CA1159694A - Method for producing a high quality, water absorbent, cellulosic sheet having high surface-perceived softness - Google Patents
Method for producing a high quality, water absorbent, cellulosic sheet having high surface-perceived softnessInfo
- Publication number
- CA1159694A CA1159694A CA000383241A CA383241A CA1159694A CA 1159694 A CA1159694 A CA 1159694A CA 000383241 A CA000383241 A CA 000383241A CA 383241 A CA383241 A CA 383241A CA 1159694 A CA1159694 A CA 1159694A
- Authority
- CA
- Canada
- Prior art keywords
- web
- sheet
- treated
- level
- chemical bonding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/005—Mechanical treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
- D21F11/14—Making cellulose wadding, filter or blotting paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
Abstract
ABSTRACT OF THE DISCLOSURE
This invention relates to a method for producing a cellulosic sheet, capable of being used in high quality grades of tissue and towel, which exhibits outstanding water absorbency properties and a high degree of surface-perceived softness. The method includes the steps of form-ing a cellulosic web, treating that web with a chemical bonding inhibitor so that the pH of the web, after treat-ment, is not more than about 5.0, and then creping and drying the treated web. The sheet produced by this method has an over-all quality factor and surface-perceived soft-ness factor, respectively, of at least about 1.5.
This invention relates to a method for producing a cellulosic sheet, capable of being used in high quality grades of tissue and towel, which exhibits outstanding water absorbency properties and a high degree of surface-perceived softness. The method includes the steps of form-ing a cellulosic web, treating that web with a chemical bonding inhibitor so that the pH of the web, after treat-ment, is not more than about 5.0, and then creping and drying the treated web. The sheet produced by this method has an over-all quality factor and surface-perceived soft-ness factor, respectively, of at least about 1.5.
Description
~ ~598~4 Background of the Invention The present invention is directed to a method for producing a highly absorbent, cellulosic sheet hav-ing excellent quality and a high level of surface-per-ceived softness.
In the production of standard grades of paper on a conventional paper machine, cellulosic fibers and water are combined in a headbox to form an aqueous fiber slurry having a fiber consistency of from about 0.05~ to 0.2% by weight, based on the total weight of that slurry. The wet web from the headbox is formed on a papermaking wire at a consistency of at least about 5% for purposes of mechanic-ally removing water therefrom. This mechanical dewatering step increases the consistency of the web up to a level of about 45-50%. As the water is mechanically displaced, the fibers are moved into close proximity one with the other, and chemical bonds, generally described as "hydrogen bonds", are formed between the adjacent cellulosic fiber surfaces.
The formation of these hydrogen bonds serves to strengthen the web, as measured! for example, by a substantial increase in physical properties such as an increase in the breaking length of the web.
The uncontroled formation of substantial numbers of hydrogen bonds between the surfaces of adjacent fibers is detrimental to certain paper properties such as softness and absorbency. Specifically, various types of paper products such as certain grades of tissue and towel in which the sheet must be absorbent and soft to the touch cannot tolerate the unlimited formation of hydrogen bonds. These high softness and absorbency properties are not present in paper products made by the above described conventional papermaking techni~ues.
~ 159694 In an attempt to produce a sheet having the above described requisite degree of softness and absorbency, cer-tain prior art methods incorporate a chemical "debonding agent" into the aqueous fiber slurry to inhibit the forma-tion of hydrogen bonds. The incorporation of the debonder must, however, be accomplished without destroying the integ-rity of the web since it is necessary to form a sheet having the requisite strength properties for its intended use as a finished product of commerce, i.e., to produce a sheet hav-ing a high, over-all quality.
U. S. Patent 3,812,000 to Salvucci et al.; U. S.
3,844,880 to Meisel et al.; and U. S. 3,903,342 to Roberts et al., respectively, describe the addition of materials such as the above mentioned debonding agents to an aqueous slurry of cellulosic fibers to minimize hydrogen bonding in an attempt to increase softness. Typically, the above chemical debonding agents comprise surfactants such as those described in the Hervey et al. U. S. patents, Nos.
3,554,862; 3,554,863; and 3,395,708. The addition of a chemical debonding agent to the fiber slurry promotes the over-all treatment of all ~ibers without regard to whether the treated fibers are located at the web surface, where hand-feel properties are measured! or in the interstices o~ the sheet. Therefore, certain patents such as U. S.
3,556,931 to Champaigne; U. S. 2,756~647 to Thompson; and U. S. 4,158,594 to Becker et al., disclose adding a debond-ing agent to a cellulosic web after web formation, but prior to drying. These latter patents describe softening the web to a certain extent, but do not provide a sheet having the requisite quality, absorbency, and surface-perceived soft-ness level, as hereinafter defined.
:
1 ~59~94 Summary of the Invention This invention is directed to a method for pro-ducing a highly absorbent cellulosic sheet having excellent over-all quality and a high level of surface-perceived soft-ness f respectively, which is capable of being employed in high softness grades of tissue and towel~
In order to overcome the previously described problems associated with the prior art resulting from the addition to the headbox of chemical debonding agents, the subject invention contemplates treating the cellulose fibers in the formed web with a chemical bonding inhibitor having an acidic pH. More specifically, the cellulosic web immedi-ately after formation preferably has an initial pH of not less than about 6.0, and preferably not less than about 6.5, and more preferably not less than about 7Ø At least one surface of the web is treated with the chemical bonding ....
i inhibitor, and the pH of the treated web immediately after ; the treatment step is not more than about 5.0, and prefer-ably not more than about 4.5, and more preferably not more than about 4.0, and most preferably not more than about 3.0, The result of treating the web with a chemical bonding inhibitor under the pH conditions described above is an unexpected, dramatic improvement in qualityf absorbency, and surface-perceived softness of the sheet products. The treatment of the cellulosic fibers with the acidic chemical ~- bonding inhibitors does not occur until the consistency of the web, as measured immediately after the treatment step !
is at least about 5% by weight, up to about 50% by weight.
Detailed Descrip~ on of the Drawing FIGURE 1 is a schematic representation of a pre-ferred method within the scope of this invention.
.
~ ~989~
Detailed Description of the Invention In accordance with the present invention, a method is provided for producing a highly absorbent, cel-lulosic sheet which exhibit~ excellent over-all quality and "~ a high degree of suxface-perceived softness. A schematic ....
~ drawing depicting a process configuration is set forth in ,....
FIGURE 1.
In the method of the present invention, an aque-;~ ous furnish including cellulose papermaking fibers is ini-.i tially formed. The cellulosic fibers have undergone some degree of lignin modification, such as at least partial chemical treatment, to produce materials such as chemi-, mechanical pulp, semichemical pulp, chemical pulp, or mix-;
tures thereof. Suitable materials from which the above cellulose fibers can be derived include the usual species `~ of coniferous and deciduous pulpwood, the cellulosic com-~:, ponents being preferably produced from coniferous pulpwood because of its greater fiber length.
The aqueous furnish is transported to a headbox 2 at a le~el sufficient to permit the formation of a substan-tially dry sheet upon completion of the hereinafter described dewatering and thermal drying steps, respectively, without requiring further drying thereof subsequent to creping.
As a practical-matter! however, the consistency of the aqueous furnish used in forming the subject ~et web is desirably maintained at a level of from about 0.05% by weight~ and more preferably from about 0.1% by weight, based on the total weight of cellulosic fibers in the a~ueous furnish~ up to a preferred consistency of about 1.0% by weight~ and more preferably up to about 0.75% by weight.
. .
,; ~
~ 1~9694 .
;; A wet web l is then formed by deposition of the ; aqueous furnish onto a web forming means 3, typically a ~.~ conventional papermaking system including a foraminous con-j` veying means 4 such as a Fourdrinier wire, Stevens former, : or the like.
- Dewatering of the wet web is then provided prior `:~ to the thermal drying operation typically employing a non-:~. thermal dewatering means 5. The nonthermal dewatering step .
.~` is usually accomplished by various means for imparting mech-anical compaction to the web l such as vacuum boxes, slot ` boxes, coacting press rolls, or combinations thereof. For ; purposes of lllustration of the method of this invention, the wet web 1 is dewatered by subjecting same to a series of vacuum boxes and/or slot boxes, as shown in FIGURE 1.
Thereafter, the web is further dewa-tered by subjectlng same ~:`
to the compressive forces exerted by nonthermal dewatering . means such as, for example, a pair of rolls, followed by a pressure roll coacting with a thermal drying means.
` The wet web 1 is carried by the foraminous con-veying means 4 through the nonthermal dewatering means 5, : where it is dewatered to a consistency of at least about 5~, preferably at l~ast 10%, and more preferably at least 15~, : up to a consistency of preferably about 50%, and more prefer-ably up to about 45%, and most preferably up to about 35%.
The cellulosic web formed, as described above, preferably has an initial pH of at least about 6 in order to minimize corrosion problems which can occur with respect to the for-aminous conveying means, as well as other portions of the .~ papermaking equipment if the pH per se is too low. More ~:. 30 preferably, the initial pH of the web is maintained at a level, as previously described. The wet web 1 prior to the , , ,:
;: - 5 -:,, : 1 ~5~4 thermal drying step is treated with an acidic chemical ' material 6, which inhibits the formation of papermaking ..:
.....
bonds between adjacent cellulosic fibers. By treating the web 1 in this manner, a sheet 20 having the hereinafter , . .
`~ defined, unexpected properties can be produced. The pH of web immediately after the treatment step, denoted "la", is not more than about 5.0, and is preferably not more than ; about 4.5, and is more preferably not more than about 4.0, , and is most preferably not more than about 3Ø
:,;
The consistency of the web immediately after the treatm~nt step is preferably within the previously defined consistency parameters. Preferably, this chemical bonding ; inhibitor per se is a "chemical debonding agent". These materials are well-known in the prior art, and are prefer-ably substantially cationic in nature. Examples of suitable chemical bonding inhibitor materials include Quaker 2001*
(~uaker Chemical), Ceranine HCS* (Sandoz), Leomin KP*
-~ (Hoechst AG), and Amasoft-PM* (American Color and Chemica~.
