles, 0 and electrically insulating magnetic carrier particles situated in a development zone encompassed by said de.flected flexible imaging member means, and said transporting means, said deflection and said relative movement of the deflected flexible imaging member means and transporting means providing sufficient force so as to cause agitation of said developer particles, means for introducing a high electric field into the development means, wherein said electrically insulating toner particles migrate from said electrically .....

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-6c-insulating magnetic carrier particles, the migration being in the direction of the deflected flexible imaging member means, said migration resulting ~rom the rotation of the electrically insulating carrier particles in one direction and subsequently in another direction, whereby said electrically insulator toner particles are made continuously available immediately adjacent the deflected flexible imaging member means, and wherein agitation and the presence of an electrical field in the development zone causes toner particles to migrate and deposit on the electrostatic latent image, followed by transferring the developed image to a substrate, and permanently fixing the image thereto.
For a better understanding of the present invention, and further features thereof, reference is made to the following detailed description of various preferred embodiments wherein:
Figure 1 is a partially schematic cross-sectional view of the development system of the present invention. Figures lA, lB, and lC illustrate the transfer of toner particles from carrier particles to the imaging member, and the transfer of toner particles from one carrier particle bead to another carrier bead;
such transfer of toner particles occurring primarily as a result of agitation.
Figure 2 is a partially schematic cross-sectional view of a conventional development zone wherein two-component insulative developer material is employed.
Figure 3 is a partially schematic cross-sectional view of a conventional development zone wherein conductive developer is employed.
Figure 4 illustrates an electroded cell for measuring the electrical and development properties of developer.
Figure 5 illustrates a preferred embodiment of the development system of the present invention that incorporates the features of a thin long and low magnetic field development zone, as well as a high .~ `~

-6d-magnetic field at the entrance and exit regions of the development zone.
Figure 6 illustrates a comparison between (1) the solid area development characteristic of the self-agitated development system of the present invention as illustrated in Figures 1 and 5; and (2) the development characteristics of a conventional magnetic brush development system as illustrated in Figure 2.
Figure 7 illustrates another preferred embodiment of a self-,~ ~
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agitated development system that incorporates an idler rolL
Figure 8 illustrates the use of the process and device of the present invention in an electrophotographic imaging system.
Illustrated in Figure l is a development system of the present 5 invention designated lO, which is comprised of a positively charged image bearing member l, negatiely charged toner particles 2, attached to positive-ly charged carrier particles 3, a developer transporting member 4, which also serves as a development electrode, toner depleted layer D, which layer has carrier particles containing a positive charge, this layer having less lO toner on the carrier than the adjacent carrier layers, ~, B, and A, a biased voltage source 6, and a toner developed layer 7. A, B, C, and D designate layers of developer comprised of carrier and toner particles. The image bearing member l, and developer transporting member 4, in this embodiment are moving in the direction shown by the arrows 5 and Sa. In this 15 illustration the transporting member 4 is moving at a greater speed than the image bearing member l. It is this difference in speed between these two members which causes a shearing action in the development zone, thereby causing agitation of the carrier and toner particles, wherein movement of the carrier particles causes toner particles to transfer from one layer of 20 carrier particles, such as layer B, to another layer OI carrier particles, such as layer A. It is not intended to be limited to the method of operation shown, nor to be limited to any theory of operation; thus other methods of operation are envisioned by this invention. For e~ample the speed of the imaging member l can be greater than the speed of the transporting member 25 4, and movement can be in the opposite direction to that which is shown.
Also although the carrier particles 3 are shown in ordered layers7 in actual operation they can be distributed randomly in size and position. The shape of the carrier particles is not necessarily completely spherical as shown, that i9, most carrier particles are non-spherical with surfaces that can be jagged 30 or textured. Further, the toner particles 2 can be charged positively, and the carrier particles 3, can be charged negatively. Such a developer would be useful in systems where the image bearing member is charged negatively.
The arrows within the carrier particles 3, indicate that such particles are moving in both directions, first in one direction, for example, 35 slightly to the right than in another direction, slightly to the left. While moving in one direction, then another, the particles are also rotating as .

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more clearly illustrated in Figures lA-lC. This movement or agitation, which results in improved development of images, is caused primarily by the movement of the imaging member 1, and developer transporting member 4, as indicated herein.
In one m ethod of operation, as indicated hereinbefore, the development electrode 4 is moving at a surface speed which is faster than the speed of the imaging member 1, both the development electrode and the imaging member moving in the same direction. This relative motion between the development electrode 4 and imaging member 1, causes the developer which is comprised of toner particles 2, and carrier particles 3, to be agitated by a shearing action. When the speed of the image bearing member 1, is less than the speed of the electrode 4, as shown in Figure 1, the shearing action c~uses movement of the carrier particles 3, that is, the carrier particles move in both a clockwise and counterclockwise direction, - 15 but on the average tend to move in a counterclockwise direction. Thedeveloper agitation the development electric field, and deflection of the flexible imaging member allow toner particles 2 adhering to the carrier particles 3 to migrate towards the imaging member 1. The toner particles closest to the imaging member 1 are deposited on the imaging surface, therefore the carrier particles adjacent the imaging surface lose some of the toner particles adhering thereto, which toner particles must be replaced in order to continue to achieve high quality development, and in particular, solid area development. In order for this to occur, toner particles must be transferred from adjacent carrier layers, and this transfer is caused on a continual and constant basis by the shearing action mentioned hereinbefore.
Maximum agitation, which is preferred, is obtained when the magnetic field in the development zone is low, and the developer layer is thin, that is, ranging in thickness from about 0.05 millimeters to about 1.5 millimeters and preferably from about 0.4 millimeters to 1.0 millimeters. By low magnetic field it is meant that the field strength is generally less than 150 gauss.
When the image bearing member is positively charged an elec-trostatic force directed towards the imaging member acts on all of the negatively charged toner particles 2, which are near the image-carrier interface, and the carrier-carrier interfaces. In the absence of developer agitation, the electrostatic force on the toner particles is not sufficient ~9 under normal conditions to overcome the toner adhesion, and thus the toner particles are retained on the carrier particles 3. However, when agitation is supplied to the developer, that is, toner particle plus carrier particles, the toner which remains between two carrier particles can easily transfer when 5 the surfaces involved are separated, by a rolling or a sliding action. The rate of electric field assisted toner migration towards the image bearing member is therefore increased in comparison to when agitation is not utilized. As illustrated in Figure l, toner migration results in a toner depleted layer D
and although the toner depleted carrier is positively charged, the effect of 10 this charge layer on the toner motion in the bulk of the developer is small due to the proximity of the layer to the development roll. Thus, both solid area and line development will cease when the charge on the imaging member is essentially neutralized with charged toner. Accordingly, the availability of toner for solid area development is enhanced for a self-15 agitated tw~component insulative development system, and when theelectrostatic force and development agitation are sufficient, nearly all of the toner in the developer bulk will deposit on the image bearing member.
The degree of developer agitation is defined by the product of the shear rate and development time. The average shear rate is equal to the 20 absolute value of the difference in the development roller or electrode velocity, VR, and imaging member velocity, VI, divided by the developer thickness, L, i.e., the average shear rate equals I VR - Vl ~/L. The development time is equal to the development zone length, W, divided by the absolute value of the development roller speed, ~ VR ¦ ; i.e., the 25 development time equals W/ i VRI . Thus the degree of developer agitation is equal to ( I VR - Vl I /L) x (W/ I VR I ) or [ 11- l/V I ] where V is equal to VR/VI and is positive or negative when the development roller or electrode moves in the same or opposite direction to the image bearing member respectively. It is assumed that the quantity I l - l/V 1, is typically near a 30 value of 1 in which case the degree of developer agitation is approximated by W/L, i.e., the ratio of the developer zone length to the developer layer thickness. When the development zone length ranges from 0.5 cm to 5 cm (W) with a preferred length of l cm to 2 cm and the developer layer ranges in thickness of from about 0.05 mm to 1.5 mm (L) and preferably about 0.4 35 mm to l.0 mm, the developer agitation ranges from 2 to lO00 units and preferably from 10 to 50 units.

