CA1153842A - Plasticized nylon with improved zinc chloride resistance - Google Patents
Plasticized nylon with improved zinc chloride resistanceInfo
- Publication number
- CA1153842A CA1153842A CA000359193A CA359193A CA1153842A CA 1153842 A CA1153842 A CA 1153842A CA 000359193 A CA000359193 A CA 000359193A CA 359193 A CA359193 A CA 359193A CA 1153842 A CA1153842 A CA 1153842A
- Authority
- CA
- Canada
- Prior art keywords
- weight percent
- nylon
- olefin
- composition
- zinc chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 title abstract description 27
- 235000005074 zinc chloride Nutrition 0.000 title abstract description 13
- 239000011592 zinc chloride Substances 0.000 title abstract description 13
- 239000004677 Nylon Substances 0.000 title abstract description 8
- 229920001778 nylon Polymers 0.000 title abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 229920000572 Nylon 6/12 Polymers 0.000 claims abstract description 24
- 229920000098 polyolefin Polymers 0.000 claims abstract description 20
- 239000004014 plasticizer Substances 0.000 claims abstract description 16
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 12
- 150000001993 dienes Chemical class 0.000 claims description 11
- 239000001530 fumaric acid Substances 0.000 claims description 11
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 9
- 229940124530 sulfonamide Drugs 0.000 claims description 8
- 150000003456 sulfonamides Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 2
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 claims 1
- 239000011347 resin Substances 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 7
- 150000003841 chloride salts Chemical class 0.000 abstract description 3
- 150000008064 anhydrides Chemical class 0.000 description 8
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexadiene group Chemical group C=CC=CCC AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000001118 alkylidene group Chemical group 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical compound C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 description 1
- VXGAPBLISGTEKE-UHFFFAOYSA-N 2-methylbenzenesulfonamide;4-methylbenzenesulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1.CC1=CC=CC=C1S(N)(=O)=O VXGAPBLISGTEKE-UHFFFAOYSA-N 0.000 description 1
- LBBVUHNMASXJAH-UHFFFAOYSA-N 3-ethylbicyclo[2.2.1]hepta-2,5-diene Chemical compound C1C2C(CC)=CC1C=C2 LBBVUHNMASXJAH-UHFFFAOYSA-N 0.000 description 1
- SEPGBJAGPSIRQL-UHFFFAOYSA-N 5-hex-1-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=CCCCC)CC1C=C2 SEPGBJAGPSIRQL-UHFFFAOYSA-N 0.000 description 1
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- DKYVVNLWACXMDW-UHFFFAOYSA-N n-cyclohexyl-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1CCCCC1 DKYVVNLWACXMDW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-UHFFFAOYSA-N norbornene Chemical class C1C2CCC1C=C2 JFNLZVQOOSMTJK-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000002311 subsequent effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- LMYRWZFENFIFIT-UHFFFAOYSA-N toluene-4-sulfonamide Chemical compound CC1=CC=C(S(N)(=O)=O)C=C1 LMYRWZFENFIFIT-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US071,195 | 1979-08-30 | ||
| US06/071,195 US4251424A (en) | 1979-08-30 | 1979-08-30 | Plasticized nylon 612 with improved zinc chloride resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1153842A true CA1153842A (en) | 1983-09-13 |
Family
ID=22099863
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000359193A Expired CA1153842A (en) | 1979-08-30 | 1980-08-28 | Plasticized nylon with improved zinc chloride resistance |
Country Status (5)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4448934A (en) * | 1982-02-02 | 1984-05-15 | Uniroyal, Inc. | Blends of ionic elastomers and nylon |
| US4745143A (en) * | 1985-07-12 | 1988-05-17 | Allied-Signal Inc. | Salt resistant polyamide composition |
| US4801633A (en) * | 1985-07-12 | 1989-01-31 | Allied-Signal Inc. | Salt resistant polyamide composition |
| US4873116A (en) * | 1986-09-30 | 1989-10-10 | Union Carbide Chemicals And Plastics Company Inc. | Method of preparing mixtures of incompatible hydrocarbon polymers |
| US5264474A (en) * | 1989-05-23 | 1993-11-23 | Mtm Americas Inc. | Polymer compositions |
| US5789529A (en) * | 1995-06-13 | 1998-08-04 | Ube Industries, Ltd. | Polyamide resin composition and tubular molding comprising the same |
| CN101065450B (zh) * | 2004-11-30 | 2014-05-07 | 阿科玛股份有限公司 | 用于流体运输器件的合金组合物 |
| ES2666877T3 (es) * | 2011-10-21 | 2018-05-08 | Ube Industries, Ltd. | Composición de resina de poliamida y cuerpo moldeado hueco que contiene la misma |
| CN103602063A (zh) * | 2013-11-12 | 2014-02-26 | 苏州博利迈新材料科技有限公司 | 增韧增塑尼龙612复合材料及其制备方法和应用 |
| EP3501820B1 (de) | 2017-12-22 | 2020-04-29 | EMS-Patent AG | Flexible kunststoffleitung sowie verfahren zu deren herstellung und deren verwendungen |
| CN117659686A (zh) * | 2023-11-30 | 2024-03-08 | 江苏金发科技新材料有限公司 | 一种尼龙复合材料及其制备方法和应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3484403A (en) * | 1966-03-14 | 1969-12-16 | Eastman Kodak Co | Preparation of polyamide-carboxylated polyolefin melt blends |
| DE1669760A1 (de) * | 1968-02-01 | 1971-05-27 | Basf Ag | Thermoplastische Formmassen auf der Basis von Olefinpolymerisaten |
| DE1901552A1 (de) * | 1969-01-14 | 1970-08-13 | Bayer Ag | Heterogene spritzfaehige Mischungen aus Polyamid und Polyolefinen |
| US3822227A (en) * | 1970-08-01 | 1974-07-02 | Bayer Ag | Homogeneous mixtures of polyamides and polyolefins |
| US4010223A (en) * | 1973-01-10 | 1977-03-01 | E. I. Du Pont De Nemours And Company | Adducts containing succinic groups attached to elastomeric copolymers |
| US3884882A (en) * | 1973-01-10 | 1975-05-20 | Du Pont | Certain EPDM copolymer/maleic anhydride adducts and thermoplastic elastomers therefrom |
| US4173556A (en) * | 1976-03-03 | 1979-11-06 | Monsanto Company | Elastoplastic compositions of rubber and polyamide |
| DE2722270A1 (de) * | 1976-05-19 | 1977-12-01 | Gen Electric | Mischung aus polyamid und modifiziertem polyaethylen |
| EP0009757B1 (en) * | 1978-09-25 | 1983-05-18 | E.I. Du Pont De Nemours And Company | Polyamide resins and process for preparing the same |
-
1979
- 1979-08-30 US US06/071,195 patent/US4251424A/en not_active Expired - Lifetime
-
1980
- 1980-08-27 EP EP80105091A patent/EP0025888B1/en not_active Expired
- 1980-08-27 DE DE8080105091T patent/DE3065168D1/de not_active Expired
- 1980-08-28 CA CA000359193A patent/CA1153842A/en not_active Expired
- 1980-08-28 JP JP11787580A patent/JPS5634755A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5634755A (en) | 1981-04-07 |
| EP0025888A2 (en) | 1981-04-01 |
| EP0025888B1 (en) | 1983-10-05 |
| EP0025888A3 (en) | 1981-05-06 |
| DE3065168D1 (en) | 1983-11-10 |
| JPH0118104B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-04-04 |
| US4251424A (en) | 1981-02-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |