CA1149481A - Flame resistant insulated electrical wire and cable construction - Google Patents
Flame resistant insulated electrical wire and cable constructionInfo
- Publication number
- CA1149481A CA1149481A CA000350751A CA350751A CA1149481A CA 1149481 A CA1149481 A CA 1149481A CA 000350751 A CA000350751 A CA 000350751A CA 350751 A CA350751 A CA 350751A CA 1149481 A CA1149481 A CA 1149481A
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- CA
- Canada
- Prior art keywords
- refractory
- coating
- insulating tape
- base fabric
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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Abstract
ABSTRACT OF THE DISCLOSURE
A flame resistant insulated electrical wire and/or cable construction formed by wrapping a wire or cable conductor with a heat resistant flexible refractory tape comprising a porous base fabric, preferably a knit fiberglass fabric that has been coated and impregnated with refractory materials.
These refractory materials are bonded to both the surface and interstices of the base fabric by means of a bonding agent, such that the fabric remains flexible and retains its stretch properties. In the presence of relatively extreme temperature and heat (e.g., above 1750°F.), the bonding agent will decom-pose without flaming, while the refractory materials will fuse into the softened surface of the knit fiberglass base fabric forming a high temperature resistant structure with ceramic qualities and insulative properties.
A flame resistant insulated electrical wire and/or cable construction formed by wrapping a wire or cable conductor with a heat resistant flexible refractory tape comprising a porous base fabric, preferably a knit fiberglass fabric that has been coated and impregnated with refractory materials.
These refractory materials are bonded to both the surface and interstices of the base fabric by means of a bonding agent, such that the fabric remains flexible and retains its stretch properties. In the presence of relatively extreme temperature and heat (e.g., above 1750°F.), the bonding agent will decom-pose without flaming, while the refractory materials will fuse into the softened surface of the knit fiberglass base fabric forming a high temperature resistant structure with ceramic qualities and insulative properties.
Description
CONSTRUCTION
This invention relates to the art of fire resistant insulated electrical wire and/or cable constructions and more 5 particularly to an improved insulated wire and/or cable con-struction that will function normally while subjected to heat and temperatures up to 1?50F. for a period of one hour.
There is a need for insulated electrical wire and/or cable constructions capable of withstanding the sustained high 10 temperatures of fires to 1750F. that may originate either externally of the wire or cable or internally as a result of electrical short circuit conditions.
Ceramics and/or glass fibers have been used heretofore to prepare electrical cables. In addition, coated fabrics and 15 ceramic structures have been prepared with a combination of glass fiber fabrics and metal oxides.
U.S. Patent No. 2,587,916 of Squier discloses a heat-detecting cable of a pair of electrical wires separated by a glass composition containing barium oxide and/or boron oxide 20 which is non-conductive at normal temperature but is conductive at high temperatures. In one embodiment, the glass is in the form of a fabric having finely divided refractory materials distributed therein to enhance the ability to withstand high temperature. The barium oxide and/or boron oxide containing 25 fiberglass tape does not insulate the wires at high temperature but rather provides a conductive path so as to detect high temperatures.
U.S. Patent No. 3,602,636 of Evans discloses an electrical cable where the conductors are helically wrapped 11494~ s 1 with an open weave glass cloth having a coating of a flame resistant synthetic rubber together with an extruded sheath of polyvinylchloride (PVC) or the like covering the assembled cable.
U.S. Patent No. 3,632,412 of Blance et al. discloses a pressure sensitive adhesive for a Class F (high temperature service) electrical tape. The adhesive is an interpolymer of acrylates, methacrylates and hydroxyacrylates or hydroxymeth-acrylates. Glass cloth is included among the useful backing members for this tape.
U.S. Patent No. 3,013,902 of Bugosh discloses fabrics coated with colloidal alumina and a final coating of a polymer having a plurality of free carboxylic acid groups. Glass fibers are included in the list of materials which may comprise the fabric substrate. These textile products have improved resistance to soiling and improved washability. No use for the fabrics in electrical tape, wire or cable is disclosed or suggested.
U.S. Patent No. 3,095,336 of Church et al. discloses the preparation of ceramic articles laminated with glass fabric by impregnating glass fibers with a mixture of a thermosetting resin and a ceramic filler, curing the resin, heating to gasify the resin and then heating to an elevated temperature to fuse the glass fabric and the ceramic filler to produce rigid, laminated ceramic structures having high strength characteris-tics. No use in electrical tape, wire or cable is disclosed or suggested.
Plastic compounds (principally vinyl) and various elastomeric compounds are widely used as insulation and protective jacketing for electrical wire and cable products.
When exposed to fire at an ignition flame temperature of 700~.
or above, vinyl and virtually all other elastomers provide fuel to propagate the fire and burn emitting toxic smoke.
1149481~
1 The danger associated with electrical fires involving wire and cable insulation and jacketing have been recognized by the industry and a variety of efforts have been made to improve the performance of these products. Thus, fire retardant electrical insulation has been formed of asbestos fiber which has been widely used as part of the insulation and cover wrap material in the construction of fire resistant electrical wire and cable. However, asbestos fibers have now been identified as a carcinogen, and attempts are being made to phase out the use of asbestos.
In an effort to meet improved smoke and fire resistant - standards for electric wire or cable in high performance appli-cations such as marine (ship and submarine), mining installa-tions, oil drilling derricks, nuclear power plants, etc., explosion-proof, fire resistant conduit installations are normally specified. This involves the installation of steel pipe into which the electrical wires or cables are placed. A
fire resistant compound is forced through the pipe under pressure to insulate the vinyl coated wires or cables from the 20 effects of fire. This type of installation does limit the self propagating effects and smoke development of electrical fires. It is, however, costly and though minimizing flame transfer externally of the steel conduit acts to confine heat within the conduit, burning the wire or cable, creating an 25 electrical short circuit condition and subsequent loss of power.
It is with the above considerations in mind that the present improved insulated electrical wire and/or cable con-struction has been evolved to provide an insulated electrical 30 wire and/or cable that is heat resistant and will function according to designated electrical load specifications when exposed to fire or other high heat sources.
~1494~1 1 Accordingly, the present invention provides a heat resistant, flexible refractory, electrical insulating tape comprising a porous base fabric; a refractory coating comprising refractory materials and a bonding agent, said 5 refractory coating formed on the surface and interstices of said fabric and said refractory materials being capable of fusing with the porous base fabric at elevated temperatures.
Said insulating tape when wrapped around an electrical conductor provides a high temperature and flame resistant 10 insulated wire or cable construction. The present invention also includes a method of forming a flame and heat resis-tant insulated electrical conductor, said method comprising the steps of: applying a refractory coating to a porous base fabric; applying an adhesive coating to the refractory 15 coated base fabric; and wrapping the adhesive coated refrac-tory coated base fabric about an electrical conductor.
The objects of the invention which will become hereafter apparent, are achieved by providing a heat resistant flexible refractory tape with stretch properties and 20 by forming an insulated electrical wire and/or cable by wrapping a conductor, preferably of copper, with this heat resistant flexible refractory tape with stretch properties.