There is shown in some detail in Figure lA, lB, and lC, what is occurring at eaeh of the different layers of developer, designated A, B, and C when employing the imaging process and apparatus of the present invention. In these figures the numerical and letter designations illustrate 5the identical components as described with reference to Figure 1, with the addition that Z represents an area or zone of the carrier particles which have been depleted of toner particles. In Figure lA there is ilustrated a carrier partiele 3, of layer A, which is depleted by toner particles 2, in the area or zone Z; while Figure lB, illustrates the transfer of toner particles 2, from carrier particle 3, of layer B, to carrier particle 3, of layer A, resulting in a toner depleted area or zone Z, on earrier particle 3, layer B.
In this Figure lB, 8 represents the interface area between carrier particles.
Likewise toner particles 2 transfer from carrier particles 3 of layer C, to carrier particles 3, of layer B and there results a toner depleted layer or zone Z, on carrier particle 3, layer C. In essence thus the carrier particles of layers A, and B for example, reference Figure lB, come into contact with each other, forcing the toner particles 2 between the carrier 3 of layers A
and B, to in effect decide what carrier particles to remain with those of layer A, or those of layer B. In view of the agitation system of the present invention the toner particles move from the carrier particles of layer B, to the carrier particles of layer A, thereby replacing the depleted toner particles on the carrier of layer A in order that such particles will be available to deposit on the imaging member and cause development. In zone ~ no toner particles are present, since the electrical fields transferred the toner from the carrier beads, for example the carrier beads of layer A, to the imging member 1. This is caused primarily because of the rocking motion of the carrier beads 3, which motion further causes a positive charge to be contained on the carrier particles.
More specifically, with reference to Figures lA, lB and lC, as the carrier beads rotate as a result of agitation in accordance with the method of the present invention, some of the toner particles 2 on the carrier bead of layer A transfer to the image bearing member. The toner particles between the carrier particles of layer A, and the carrier particles of layer B, are being acted upon by two opposing forces that fromthe carrier bead of layer A, and the imaging member, and that from the carrier bead of layer B. As the force from the carrier bead of layer A and the imaging member is 3~7~

greater than the force from the carrier bead of layer B, the toner particles beeome detached from the carrier particles of layer B and attach to the carrier particles of lflyer A during bead rotation, reference ~igure lB. This action replaced the toner particles on the carrier particles of layer A but 5 leaves the carrier particles of layer B, with less toner particles. The carrier particle of layer A now has a net electrical charge of zero, whereas the carrier particle of layer B has a net positive electrical charge. The same transfer of toner particles and electrical forces is illustrated in Figure lC, however, an additional layer of carrier particles is shown, namely layer C.
lO Thus the carrier particles of la~er B obtains toner particles from the carrier particles of layer C by the methods described herein. This transfer of toner particles across the different carrier interfaces actually occurs simultan-eously throughout the development zone, and as a result toner particles are continually available on the carrier particles immediately adjacent the 15 imaging member, while the carrier particles near the transporting member 4 contain thereon an excess of positive charges, in view of the loss of toner particles to the next layer of carrier particles. After a short period of time, the charge on the carrier particles near the member 4, become neutralized as a result of the high electrical field between the carrier particles and the 20 imaging member. Subsequently, the carrier and toner particles contained thereon are allowed to pass through a development sump in order that neutral toner particles from a toner dispenser can replenish those toner particles that have been used for developing images, reference Figure 5.
Developer mixing in the developer sump charges the added toner by 25 triboeleetric charging.
When the apparatus and process of the present invention are employed in an imaging system, there is provided increased line and increased solid area development even when the developers have a rather low toner concentration in comparison to the developers used in convention-30 al systems. The minimum toner concentration for acceptable solid areadevelopment depends on several factors inclllding the ratio of the develop-ment roll speed to photoreceptor speed and the degree of developer agitation which depends on the magnetic field strength, the development zone length and the spacing between the imaging member and the develop-35 ment roll. Thus for example for a developer containing o.a5 percent byweight of toner, mixed with about 0.75 percent by weight of 100 um tj~3~

