KR850006436A - Fire Retardant Cross-linking Compound And Fire Retardant Cable Using It - Google Patents

Fire Retardant Cross-linking Compound And Fire Retardant Cable Using It Download PDF

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KR850006436A
KR850006436A KR1019850001454A KR850001454A KR850006436A KR 850006436 A KR850006436 A KR 850006436A KR 1019850001454 A KR1019850001454 A KR 1019850001454A KR 850001454 A KR850001454 A KR 850001454A KR 850006436 A KR850006436 A KR 850006436A
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tape
polyolefin resin
flame retardant
silane
weight
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KR930006208B1 (en
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마사다께 하세가와
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가가야 세이이찌
후지구타 덴센 가부시기가이샤
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Priority claimed from JP59170778A external-priority patent/JPS6149310A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
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    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment

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  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Insulated Conductors (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음No content

Description

방화염 교차연결 화합물과 그것을 사용하는 방화염 케이블Fire Retardant Cross-linking Compound And Fire Retardant Cable Using It

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도는 방화염 케이블의 횡단면도.1 is a cross-sectional view of a flame retardant cable.

*도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

(11)…도체, (13)…전기절연, (15)…서브코어, (17)…휠터, (19)…탄화 테이프층, (21)…화염 베리어층, (23)…화염 베리어층, (27)…베리어 보호층, (29)…외장(11)... Conductor, (13). Electrical insulation, (15). Subcore, 17... (19). Carbonized tape layer 21. Flame barrier layer, (23). Flame barrier layer, 27... Barrier protective layer, (29). sheath

Claims (19)