This high temperature and heat resistant flexible refractory tape with stretch properties is formed by coating 25 and impregnating a heat resistant porous base fabric, prefer-ably a knitted fiberglass fabric with high temperature and heat resistant refractory materials such as alumina or zirconia utilizing a bonding agent such as a combination of acrylic latex and colloidal silica or acrylic latex alone.
30The refractory material may be admixed with the bonding agent so that the refractory materials are uniformly displaced throughout the bonding agent and then the mixture may be applied to the porous base fabric to form the refractory - coating. This refractory coating comprising the refractory 1~4948~
1 materials and bonding agent is bonded to both the surface and the interstices of the porous base fabric. After impregnation and coating of the base fabric with the refractory coating, the coated fabric is preferably coated on both sides with a 5 fire retardant, abrasion resistant, polymeric coating, dried and slit into desired widths to form the high temperature resistant tape.
The tape is preferably wrapped around the wire or cable conductor overlapping a previous tape turn by 50%
10 thereby creating a double layer of insulation for each wrapping of tape. A second tape may be wrapped over the first in the same manner creating a second double layer of insulation making a total of four layers of insulation wrapped around the conductor. In cables that contain two or more separate con-15ductors, each conductor is preferably wrapped separately witha double layer of insulation; all the separately wrapped con-ductors are then brought together to form the desired electrical cable and are wrapped together in a bundle with high temperature insulation tape as previously described to 20provide a double layer of outer insulation.
In the presence of extreme temperatures and heat, the bonding agent containing the refractory materials will decom-pose, causing the refractory materials to fuse into the softened surface of the knit fiberglass base fabric, enabling 25it to withstand intense heat and elevated temperatures well beyond the normal melt temperature of the fiberglass fabric.
The resulting fabric structure will have ceramic qualities and will not soften, melt, drip or lose its insulating p~operties.
A feature of the invention resides in the fact that 30 the refractory materials are bonded in the interstices as well as to the surface of the base fabric, such that a significant amount of the fabric's flexibility and stretch properties are retained.
1 The specific details of the best mode contemplated for carrying out the invention, and the manner and process of making and using it, will be particularly pointed out in clear, concise, and exact terms in conjunction with the accompanying 5 drawings, wherein:
FIG. 1 is an enlarged partially sectioned perspective view of a segment of flame resistant insulated electric cable made in accordance with the invention showing two separately insulated copper wire conductors wrapped together;
FIG. 2 is an enlarged partially sectioned perspective view of a segment of a flame resistant electrical cable con-struction showing a multi-stranded conductor with a double wrapped outer insulation;
FIG. 3 is an enlarged cross-sectional view of the 15 insulation made with a knit base fabric showing the impregnation coating of the refractory materials on both fabric surfaces as well as in the interstices of the fabric; and j FIG. 4 is an enlarged perspective plan view of the knit base fabric construction showing the impregnation coating of the 20 refractory materials on the surface and in the interstices of the fabric.
Referring now more particularly to the drawings, like numerals in the various illustrative FIGS. will be employed to designate like parts.
The flame resistant insulated electrical cable 10, as illustratively depicted in FIG. 1, is comprised of two copper conductors 11, separately wrapped in high temperature resistant insulation tape 12, and bound together as a pair with an additional outer insulating wrapper 13 of high temperature 30 resistant insulation tape. The insulation tape in both instances is wrapped such that it overlaps the previous turn by 50% thereby 114948~
1 providing a double layer of insulation for each wrapping of tape.
A flameproof adhesive is preferably applied to the tape just prior to wrapping to prevent any movement or lifting of the insulation when the cable is cut.
Alternatively, the flameproof adhesive may be pre-applied to the tape. Several embodiments are thus possible.
In one, the adhesive is applied to either side of the tape, i.e., to either face which contains the polymeric coating. In another, following the application of the refractory coating 10 to both sides of the porous base fabric, the polymeric coating is applied to one of the refractory coating surfaces and the adhesive is applied to the other. The choice here will depend on the overall economics of the final electrical cable and the performance features which the user finds most desirable in the 15 high temperature resistant insulation tape.
The flameproof electrical cable construction 15, illustratively shown in FIG. 2, comprises a central multi-stranded copper cable conductor 16 wrapped with an inner insula-tion tape layer 17 and an outer insulation tape layer 18. In 20 both instances the insulation tape is wrapped, as in FIG. 1, such that it overlaps the previous turn by 50% thereby providing a double layer of insulation for each wrapping of tape.
The flame resistant fabric construction 20 (from which insulating tape 12 is formed), as illustratively shown in FIG.
25 3, is constructed of a knit fiberglass base fabric 26 having knit yarns 24 and fill yarns 25.
Satisfactory results have been obtained employing knit yarns 24 comprised of DE type fiberglass with a yarn designa-tion of DE-150-1/0 and fill or lay in yarns 25 comprised of 3 fiberglass with a yarn designation of DE-150-1/0.
8 114948~
1 The porous base fabric 26 of knit fiberglass used in the illustrated preferred embodiment of fabric construction may be produced on warp knitting machinery such as the Raschel type warp knitting machines, manufactured by Karl Mayer, GmbH, 5 Germany; Liba, GmbH, Germany; Rockwell International, U.S.A.;
and the Kidde Textile ~achine Company, U.S.A. with the following preferred specifications.
Fabric Thickness: .016 inches.
Fabric Weight: 9 ounces per s~uare yard.
Knit Pattern: Cable stitch and weft lay in.
Knit Construction: 3 Bar.
1st Bar: knit yarn-cable stitch 20 knitting stitches per inch of fabric width (yarn: fiberglass DE-105-1/0) 2nd Bar: lay in yarn-weft lay in 1 24 stitches or courses per inch of fabric length (yarn: fiberglass DE-150-1/0) 3rd Bar: reinforcing yarn (optional) (yarn: fiberglass DE-150-1/0) As will be understood by those skilled in the art, the knit fiberglass substrate fabric 26, though preferably formed 20Of all fiberglass yarns, may be constructed with other kinds of fire resistant knit yarns 24 or with only the weft lay in yarn 25 comprised of fiberglass. The substrate or porous base fabric may also be a woven fiberglass or a non-woven, porous web of fiberglass.
As used herein the term "fabric" includes materials which are woven, knitted, felted, fused, non-woven or otherwise constructed from fibers. Since the base fabric must have a porosity there must be an openness to the texture of the fabric so as to permit the refractory coating to impregnate the sur-3Oface of the fabric and fill, at least partially, some, if notall, of the interstices of the porous fabric.
1~494~1 1 The refractory coating which is applied to both sides and impregnates the interstices of the porous base fabric com-prises heat resistant refractory materials intermixed or dis-persed in a bonding agent. The refractory materia~s may be any 5 of the usual known refractory materials in finely divided form which will fuse with the porous base fabric when subjected to elevated temperatures, e.g., above about 1750F., and includes compounds of aluminum, calcium, chromium, magnesium, silicon, titanium, zirconium and the like, such as aluminum oxide, lO calcium oxide, magnesium oxide, silicon oxide, titanium oxide, zirconium oxide, aluminum silicate, calcium silicate, magnesium silicate, silicon carbide, zirconium carbide and the like.
Alumina, zirconia, calcium silicate and silicon dioxide are preferred, alone or in combination.