diameter steel carrier beads, the solid area development is 0.5 mg/cm2 for a development voltage of 300 volts7 a speed ratio of 3, a magnetic field less than 20 gauss, a development zone length of 3.3 cm and a developer layer thickness of 0.5 mm.
Illustrated in Figure 2 is a conventional magnetic brush develop-ment system, wherein two component insulative developer material is used, this illustration being provided in order to more clearly point out the advantages of the present invention in some respects over conventional magnetic brush systems. The imaging system of Figure 2 is comprised of an imaging member l, negatively charged toner particles 2, positively charged carrier particles 3, development electrode 4, developed toner layer 7, irnage developer interface 9, and a biased voltage source 6. The developer, that is, toner plus carrier is a two-component insulative developer as described with reference to Figure l.
The magnetic field causes the developer to form bead chains or bristles which are rigid or stiff. Thus developer agitation is limited to a region near the image developer interface 9, as no agitation is occurring with the other developer particles, transfer of toner from the carrier particles does not result, thereby in effect rendering these other developer 20 particles substantially useless. The charge density on the developer layer A
is equal to the negative of the toner charge density 7 on the image bearing member, divided by the ratio of the development roll speed to imaging member speed. The electric field from the layer of charged developer A is highly effective in reducing the net electric field at the image developer 25 interface. This electric field becomes zero despite the fact that the image charge is not neutralized by toner eharge. Solid area development with insulative developers is limited by field collapse even though a sufficient supply of toner might be contained within the first layer of developer A.
Furthermore, the solid area development rate decreases when the toner 30 concentration is low and the stiffening of developer by the magnetic field aids in limiting the supply of toner.
Illustrated in Figure 3 is an enlarged view of a development zone containing conductive developer. In this Figure, l represents the imaging member, 2 represents negatively charged toner particles, 3 represents 35 positively charged carrier particles, 4 is a development electrode, 6 represents the voltage source, 7 represents the developed toner layer. As ~ j illustrated in this Figure, the charged image bearing member induces an opposite charge in the layer of developer adjacent to the image. Toner in the developer (within the layer of developer) is inaccessible since the electric field is zero because the high developer conductivity, and the magnetic field stiffens the developer and reduces the migration of toner to the image bearing member, that is, toner particles are not transferred from one layer of carrier particles, such as B to another layer of carrier particles such as A, and thus no development will occur after a short period of time.
Thus toner development onto the imaging member only occurs from the first 10 bead layer 1. In both the systems as described in Figures 2 and 3, the amount of toner transferred from one layer of carrier particles to another layer of carrier particles is substantially zero, whereas with the system of the present invention, toner particles are being constantly replenished to the first layer of carrier particles, which replenishment is important for 15 efficient solid area development, and efficient development of lines.
The conditions which make possible a self-agitated development zone for the improvement of solid area development efficiency is more clearly appreciated by describing measurements on a well defined system.
This is illustrated in Figure 4, which represents an electroded cell for 2U measuring the development properties of developer under controlled condi-tions. In this Figure, the developer is located in a conducting tray 11 that can be biased with a voltage supply. The upper electrode 12 is coated with an insulating material such as a polyester or photoreceptor layer 13, which is contacted with the developer 14, when a bias is applied to the de~eloper tray 25 11. Movement of the electrode as indicated by the arrow causes agitation of the developer layer. The toner density developed onto layer 13 is measured by weighing the electrode assembly before and subjecting the assembly to an air jet for the purpose of removing loose toner particles. Using the device shown in Figure 4, in one embodiment, the toner weight per unit area was 30 0.23 mg/cm2 which was deposited on an insulating overcoated electrode 12 under the following conditions; a developer bed thickness of 1.5 mm, an applied voltage of 600 volts and an electrode displacement of 1.9 cm. When a magnetic field of 450 gauss was applied perpendicular to the cell electrodes, the developed toner mass decreased to 0.09 mg/cm2. The larger 35 developed toner mass for magnetic field free conditions is attributed to increased developer agitation. In a situation where an operable development ;9~ ,'h system is used the toner weight developed on the imge bearing member is proportional to the ratio of the development roll speed to the imaging member speed. Thus when this ratio is 2, and under the conditions stated herein, the toner weight per unit area of 0.46 mgtcm2 would be obtained on 5 the image bearing member. This would result in an acceptable reflective optical density of ( ¦).
When similar development data is obtained with a thinner developer layer of 0.5 mm the solid area development increases since the development electric field is higher. With a 450 gauss magnetic field 10 applied across the developer, the developed toner density is 0.28 mg/cm2 compared to the 0.09 mg/cm2 obtained for a developer thickness of 1.5 millimeters. For magnetic field free conditions, the developed density increases to 0.80 mg/cm2 compared to the 0.23 mg/cm2 obtained when the developer thickness is 1.5 mm. The increase in solid area development for 15 the magnetic field-free case is ude to a high agitation of the thin developerlayer. The agitation increases the toner supply and displaces the developer net-charge towards the development electrode. Increased solid area devel-opment is thus obtained by making the developer layer lthin and the development zone magnetic field free.
Self-agitation of developer in the development zone requires relative motion between the developer transporting electrode member and the image bearing member. When the electrode is brought into contact with the developer without lateral movement, a small quantity of toner is transferred to the electrode when a voltage is applied and the electrode is 25 removed. When the electrode is displaced while in contact with the developer, increased development occurs since the developer is agitated by the relative motion, the degree of agitation depending on the magnitude of the relative displacement which is the product of the relative speed and displacement time.
In a practical development system based on insulative developer a high solid area development rate is achieved when the development zone is thin, magnetic field free, and long, such development systems containing a means of flowing fresh developer through the development zone. Since the developer transporting roller is typically moving at a speed faster than the 35 image bearing member, developer will tend to accumulate at the entrance to the magnetic field free zone. To ensure good developer flow, a strong ~.