The bonding inhibitor 6 employed for treatment of ` 20 the web is provided at a treatment level which is sufficient to minimize the formation of the above described hydrogen bonds, but less than an amount which would cause significant runnability and sheet strength problems in the final commer-cial product. The amount of acid chemical bonding inhibitor 6 employed~ on a 100% active basis, is preferably from about 0.5 pound per ton (1 kg/tonne~ of cellulose pulp, up to about 15 pounds per ton (30 kg/tonne) of cellulose pulp. However, a more preferred addition of from about 1 pound (2 kg), up ;~ to about 10 pounds (20 kg), of chemical bonding inhibitor per tonne of cellulose pulp can be employed.
* trademark ,'"'~
:, . ~ . .
6 9 ~
Treatment of the wet web with the bonding inhibi-tor material can be accomplished by various means. Eor instance, the treatment step can comprise spraying, applying with a direct contact applicator means or by employing an ~' applicator felt. However, the preferred method of applica-tion is by spraying the web such as by employing spray header 6a! at various points prior to thermal drying means 8 ~see FIGURE 1). The adjustment of the pH of the web is localized at a giYen point of treatment ! as opposed to hav-ing the web adjusted to the desired acidic pH level in the headbox. In a preferred method, the pH of the chemical bonding inhibitor 6 is adjusted to a pH level, prior to treatment therewith, which will facilitate the requisite mini-mum pH of the treated web at a level within the previously ; set forth pH limits, In a further preferred method, the pH
of the web is first adjusted to a prescribed level and thereafter the sheet is treated with the chemical bonding inhibitor~
The acidity level of the bonding inhibitor material 6 can be adjusted employing numerous materials capable of performing that function. However, organic acids such as formic acid, acetic acid, propionic acid and benzoic acid, and inorganic acids such as hydrochloric acid~ sulfuric acid, phosphoric acid and nitric acid! or salts thereof, are preferred. Of the above acidic materials, however, sulfuric acid is the most preferred.
The surface treated web la is then applied to the surface 7 of the thermal drying means 8, preferably a ther-mal drying cylinder such as a Yankee drying cylinder, employing preferably an adhesive to supplement the adhesion process. Examples of typical adhesive compounds which may be l;
*` l 15969~
used include carboxymethyl cellulose, polyvinyl alcohol, . .
~, anionic starch, various soluble natural polymers such as ; gums and the like, and synthetic resins such as polyamide :, ;; resins, and the like. Adhesion of the treated web la to ; the cylinder surface 7 is preferably facilitated by the '~' mechanical compressive action exerted thereon, generally ~, using one or more press rolls 9, which form a nip in combi-,~, nation with thermal drying means 8 and which brings the web `'l into more uniform contact with the thermal drying surface 7.
; 10 The ,web is then dried on the thermal drying sur-face preferably to a consistency of at least about 92%, and '~'' more preferably to a consistency of at least about 97~.
:~;
The creping means 11 then removes the dried, creped sheet 20 from the thermal drying surface, the creping action disrupting bonds between respective fibers and causing ~` a softening effect to be imparted to the sheet. In general, ~; the creping means is a doctor blade which crepes and removes -the sheet from the thermal drying surface.
Sheet 20 has a high degree of bulk softness.
, 20 "Bulk softness" is measured by conducting a Handle-O-Meter test (,HOM~ according to TAPPI T-498. The bulk softness ~reciprocal of stiffness) of a given sheet is then calculated ~- by dividing the HOM value by the square o~ the caliper of a : given single sheet being tested, the quotient thereof being multiplied by 105. For example, in single-ply tissue and , ; towel applications~ depending on the type of furnish , employed~ bulk softness, expressed as HOM/(Caliper)~ ~ 105 ', is pre~erably not-more than about 1.0, and more preferably ; not more than about 0.8, and most preferably not more than ' 30 about 0.6.
":
, - 8 -, I ~g694 An important aspect of this invention is the ability of the subject method to produce sheets in an , extremely broad basis weight range. The basis weight of a : given sheet is determined according to TAPPI test number T-410. The basis weight of the sheet produced by the sub-ject method can, in general, range from about 5 pounds per ` 3,000 square feet (118.8 kg/3000 m2), and preferably from about 8 pounds per 3,000 square feet (190.1 kg/3000 m2), up to about 50 pounds per 3,000 square feet (1180 kg/3000 m2), and preferably up to about 40 pounds per 3,000 square feet (950.4 kg/3000 m2).
Each sheet must have enough structural integrity so that it will be capable of being manufactured without being damaged. A measure of the structural integrity of a sheet is breaking length. This procedure is run according to TAPPI T-222, except that instead of a 15-millimeter-wide - sample strip, a one-inch (25.4 mm) wide strip is used.
; Average breaking length (BL vg) of a sheet is then calcu-lated after the tensile strength of the sample in the mach-ine direction (MD) and cross-machine direction (CMD), respectively, is determined, using the following equation:
BLaVg - 685 (tensile MD + tensile CMD)
In the production of standard grades of paper on a conventional paper machine, cellulosic fibers and water are combined in a headbox to form an aqueous fiber slurry having a fiber consistency of from about 0.05~ to 0.2% by weight, based on the total weight of that slurry. The wet web from the headbox is formed on a papermaking wire at a consistency of at least about 5% for purposes of mechanic-ally removing water therefrom. This mechanical dewatering step increases the consistency of the web up to a level of about 45-50%. As the water is mechanically displaced, the fibers are moved into close proximity one with the other, and chemical bonds, generally described as "hydrogen bonds", are formed between the adjacent cellulosic fiber surfaces.
