CA1163191A - Flowable pesticides - Google Patents
Flowable pesticidesInfo
- Publication number
- CA1163191A CA1163191A CA000389053A CA389053A CA1163191A CA 1163191 A CA1163191 A CA 1163191A CA 000389053 A CA000389053 A CA 000389053A CA 389053 A CA389053 A CA 389053A CA 1163191 A CA1163191 A CA 1163191A
- Authority
- CA
- Canada
- Prior art keywords
- suspension
- active compound
- water
- dispersant
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 24
- 230000009969 flowable effect Effects 0.000 title claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 95
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000000725 suspension Substances 0.000 claims abstract description 66
- 239000002270 dispersing agent Substances 0.000 claims abstract description 55
- 239000002245 particle Substances 0.000 claims abstract description 47
- 239000000945 filler Substances 0.000 claims abstract description 39
- 239000007787 solid Substances 0.000 claims abstract description 35
- 239000002904 solvent Substances 0.000 claims abstract description 32
- 239000004615 ingredient Substances 0.000 claims abstract description 21
- 238000003860 storage Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000001016 Ostwald ripening Methods 0.000 claims abstract description 6
- 238000005054 agglomeration Methods 0.000 claims abstract 2
- 230000002776 aggregation Effects 0.000 claims abstract 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 54
- 239000003960 organic solvent Substances 0.000 claims description 23
- CJJOSEISRRTUQB-UHFFFAOYSA-N azinphos-methyl Chemical group C1=CC=C2C(=O)N(CSP(=S)(OC)OC)N=NC2=C1 CJJOSEISRRTUQB-UHFFFAOYSA-N 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000002609 medium Substances 0.000 claims description 19
- 238000009826 distribution Methods 0.000 claims description 17
- 230000000274 adsorptive effect Effects 0.000 claims description 15
- 239000003085 diluting agent Substances 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 239000000080 wetting agent Substances 0.000 claims description 12
- -1 sodium silica aluminate Chemical class 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 238000005549 size reduction Methods 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 150000002500 ions Chemical group 0.000 claims description 6
- 239000003090 pesticide formulation Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229920001732 Lignosulfonate Polymers 0.000 claims description 4
- FGDMJJQHQDFUCP-UHFFFAOYSA-M sodium;2-propan-2-ylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(C(C)C)=CC=C21 FGDMJJQHQDFUCP-UHFFFAOYSA-M 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 230000001351 cycling effect Effects 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 238000001953 recrystallisation Methods 0.000 claims description 3
- 230000009974 thixotropic effect Effects 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 230000001687 destabilization Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 230000000361 pesticidal effect Effects 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims 2
- 150000001340 alkali metals Chemical group 0.000 claims 1
- 230000000368 destabilizing effect Effects 0.000 claims 1
- 229920005611 kraft lignin Polymers 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 230000035945 sensitivity Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 230000003381 solubilizing effect Effects 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 238000007614 solvation Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 59
- 238000009472 formulation Methods 0.000 description 45
- 239000004480 active ingredient Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000002917 insecticide Substances 0.000 description 10