magnetic field at the zone entrance helps to establish proper developer flow through a low magnetic field region. A strong magnetic field at the exit region of the developer zone reduces carrier adhesion to the image bearing member, and prevents scavaging of the toner in solid areas, since as the 5 electrode spacing increases the fields in the solid areas decreases.
Illustrated in Figure 5 is a development system that incorporates the features of a thin and low magnetic field development zone, as well as a high magnetic field at the entrance and exit regions of the development zone. In this figure, there is represented a flexible development roller 15, 10 containing magnets tnerein, 16 attached to a core or "keeper" 17. The roller 15 obtains developer 18 (toner and carrier~ when it passes through the development sump 19. Metering blade 20 is used to control the thickness of the developer material. As the deflected flexible image bearing member 1 moves in the direction shown it comes into contact with the development 15 roll 15, whereby toner particles are transferred to the imaging member 1. At this point there is a low magnetic field region 21. There are high magnetic field regions located at the entrance 22 and the exit 23 of the system.
~egion (21) allows developer to remain on the roller 15, while region 22 insures good developer flow and region 23 prevents developer from contact-20 ing the latent image surface as the electrode spacing increases.
In this embodiment developer agitation occurs in the region oflow magnetic field, and the image bearing member can be a belt photo-receptor or an electroreceptor (charge patterns generated by electric~l means; such as electronic printers), both OI which can be partially wrapped 25 around the developer-covered development roll. The developer layer provides the spacing between the development roll and image bearing member. Steel shunting inside the development roll is used to reduce the magnetic field between the magnetic poles at the entrance and exit regions.
Designating v as the ratio of the development roll velocity and imaging 30 member velocity, good developer flow is obtained when the value of v is greater than zero and less than -1. If v is greater than -1, but less than zero inadequate developer flow results in the development zone.
A thin layer of developer is applied to the development roll with the aid of a metering blade 20, closely spaced -from the development roll.
35 The uniformity of the developer thickness is determined by the run-out in the roll and the straightness of the matering blade. When the metering .
.

.

blade is positioned where the magnet;c field is in a radial direction ~perpendicular to the development roll), the developer layer thickness is approximately equal to the metering blade gap setting, while when the metering blade is located where the magnetic field is tangential to the roll, the developer layer thickness is approximately 0.4 of the metering gap setting. A redueed developer layer thickness is obtained because the developer bead chains tangential to the development roll are magnetically attracted to the mass of developer peeled away by the metering blade.
Developer metering in a tangential magnetic field enables one to obtain a thin developer layer of approximately 0.5 mm when the metering gap is set at 1.2 millimeters.
Figure 6 is a graph of data displaying the solid area development characteristics of the self-agitated development system depicted in Figure 5. This figure also includes data obtained with a conventional single development roll magnetic brush development system. In Figure 6, the curve G represents data obtained for self-agitated development with a 0.4 mm gap, (distance between imaging member and transporting member) while curve H represents data obtained with a conventional magnetic brush system, 1.5 mm gap. The same developer with a toner concentration of 2.7 percent and polymer coated ferrite beads coated with a fluoropolymer was used for both systems operating at a speed ratio of 2. Increased develop-ment with the self-agitated system, curve G, is attributed to the thin developer layer (0.4 mm), low magnetic field (20 gauss) and long develop-ment zone (3 cm). For the conventional system, curve H, the gap between the photoreceptor and development roll is maintained at 1.5 mm. The magnetic field is 500 gauss over the development zone length of 0.5 cm. At a development potential of 200 volts, the reflection image density, curve G
is greater than 1, while for conventional systems at 200 volts the reflection image density, curve H, is less than 0.2.
For the self-agitated development system described herein, the spacing between the development roll and image bearing member is deter-mined by the developer layer thickness. As indicated this spacing typically ranges from about 0.05 millimeters to about 1.5 millimeters and preferably from about 0.4 millimeters to about 1.0 millimeters. The magnetic field within the central area of the development zone is generaly less than 150 gauss and preferably less than 20 gauss, while the magnetic field at the ."
;
, . . . .

g7~i entrance and exit regions of the development zone is ra~ially directed and typically 300 to 800 gauss, with magnetic poles being like polarity. The magnetic field profile is obtained by a suitable choice of permanent magnets, thus steel shunting inside the development roll can provide 5 magnetic field shaping at the surface of the development rolL
The length of the development zone depends on the configuration of the image bearing member and developer transport member. In a preferred embodiment, the image bearing member is a ~elt partially wrapped around a development roll with a diameter which is typically 3.8 10 cm to 6.4 cm. The length of contact between the developer and image bearing member ranges from 0.5 cm to 5 cm. The preferred length is 1 cm to 2 cm. Idler rolls positioned against the backside of the belt can be used to alter the belt path.
Figure 7 illustrates one example of a self-agitated development 15 system design that incorporates the use of an idler roll. Although not shown more than one idler roll can be used. The purpose of the idler roll, or rolls, is to allow freedom in the position of the zones, such as the paper transport zone for example in an electrophotographic or similar apparatus. In this Figure the numerical designations 15, 16, 17, 19, 21, 22 and 23 represent the same components as described in Figure 5. In Figure 7 the idler roll in the region 22is designated 24. Itis understood that a second idler roll could be placed near the region 23 to alter the path of the imaging member without causing a change in the operation of the development sys~em. The system shown in Figure 7 is operating in a mode in which the development roller and 25 imaging member are moving in opposite directions.
The apparatus and process of the present invention is useful in many systems including electronic printers and electrophotographic copy machines, such as those employing xerographic apparatus well known in the art. In Figure 8 there is illustrated an electrophotographic printing machine employing an imaging member 1 having a photoconductive surface deposited on a conductive substrate, such as aluminized Mylar, which is electrically grounded. The imaging member 1, or the photoconductive surface can be comprised of numerous suitable materials as described herein for example, however, for this illustration the photoconductive material is comprised of a transport layer containing small molecules of N,N,N',N'tetraphenyl-[l,l'-biphenyl~ 4-4'-diamine, or similar diamines (m-TBD) dispersed in a polycar-': , ' '` ' `