The formation of these hydrogen bonds serves to strengthen the web, as measured! for example, by a substantial increase in physical properties such as an increase in the breaking length of the web.
The uncontroled formation of substantial numbers of hydrogen bonds between the surfaces of adjacent fibers is detrimental to certain paper properties such as softness and absorbency. Specifically, various types of paper products such as certain grades of tissue and towel in which the sheet must be absorbent and soft to the touch cannot tolerate the unlimited formation of hydrogen bonds. These high softness and absorbency properties are not present in paper products made by the above described conventional papermaking techni~ues.
~ 159694 In an attempt to produce a sheet having the above described requisite degree of softness and absorbency, cer-tain prior art methods incorporate a chemical "debonding agent" into the aqueous fiber slurry to inhibit the forma-tion of hydrogen bonds. The incorporation of the debonder must, however, be accomplished without destroying the integ-rity of the web since it is necessary to form a sheet having the requisite strength properties for its intended use as a finished product of commerce, i.e., to produce a sheet hav-ing a high, over-all quality.
U. S. Patent 3,812,000 to Salvucci et al.; U. S.
3,844,880 to Meisel et al.; and U. S. 3,903,342 to Roberts et al., respectively, describe the addition of materials such as the above mentioned debonding agents to an aqueous slurry of cellulosic fibers to minimize hydrogen bonding in an attempt to increase softness. Typically, the above chemical debonding agents comprise surfactants such as those described in the Hervey et al. U. S. patents, Nos.
3,554,862; 3,554,863; and 3,395,708. The addition of a chemical debonding agent to the fiber slurry promotes the over-all treatment of all ~ibers without regard to whether the treated fibers are located at the web surface, where hand-feel properties are measured! or in the interstices o~ the sheet. Therefore, certain patents such as U. S.
3,556,931 to Champaigne; U. S. 2,756~647 to Thompson; and U. S. 4,158,594 to Becker et al., disclose adding a debond-ing agent to a cellulosic web after web formation, but prior to drying. These latter patents describe softening the web to a certain extent, but do not provide a sheet having the requisite quality, absorbency, and surface-perceived soft-ness level, as hereinafter defined.
:
1 ~59~94 Summary of the Invention This invention is directed to a method for pro-ducing a highly absorbent cellulosic sheet having excellent over-all quality and a high level of surface-perceived soft-ness f respectively, which is capable of being employed in high softness grades of tissue and towel~
In order to overcome the previously described problems associated with the prior art resulting from the addition to the headbox of chemical debonding agents, the subject invention contemplates treating the cellulose fibers in the formed web with a chemical bonding inhibitor having an acidic pH. More specifically, the cellulosic web immedi-ately after formation preferably has an initial pH of not less than about 6.0, and preferably not less than about 6.5, and more preferably not less than about 7Ø At least one surface of the web is treated with the chemical bonding ....
i inhibitor, and the pH of the treated web immediately after ; the treatment step is not more than about 5.0, and prefer-ably not more than about 4.5, and more preferably not more than about 4.0, and most preferably not more than about 3.0, The result of treating the web with a chemical bonding inhibitor under the pH conditions described above is an unexpected, dramatic improvement in qualityf absorbency, and surface-perceived softness of the sheet products. The treatment of the cellulosic fibers with the acidic chemical ~- bonding inhibitors does not occur until the consistency of the web, as measured immediately after the treatment step !
is at least about 5% by weight, up to about 50% by weight.
Detailed Descrip~ on of the Drawing FIGURE 1 is a schematic representation of a pre-ferred method within the scope of this invention.
.
~ ~989~
Detailed Description of the Invention In accordance with the present invention, a method is provided for producing a highly absorbent, cel-lulosic sheet which exhibit~ excellent over-all quality and "~ a high degree of suxface-perceived softness. A schematic ....
~ drawing depicting a process configuration is set forth in ,....
FIGURE 1.
In the method of the present invention, an aque-;~ ous furnish including cellulose papermaking fibers is ini-.i tially formed. The cellulosic fibers have undergone some degree of lignin modification, such as at least partial chemical treatment, to produce materials such as chemi-, mechanical pulp, semichemical pulp, chemical pulp, or mix-;
tures thereof. Suitable materials from which the above cellulose fibers can be derived include the usual species `~ of coniferous and deciduous pulpwood, the cellulosic com-~:, ponents being preferably produced from coniferous pulpwood because of its greater fiber length.
The aqueous furnish is transported to a headbox 2 at a le~el sufficient to permit the formation of a substan-tially dry sheet upon completion of the hereinafter described dewatering and thermal drying steps, respectively, without requiring further drying thereof subsequent to creping.
As a practical-matter! however, the consistency of the aqueous furnish used in forming the subject ~et web is desirably maintained at a level of from about 0.05% by weight~ and more preferably from about 0.1% by weight, based on the total weight of cellulosic fibers in the a~ueous furnish~ up to a preferred consistency of about 1.0% by weight~ and more preferably up to about 0.75% by weight.
. .
,; ~
~ 1~9694 .
;; A wet web l is then formed by deposition of the ; aqueous furnish onto a web forming means 3, typically a ~.~ conventional papermaking system including a foraminous con-j` veying means 4 such as a Fourdrinier wire, Stevens former, : or the like.
