CA1159271A - Flower preservation - Google Patents

Abstract

ABSTRACT
A relatively inexpensive solution for the single step preservation of fresh naturally coloured blooms, compris-ing (in amounts per litre) 600-700 ml tert-butyl alcohol 200-250 ml 2-propanol 3- 30 g thiourea 3- 30 g citric acid 3- 30 y sodium citrate 50-150 ml propionic acid 0-250 ml phenol.

Description

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FLOWER PRESERVATION

This application relates generally to the preservation of flowers and more particularly to a process and novel compos-ition of matter for the preservation of the natural colours of flowers, and to the preserved flower product.
The preservation of flowers for museum specimens, for educational purposes in the natural sciences and elsewhere, for decorative and ornamental use, for displays and the like has been practised for many years and many processes for such pre-servation have been described in the literature. ~ttention is particularly directed to U.S. Patents 2l65~,929; 2,658,836 and 3,698,809 to Fessenden and U.S. Patent 2,971,292 to Malecki and to "Handbook of Plastic Embedding" E. L. Lutz (1969) P. 60-73 for descriptions of the processes employed heretofore for the preservation of flowers and other plant and animal tissues.
Such prior art processes are not, however, entirely satisfactory because the delicate natural colours of the flowers tend -to fade relatively quickly and the flowers are also extremely brittle, fragile and highly susceptible to damage in extremes of temper-ature or humidity so that special handling and storage techniques are necessary. Without such special techniques the natural beauty oE the flowers is ~uickly lost and the flowers lose their usefulness for display or educational purposes.
Indeed, storage in sealed bells or embedding in plastic have heretofore been the onLy practical methods oi storage and handl~

~591~1 ing. Further, in order to trea-t d:ifferently coloured flowers according to the prior art it has been found necessary to use a variety of treatment solu-tions as no single treatment solu-tion which is suitable for all colours of flowers, has evolved.
It is, therefore, an object of the present invention to provide a process and a single composition of matter for the preservation of flowers which is suitable for use with substant-ially all colours and varieties of flowers and which will result in naturally coloured flowers which retain the freshness, flex-ibility and beauty for relatively long periods of time wi-thout the necessity of special handling and storage techniques.
-In our earlier Canadi`an Patent 1,091,950 issued Decen~er 23, 1980 and assigned to the assignee of the present application, we have disclosed essentially water free composi.~ions, for the single step preserva-tion of fresh, naturally coloured blooms, comprising at least one de-hydrating alcohol, a urea-containing compound, a carboxylic acid, an alkaline citrate, an affective amount of at least one of: aluminum or magnesium sulphate, a transitional metal sulphate and an alkaline formaldehyde sulfoxylate, and zero to an effective amount of at least one of a silicone fluid and a silicone resin and which also contains a sufficient quantity of at least one compound of the group consisting of an alkaline phosphate, a lower carboxyli.c acid and phenol so as to ensure that the composition has a pH in the range 5 to 7.
A preferred composition within the a~ove general formula comprises, in amounts per litre:
175-575 ml.. tertiary butyl alcohol 100-300 m:l.. l-propanol 200-400 nll.. 2-propan Q 1 ~ ~;927~L

6-8 g. sodium phosphate 0-3 g. sodium formaldehyde sulfoxylate

2.5-7.5 g. ci-tric acid 10-20 g. thiourea 0-10 g. aluminum sulpha-te

3-12 g. sodium citrate 0-2 g. cupric sulphate 10-200 ml. silicone fluid 0-50 ml. silicone resin, and 0-62 ml. phenol (88%).
Such formulations are effective for substantially all coloured blooms but have the disadvantage that they are relatively cost-ly to prepare. We have now found that surprising good results may be obtained using generally similar solutions which are very much cheaper to prepare.
By one aspect of the present invention there is provided a composition for the single step preservation of fresh, natural-ly coloured blooms comprising (in amounts per litre of solution):
600-700 ml. tertiary butyl alcohol 200-250 ml. 2-propanol .~ ~
3-30 g. thiourea 3-30 g. citric acid 3-30 g. sodium citrate 50-15Q ml. proprionic acid 0-250 ml. phenol.
By a preferred aspect of the present inventlon there is provided a composition for the single step preservation Gf fresh naturally coloured blooms, comprising (in amounts per litre):

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675 ml. tert-butyl alcohol 225 ml. 2-propanol g. thiourea g. citric acid g. sodium citrate 100 ml. propionic acid.
Tertiary butyl alcohol is an extremely efficient de-hydrating agent and if used alone tends to produce brittle blooms.
The effects of the tertiary butyl alcohol are modified to some extent by inclusion of 2-propanol which also lowers the freezing point of the tert-butyl alcohol.
A urea-containing compound, preferably thiourea~ is an essential constituent to prevent loss of pigments from the blooms and, when used together with citric acid and sodium citrate which are also colour preservatives, it increases the efficiency of these chemicals and prolongs the act.ive life of the composition.
Although effective at relativel~ low concentrations the life of the composition is severely restricted for reasons described in more detail in our copending application referred to above. A higher concentration of thiourea is generally used in the present formul-ations than in the formulations of the copending application to compensate for the omission of many of the other, more expensive, constituents used therein.
Propionic acid and phenol are employed as pH buffers, de-hydrating agents and colour stabilizers. A relatively large pro-portion of propionic acid is particularly effective to control the darker reds and pinks and phenol is particularly effective to control the lighter reds. A mixture of phenol and propionic acid tends to make the reds more vivid~
The process to treat the iJlooms according to the pre-': ..-'' ~ ~ S~ 27~