bonate and a generation layer of trigonal selenium. Imaging member 1moves in the direction of arrow 27 to advance successive portions of the photoconductive surface sequentially through the various processing stations disposed about the path of movement thereof. The imaging member is 5 entrained about a sheet-stripping roller 28, tensioning system 299 and drive roller 30. Tensioning system 29 includes a roller 31 having flanges on opposite sides thereof to define a path through which member 1 moves.
Roller 31 is mounted on each end of guides attached to the springs. Spring 32 is tensioned such that roller 31 presses against the imaging belt member 1.
10 In this way, member 1 is placed under the desired tension. The level of tension is relatively low permitting member 1 to be relatively easily deformed with continued reference to Figure 8, drive roller 30 is mounted rotatably and in engagement with member 1. Motor 33 rotates roller 30 to advance member 1 in the direction of arrow 2q. Roller 30 is coupled to 15 motor 33 by suitable means such as a belt drive. sheet-stripping roller 28 isfreely rotatable so as to readily permit member 1 to move in the direction of arrow 27 with a minimum of friction.
Initially, a portion of imaging member 1 passes through charging station H. At charging station H, a corona generating device, indicated 20 generally by the reference numeral 34, charges the photoconductive surface of imaging member 1 to a relatively high, substantially uniform potential.
Next, the charged portion of the photoconductive surface is advanced through exposure station I. An original document 35 is positioned face down upon transparent platen 36. Lamps 3~ flash light rays onto 25 original document 35. The light rays reflected from original document 35 are transmitted through lens 38 forming a light image thereof. Lens 38 focuses the light image onto the charged portion of the photoconductive surface to selectively dissipate the charge thereon. This records an electrostatic latent image on the photoconductive surface which corres-30 ponds to the informational areas contained within original document 35.
Thereafter, imaging member 1 advances the electrostatic latentimage recorded on the photoconductive surface to development station J.
At development station J, a self-agitated development system, indicated generally by the reference numeral 39, advances a developer material into 35 contact with the electrostatic latent image. The self-agitated development system 39 includes a developer roller 40 which transports a layer of .

, developer material comprising magnetic carrier particles and toner particles into contact with imaging member 1. As shown in Figure 1, developer roller 40 is positioned such that the brush of developer material deforms imaging member 1 in an arc such that member 1 conforms at least partially, to the 5 configuration of the developer materi~l. The electrostatic latent image attracts the toner particles from the carrier granules forming a toner powder image on the photoconducitve surface of member 1. The develop-ment roller 40 returns the developer material to the sump of development system 39 for subsequent re-use. The detailed structure of the development system 39 has been described herein, reference Figures 1, lA, lB, lC, 5 and 7.
Imaging member 1 then advances the toner powder image to transfer station R. At transer station K, a sheet of support material 44 is moved into contact with the toner powder image. The sheet of support material 44 is advanced to transfer station K by a sheet feeding apparatus 15 (not shown). Preferably9 the sheet feeding apparatus includes a feed roll contacting the uppermost sheet of a stack of sheets. The feed roll rotates so as to advance the uppermost sheet from the stack of sheets. The feed roll rotates so as to advance the uppermost sheet from the stack into a chute. The chute directs the advancing sheet of support material into 20 contact with the photoconductive surface of member 1 in a timed sequence so that the toner powder image developed thereon contacts the advancing sheet of support material at transfer station K.
Transfer station K includes a corona generating device 46 which sprays ions onto the backside of sheet 44. This attracts the toner powder 25 image from the photoconductive surface to sheet 44. After transfer, sheet 44 moves in the direction of arrow 48 onto a conveyor (not shown) which advances sheet 44 to fusing station L.
Fusing station L includes a fuser assernbly, indicated generally by the reference numeral 50, which permanently affixes the transferred 30 toner powder image to sheet 44. Preferably, fuser assembly 50 includes a heated fuser roller 52 and a back-up roller 54. Sheet 44 passes between fuser roller 52 and back-up roller 54 with the toner powder image contacting fuser roller 52. In this manner, the toner powder image is permanently affixed to sheet 44. After fusing, a chute guides the advancing sheet 44 to a 35 catch tray for subsequent removal from the printing machine by the operator.

`~

~ " , ~ .

.

Invarlably, after the sheet o~ support material is separated from the photoconductive surface or imaging member 1 some residual particles remain adhering thereto. These residual particles are removed from the photoconductive surface at cleaning .sta~ion M.
Cleaning station L includes a rotatably mounted fibrous brush 56 in contact with the photoconductive surface.
The particles are cleaned from the photoconductive surface by the rotation of brush 56 in contact therewith. Subsequent to cleaning, a discharge lamp (not shown) floods photoconductive surface 12 with light to dissipate any residual electrostatic charge remaining thereon prior to the charging thereof for the next successive imaging cycle.
It is believed that the foregoing description is sufficient for purposes of the present application to illustrate the general operation of an electrophotographic printing machine incorporating the features of the present invention therein.
Illustrative examples of the flexible image bearing member 1, include inorganic and organic photoreceptor materials such as for example amorphous selenium, selenium alloys, including alloys of selenium-tellurium, selenium arsenic, selenium antimony, selenium-tellurium-arsenic, cadmium sulfide, zinc oxide, polyvinylcarbazole, layered organic photoreceptors, such as those containing as an injecting contact, carbon dispersed in a polymer, overcoated with a transport layer, which in turn i5 overcoated with a generating layer, and finally an overcoating of an insulating organic resin, such as those described in U.S. Patent 4,251,612, on Dielectric Overcoated Photoresponsive Imaging Member and Imaging Method.
Thus, as disclosed in U.S. Patent 4,251,612, the flexible image bearing member may be comprised of a layered organic photoresponsive device comprised of a substrate overcoated with a hole injecting material which, in turn, is overcoated with a hole transport ~ ~ .

7~
-20a-layer overcoated with a charge generating layer in contact with an electrically insulating resin.
Alternatively, as disclosed in U.S. Patent 4,251,612, the flexible image bearing member ma~v be comprised of a substrate, a hole transport layer and a charge generating layer.
As specifically disclosed in U.S. Patent 4,251,612, the photogenerating layer may be comprised of vanadyl phthalocyanine, metal phthalocyanines or metal free phthalocyanines and the transport layer may be comprised of electrically active diamine molecules dispersed in an inactive resinous binder, the diamine molecules being of the formula ~N

wherein X is selected from the group consisting of (ortho) CH3, (meta) CH3, (para) C~3, (ortho) Cl, (meta) Cl, (para) Cl.
Other organic photoreceptor materials include 4-dimethylaminobenzylidene, benzhydrazide; 2-benzyl idene-amino-carbazole, 4-dimethylamino-benzylidene, benzhydrazide; 2-benzylidene-amino-carbazole, polyvinyl carbazole; (2-nitro-benzylidene)p-bromo-aniline; 2,4-diphenyl quinazoline, 1,2,4-triazone; 1,5-diphenyl-3-methyl pyrazoline 2-(4'-dimethylamino phenyl) benzox-azole; 3 amino-carbazole; polyvinylcarbazole-trinitro-30fluorenone charge transfer complex; phthalocyanines and mixtures thereof, and the like.
Illustrative examples of the transporting member 4 include virtually any conducting material made for this purpose, such as stainless steel, aluminum and the like. Texture in the development roll provides .