The bonding agent is used to adhere or bond the refractory materials to the porous base fabric. Although the bonding agent will decompose at extremely high temperatures, e.g., above about 1750F., it must do so without producing a ~flame. At these temperatures, the refractory materials will 20fuse into the surface of the porous fabric forming a high temperature resistant ceramic structure with insulation pro-perties. Useful bonding agents include acrylic latex resin alone or in combination with colloidal silica.
- The examples below describe a number of refractory 25coatings which are referred to in these examples as "refractory cements". The terms "refractory cement" and "refractory coating" are used synonymously in this specification. Further, in these same examples, components of the bonding agent are described as a "binder". One or two "binders" comprise the 3Obonding agent.
1~4~4~1 1 In addition to the bonding agent and the refractory materials, the refractory coating may, optionally and preferably, contain a thickening agent. The purpose of the thickening agent is to add body and increase the viscosity of the refractory 5 coating so as to simplify the process of applying the coating onto the porous base fabric and, additionally, to cause the refractory coating to adhere to the surface of the fabric. The preferred thickening agent is a 50 wt. ~ dispersion of an acrylate-vinylpyrrolidone copolymer in water.
As illustratively shown in FIG. 3, the base fabric 26 has been coated on both surfaces and impregnated with refractory materials 21 as contained in a refractory cement (also referred to herein as a refractory coating) which may be made up of a number of formulations as follows:
3o 1~9481 1 E ~ ~LE 1 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721
This invention relates to the art of fire resistant insulated electrical wire and/or cable constructions and more 5 particularly to an improved insulated wire and/or cable con-struction that will function normally while subjected to heat and temperatures up to 1?50F. for a period of one hour.
There is a need for insulated electrical wire and/or cable constructions capable of withstanding the sustained high 10 temperatures of fires to 1750F. that may originate either externally of the wire or cable or internally as a result of electrical short circuit conditions.
Ceramics and/or glass fibers have been used heretofore to prepare electrical cables. In addition, coated fabrics and 15 ceramic structures have been prepared with a combination of glass fiber fabrics and metal oxides.
U.S. Patent No. 2,587,916 of Squier discloses a heat-detecting cable of a pair of electrical wires separated by a glass composition containing barium oxide and/or boron oxide 20 which is non-conductive at normal temperature but is conductive at high temperatures. In one embodiment, the glass is in the form of a fabric having finely divided refractory materials distributed therein to enhance the ability to withstand high temperature. The barium oxide and/or boron oxide containing 25 fiberglass tape does not insulate the wires at high temperature but rather provides a conductive path so as to detect high temperatures.
U.S. Patent No. 3,602,636 of Evans discloses an electrical cable where the conductors are helically wrapped 11494~ s 1 with an open weave glass cloth having a coating of a flame resistant synthetic rubber together with an extruded sheath of polyvinylchloride (PVC) or the like covering the assembled cable.
U.S. Patent No. 3,632,412 of Blance et al. discloses a pressure sensitive adhesive for a Class F (high temperature service) electrical tape. The adhesive is an interpolymer of acrylates, methacrylates and hydroxyacrylates or hydroxymeth-acrylates. Glass cloth is included among the useful backing members for this tape.
U.S. Patent No. 3,013,902 of Bugosh discloses fabrics coated with colloidal alumina and a final coating of a polymer having a plurality of free carboxylic acid groups. Glass fibers are included in the list of materials which may comprise the fabric substrate. These textile products have improved resistance to soiling and improved washability. No use for the fabrics in electrical tape, wire or cable is disclosed or suggested.
U.S. Patent No. 3,095,336 of Church et al. discloses the preparation of ceramic articles laminated with glass fabric by impregnating glass fibers with a mixture of a thermosetting resin and a ceramic filler, curing the resin, heating to gasify the resin and then heating to an elevated temperature to fuse the glass fabric and the ceramic filler to produce rigid, laminated ceramic structures having high strength characteris-tics. No use in electrical tape, wire or cable is disclosed or suggested.
Plastic compounds (principally vinyl) and various elastomeric compounds are widely used as insulation and protective jacketing for electrical wire and cable products.
When exposed to fire at an ignition flame temperature of 700~.
or above, vinyl and virtually all other elastomers provide fuel to propagate the fire and burn emitting toxic smoke.
1149481~
1 The danger associated with electrical fires involving wire and cable insulation and jacketing have been recognized by the industry and a variety of efforts have been made to improve the performance of these products. Thus, fire retardant electrical insulation has been formed of asbestos fiber which has been widely used as part of the insulation and cover wrap material in the construction of fire resistant electrical wire and cable. However, asbestos fibers have now been identified as a carcinogen, and attempts are being made to phase out the use of asbestos.
In an effort to meet improved smoke and fire resistant - standards for electric wire or cable in high performance appli-cations such as marine (ship and submarine), mining installa-tions, oil drilling derricks, nuclear power plants, etc., explosion-proof, fire resistant conduit installations are normally specified. This involves the installation of steel pipe into which the electrical wires or cables are placed. A
fire resistant compound is forced through the pipe under pressure to insulate the vinyl coated wires or cables from the 20 effects of fire. This type of installation does limit the self propagating effects and smoke development of electrical fires. It is, however, costly and though minimizing flame transfer externally of the steel conduit acts to confine heat within the conduit, burning the wire or cable, creating an 25 electrical short circuit condition and subsequent loss of power.
It is with the above considerations in mind that the present improved insulated electrical wire and/or cable con-struction has been evolved to provide an insulated electrical 30 wire and/or cable that is heat resistant and will function according to designated electrical load specifications when exposed to fire or other high heat sources.
~1494~1 1 Accordingly, the present invention provides a heat resistant, flexible refractory, electrical insulating tape comprising a porous base fabric; a refractory coating comprising refractory materials and a bonding agent, said 5 refractory coating formed on the surface and interstices of said fabric and said refractory materials being capable of fusing with the porous base fabric at elevated temperatures.
Said insulating tape when wrapped around an electrical conductor provides a high temperature and flame resistant 10 insulated wire or cable construction. The present invention also includes a method of forming a flame and heat resis-tant insulated electrical conductor, said method comprising the steps of: applying a refractory coating to a porous base fabric; applying an adhesive coating to the refractory 15 coated base fabric; and wrapping the adhesive coated refrac-tory coated base fabric about an electrical conductor.
The objects of the invention which will become hereafter apparent, are achieved by providing a heat resistant flexible refractory tape with stretch properties and 20 by forming an insulated electrical wire and/or cable by wrapping a conductor, preferably of copper, with this heat resistant flexible refractory tape with stretch properties.
This high temperature and heat resistant flexible refractory tape with stretch properties is formed by coating 25 and impregnating a heat resistant porous base fabric, prefer-ably a knitted fiberglass fabric with high temperature and heat resistant refractory materials such as alumina or zirconia utilizing a bonding agent such as a combination of acrylic latex and colloidal silica or acrylic latex alone.
30The refractory material may be admixed with the bonding agent so that the refractory materials are uniformly displaced throughout the bonding agent and then the mixture may be applied to the porous base fabric to form the refractory - coating. This refractory coating comprising the refractory 1~4948~
1 materials and bonding agent is bonded to both the surface and the interstices of the porous base fabric. After impregnation and coating of the base fabric with the refractory coating, the coated fabric is preferably coated on both sides with a 5 fire retardant, abrasion resistant, polymeric coating, dried and slit into desired widths to form the high temperature resistant tape.