sen-t invention is quite simple and straightforward. ~ fresh bloom is chosen and a floral wire is inserted into the stem or bloom and a weight is added to keep the bloom submerged in the composition. The composition, formulated as described herein-above is contained in a suitable bath or container at a tempera-ture in the range of about 45-75F. The bloom is left suspended in the bath for from 6 to 24 hours without any agitation, depend-ing upon size and water content of the bloom and the freshness of the solution. Upon immersion in the composition, substantially all colour appears to disappear from the petals as dehydration occurs under the action of the clehydrating alcohols. rrhe colour slowly returns to the normal pretreatment level as the solid colour fixers and the like take up the extracted water and active-ly enter solution, thus ~iving a useful indication of the treat-ment time required. Large, fleshy blooms require longer periods of immersion and care must be taken to ensure the bloom is immersed sufficiently long to treat the relatively heavy and impervious torus. Fpllowing the immersion treatment the bloom is removed from the composition and air dried at room temperature ~0 and relatively low humidity for 8 to 10 hours. Blooms thus treated can generally be stored and displayed without further treatment for relatively long periods of time (of the order of 4-6 months at least) provided the temperature and humidity conditions are suitable (i.e. up tv about 80F and 60-70~ relative humidity.
More stressful environmental conditions require that the bloo~ms be stored in sealed ylass domes, where they will likely las-t fci~ x~e;, ;^s or be further cocltea. I-t has been found that dipping or sprayin~
with a conformal (oating resin, such as Dow Corning R~3117 ~iilicc>ne Resin alone or diluted with Dow Corning Fluid 200 (Registered ,.~

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Trademark) (at 0.65 centistokes) or any o-ther diluent, is satisfactory for this purpose. Preferably the coating is applied by dipping the bloom into the resin thinned wi-th a diluent such as xylene at a temperature in the range 50-80F
for a few minutes. ~he coated bloom is then dried at room temperature for several hours to cure the resin coating. The resin cures to a clear shiny coating and leaves the bloom relatively pliable. The shiny surface is often desirable but if a matte surface is desired this can be sprayed on with any one of a number of known finishes. The thickness of the coat-ing has a bearing on the appearance of the bloom --thin coatings lend a natural and delicate appearance to the bloom, while thick coatings make for sturdy blooms often of special beauty. After a coating treatment as described herein, roses and geraniums for example, have been exposed to light equal to several million foot-candle-hours, 95% humidity and tempera-tures up to 85F with only slight colour fading. Under more normal conditions the colours remain unaltered.
Example 1 Samples of roses and orchids as detailed below were preserved in a solution comprising:

675 ml. tert-butyl alcohol 225 ml. 2-propanol 25 g, thiourea 25 g. citric acid 25 g. sodium citrate 100 ml. propionic acid.

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The stems of individual blooms were wired and the blooms suspended in the preserving compositions a-t room temperature (45-70F~ for periods ranging from 6-24 hours depending on the size and water con-tent oi the bloom and the freshness of the preserving composition. In some cases i-t was necessary to attach a weight to the wire to ensure total imrnersion o~ the bloom in the composition. After the immersion treatment the blooms were removed from the composition and air dried at relatively low humidity (preferably less than 50%) for 8 to 10 hours. If higher humidities are encountered it may be necessary to take special steps to avoid reabsorption of water, such as be immersion in a resin such as Dow Corning R43117 with a solvent such as xylene. In some instances the dried blooms were subsequently coated with a coating or spray of a silicone resin at 50-80F. The quality of the preserved blooms was then evaluated.
_oses Orchids_ __ Li~ht Red - yood Blue - good Dark Red - good Yellow - good White - good White ~ good Example 2 Sam~les o~ roses and orchids as in Example 1 were preserved in a solution comprising: ~
600 ml. -tert-butyl alcohol 200 ml. 2-propa~ol 100 ml. vhenol 100 ml. propionic acid g. citric acid g. sodium citrate g. thiourea ~L~L59Z71 according to the method of Example 1. The results were as follows:
Roses Orchids Light Red - goodBlue - good Dark Red - goodYellow - good White - good White - good.

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Claims (3)

1. THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
   PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
   l. An essentially water-free composition, for the single step preservation of fresh, naturally coloured blooms compris-ing (in amounts per litre):
   600-700 ml. tert-butyl alcohol 200-250 ml. 2-propanol 3-30 g. thiourea 3-30 g. citric acid 3-30 g. sodium citrate 50-150 ml. propionic acid 0-250 ml. phenol.
2. 2. A composition as claimed in claim 1 comprising:
   675 ml. tert butyl alcohol 225 ml. 2-propanol g. thiourea g. citric acid g. sodium citrate 100 ml. propionic acid.
3. 3. A composition as claimed in claim 1 comprising:
   600 ml. tert butyl alcohol 200 ml. 2-propanol g. thiourea g. citric acid g. sodium citrate 100 ml. propionic acid 100 ml. phenol.