~ 6~

traction necessary for good developer transport from the developer sump and through the development zone. The development roll texture is obtained by one of several methods involving flame-spray treating, etching, knurling, etc.
The developer material is comprised of a toner resin, colorant or pigment, and a suitable insulatin~ magnetic carrier material. By insulating as used throughout the description, is meant non-conducting, that is, for example charge does not tend to flow from the transport member to the ends of the carrier particles nearest the image bearing member within a time that is less than the development time. In one embodiment thus the range of development times is calculated as follows:

Longest Time W = 5 cm =~second -~ ~"Fi' cm/sec Shortest time 10~ r~n/sec = 5 10 seconds While any suitable material may be employed as the toner resin in the system of the present invention, typical of such resins are polyamides, epoxies, polyurethanes, vinyl resins and polymeric esterification products of 20 a dicarboxylic acid and a diol comprising a diphenol. Any suitable vinyl resin may be employed in the toners of the present system including homopolymers or copolymers of two or more vinyl monomers. Typical of such vinyl monomeric units include: styrene, p-chlorostyrene vinyl naphtha-lene, ethylenecally unsaturated mono olefins such as ethylene, propylene, 25 butylene, isobutylene and the like; vinyl esters such as vinyl chloride, vinyl bromide, vinyl fluoride, vinyl acetate,vinyl propionate, vinyl benzoate, vinyl butyrate and the like; esters of alphamethylene aliphatic monocarboxylic acids such as methyl acrylate, ethyl acrylate, n-butylacrylate, isobutyl acrylate, dodecyl acrylate, n-octyl acrylate, 2-chloroethyl acrylate, phenyl 30 acrylate, methyl alphachloroacrylate, methyl methacrylate, ethyl methacry-late, butyl methacrylate and the like; acrylonitrile, rnethacrylonitrile, acrylamide, vinyl ethers such as vinyl methyl ether, vinyl isobutyl ether, vinyl ethyl ether, and the like; vinyl ketones such as vinyl methyl ketone, vinyl hexyl ketone, methyl isopropenyl ketone and the like; vinylidene 35 halides such as vinylidene chloride, vinylidene chlorofluoride and the like;
and N-vinyl indole,N-vinyl pyrrolidene and the like; and mixtures thereof.

A~, .

Generally toner resins containing a relatively high percentage of styrene are preferred since greater image dPfinition and density is obtained with their use. The styrene resin employed may be a homopolymer of styrene or styrene homologs of copolymers of styrene with other - 5 monomeric groups containing a single methylene group attached to a carbon atom by a double bond. Any of the above typical monomeric units may be copolymerized with styrene by addition polymerizationO Styrene resins may also be formed by the polymerization of mixtures of two or more unsaturated monomeric materials with a styrene monomer. The addition polymerization techique employed embraces known polymerization techiques such as free radical, anionic and cationic polymerization processes. Any of these vinyl resins may be blended with one or more resins if desired, preerably other vinyl resins which insure good triboelectric properties and uniform resistance against physical degradation. However, non-vinyl type thermoplastic resins may also be employed including resin modified phenolformaldehyde resins, oil modified epoxy resins, polyurethane resins, cellulosic resins, polyether resins and mixtures thereof.
Also esterification products of a dicarboxylic acid and a diol comprising a diphenol may be used as a preferred resin material for the toner composition of the present invention. These materials are illustrated in U. S. Patent 3,655,374, the diphenol reactant being of the formula as shown in column 4, beginning at line 5 of this patent and the dicarboxylic acid being of the formula as shown in column 6 of the above patent. The resin is present in an amount so that the total of all ingredients used in the toner total about 100 percent, thus when 5 percent by weight of the alkyl pyridinium compound is used and 10 percent by weight of pigment such as carbon black, about 85 percent by weight of resin material is used.
Optimum electrophotographic resins are achieved with styrene butylmethacrylate copolymers, styrene vinyl toluene copolymers, styrene acrylate copolymers, polyester resins, predominantly styrene or polystyrene based resins as generally described in U. S. Reissue 24,136 to Carlson and polystyrene blends as described in U. S. Patent No. 2,788,2~8 to Rheinfrank and Jones.
The toner resin particles can vary in diameter, but generally range from about 5 microns to about 30 microns in diameter, and preferably from about 10 microns to about 20 microns.
Any suitable pigment or dye may be employed as the colorant for the toner particles, such materials being well known and including for example, carbon black, nigrosine dye, aniline blue, calco oil blue, chrome yellow, ultramarine blue, DuPont oil red, methylene blue chloride, phthalocyanine blue and mixtures thereof. The pigment or dye should be present in sufficient quantity to render it highly colored so that it will form a clearly visible image on the recording member.
For example, where conventional xerographic copies of docu-ments are desired, the toner may comprise a black pigment such as carbon black or a black dye such as Amaplast* black dye available from the National Aniline Products Inc. Pre-ferably the pigment is employed in amounts from about 3 per-cent to about 20 percent by weight based on the total weight of toner, however, if the toner color employed is a dye, - 25 substantially smaller quantities of the color may be used.
Also there can be incorporated in the toner (resin plus colorant) various charge control agents primarily for the purpose of imparting a positive charge to the toner resin. Examples of charge control agents includes quaternary ammonium compounds as described in U. S. Patent 3 t 970,571, and alkyl pyridinium halides such as cetyl pyridinium chloride.
Any suitable insulating magnetic carrier material can be employed as long as such particles are capable of - triboelectrically obtaining a charge of opposite polarity to that of the toner particles. In the present invention in one embodiment that would be negative polarity, to that of the *trade mark ' -23a-toner particles which are positively charged so that the toner particles will adhere to and surround the carrier particles. Thus, the carriers can be selected so that the toner particles acquire a charge of a positive polarity and include materials such as steel, nickel, iron ~errites, magnetites and the like. The carriers can be used with or without a coating, examples of coatings including fluoropolymers such as polyvinylidene fluoride, methyl terpolymers and the like. Also nickel berry carriers as described in U. S. Patents 3,847,604 and 3,767,538 can be employed, provided they are rendered insulating in accordance with the process defined herein, these carriers being nodular carrier beads of nickel characterized by surface of reoceurring recesses and protrusions providing particles with a relativel~J
lar~e external area. Preferably the carrier particles, or their cores are of materials that are sufficiently conducting but yet insulating to dissipate net 5 charge accumulation from the development process such as for example steel shot carriers. The diameter of the coated carrier particle ranges from about 50 to about 1000 microns, thus allowing the carrier to possess sufficient density and inertia to avoid adherene to the electrostatic images during the development proeess.
The carrier may be employed with the toner coMposition in any suitable combination, however, best results are obtained when about 1 part per toner is used and about 10 to about 4000 parts by weight of carrier.
Other modifications of the present invention will occur to those skilled in the art based upon a reading of the present disclosure. These are 15 intended to be included within the scope of the present invention.

Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS
FOLLOWS:

1. An improved process for causing the development of electrostatic latent images on an imaging member, comprising providing a development zone ranging in length of from about 0.5 centimeters to about 5 centimeters, which development zone is encompassed by a tensioned deflected flexible imaging member and a transporting member wherein the flexible imaging member is comprised of a supporting substrate, a photo generating layer, and a transport layer, causing the deflected flexible imaging member to move at a speed of from about 5 cm/sec to about 50 cm/sec, causing the transporting member to move at a speed of from about 6 cm/sec to about 100 cm/sec, said deflected flexible imaging member and said transporting member moving at different speeds, the ratio of the velocity of the transporting member to the flexible imaging member being greater than zero and less than 1, maintaining a distance between the flexible imaging member and the transporting member of from about 0.05 millimeters to about 1.5 millimeters, adding insulating developer particles to the development zone, which particles are comprised of electrically insulating toner particles, and electrically insulating magnetic carrier particles, the flexible imaging member being deflected by the electrically insulating developer particles r wherein the deflection of the flexible imaging member caused by the insulating developer particles contained in the development zone is in the form of an arc, introducing a high electric field in the development zone, wherein the developer particles contained in the development zone are agitated, and the insulating toner particles migrate from one layer of carrier particles to another layer of carrier particles in the development zone, the carrier particles rotating in one direction and subsequently in another direction whereby toner particles are continuously made available immediately adjacent the deflected flexible imaging member, said process being accomplished in the absence of a magnetic field.

2. A process in accordance with claim 1 wherein said transport layer is comprised of electrically active diamine molecules dispersed in an inactive resinous binder, the diamine molecules being of the formula wherein X is selected from the group consisting of (ortho) CH3, (meta) CH3, (para) CH3, (ortho) Cl, (meta) Cl, (para) Cl.

3. A process in accordance with claim 2 wherein the development time ranges from 0.83 seconds to about 5.10-3 seconds.

4. A process in accordance with any of claims 1, 2 or 3 wherein the distance between the deflected flexible imaging member and the transporting member ranges from about 0.4 millimeters to about 1.0 millimeters.

5. A process in accordance with any of claims 1, 2 or 3 wherein the length of the development zone varies from about 1 centimeter to about 2 centimeters.

6. A process in accordance with any of claims 1, 2 or 3 wherein the deflected flexible imaging member and transporting member are moving in the same direction, or in opposite directions.

7. A process in accordance with any of claims 1, 2 or 3 wherein the magnetic field present in the development zone is less than 150 gauss.

8. A process in accordance with any of claims 1, 2 or 3 wherein the electrically insulating toner particles contained in the developer are charged positively, the electrically insulating magnetic carrier particles contained in the developer are negatively charged, and the flexible imaging member is charged negatively.

9. A process in accordance with any of claims 1, 2 or 3 wherein the electrically insulating toner particles contained in the developer are charged positively, the electrically insulating magnetic carrier particles contained in the developer are negatively charged, and the flexible imaging member is charged negatively, and wherein the insulating developer particles include a charge control additive for the purpose of imparting a positive charge to said toner particles.

10. A process in accordance with any of claims 1, 2 or 3 wherein the electrically insulating toner particles contained in the developer are charged positively, the electrically insulating magnetic carrier particles contained in the developer are negatively charged, and the flexible imaging member is charged negatively, and wherein the insulating developer particles include a charge control additive for the purpose of imparting a positive charge to said toner particles, said charge control additive being a quaternary ammonium compound.

11. A process in accordance with any of claims 1, 2 or 3 wherein the electrically insulating toner particles contained in the developer are charged positively, the electrically insulating magnetic carrier particles contained in the developer are negatively charged, and the flexible imaging member is charged negatively, and wherein the insulating developer particles include a charge control additive for the purpose of imparting a positive charge to said toner particles, said charge control additive being an alkyl pyridinium halide.

12. A process in accordance with any of claims 1, 2 or 3 wherein the electrically insulating toner particles contained in the developer are charged positively, the electrically insulating magnetic carrier particles contained in the developer are negatively charged, and the flexible imaging member is charged negatively, and wherein the insulating developer particles include a charge control additive for the purpose of imparting a positive charge to said toner particles, said charge control additive being an alkyl pyridinium halide, said alkyl pyridinium halide being cetyl pyridinium chloride.

13. A process in accordance with any of claims 1, 2 or 3 wherein the deflected flexible imaging member is comprised of a layered organic photoresponsive device comprised of a substrate, overcoated with a hole injecting material, which in turn is overcoated with a transport layer, overcoated with a generating layer in contact with an electrically insulating resin.

14. A process in accordance with any of claims 1, 2 or 3 wherein the photogenerating layer is comprised of vanadyl phthalocyanine, metal phthalocyanines, or metal free phthalocyanines, and the transport layer is comprised of a diamine.