- Dewatering of the wet web is then provided prior `:~ to the thermal drying operation typically employing a non-:~. thermal dewatering means 5. The nonthermal dewatering step .
.~` is usually accomplished by various means for imparting mech-anical compaction to the web l such as vacuum boxes, slot ` boxes, coacting press rolls, or combinations thereof. For ; purposes of lllustration of the method of this invention, the wet web 1 is dewatered by subjecting same to a series of vacuum boxes and/or slot boxes, as shown in FIGURE 1.
Thereafter, the web is further dewa-tered by subjectlng same ~:`
to the compressive forces exerted by nonthermal dewatering . means such as, for example, a pair of rolls, followed by a pressure roll coacting with a thermal drying means.
` The wet web 1 is carried by the foraminous con-veying means 4 through the nonthermal dewatering means 5, : where it is dewatered to a consistency of at least about 5~, preferably at l~ast 10%, and more preferably at least 15~, : up to a consistency of preferably about 50%, and more prefer-ably up to about 45%, and most preferably up to about 35%.
The cellulosic web formed, as described above, preferably has an initial pH of at least about 6 in order to minimize corrosion problems which can occur with respect to the for-aminous conveying means, as well as other portions of the .~ papermaking equipment if the pH per se is too low. More ~:. 30 preferably, the initial pH of the web is maintained at a level, as previously described. The wet web 1 prior to the , , ,:
;: - 5 -:,, : 1 ~5~4 thermal drying step is treated with an acidic chemical ' material 6, which inhibits the formation of papermaking ..:
.....
bonds between adjacent cellulosic fibers. By treating the web 1 in this manner, a sheet 20 having the hereinafter , . .
`~ defined, unexpected properties can be produced. The pH of web immediately after the treatment step, denoted "la", is not more than about 5.0, and is preferably not more than ; about 4.5, and is more preferably not more than about 4.0, , and is most preferably not more than about 3Ø
:,;
The consistency of the web immediately after the treatm~nt step is preferably within the previously defined consistency parameters. Preferably, this chemical bonding ; inhibitor per se is a "chemical debonding agent". These materials are well-known in the prior art, and are prefer-ably substantially cationic in nature. Examples of suitable chemical bonding inhibitor materials include Quaker 2001*
(~uaker Chemical), Ceranine HCS* (Sandoz), Leomin KP*
-~ (Hoechst AG), and Amasoft-PM* (American Color and Chemica~.
The bonding inhibitor 6 employed for treatment of ` 20 the web is provided at a treatment level which is sufficient to minimize the formation of the above described hydrogen bonds, but less than an amount which would cause significant runnability and sheet strength problems in the final commer-cial product. The amount of acid chemical bonding inhibitor 6 employed~ on a 100% active basis, is preferably from about 0.5 pound per ton (1 kg/tonne~ of cellulose pulp, up to about 15 pounds per ton (30 kg/tonne) of cellulose pulp. However, a more preferred addition of from about 1 pound (2 kg), up ;~ to about 10 pounds (20 kg), of chemical bonding inhibitor per tonne of cellulose pulp can be employed.
* trademark ,'"'~
:, . ~ . .
6 9 ~
Treatment of the wet web with the bonding inhibi-tor material can be accomplished by various means. Eor instance, the treatment step can comprise spraying, applying with a direct contact applicator means or by employing an ~' applicator felt. However, the preferred method of applica-tion is by spraying the web such as by employing spray header 6a! at various points prior to thermal drying means 8 ~see FIGURE 1). The adjustment of the pH of the web is localized at a giYen point of treatment ! as opposed to hav-ing the web adjusted to the desired acidic pH level in the headbox. In a preferred method, the pH of the chemical bonding inhibitor 6 is adjusted to a pH level, prior to treatment therewith, which will facilitate the requisite mini-mum pH of the treated web at a level within the previously ; set forth pH limits, In a further preferred method, the pH
of the web is first adjusted to a prescribed level and thereafter the sheet is treated with the chemical bonding inhibitor~
The acidity level of the bonding inhibitor material 6 can be adjusted employing numerous materials capable of performing that function. However, organic acids such as formic acid, acetic acid, propionic acid and benzoic acid, and inorganic acids such as hydrochloric acid~ sulfuric acid, phosphoric acid and nitric acid! or salts thereof, are preferred. Of the above acidic materials, however, sulfuric acid is the most preferred.
The surface treated web la is then applied to the surface 7 of the thermal drying means 8, preferably a ther-mal drying cylinder such as a Yankee drying cylinder, employing preferably an adhesive to supplement the adhesion process. Examples of typical adhesive compounds which may be l;
*` l 15969~
used include carboxymethyl cellulose, polyvinyl alcohol, . .
~, anionic starch, various soluble natural polymers such as ; gums and the like, and synthetic resins such as polyamide :, ;; resins, and the like. Adhesion of the treated web la to ; the cylinder surface 7 is preferably facilitated by the '~' mechanical compressive action exerted thereon, generally ~, using one or more press rolls 9, which form a nip in combi-,~, nation with thermal drying means 8 and which brings the web `'l into more uniform contact with the thermal drying surface 7.
; 10 The ,web is then dried on the thermal drying sur-face preferably to a consistency of at least about 92%, and '~'' more preferably to a consistency of at least about 97~.