- 230000007423 decrease Effects 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 230000000749 insecticidal effect Effects 0.000 description 6
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 6
- 229920005552 sodium lignosulfonate Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000005583 Metribuzin Substances 0.000 description 5
- 230000002411 adverse Effects 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 230000000994 depressogenic effect Effects 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- YFBPRJGDJKVWAH-UHFFFAOYSA-N methiocarb Chemical compound CNC(=O)OC1=CC(C)=C(SC)C(C)=C1 YFBPRJGDJKVWAH-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 4
- 244000144730 Amygdalus persica Species 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000006040 Prunus persica var persica Nutrition 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000003701 inert diluent Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 description 2
- 239000005745 Captan Substances 0.000 description 2
- STUSTWKEFDQFFZ-UHFFFAOYSA-N Chlordimeform Chemical compound CN(C)C=NC1=CC=C(Cl)C=C1C STUSTWKEFDQFFZ-UHFFFAOYSA-N 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 239000005951 Methiocarb Substances 0.000 description 2
- 241001585678 Orthosia hibisci Species 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 2
- 235000012216 bentonite Nutrition 0.000 description 2
- 229930188620 butyrolactone Natural products 0.000 description 2
- 229940117949 captan Drugs 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000006911 nucleation Effects 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000254175 Anthonomus grandis Species 0.000 description 1
- 101100204264 Arabidopsis thaliana STR4 gene Proteins 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- PHVNLLCAQHGNKU-UHFFFAOYSA-N Dimethipin Chemical compound CC1=C(C)S(=O)(=O)CCS1(=O)=O PHVNLLCAQHGNKU-UHFFFAOYSA-N 0.000 description 1
- 241001183277 Epitrix similaris Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 235000008098 Oxalis acetosella Nutrition 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 241000231739 Rutilus rutilus Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 101100393134 Streptococcus pneumoniae serotype 4 (strain ATCC BAA-334 / TIGR4) glyG gene Proteins 0.000 description 1
- 101150076149 TROL gene Proteins 0.000 description 1
- 244000126309 Trifolium dubium Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- IMHBYKMAHXWHRP-UHFFFAOYSA-N anilazine Chemical compound ClC1=CC=CC=C1NC1=NC(Cl)=NC(Cl)=N1 IMHBYKMAHXWHRP-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 238000010296 bead milling Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000012656 cationic ring opening polymerization Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000010959 commercial synthesis reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000003621 hammer milling Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 1
- 229920000940 maneb Polymers 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- NRHFWOJROOQKBK-UHFFFAOYSA-N triphenyltin;hydrate Chemical compound O.C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 NRHFWOJROOQKBK-UHFFFAOYSA-N 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/207,318 US4348385A (en) | 1980-11-17 | 1980-11-17 | Flowable pesticides |
| US207,318 | 1980-11-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1163191A true CA1163191A (en) | 1984-03-06 |
Family
ID=22770031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000389053A Expired CA1163191A (en) | 1980-11-17 | 1981-10-29 | Flowable pesticides |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4348385A (en:Method) |
| EP (1) | EP0052313B1 (en:Method) |
| JP (1) | JPS57109701A (en:Method) |
| AR (1) | AR229516A1 (en:Method) |
| AT (1) | ATE15747T1 (en:Method) |
| AU (1) | AU543845B2 (en:Method) |
| BR (1) | BR8107457A (en:Method) |
| CA (1) | CA1163191A (en:Method) |
| DE (1) | DE3172450D1 (en:Method) |
| DK (1) | DK507181A (en:Method) |
| ES (1) | ES8303025A1 (en:Method) |
| GR (1) | GR78018B (en:Method) |
| IL (1) | IL64293A0 (en:Method) |
| NZ (1) | NZ198962A (en:Method) |
| PT (1) | PT73944B (en:Method) |
| ZA (1) | ZA817903B (en:Method) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4891385A (en) * | 1981-11-23 | 1990-01-02 | Mobay Corporation | Insecticidal compositions |
| US4849415A (en) * | 1983-03-03 | 1989-07-18 | The Dow Chemical Company | Sustained release compositions |
| IT1173066B (it) * | 1984-01-18 | 1987-06-18 | Sipcam Spa | Sospensione fluida stabilizzata di antiparassitari in solventi organici non clorurati e procedimento di preparazione e di impiego della stessa |
| EP0217125B1 (en) * | 1985-09-27 | 1990-08-16 | American Cyanamid Company | Pesticidal aqueous flowable compositons |
| AU596637B2 (en) * | 1986-08-06 | 1990-05-10 | Sumitomo Chemical Company, Limited | Mulching film for repelling insect pests |
| WO1988007813A1 (en) * | 1987-04-14 | 1988-10-20 | Greencare Pty. Limited | Soil spreader |
| US4954349A (en) * | 1987-09-11 | 1990-09-04 | Ciba-Geigy Corporation | Oral magnesium and potassium compositions and use |
| IL89559A (en) * | 1989-03-09 | 1992-09-06 | Adhestick Ramle | Sprayable bird and animal pest repellent composition containing a tacky polyolefin and methods for the preparation and use thereof |
| DE3910921C1 (en:Method) * | 1989-04-05 | 1990-05-17 | Bayer Ag, 5090 Leverkusen, De | |
| DE3910922C1 (en:Method) * | 1989-04-05 | 1990-05-17 | Bayer Ag, 5090 Leverkusen, De | |
| CA2075920A1 (en) * | 1990-12-18 | 1992-06-19 | Jeffrey L. Jensen | Precipitated flowable concentrate formulations, their preparation and their agricultural uses |
| RU2103873C1 (ru) * | 1991-01-09 | 1998-02-10 | Е.Райт Джеймс | Штамм гриба beauveria bassiana, предназначенный для получения энтомопатогенного препарата против хлопкового долгоносика, белянки сладкого картофеля и хлопкового слепняка, композиция для борьбы с насекомыми-вредителями, способ борьбы с насекомыми-вредителями |
| JP3804072B2 (ja) * | 1991-08-07 | 2006-08-02 | 日産化学工業株式会社 | 水性懸濁状農薬製剤 |
| ZA93394B (en) * | 1992-01-24 | 1993-08-05 | Ici Australia Operations | Water dispersible granules of low melting point pesticides. |
| AU712319B2 (en) * | 1996-03-20 | 1999-11-04 | Rhodia Inc. | Nonaqueous suspension concentrates of highly water-soluble solids |
| AU4165999A (en) * | 1998-06-24 | 2000-01-10 | Shionogi & Co., Ltd. | Pesticide preparations in the form of aqueous suspension |
| IL160103A0 (en) * | 2001-08-06 | 2004-06-20 | Astrazeneca Ab | Aqueous dispersion comprising stable nanoparticles of a water-insoluble active substance and an excipient like middle chain triglycerides (mct) |
| GB0126144D0 (en) * | 2001-10-31 | 2002-01-02 | Syngenta Ltd | Pesticidal formulations |
| AU755845B1 (en) * | 2001-11-27 | 2002-12-19 | Gem Of The North Pty Ltd | An pesticide composition containing finely ground amorphous silica |
| GB0216700D0 (en) * | 2002-07-18 | 2002-08-28 | Astrazeneca Ab | Process |
| GB0230087D0 (en) * | 2002-12-24 | 2003-01-29 | Astrazeneca Ab | Therapeutic agents |
| GB0230088D0 (en) * | 2002-12-24 | 2003-01-29 | Astrazeneca Ab | Therapeutic agents |
| GB0302673D0 (en) * | 2003-02-06 | 2003-03-12 | Astrazeneca Ab | Pharmaceutical formulations |
| GB0302672D0 (en) * | 2003-02-06 | 2003-03-12 | Astrazeneca Ab | Pharmaceutical formulations |
| GB0302671D0 (en) * | 2003-02-06 | 2003-03-12 | Astrazeneca Ab | Pharmaceutical formulations |
| EP1641779A1 (en) * | 2003-06-18 | 2006-04-05 | AstraZeneca AB | 2-substitued 5, 6-diaryl-pyrazine derivatives as cb1 modulator. |