15. An electrostatographic imaging apparatus comprised of an imaging means, a charging means, an exposure means, a development means, and a fixing means, the improvement residing in the development means comprising in operative relationship a tensioned deflected flexible imaging means; a transporting means;
a development zone situated between the imaging means and the transporting means; the development zone containing therein electrically insulating toner particles, and electrically insulating magnetic carrier particles, means for causing the flexible imaging means to move at a speed of from about 5 cm/sec, to about 50 cm/sec, means for causing the transporting means to move at a speed of from about 6 cm/sec to about 100 cm/sec, the means for imaging and the means for transporting moving at different speeds; and the means for imaging and the means for transporting having a distance therebetween of from about 0.05 millimeters to about 1.5 millimeters.

16. An electrostatographic imaging apparatus in accordance with claim 15 wherein there is further included in the development means, means for introducing a high electric field.

17. An electrostatographic imaging apparatus in accordance with claim 16 wherein the electrically insulating toner particles migrate from the electrically insulating magnetic particles in the direction of the deflected flexible imaging member, said migration resulting from the rotation of the electrically insulating carrier particles in one direction, and subsequently in another direction, whereby the electrically insulating toner particles are made continuously available immediately adjacent to the deflected flexible imaging means.

18. An electrostatographic imaging apparatus in accordance with claim 16 wherein the tensioned deflected flexible imaging member and transporting member are moving in the same direction or in an opposite direction.

19. An electrostatographic imaging apparatus in accordance with claim 16 wherein the distance between the deflected flexible imaging member means and the transporting member means ranges from about 0.4 millimeters to about 1 millimeter, and the development zone length ranges from about 1 centimeter to about 2 centimeters.

20. An electrostatographic imaging apparatus in accordance with claim 16 wherein the electrically insulating toner particles contained in the developer composition are charged positively, and the electrically insulating magnetic carrier particles contained in the developer composition are charged negatively, and the flexible imaging member is charged negatively.

21. An electrostatographic imaging apparatus in accordance with claim 20 wherein there is added thereto a charge control additive for the purpose of imparting a positive charge to the toner resin.

22. An electrostatographic imaging apparatus in accordance with claim 21 wherein the charge control additive is a quaternary ammonium compound or an alkyl pyridinium halide.

23. An electrostatographic imaging apparatus in accordance with claim 16 wherein the deflected flexible imaging member is comprised of a photoresponsive member containing a substrate, a hole injecting layer, a hole transport layer, a charge generating layer, and an overcoated layer of an electrically insulating organic resin.

24. An electrostatographic 16 imaging apparatus in accordance with claim 16 wherein the deflected flexible imaging member contains a substrate, a charge generating layer, and a hole transport layer.

25. An electrostatographic imaging apparatus comprised in operative relationship of a tensioned deflected flexible imaging member, a transporting roller means containing magnets therein attached to the transporting roller core, said roller containing thereon insulative developer particles comprised of electrically insulating toner particles, and electrically insulating magnetic carrier particles, whereby toner particles are transferred to the deflected flexible imaging member with the further provision that there is provided a low magnetic field means in a development zone encompassed by the deflected flexible imaging member, and the transporting roller means, and high magnetic fields at the entrance and exit regions of said development zone.

26. An electrostatographic imaging apparatus in accordance with claim 25 wherein the deflected flexible imaging member is comprised of a substrate, a hole injecting layer, a hole transport layer, a charge generating layer, and an overcoated layer of an electrically insulating organic resin.

27. An electrostatographic imaging apparatus in accordance with claim 25 wherein the deflected flexible imaging member is comprised of a substrate, a hole transport layer, and a charge generating layer.

28. An electrostatographic imaging apparatus in accordance with claim 25 wherein there is maintained a distance of from about 0.05 millimeters to about 1.5 millimeters between the deflected flexible imaging member and the transporting roller.

29. An electrostatographic imaging apparatus in accordance with claim 15 wherein there is further included an idler roller.

30. An electrostatographic imaging method which comprises forming an electrostatic image on a tensioned deflected flexible imaging member contained in an electrostatographic imaging apparatus comprised of an imaging means, a charging means, an exposure means, a development means, a transfer means, and a fixing means, the improvement residing in the development means comprised in operative relationship of a deflected flexible imaging means, and a transporting means, means for causing the transporting means to move at a speed of from about 6 cm/sec to about 100 cm/sec, means for causing the deflected flexible imaging member means to move at a speed of from about 5 cm/sec to about 50 cm/sec, the means for transporting and the means for imaging moving at different speeds, said deflected flexible imaging member means and said transporting means having a distance therebetween of from about 0.05 millimeters to about 1.5 millimeters, the deflection of the flexible imaging member means caused by electrically insulating developer particles comprised of electrically insulating toner particles, and electrically insulating magnetic carrier particles situated in a development zone encompassed by said deflected flexible imaging member means, and said transporting means, said deflection and said relative movement of the deflected flexible imaging member means and transporting means providing sufficient force so as to cause agitation of said developer particles, means for introducing a high electric field into the development means, wherein said electrically insulating toner particles migrate from said electrically insulating magnetic carrier particles, the migration being in the direction of the deflected flexible imaging member means, said migration resulting from the rotation of the electrically insulating carrier particles in one direction and subsequently in another direction, whereby said electrically insulator toner particles are made continuously available immediately adjacent the deflected flexible imaging member means, and wherein agitation and the presence of an electrical field in the development zone causes toner particles to migrate and deposit on the electrostatic latent image, followed by transferring the developed image to a substrate, and permanently fixing the image thereto.

31. An electrostatographic imaging method in accordance with claim 30 wherein the deflected flexible imaging member is comprised of a substrate, a hole injecting layer, a hole transport layer, a charge generating layer, and an overcoating layer of an insulating organic resin.

32. An electrostatographic imaging method in accordance with claim 30 wherein said deflected flexible imaging member is comprised of a substrate, a hole transport layer, and a charge generating layer.

33. An electrostatographic imaging method in accordance with claim 30 wherein the deflected flexible imaging member and transporting member are moving in the same direction, or said members are moving in opposite directions.

34. An electrostatographic imaging method in accordance with claim 30 wherein the toner particles are comprised of a styrene butylmethacrylate copolymer resin, and carbon black.

35. An electrostatographic imaging method in accordance with claim 30 wherein there is added to the developer composition a charge enhancing additive.

36. An electrostatographic imaging method in accordance with claim 35 wherein the charge enhancing additive is a quaternary ammonium compound, or an alkyl pyridinium halide.