:~;
The creping means 11 then removes the dried, creped sheet 20 from the thermal drying surface, the creping action disrupting bonds between respective fibers and causing ~` a softening effect to be imparted to the sheet. In general, ~; the creping means is a doctor blade which crepes and removes -the sheet from the thermal drying surface.
Sheet 20 has a high degree of bulk softness.
, 20 "Bulk softness" is measured by conducting a Handle-O-Meter test (,HOM~ according to TAPPI T-498. The bulk softness ~reciprocal of stiffness) of a given sheet is then calculated ~- by dividing the HOM value by the square o~ the caliper of a : given single sheet being tested, the quotient thereof being multiplied by 105. For example, in single-ply tissue and , ; towel applications~ depending on the type of furnish , employed~ bulk softness, expressed as HOM/(Caliper)~ ~ 105 ', is pre~erably not-more than about 1.0, and more preferably ; not more than about 0.8, and most preferably not more than ' 30 about 0.6.
":
, - 8 -, I ~g694 An important aspect of this invention is the ability of the subject method to produce sheets in an , extremely broad basis weight range. The basis weight of a : given sheet is determined according to TAPPI test number T-410. The basis weight of the sheet produced by the sub-ject method can, in general, range from about 5 pounds per ` 3,000 square feet (118.8 kg/3000 m2), and preferably from about 8 pounds per 3,000 square feet (190.1 kg/3000 m2), up to about 50 pounds per 3,000 square feet (1180 kg/3000 m2), and preferably up to about 40 pounds per 3,000 square feet (950.4 kg/3000 m2).
Each sheet must have enough structural integrity so that it will be capable of being manufactured without being damaged. A measure of the structural integrity of a sheet is breaking length. This procedure is run according to TAPPI T-222, except that instead of a 15-millimeter-wide - sample strip, a one-inch (25.4 mm) wide strip is used.
; Average breaking length (BL vg) of a sheet is then calcu-lated after the tensile strength of the sample in the mach-ine direction (MD) and cross-machine direction (CMD), respectively, is determined, using the following equation:
BLaVg - 685 (tensile MD + tensile CMD)
(2) (Basis Weight) In order to insure runnability o~ a web on paper-making equipment, the BLaVg of preferably at least about 150 meters, and more preferably at least about 250 meters is provided. Furthermore, if the creped sheet has too high a BLayg value, it will be too harsh to the feel and! therefore, unacceptable to the consumer. Thus, it is preferred that the ' 30 BLaVg be not more than about 450 meters, and more preferably not greater than about ~00 meters.
~t~
~ il 59~4 Another important sheet property is its ability to absorb water. The water absorbency parameter is expressed as the number of seconds it takes for a single sheet (4.5 inches by 4.5 inches) (11.43 cm by 11.43 cm) to absorb 0.1 cc of water, the test being described in TAPPI T-432.
If the method of the present invention is employed in a wet treatment step, as opposed to the prior art methods in which chemical bonding inhibitor per se is employed, an unexpected increase in the absorbency will result, Prefer-ably, an increase in water absorbency of at least about 50%, and more preferably at least 100%~ and most preferably at least 150% can be provided.
A series of three experiments (A-C) was conducted, employing a paper machine having a configuration set out in FIGURE 1. In the first experiment~ 0.25% of a chemical bonding inhibitor material, namely, Quaker 2001, a cationic quaternary ammonium compound produced by Quaker Chemical Company, at a pH of 5.48 was sprayed on the formed web at a consistency of about 10%. In Experiments s and C, 25 and 50 ml of a 10% solution of sulfuric acid was added to 4 gal-lons (15.2 liters) of bonding inhibitor solution prior to spraying same on the wet web. This produced a pH of 2.78 i .
and 2.48, respectively, immediately after treatment of the wet web in Experiments B and C. Sheets produced in Experi-ments A-C were tested, and the results re water absorbency and bulk softness are summarized in Table I.
TABLE I
A B C
Water Absorbency (Sec.) 37.64 11.60 14.10 HOM/(Caliper) x 10 1.02 0.55 0.53 ~ ""
; 1 159S94 ~ The effect of employing an acidic bonding inhibitor . ~
~ treatment solution is clearly demonstrated by the above :, ~ experimental comparison. SpeciEically, the stiffness of the subject sheets (B and C) have been substantially reduced (softness increased) by employing the method of the subject invention to about one-half that of the sheet (A) employing a chemical bonding inhibitor per se. At the same time, the ; water absorbency of sheets B and C is dramatically increased, as compared to its higher pH counterpart, so that the sheets produced in Experiments B and C are 324% and 260~, respect-ively, more absorbent than the sheet produced in Experiment A.
The over-all quality and surface-perceived soft-ness, respectively, of a cellulose sheet are subjectively determined to a great extent by the hand-feel as discerned by the ultimate consumer. Objective testing of the sheets in question are a measure of these properties and cannot totally act as a substitute for such a subjective determina-tion. Therefore, the over-all quality and surface-perceived softness of sheets such as those produced by the method of this invention can best be subjectively determined by pol--~ ling randomly selected respondents who have compared cellu-~, losic sheets prepared by various methods ! including the subject method. More specifically, four sheets prepared in `` substantially the same manner, except for pH of the chemical bonding inhibitor employed, were compared. Each of the four - sheets was then rated by a group of ten respondents with respect to over-all quality and surface-perceived softness~
An average over-all ~uality and surface perceived softness for each of the sheets tested was then determined by adding the total points received for each of the sheets tested from a given respondent and dividing that total by ten!