| GB0314057D0 (en) * | 2003-06-18 | 2003-07-23 | Astrazeneca Ab | Therapeutic agents |
| GB0314261D0 (en) * | 2003-06-19 | 2003-07-23 | Astrazeneca Ab | Therapeutic agents |
| IL160858A (en) * | 2004-03-14 | 2015-09-24 | Adama Makhteshim Ltd | Nano-pesticide pesticide preparation and process for preparation |
| US8173576B2 (en) * | 2005-05-26 | 2012-05-08 | Nippon Soda Co., Ltd. | Method of producing suspended agricultural chemical composition |
| US20060270559A1 (en) * | 2005-05-26 | 2006-11-30 | Nippon Soda Co., Ltd. | Method of producing suspended agricultural chemical composition |
| WO2008013785A2 (en) | 2006-07-24 | 2008-01-31 | Singh-Broemer And Company, Inc. | Solid nanoparticle formulation of water insoluble pharmaceutical substances with reduced ostwald ripening |
| US20130053247A1 (en) * | 2011-08-25 | 2013-02-28 | Dow Agrosciences Llc | Increasing particle size of pesticides to reduce movement in soil |
| CN108135185B (zh) * | 2016-03-08 | 2024-05-17 | 银都拉玛投资氧化物有限责任公司 | 浓缩的低粘度农用制剂 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2758115A (en) * | 1955-02-10 | 1956-08-07 | Bayer Ag | Derivatives of thiophosphoric acid |
| US3060084A (en) * | 1961-06-09 | 1962-10-23 | Du Pont | Improved homogeneous, readily dispersed, pesticidal concentrate |
| US3342581A (en) * | 1963-05-20 | 1967-09-19 | Gen Aniline & Film Corp | Pesticidal wettable powder formulation |
| US3399991A (en) * | 1964-05-05 | 1968-09-03 | Du Pont | Freeze-resistant pesticidal composition |
| US3737551A (en) * | 1969-08-20 | 1973-06-05 | Vanderbilt Co R T | Wettable and dispersible powders |
| US3791811A (en) * | 1970-01-14 | 1974-02-12 | Hoechst Ag | Storable highly concentrated pesticides and process for their manufacture |
| US3689245A (en) * | 1970-09-21 | 1972-09-05 | Du Pont | Alkali metal silicate-stabilized pesticide foams |
| US4000258A (en) * | 1972-01-19 | 1976-12-28 | Sandoz, Inc. | Liquid compositions of Bacillus thuringiensis |
| US3920442A (en) * | 1972-09-18 | 1975-11-18 | Du Pont | Water-dispersible pesticide aggregates |
-
1980
- 1980-11-17 US US06/207,318 patent/US4348385A/en not_active Expired - Lifetime
-
1981
- 1981-10-29 CA CA000389053A patent/CA1163191A/en not_active Expired
- 1981-11-06 AT AT81109541T patent/ATE15747T1/de not_active IP Right Cessation
- 1981-11-06 DE DE8181109541T patent/DE3172450D1/de not_active Expired
- 1981-11-06 EP EP81109541A patent/EP0052313B1/de not_active Expired
- 1981-11-09 PT PT73944A patent/PT73944B/pt unknown
- 1981-11-12 JP JP56180436A patent/JPS57109701A/ja active Pending
- 1981-11-13 AU AU77470/81A patent/AU543845B2/en not_active Ceased
- 1981-11-13 AR AR287438A patent/AR229516A1/es active
- 1981-11-13 NZ NZ198962A patent/NZ198962A/en unknown
- 1981-11-16 GR GR66524A patent/GR78018B/el unknown
- 1981-11-16 DK DK507181A patent/DK507181A/da not_active Application Discontinuation
- 1981-11-16 ZA ZA817903A patent/ZA817903B/xx unknown
- 1981-11-16 ES ES507175A patent/ES8303025A1/es not_active Expired
- 1981-11-16 IL IL64293A patent/IL64293A0/xx unknown
- 1981-11-17 BR BR8107457A patent/BR8107457A/pt unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3172450D1 (en) | 1985-10-31 |
| GR78018B (en:Method) | 1984-09-26 |
| IL64293A0 (en) | 1982-02-28 |
| AU7747081A (en) | 1982-05-27 |
| JPS57109701A (en) | 1982-07-08 |
| PT73944B (en) | 1983-04-18 |
| DK507181A (da) | 1982-05-18 |
| ATE15747T1 (de) | 1985-10-15 |
| ES507175A0 (es) | 1983-02-01 |
| ES8303025A1 (es) | 1983-02-01 |
| AU543845B2 (en) | 1985-05-02 |
| EP0052313B1 (de) | 1985-09-25 |
| NZ198962A (en) | 1984-02-03 |
| PT73944A (en) | 1981-12-01 |
| EP0052313A1 (de) | 1982-05-26 |
| US4348385A (en) | 1982-09-07 |
| BR8107457A (pt) | 1982-08-10 |
| AR229516A1 (es) | 1983-09-15 |
| ZA817903B (en) | 1982-10-27 |
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