The tape is preferably wrapped around the wire or cable conductor overlapping a previous tape turn by 50%
10 thereby creating a double layer of insulation for each wrapping of tape. A second tape may be wrapped over the first in the same manner creating a second double layer of insulation making a total of four layers of insulation wrapped around the conductor. In cables that contain two or more separate con-15ductors, each conductor is preferably wrapped separately witha double layer of insulation; all the separately wrapped con-ductors are then brought together to form the desired electrical cable and are wrapped together in a bundle with high temperature insulation tape as previously described to 20provide a double layer of outer insulation.
In the presence of extreme temperatures and heat, the bonding agent containing the refractory materials will decom-pose, causing the refractory materials to fuse into the softened surface of the knit fiberglass base fabric, enabling 25it to withstand intense heat and elevated temperatures well beyond the normal melt temperature of the fiberglass fabric.
The resulting fabric structure will have ceramic qualities and will not soften, melt, drip or lose its insulating p~operties.
A feature of the invention resides in the fact that 30 the refractory materials are bonded in the interstices as well as to the surface of the base fabric, such that a significant amount of the fabric's flexibility and stretch properties are retained.
1 The specific details of the best mode contemplated for carrying out the invention, and the manner and process of making and using it, will be particularly pointed out in clear, concise, and exact terms in conjunction with the accompanying 5 drawings, wherein:
FIG. 1 is an enlarged partially sectioned perspective view of a segment of flame resistant insulated electric cable made in accordance with the invention showing two separately insulated copper wire conductors wrapped together;
FIG. 2 is an enlarged partially sectioned perspective view of a segment of a flame resistant electrical cable con-struction showing a multi-stranded conductor with a double wrapped outer insulation;
FIG. 3 is an enlarged cross-sectional view of the 15 insulation made with a knit base fabric showing the impregnation coating of the refractory materials on both fabric surfaces as well as in the interstices of the fabric; and j FIG. 4 is an enlarged perspective plan view of the knit base fabric construction showing the impregnation coating of the 20 refractory materials on the surface and in the interstices of the fabric.
Referring now more particularly to the drawings, like numerals in the various illustrative FIGS. will be employed to designate like parts.
The flame resistant insulated electrical cable 10, as illustratively depicted in FIG. 1, is comprised of two copper conductors 11, separately wrapped in high temperature resistant insulation tape 12, and bound together as a pair with an additional outer insulating wrapper 13 of high temperature 30 resistant insulation tape. The insulation tape in both instances is wrapped such that it overlaps the previous turn by 50% thereby 114948~
1 providing a double layer of insulation for each wrapping of tape.
A flameproof adhesive is preferably applied to the tape just prior to wrapping to prevent any movement or lifting of the insulation when the cable is cut.
Alternatively, the flameproof adhesive may be pre-applied to the tape. Several embodiments are thus possible.
In one, the adhesive is applied to either side of the tape, i.e., to either face which contains the polymeric coating. In another, following the application of the refractory coating 10 to both sides of the porous base fabric, the polymeric coating is applied to one of the refractory coating surfaces and the adhesive is applied to the other. The choice here will depend on the overall economics of the final electrical cable and the performance features which the user finds most desirable in the 15 high temperature resistant insulation tape.
The flameproof electrical cable construction 15, illustratively shown in FIG. 2, comprises a central multi-stranded copper cable conductor 16 wrapped with an inner insula-tion tape layer 17 and an outer insulation tape layer 18. In 20 both instances the insulation tape is wrapped, as in FIG. 1, such that it overlaps the previous turn by 50% thereby providing a double layer of insulation for each wrapping of tape.
The flame resistant fabric construction 20 (from which insulating tape 12 is formed), as illustratively shown in FIG.
25 3, is constructed of a knit fiberglass base fabric 26 having knit yarns 24 and fill yarns 25.
Satisfactory results have been obtained employing knit yarns 24 comprised of DE type fiberglass with a yarn designa-tion of DE-150-1/0 and fill or lay in yarns 25 comprised of 3 fiberglass with a yarn designation of DE-150-1/0.
8 114948~
1 The porous base fabric 26 of knit fiberglass used in the illustrated preferred embodiment of fabric construction may be produced on warp knitting machinery such as the Raschel type warp knitting machines, manufactured by Karl Mayer, GmbH, 5 Germany; Liba, GmbH, Germany; Rockwell International, U.S.A.;
and the Kidde Textile ~achine Company, U.S.A. with the following preferred specifications.
Fabric Thickness: .016 inches.
Fabric Weight: 9 ounces per s~uare yard.
Knit Pattern: Cable stitch and weft lay in.
Knit Construction: 3 Bar.
1st Bar: knit yarn-cable stitch 20 knitting stitches per inch of fabric width (yarn: fiberglass DE-105-1/0) 2nd Bar: lay in yarn-weft lay in 1 24 stitches or courses per inch of fabric length (yarn: fiberglass DE-150-1/0) 3rd Bar: reinforcing yarn (optional) (yarn: fiberglass DE-150-1/0) As will be understood by those skilled in the art, the knit fiberglass substrate fabric 26, though preferably formed 20Of all fiberglass yarns, may be constructed with other kinds of fire resistant knit yarns 24 or with only the weft lay in yarn 25 comprised of fiberglass. The substrate or porous base fabric may also be a woven fiberglass or a non-woven, porous web of fiberglass.
As used herein the term "fabric" includes materials which are woven, knitted, felted, fused, non-woven or otherwise constructed from fibers. Since the base fabric must have a porosity there must be an openness to the texture of the fabric so as to permit the refractory coating to impregnate the sur-3Oface of the fabric and fill, at least partially, some, if notall, of the interstices of the porous fabric.
1~494~1 1 The refractory coating which is applied to both sides and impregnates the interstices of the porous base fabric com-prises heat resistant refractory materials intermixed or dis-persed in a bonding agent. The refractory materia~s may be any 5 of the usual known refractory materials in finely divided form which will fuse with the porous base fabric when subjected to elevated temperatures, e.g., above about 1750F., and includes compounds of aluminum, calcium, chromium, magnesium, silicon, titanium, zirconium and the like, such as aluminum oxide, lO calcium oxide, magnesium oxide, silicon oxide, titanium oxide, zirconium oxide, aluminum silicate, calcium silicate, magnesium silicate, silicon carbide, zirconium carbide and the like.
Alumina, zirconia, calcium silicate and silicon dioxide are preferred, alone or in combination.
The bonding agent is used to adhere or bond the refractory materials to the porous base fabric. Although the bonding agent will decompose at extremely high temperatures, e.g., above about 1750F., it must do so without producing a ~flame. At these temperatures, the refractory materials will 20fuse into the surface of the porous fabric forming a high temperature resistant ceramic structure with insulation pro-perties. Useful bonding agents include acrylic latex resin alone or in combination with colloidal silica.
- The examples below describe a number of refractory 25coatings which are referred to in these examples as "refractory cements". The terms "refractory cement" and "refractory coating" are used synonymously in this specification. Further, in these same examples, components of the bonding agent are described as a "binder". One or two "binders" comprise the 3Obonding agent.
1~4~4~1 1 In addition to the bonding agent and the refractory materials, the refractory coating may, optionally and preferably, contain a thickening agent. The purpose of the thickening agent is to add body and increase the viscosity of the refractory 5 coating so as to simplify the process of applying the coating onto the porous base fabric and, additionally, to cause the refractory coating to adhere to the surface of the fabric. The preferred thickening agent is a 50 wt. ~ dispersion of an acrylate-vinylpyrrolidone copolymer in water.
As illustratively shown in FIG. 3, the base fabric 26 has been coated on both surfaces and impregnated with refractory materials 21 as contained in a refractory cement (also referred to herein as a refractory coating) which may be made up of a number of formulations as follows:
3o 1~9481 1 E ~ ~LE 1 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721
2. Binder - Organic Acrylic Latex Resin 100.
. UCAR 189 - (2-1/2~ solids in water) Union Carbide Corp.
New York, NY
- 5 3. Aluminum Oxide - 300.
Reynolds Metals Company -Chemicals Division Richmond, VA 23261 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
~, Total 900.
3o High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
(2-1/2% solids in water3 Union Carbide Corp.
New York, NY
15 3. Calcium Metasilicate 100.
- Interspace Corporation -Willsboro, NY 12996 20 4. Silicon Dioxide 100.
Min-U-Sil Pennsylvania Glass Sand Corp.
` Pittsburg, PA 15235 5. Aluminum Oxide 100.
- Reynolds Metals Company Chemicals Division Richmond, VA 23261 6. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba Geigy Ardsley, NY
Total 900.
11494~1 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Kaowool Cement 400-Alumina - A12O3: 41%
Silica - SiO2 : 57%
Other : 02%
Total 100%
Babcock and Wilcox Refractories Division Augusta, GA ..
2-. -Binder - Organic Acrylic Latex Resin . 30.
(2-1/2% solids in water) Union Carbide Corp.
New York, NY
....
. UCAR 189 - (2-1/2~ solids in water) Union Carbide Corp.
New York, NY
- 5 3. Aluminum Oxide - 300.
Reynolds Metals Company -Chemicals Division Richmond, VA 23261 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
~, Total 900.
3o High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
(2-1/2% solids in water3 Union Carbide Corp.
New York, NY
15 3. Calcium Metasilicate 100.
- Interspace Corporation -Willsboro, NY 12996 20 4. Silicon Dioxide 100.
Min-U-Sil Pennsylvania Glass Sand Corp.
` Pittsburg, PA 15235 5. Aluminum Oxide 100.
- Reynolds Metals Company Chemicals Division Richmond, VA 23261 6. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba Geigy Ardsley, NY
Total 900.
11494~1 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Kaowool Cement 400-Alumina - A12O3: 41%
Silica - SiO2 : 57%
Other : 02%
Total 100%
Babcock and Wilcox Refractories Division Augusta, GA ..
2-. -Binder - Organic Acrylic Latex Resin . 30.
(2-1/2% solids in water) Union Carbide Corp.
New York, NY
....
3. Thickening Agent Collacral VL 30.
- (Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba-Geigy Ardsley, NY
Total 460.
3o 1149~Bl High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. QF - 180 Coating Cement 400.
Alumina - A1203: 41%
Silica - SiO2 : 57%
Other : 02%
Total 100% t The Carborundum Co.
Niagara Falls, NY 14302 ' 10 . ' .. ~ 2. Binder - Organic - Acrylic Latex Resin 30.
(2-1/2~ solids in water) Union Carbide Corp.
New York, NY
3. Thickening Agent -Collacral VL 30.
(Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba--Geigy Ardsley, NY
Total 460.
,.~
3o 1~49481 1 EX~IPLE 5 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
; UCAR 189 (2-1/2~ solids in water) Union Carbide Corp.
New York, NY
15 3. Alumina Bulk Fiber 300.
Ball Milled - "Saffil" Fiber Imperial Chemical Industries Ltd.
United Kingdom 20 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 900.
_ _ .
11494~1 1 E ~PLE 6 High Temperature and Heat Resistant Refractory Cement Materials Parts By ~leight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
- (2-1/2% solids in water) Union Carbide Corp.
New York, NY
- 5 3. Zirconia Fiber - 300 Ball Milled Zirconia Fiber Imperial Chemical Industries Ltd.
United Kingdom 20 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone ` copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 900.
.
1149q8~
1 The base fabric 26 as illustratively shown in FIG.3 and FIG. 4 has been coated on both sides and impregnated with a refractory coating or cement 21 formulated in accordance with the above examples at a coating density of approximately 10 5 ounces per square yard, based on dry net weight which represents about 50% of the overall weight of the impregnated base fabric.
A flameproof polymeric coating 23 is then applied over E
the refractory impregnation coating at a coating density of approximately 1 ounce per square yard, based on dry net weight, 10 to improve the surface abrasion qualities of the fabric and to X seal in and contain any refractory materials tha,t may otherwise loosen from the fabric as it is stretched in the wire and/or cable wrapping process.
The flameproof polymeric coating is applied to both 15 surfaces of the refractory coating or, optionally, to only one surface, particularly where the flameproof adhesive is pre-applied to the other surface of the refractory coating.
The polymer used in the polymeric coating must not produce a flame,when exposed to a flame or the intense heat 20 developed by a flame, i.e., temperatures of 1750F. and above, even though it may decompose at these elevated temperatures.
Polyvi`nyl chloride resin is the preferred polymer used in the polymeric coating. This coating is a mixture of selected plasticizers, stabilizers and modifiers, dispersion resins and 25 oxides. A number of components are combined with the polyvinyl ' resins to provide the required properties of high temperature resistance and flexibility. The polymeric coating preferred in this invention has the following formulation:
~ .
1 Polymeric Coating Materials Parts By Weight As Is 1. Plasticizers a) Tricresyl Phosphate (TCP) 20 Stauffer Chemical New York, NY
or Ashland Chemical Columbus, OH
b) Santicizer 148 20 (phosphate-type plasticizer) - Monsanto Chemical Co.
St. Louis, MO
15 c) Santicizer 154 20 (phosphate-type plasticizer) Monsanto Chemical Co.
St. Louis, MO
d) Texanol Isobutylrate (TXIB) 10 Eastman Chemical Products Inc.
Kingsport, TN
e) Epoxol 8-2B 5 Epoxidized butyl linseed oil Swift Chemical Co.
Chicago, IL
Total 75 2. Stabilizers and Modifiers a) Nuostabe Z-142 3 Calcium-zinc complex Tenneco Chemicals Inc.
Piscataway, NJ
114948~
1 Materials Parts By Weight As Is b) Apon 828 4 Epoxy resin Shell Chemical Co.
Houston, TX
c) Cymel 301 5 Hexaneethoxymethylmelamine American Cyanamid Co.
Wayne, NJ
d) Pego Sperse 400MO
. Polyethylene glycol mono-oleate Glyco Chemicals Inc.
Greenwich, CT 06830 Total 11 . 15 3. Dispersion Resins a) Geon 130 X17 50 Polyvinyl chloride B.F. Goodrich Chemical Co.
Cleveland, OH
b). Geon 128 50 Polyvinyl chloride B.F. Goodrich Chemical Co.
Cleveland, OH
: 25 . Total 100
- (Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba-Geigy Ardsley, NY
Total 460.
3o 1149~Bl High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. QF - 180 Coating Cement 400.
Alumina - A1203: 41%
Silica - SiO2 : 57%
Other : 02%
Total 100% t The Carborundum Co.
Niagara Falls, NY 14302 ' 10 . ' .. ~ 2. Binder - Organic - Acrylic Latex Resin 30.
(2-1/2~ solids in water) Union Carbide Corp.
New York, NY
3. Thickening Agent -Collacral VL 30.
(Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba--Geigy Ardsley, NY
Total 460.
,.~
3o 1~49481 1 EX~IPLE 5 High Temperature and Heat Resistant Refractory Cement Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
; UCAR 189 (2-1/2~ solids in water) Union Carbide Corp.
New York, NY
15 3. Alumina Bulk Fiber 300.
Ball Milled - "Saffil" Fiber Imperial Chemical Industries Ltd.
United Kingdom 20 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 900.
_ _ .
11494~1 1 E ~PLE 6 High Temperature and Heat Resistant Refractory Cement Materials Parts By ~leight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
Ashland, MA 01721 2. Binder - Organic Acrylic Latex Resin 100.
- (2-1/2% solids in water) Union Carbide Corp.
New York, NY
- 5 3. Zirconia Fiber - 300 Ball Milled Zirconia Fiber Imperial Chemical Industries Ltd.
United Kingdom 20 4. Thickening Agent Collacral VL 100.
(Acrylate-vinylpyrrolidone ` copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 900.
.
1149q8~
1 The base fabric 26 as illustratively shown in FIG.3 and FIG. 4 has been coated on both sides and impregnated with a refractory coating or cement 21 formulated in accordance with the above examples at a coating density of approximately 10 5 ounces per square yard, based on dry net weight which represents about 50% of the overall weight of the impregnated base fabric.
A flameproof polymeric coating 23 is then applied over E
the refractory impregnation coating at a coating density of approximately 1 ounce per square yard, based on dry net weight, 10 to improve the surface abrasion qualities of the fabric and to X seal in and contain any refractory materials tha,t may otherwise loosen from the fabric as it is stretched in the wire and/or cable wrapping process.
The flameproof polymeric coating is applied to both 15 surfaces of the refractory coating or, optionally, to only one surface, particularly where the flameproof adhesive is pre-applied to the other surface of the refractory coating.
The polymer used in the polymeric coating must not produce a flame,when exposed to a flame or the intense heat 20 developed by a flame, i.e., temperatures of 1750F. and above, even though it may decompose at these elevated temperatures.
Polyvi`nyl chloride resin is the preferred polymer used in the polymeric coating. This coating is a mixture of selected plasticizers, stabilizers and modifiers, dispersion resins and 25 oxides. A number of components are combined with the polyvinyl ' resins to provide the required properties of high temperature resistance and flexibility. The polymeric coating preferred in this invention has the following formulation:
~ .
1 Polymeric Coating Materials Parts By Weight As Is 1. Plasticizers a) Tricresyl Phosphate (TCP) 20 Stauffer Chemical New York, NY
or Ashland Chemical Columbus, OH
b) Santicizer 148 20 (phosphate-type plasticizer) - Monsanto Chemical Co.
St. Louis, MO
15 c) Santicizer 154 20 (phosphate-type plasticizer) Monsanto Chemical Co.
St. Louis, MO
d) Texanol Isobutylrate (TXIB) 10 Eastman Chemical Products Inc.
Kingsport, TN
e) Epoxol 8-2B 5 Epoxidized butyl linseed oil Swift Chemical Co.
Chicago, IL
Total 75 2. Stabilizers and Modifiers a) Nuostabe Z-142 3 Calcium-zinc complex Tenneco Chemicals Inc.
Piscataway, NJ
114948~
1 Materials Parts By Weight As Is b) Apon 828 4 Epoxy resin Shell Chemical Co.
Houston, TX
c) Cymel 301 5 Hexaneethoxymethylmelamine American Cyanamid Co.
Wayne, NJ
d) Pego Sperse 400MO
. Polyethylene glycol mono-oleate Glyco Chemicals Inc.
Greenwich, CT 06830 Total 11 . 15 3. Dispersion Resins a) Geon 130 X17 50 Polyvinyl chloride B.F. Goodrich Chemical Co.
Cleveland, OH
b). Geon 128 50 Polyvinyl chloride B.F. Goodrich Chemical Co.
Cleveland, OH
: 25 . Total 100
4. Oxide Slurry ; a) Tricresyl Phosphate ~TCP) 24.5 Stauffer Chemical New York, NY
or -; Ashland Chemical Columbus, OH
~14948~
1 Material Parts By Weight As Is b) Pego Sperse 400MO 0.35 Polyethylene glycol mono-oleate Glyco Chemicals Inc.
Greenwich, CT
c) T-Top-12 0.15 Titanate coupling agent Kenrich Petrochemicals, Inc.
Bayonne, NJ
. ' d) Ti Pure R-900 10.
. Titanium Dioxide (TiO2), rutite type E.I. duPont deNemours & Co.
Wilmington, DE
e) Antimony oxide 10.
Total 45.
The construction of the base knit fiberglass 26 is 20 designed to provide a coarseness such that the maximum thick-ness of the knit fabric, at a point where the yarns cross be at least 70% to 150% greater than the fabric thickness in areas of minimum thickness. The fabric construction further provides for interstices 22 of sufficient size such that when the fabric 25 is impregnated and coated with the refractory materials, the ~uantity of refractory material contained and embedded in the fabric interstices will be sufficient to cause the overall weight of the impregnated fabric to be 70% to 150% greater than the weight of the base fiberglass fabric.
The impregnated fabric 20 as herein disclosed, is then slit to desired tape widths suitable for wrapping wire and/or cable conductors.
~14948~
1 During the wire and/or cable wrapping process, a flame-proof polymeric adhesive is preferably applied to the inside surface of the tape to prevent it from unraveling or slipping from its 50% overwrap configuration. Alternatively, the
or -; Ashland Chemical Columbus, OH
~14948~
1 Material Parts By Weight As Is b) Pego Sperse 400MO 0.35 Polyethylene glycol mono-oleate Glyco Chemicals Inc.
Greenwich, CT
c) T-Top-12 0.15 Titanate coupling agent Kenrich Petrochemicals, Inc.
Bayonne, NJ
. ' d) Ti Pure R-900 10.
. Titanium Dioxide (TiO2), rutite type E.I. duPont deNemours & Co.
Wilmington, DE
e) Antimony oxide 10.
Total 45.
The construction of the base knit fiberglass 26 is 20 designed to provide a coarseness such that the maximum thick-ness of the knit fabric, at a point where the yarns cross be at least 70% to 150% greater than the fabric thickness in areas of minimum thickness. The fabric construction further provides for interstices 22 of sufficient size such that when the fabric 25 is impregnated and coated with the refractory materials, the ~uantity of refractory material contained and embedded in the fabric interstices will be sufficient to cause the overall weight of the impregnated fabric to be 70% to 150% greater than the weight of the base fiberglass fabric.
The impregnated fabric 20 as herein disclosed, is then slit to desired tape widths suitable for wrapping wire and/or cable conductors.
~14948~
1 During the wire and/or cable wrapping process, a flame-proof polymeric adhesive is preferably applied to the inside surface of the tape to prevent it from unraveling or slipping from its 50% overwrap configuration. Alternatively, the
5 adhesive may be pre-applied to one side of the surface of the tape during its fabrication. It may be applied directly onto one of the surfaces of the refractory coating or, where the polymeric coating has been applied to both surfaces of the refractory coating, to one of the polymeric coating surfaces.
10 The thus assembled tape can be applied with the 50% overwrap -configuration in a fashion similar to that described above where ... . .
the adhesive is applied during the wrapping process. The flame-proof tape adhesive may be made up of a number of preferred formulations as follows:
,~.
3o 1149~81 Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
- Ashland, MA 01721 t 2. Binder - Organic Acrylic Latex Resin 50.
.-~ UCAR 189 (40% solids) Union Carbide Corp.
New York, NY
15 3. Thickening Agent.
Collacral VL 10.
- (Acrylate-vinylpyrrolidone .-copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 460.
3o 1~9~8i Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Nitrile Latex-Type 1570 x 60 200.
(20% solids in water) B.F. Goodrich Chemical Co.
Cleveland, OH 44115 2. Aluminum ~ydrate 100.
Solem Industries, Inc.
Atlanta, GA 30341 3. Thickening Agent Collacral VL 20.
(Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba-Geigy Ardsley, NY
Total 320.
~}
~149~
Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 40.
NYACOL, Inc.
Ashland, MA
2. Binder - Organic Acrylic Latex Resin 5. -` ~40% solids) Union Carbide Corp.
New York, NY
15 3, Thickening Agent Fumed Silica 2.5 Cab-O-Sil M-5 Cabot Corporation Boston, MA
Total47.5 , 3o 1 EXA~IPLE 10 Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 40.
Ludox HS-40 E.I. duPont deNemours ~ Co.
Wilmington, DE
2. Binder - Organic Acrylic Latex Resin 5.
.- HYCAR 2679 x 6 - B.F. Goodrich Chemical Co.
Cleveland, OH
15 3~ Thickening Agent Fumed Silica 2.5 Cab-O-Sil M-5 Cabot Corporation Boston, MA
Total47.5 .~
3o 4g~8~
l Operation In use, an insulated wire or cable is formed as above-described utilizing a refractory impregnated porous base fabric 26 to form insulating tape.
The impregnation coating of refractory material fills the interstices of the preferred base fabric comprising a knit fiberglass and is bonded to the surface of the fiberglass yarns forming a discontinuous film coating that allows the fiberglass yarn, as well as the coated fiberglass fabric to retain between lO 50% and 7~% of its original uncoated flex properties. Further, the soft acrylate resin that is the principal ingredient of the collacral thickening agent used in the refractory coating cement serves as an internal lubricant by coating and suspending the very fine alumina, silica, etc. particles that comprise the 15 refractory cement. The collacral thickening agent, upon drying, softens and modifies the otherwise very hard bonding character-istics of the refractory cement such that a more flexible bond to the fiberglass substrate fabric is formed.
The polymeric coating on the refractory impregnated 20base fabric acts to improve the surface abrasion characteristic and to seal in and contain any refractory material that may otherwise loosen or dust off during the wire and/or cable wrapping process. Wire and cable insulation tape is formed by slitting this coated and impregnated knit fabric to a desired-25tape width.
-~ The adhesive applied to the inside surface of the insulation tape serves to implement adhesion of the tape as it is wrapped around the conductor forming a bond that will prevent slippage of the insulation wrap when the wire or cable is cut 30or subjected to surface abrasion as during electrical installa-tions.
1~4948~
1 When the electrical and cable construction is subjected to a flame or the intense heat of a flame, the abrasion resistant polymeric coating on the surface of the insulation tape will decompose without flaming. Continued exposure to heat and/or flame causes the alumina and silica and other oxide components of the refractory cement coating -to fuse into the surface of the fiberglass base fabric (fiber-glass begins losing tensile strength at 800F. and softens at about 1350F.) forming a high temperature resistant fabric structure that behaves like a refractory, enabling the fiber-glass substrate fabric to withstand intense heat and elevated temperatures well beyond its normal melt temperature. (The aluminas, silicas, and other inorganic oxide components of the refractory cement have continuous use temperatures of 2300~.
15 with melting points in excess of 3300F.).
Only a smal-l portion of the overall refractory oxide residues are fused into the fiberglass fabric surface. The remaining oxide residues (i.e., A12O3, SiO2, CaO, ZrO2, etc.) aggregate on the surface and in the interstices 22 of the fiberglass substrate fabric forming a high temperature resist-ant composite fabric structure with excellent thermal reflectance and resistance to flame abrasion and thermal shock; and excellent insulating efficiency and dielectric strength. The refractory oxide residues further form a pro-tective coating for the metallic wire and/or cable conductorsproviding additional heat insulative protection and dielectric properties. In addition, the alumina, silica and other oxides ; aggregate in and fill the interstices of the base fiberglass fabric forming together with the fused fiberglass fabric 3O component, a highly efficient heat reflective surface.
It is thus seen that an improved flame resistant insulated electrical wire and/or cable construction has been 1~494~
1 provided which is relatively flexible with the ability to transmit electrical power without interruption while subjected to the heat of fire or the like.
3o
10 The thus assembled tape can be applied with the 50% overwrap -configuration in a fashion similar to that described above where ... . .
the adhesive is applied during the wrapping process. The flame-proof tape adhesive may be made up of a number of preferred formulations as follows:
,~.
3o 1149~81 Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 400.
NYACOL, Inc.
- Ashland, MA 01721 t 2. Binder - Organic Acrylic Latex Resin 50.
.-~ UCAR 189 (40% solids) Union Carbide Corp.
New York, NY
15 3. Thickening Agent.
Collacral VL 10.
- (Acrylate-vinylpyrrolidone .-copolymer, 50% solids in water) Ciba-Geigy Ardsley, NY
Total 460.
3o 1~9~8i Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Nitrile Latex-Type 1570 x 60 200.
(20% solids in water) B.F. Goodrich Chemical Co.
Cleveland, OH 44115 2. Aluminum ~ydrate 100.
Solem Industries, Inc.
Atlanta, GA 30341 3. Thickening Agent Collacral VL 20.
(Acrylate-vinylpyrrolidone copolymer, 50~ solids in water) Ciba-Geigy Ardsley, NY
Total 320.
~}
~149~
Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 40.
NYACOL, Inc.
Ashland, MA
2. Binder - Organic Acrylic Latex Resin 5. -` ~40% solids) Union Carbide Corp.
New York, NY
15 3, Thickening Agent Fumed Silica 2.5 Cab-O-Sil M-5 Cabot Corporation Boston, MA
Total47.5 , 3o 1 EXA~IPLE 10 Flameproof Tape Wrapping Adhesive Materials Parts By Weight As Is 1. Binder Colloidal Silica Dispersion 40.
Ludox HS-40 E.I. duPont deNemours ~ Co.
Wilmington, DE
2. Binder - Organic Acrylic Latex Resin 5.
.- HYCAR 2679 x 6 - B.F. Goodrich Chemical Co.