' ~ l 1$~9~
i.e., the total number of respondents. An over-all quality factor and surface-perceived softness factor for sheets pro-duced by the subject invention were then determined by dividing the average over-all quality, or the average surface-perceived softness, for the subject sheet by the com- --parable average value of the sheet, using a chemical bonding inhibitor per se. For example, a series of four experimental sheets, including the three cellulosic sheet products de-scribed in Example 1 (Nos. A-C), were tested, and an aYerage over-all quality factor and an average surface-perceived softness factor for each were determined.
TABLE II
A B C
Average Over-all Quality Factor 1.0 3.6 3.4 Average Surface-perceived Softness Factor 1.0 3,4 3~5 Accordingly, the sheets produced by the method of this invention have an over-all quality factor and a surface-perceived softness factor of preferably at least about 1.5,and more preferably at least about 2.0, and most preferably at least about 2.5.
. ~
,,
~t~
~ il 59~4 Another important sheet property is its ability to absorb water. The water absorbency parameter is expressed as the number of seconds it takes for a single sheet (4.5 inches by 4.5 inches) (11.43 cm by 11.43 cm) to absorb 0.1 cc of water, the test being described in TAPPI T-432.
If the method of the present invention is employed in a wet treatment step, as opposed to the prior art methods in which chemical bonding inhibitor per se is employed, an unexpected increase in the absorbency will result, Prefer-ably, an increase in water absorbency of at least about 50%, and more preferably at least 100%~ and most preferably at least 150% can be provided.
A series of three experiments (A-C) was conducted, employing a paper machine having a configuration set out in FIGURE 1. In the first experiment~ 0.25% of a chemical bonding inhibitor material, namely, Quaker 2001, a cationic quaternary ammonium compound produced by Quaker Chemical Company, at a pH of 5.48 was sprayed on the formed web at a consistency of about 10%. In Experiments s and C, 25 and 50 ml of a 10% solution of sulfuric acid was added to 4 gal-lons (15.2 liters) of bonding inhibitor solution prior to spraying same on the wet web. This produced a pH of 2.78 i .
and 2.48, respectively, immediately after treatment of the wet web in Experiments B and C. Sheets produced in Experi-ments A-C were tested, and the results re water absorbency and bulk softness are summarized in Table I.
TABLE I
A B C
Water Absorbency (Sec.) 37.64 11.60 14.10 HOM/(Caliper) x 10 1.02 0.55 0.53 ~ ""
; 1 159S94 ~ The effect of employing an acidic bonding inhibitor . ~
~ treatment solution is clearly demonstrated by the above :, ~ experimental comparison. SpeciEically, the stiffness of the subject sheets (B and C) have been substantially reduced (softness increased) by employing the method of the subject invention to about one-half that of the sheet (A) employing a chemical bonding inhibitor per se. At the same time, the ; water absorbency of sheets B and C is dramatically increased, as compared to its higher pH counterpart, so that the sheets produced in Experiments B and C are 324% and 260~, respect-ively, more absorbent than the sheet produced in Experiment A.
The over-all quality and surface-perceived soft-ness, respectively, of a cellulose sheet are subjectively determined to a great extent by the hand-feel as discerned by the ultimate consumer. Objective testing of the sheets in question are a measure of these properties and cannot totally act as a substitute for such a subjective determina-tion. Therefore, the over-all quality and surface-perceived softness of sheets such as those produced by the method of this invention can best be subjectively determined by pol--~ ling randomly selected respondents who have compared cellu-~, losic sheets prepared by various methods ! including the subject method. More specifically, four sheets prepared in `` substantially the same manner, except for pH of the chemical bonding inhibitor employed, were compared. Each of the four - sheets was then rated by a group of ten respondents with respect to over-all quality and surface-perceived softness~
An average over-all ~uality and surface perceived softness for each of the sheets tested was then determined by adding the total points received for each of the sheets tested from a given respondent and dividing that total by ten!
' ~ l 1$~9~
i.e., the total number of respondents. An over-all quality factor and surface-perceived softness factor for sheets pro-duced by the subject invention were then determined by dividing the average over-all quality, or the average surface-perceived softness, for the subject sheet by the com- --parable average value of the sheet, using a chemical bonding inhibitor per se. For example, a series of four experimental sheets, including the three cellulosic sheet products de-scribed in Example 1 (Nos. A-C), were tested, and an aYerage over-all quality factor and an average surface-perceived softness factor for each were determined.
TABLE II
A B C
Average Over-all Quality Factor 1.0 3.6 3.4 Average Surface-perceived Softness Factor 1.0 3,4 3~5 Accordingly, the sheets produced by the method of this invention have an over-all quality factor and a surface-perceived softness factor of preferably at least about 1.5,and more preferably at least about 2.0, and most preferably at least about 2.5.