Cleveland, OH
15 3~ Thickening Agent Fumed Silica 2.5 Cab-O-Sil M-5 Cabot Corporation Boston, MA
Total47.5 .~
3o 4g~8~
l Operation In use, an insulated wire or cable is formed as above-described utilizing a refractory impregnated porous base fabric 26 to form insulating tape.
The impregnation coating of refractory material fills the interstices of the preferred base fabric comprising a knit fiberglass and is bonded to the surface of the fiberglass yarns forming a discontinuous film coating that allows the fiberglass yarn, as well as the coated fiberglass fabric to retain between lO 50% and 7~% of its original uncoated flex properties. Further, the soft acrylate resin that is the principal ingredient of the collacral thickening agent used in the refractory coating cement serves as an internal lubricant by coating and suspending the very fine alumina, silica, etc. particles that comprise the 15 refractory cement. The collacral thickening agent, upon drying, softens and modifies the otherwise very hard bonding character-istics of the refractory cement such that a more flexible bond to the fiberglass substrate fabric is formed.
The polymeric coating on the refractory impregnated 20base fabric acts to improve the surface abrasion characteristic and to seal in and contain any refractory material that may otherwise loosen or dust off during the wire and/or cable wrapping process. Wire and cable insulation tape is formed by slitting this coated and impregnated knit fabric to a desired-25tape width.
-~ The adhesive applied to the inside surface of the insulation tape serves to implement adhesion of the tape as it is wrapped around the conductor forming a bond that will prevent slippage of the insulation wrap when the wire or cable is cut 30or subjected to surface abrasion as during electrical installa-tions.
1~4948~
1 When the electrical and cable construction is subjected to a flame or the intense heat of a flame, the abrasion resistant polymeric coating on the surface of the insulation tape will decompose without flaming. Continued exposure to heat and/or flame causes the alumina and silica and other oxide components of the refractory cement coating -to fuse into the surface of the fiberglass base fabric (fiber-glass begins losing tensile strength at 800F. and softens at about 1350F.) forming a high temperature resistant fabric structure that behaves like a refractory, enabling the fiber-glass substrate fabric to withstand intense heat and elevated temperatures well beyond its normal melt temperature. (The aluminas, silicas, and other inorganic oxide components of the refractory cement have continuous use temperatures of 2300~.
15 with melting points in excess of 3300F.).
Only a smal-l portion of the overall refractory oxide residues are fused into the fiberglass fabric surface. The remaining oxide residues (i.e., A12O3, SiO2, CaO, ZrO2, etc.) aggregate on the surface and in the interstices 22 of the fiberglass substrate fabric forming a high temperature resist-ant composite fabric structure with excellent thermal reflectance and resistance to flame abrasion and thermal shock; and excellent insulating efficiency and dielectric strength. The refractory oxide residues further form a pro-tective coating for the metallic wire and/or cable conductorsproviding additional heat insulative protection and dielectric properties. In addition, the alumina, silica and other oxides ; aggregate in and fill the interstices of the base fiberglass fabric forming together with the fused fiberglass fabric 3O component, a highly efficient heat reflective surface.
It is thus seen that an improved flame resistant insulated electrical wire and/or cable construction has been 1~494~
1 provided which is relatively flexible with the ability to transmit electrical power without interruption while subjected to the heat of fire or the like.
3o
Claims (17)
1. A heat resistant, flexible, refractory, electrical insulating tape characterized by:
(a) a porous base fabric;
(b) a refractory coating comprising refractory materials and a bonding agent, said refractory coating formed on the surface and interstices of said fabric and said refractory materials being capable of fusing with the porous base fabric at elevated temperatures.
(a) a porous base fabric;
(b) a refractory coating comprising refractory materials and a bonding agent, said refractory coating formed on the surface and interstices of said fabric and said refractory materials being capable of fusing with the porous base fabric at elevated temperatures.
2. An insulating tape according to Claim 1 wherein the refractory coating is on both sides of the porous base fabric.
3. An insulating tape according to Claim 1 which includes a polymeric coating on the outside surfaces of at least one of the refractory coatings.
4. An insulating tape according to Claim 3 wherein the polymeric coating is on the outside surface of both of the refractory coatings,
5. An insulating tape according to Claim 1 or 2, which includes an adhesive on the surface-of the refractory coating,
6. An insulating tape according to Claim 2 or 3 wherein a polymeric coating is on the outside of one of the refractory coatings and an adhesive is on the outside surface of the other refractory coating.
7. An insulating tape according to Claim 4 wherein an adhesive is on the surface of one of the polymeric coatings.
8. An insulating tape according to any of Claims 1 to 3 wherein the porous base fabric is a knitted fiber-glass, a woven fiberglass or a non-woven, porous web of fiberglass.
9. An insulating tape according to Claim 1 wherein the refractory materials are alumina, zirconia, calcium silicate, silicon dioxide or mixtures thereof.
10. An insulating tape according to Claim 9 wherein the bonding agent is acrylic latex resin or acrylic latex resin and colloidal silica.
11. An insulating tape according to any of Claims 1 to 3 wherein the bonding agent contains a thickening agent.
12. An insulating tape according to any of Claims 3, 4 or 10 wherein the polymeric coating contains polyvinyl chloride.
13. An insulating tape as described in any of Claims 1 to 3 wrapped around an electrical conductor to provide a high temperature and flame resistant-insulator wire or cable construction.
14. A method of forming a flame and heat resis-tant insulated electrical conductor, said method charac-terized by the steps of;
applying a refractory coating to a porous base fabric;
applying an adhesive coating to the refractory coated base fabric; and wrapping the adhesive coated refractory coated base fabric about an electrical conductor.
applying a refractory coating to a porous base fabric;
applying an adhesive coating to the refractory coated base fabric; and wrapping the adhesive coated refractory coated base fabric about an electrical conductor.
15. A method of forming a flame and heat resis-tant insulated electrical conductor according to Claim 14 in which the refractory coating comprises refractory materials and a bonding agent.
16. A method according to Claim 14 or 15 in which a polymeric coating is applied to the refractory coating before applying the adhesive.
17. A method according to Claim 15 in which said base fabric is cut into strips before application of the adhesive and before wrapping about the conductor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000350751A CA1149481A (en) | 1980-04-28 | 1980-04-28 | Flame resistant insulated electrical wire and cable construction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000350751A CA1149481A (en) | 1980-04-28 | 1980-04-28 | Flame resistant insulated electrical wire and cable construction |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1149481A true CA1149481A (en) | 1983-07-05 |
Family
ID=4116795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000350751A Expired CA1149481A (en) | 1980-04-28 | 1980-04-28 | Flame resistant insulated electrical wire and cable construction |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1149481A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107293371A (en) * | 2017-06-30 | 2017-10-24 | 重庆渝丰鑫新线缆科技有限公司 | A kind of construction Special safety type service cable and preparation method thereof |
-
1980
- 1980-04-28 CA CA000350751A patent/CA1149481A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107293371A (en) * | 2017-06-30 | 2017-10-24 | 重庆渝丰鑫新线缆科技有限公司 | A kind of construction Special safety type service cable and preparation method thereof |
| CN107293371B (en) * | 2017-06-30 | 2023-07-07 | 渝丰科技股份有限公司 | Special safe power supply cable for building construction and preparation method thereof |
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