. ~
,,
Claims (13)
1. A method for producing a highly absorbent, cellulosic sheet having excellent quality and a high level of surface-perceived softness, respectively, which comprises a) forming a web of cellulosic fibers;
b) treating the web with an acidic chemical material for inhibiting the formation of paper-making bonds between said cellulose fibers and said web, the consistency of the treated web immediately after said treatment step being from about 5% by weight, up to about 50% by weight, and the pH of the treated web immediately after the treatment step being not more than about 5.0;
c) adhering the treated web to a thermal drying means, and drying said treated web thereon;
and d) creping the dried web, the dried web having an over-all quality factor and a surface-perceived softness factor, respectively, of at least about 1.5.
b) treating the web with an acidic chemical material for inhibiting the formation of paper-making bonds between said cellulose fibers and said web, the consistency of the treated web immediately after said treatment step being from about 5% by weight, up to about 50% by weight, and the pH of the treated web immediately after the treatment step being not more than about 5.0;
c) adhering the treated web to a thermal drying means, and drying said treated web thereon;
and d) creping the dried web, the dried web having an over-all quality factor and a surface-perceived softness factor, respectively, of at least about 1.5.
2. The method of claim 1, wherein at least one sur-face of the web is treated with the acidic chemical bonding inhibitor.
3. The method of claim 1, wherein the initial pH of the web prior to treatment is not less than about 6Ø
4. The method of claim 3, wherein the initial pH is not more than about 6.5.
5. The method of claim 4, wherein the initial pH
is not less than about 7Ø
is not less than about 7Ø
6. The method of claim 1, wherein the pH immediately after the treatment step is not more than about 4Ø
7. The method of claim 6, wherein the pH is not more than about 3Ø
8. The method of claim 1, wherein the acidity level is adjusted in the treatment step by employing an inorganic acid.
9. The method of claim 1, wherein the pH of the wet web is first adjusted to the prescribed level and, there-after, the sheet is treated with a chemical bonding inhibitor material.
10. The method of claim 1, wherein the pH of the chemical bonding inhibitor is adjusted to a level which will facilitate the requisite minimum pH level of the treated web at a pH of not greater than 5Ø
11. The method of claim 1, wherein the acidity level is adjusted with an organic acid,
12. The method of claim 1, wherein the respective over-all quality and surface-perceived softness factors of the sheet are at least about 2Ø
13. The method of claim 1, wherein the treatment step comprises spraying said chemical bonding inhibitor onto the wet web.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17622580A | 1980-08-07 | 1980-08-07 | |
| US176,225 | 1980-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1159694A true CA1159694A (en) | 1984-01-03 |
Family
ID=22643497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000383241A Expired CA1159694A (en) | 1980-08-07 | 1981-08-05 | Method for producing a high quality, water absorbent, cellulosic sheet having high surface-perceived softness |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0057212A1 (en) |
| CA (1) | CA1159694A (en) |
| WO (1) | WO1982000485A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0184603A1 (en) * | 1984-12-07 | 1986-06-18 | Korsnäs-Marma Ab | Process for preparing a fluff pulp |
| US4795530A (en) * | 1985-11-05 | 1989-01-03 | Kimberly-Clark Corporation | Process for making soft, strong cellulosic sheet and products made thereby |
| US5059282A (en) * | 1988-06-14 | 1991-10-22 | The Procter & Gamble Company | Soft tissue paper |
| US5164046A (en) * | 1989-01-19 | 1992-11-17 | The Procter & Gamble Company | Method for making soft tissue paper using polysiloxane compound |
| US5227242A (en) * | 1989-02-24 | 1993-07-13 | Kimberly-Clark Corporation | Multifunctional facial tissue |
| US4992140A (en) * | 1989-04-06 | 1991-02-12 | Scott Paper Company | Method for creping a paper web and product produced thereby |
| US5399241A (en) * | 1993-10-01 | 1995-03-21 | James River Corporation Of Virginia | Soft strong towel and tissue paper |
| US5730839A (en) * | 1995-07-21 | 1998-03-24 | Kimberly-Clark Worldwide, Inc. | Method of creping tissue webs containing a softener using a closed creping pocket |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2032645A (en) * | 1933-08-18 | 1936-03-03 | Northern Paper Mills | Absorbent paper product and process of producing the same |
| US1986291A (en) * | 1933-11-23 | 1935-01-01 | Brown Co | Manufacture of absorbent waterlaid webs of felted fiber |
| US2683088A (en) * | 1952-06-10 | 1954-07-06 | American Cyanamid Co | Soft bibulous sheet |
| US2940890A (en) * | 1956-06-25 | 1960-06-14 | Kimberly Clark Co | Treatment of cellulosic pulps |
| GB852678A (en) * | 1958-03-18 | 1960-10-26 | Canadian Aniline And Extract C | Pulp production using non-ionic surface active agents |
| DE2314060A1 (en) * | 1973-03-21 | 1974-10-10 | Honshu Paper Co Ltd | SURFACE-ACTIVE SUBSTANCE |
-
1981
- 1981-08-03 WO PCT/US1981/001046 patent/WO1982000485A1/en unknown
- 1981-08-03 EP EP19810902213 patent/EP0057212A1/en not_active Withdrawn
- 1981-08-05 CA CA000383241A patent/CA1159694A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| WO1982000485A1 (en) | 1982-02-18 |
| EP0057212A1 (en) | 1982-08-11 |
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