폴리올레핀수지의 제1화합물과 제2화합물을 구성한 실란이 결합된 폴리올레핀을 가한 금속수화물, 이에 어느 할로겐이 유리되어 있는 수지를 혼합한 것과 실란이 교차결합된 제2화합물과 그리고 여기서 금속수화물은 폴리올레핀수지와 실란이 결합된 폴리올레핀수지를 중량에 의하여 각 100부식의 무거로서 약 200부가 되도록 약 50의 량으로 혼합하고 또한 폴리올레핀수지는 "X"가 실란이 결합된 폴리올레핀수지의 무게로서 20≤X≤80부의 량이고 이를 무게로서 약 "100-x"의 량으로 혼합한 것을 특징으로하는 방화염교차결합 화합물.The metal hydrate to which the polyolefin which combined the silane which comprises the 1st compound of the polyolefin resin and the silane which comprised the 2nd compound, the resin which any halogen is liberated, the 2nd compound which crosslinked silane, and a metal hydrate are polyolefin resin And silane-bonded polyolefin resin by weight to about 200 parts by weight of each 100-corrosion by weight, and the polyolefin resin is "X" is the weight of the polyolefin resin bonded silane 20≤X≤80 A flame retardant crosslinking compound, characterized in that the amount is negative and mixed in an amount of about "100-x" by weight. 제1항에 있어서, 방화염 교차결합된 합성물에 있어서 제1화합물은 폴리올레핀수지와 실란이 결합된 폴리올레핀 수지를 각기 무게로서 100부식에 탄소분을 무게로소 약 5내지 70부를 포함하는 것을 특징으로 하는 방화염 교차연결 화합물.The method according to claim 1, wherein the first compound in the flame retardant crosslinked composite comprises about 5 to 70 parts by weight of 100 parts by weight of carbon powder and 100 parts by weight of polyolefin resin in which polyolefin resin and silane are combined. Fire Flame Crosslinking Compound. 제2항에 있어서, 제1화합물이 폴리올레핀수지와 실란이 결합된 폴리올레핀 수지를 각기 무게로서 100부에 적색인을 무게로서 약 2부 내지 50부를 포함하는 것을 특징으로하는 방화염 교차연결 화합물3. The flame retardant crosslinking compound according to claim 2, wherein the first compound comprises about 2 parts to 50 parts by weight of the polyolefin resin in which the polyolefin resin and the silane are bonded to 100 parts by weight of red, respectively. 제1,2항 혹은 제3항에 있어서, 폴리올레핀수지가 폴이에틸렌, 에틸렌-알파-올레핀 중합체, 에틸렌-프로필렌 중합체, 에틸렌-비닐 아세테이트 중합체, 에틸렌프로필렌 diene탄성중합체, 에틸렌-메틸크릴레이트 중합체, 폴리메틸 아크릴레이트, 폴리에틸아크릴레이트, 폴리메타아크릴레이트, 에틸렌 아크릴의 탄성중합체, 수소와테렌-부타딘 고무와 그혼합물로 구성된 구룹(group)으로부터 선택된 수지인 것을 특징으로 하는 방화염 교차연결 화합물.The polyolefin resin according to claim 1, 2 or 3, wherein the polyolefin resin is polyethylene, ethylene-alpha-olefin polymer, ethylene-propylene polymer, ethylene-vinyl acetate polymer, ethylene propylene diene elastomer, ethylene-methyl acrylate polymer, Flame retardant crosslinking compound, characterized in that the resin is selected from a group consisting of polymethyl acrylate, polyethyl acrylate, polymethacrylate, elastomer of ethylene acryl, hydrogen and terene-butadiene rubber and mixtures thereof . 제4항에 있어서, 금속성 수산화물은 알루미늄 산화물, 마그네슘 산화물, 칼슘 산화물과 기본 마그네슘 카아보네이티드로 구성되는 구룹으로부터 선택된 재료인 것을 특징으로하는 방화염 교차연결 화합물.5. The flame retardant crosslinking compound according to claim 4, wherein the metallic hydroxide is a material selected from a group consisting of aluminum oxide, magnesium oxide, calcium oxide and basic magnesium carbonate. 제5항에 있어서, 금속성 수산화물이 지방산, 인을 포함한 에스테르, 실란 커플링 작용물과 티탄산염커플링 작용물의 하나로 처리된 표면인 것을 특징으로 하는 방화염 교차연결 화합물.6. The flame retardant crosslinking compound according to claim 5, wherein the metallic hydroxide is a surface treated with one of a fatty acid, an ester comprising phosphorus, a silane coupling agent and a titanate coupling agent. 어떤 할로겐으로부터 자유로운 재료로 만들어진 전기 절연으로 덮힌 도체를 지니는 하나의 서브코어혹은 하나 이상의 서브코어를 함께 감은 코어, 코어에 대해 만들어지고 생성된 방화염 교차연결 화합물로 만들어진 의장으로 구성되며 어떤 할로겐으로부터 자유로운 수지인 폴리올레핀수지와 금속성 수산화물의 제1화합물이 제2화합물을 만들기 위해 섞이며 방화염 교차연결 화합물을 형성하기 위한 실란 교차연결제2화합물로 구성되며 여기서 금속성 수산화물이 폴리올레핀수지와 실란-결합 폴리올레핀수지의 중량 100부당중량 약 50부 내지 200부의 양으로 혼합되고 폴리올레핀수지는 중량 약 (100-x)부의 양으로 혼합되며 여기서 x는 실란-결합폴리올레핀 수지의 양이며 중량에 의해 20≤X≤ 약 80인 것을 특징으로 하는 방화염 케이블.One subcore with a conductor covered by an electrical insulation made of a material free of any halogen, or a core wound together with one or more subcores, consisting of a design made of a flame-retardant crosslinking compound made and produced for the core, free of any halogen The first compound of the polyolefin resin, which is a resin, and the metal hydroxide, is mixed to form the second compound, and is composed of a silane crosslinking second compound for forming a flame retardant crosslinking compound, wherein the metal hydroxide is composed of a polyolefin resin and a silane-linked polyolefin resin. And the polyolefin resin is mixed in an amount of about (100-x) parts by weight, where x is an amount of silane-linked polyolefin resin and is 20≤X≤ about 80 parts by weight. Flame-proof cable characterized in that the. 제7항에 있어서, 폴리올레핀 수지와 실란-결합 폴리올레핀 수지 중량 100부당 카오본 파우더 약 5부 내지 70부를 포함하는 제1화합물을 포함하는 것을 특징으로 하는 방화염 케이블.The flame retardant cable according to claim 7, comprising a first compound comprising from about 5 parts to about 70 parts of carbon powder per 100 parts by weight of the polyolefin resin and the silane-linked polyolefin resin. 제8항에 있어서, 제1화합물은 폴리올레핀수지와 실란-결합폴리올레핀 수지의 중량 100부당 중량 약 2부 내지 50부의 양으로 적색인을 지니는 적색인 방화염을 포함하는 특징으로 하는 방화염 케이블.The flame retardant cable according to claim 8, wherein the first compound comprises a red flame retardant having red phosphorus in an amount of about 2 to 50 parts by weight per 100 parts by weight of the polyolefin resin and the silane-linked polyolefin resin. 제7항, 8항 또는 6항에 있어서, 오버랩방식으로 코오주위에 감겨진 한 피이스이 비가연설 테이프로 형성되는 베리어층이 코어와 의장사이에치 위하는 것을 특징으로하는 방화염 케이블.The flame retardant cable according to claim 7, 8 or 6, wherein a barrier layer in which one piece of the piece wound around the nose in an overlapping manner is formed of a non-slip tape is placed between the core and the design. 제10항에 있어서, 화염 베리어층은 산소지수가 35 혹은 2 이상인 유기 재료로 만들어진 방화염 테이프로 형성되는 것을 특징으로 하는 방화염 케이블.11. The flame retardant cable according to claim 10, wherein the flame barrier layer is formed of a flame retardant tape made of an organic material having an oxygen index of 35 or 2 or more. 제10항에 있어서, 비가연성 테이프는 큰 부분의 세라믹을 포함하며 금속성 테이프와 비유기적 테이프의 두층 합성을 포함하는 비유기적 테이프와 금속성 테이프의 하나인 것을 특징으로 하는 방화염 케이블.11. The flame retardant cable of claim 10 wherein the non-combustible tape is one of an inorganic tape and a metallic tape comprising a large portion of ceramic and comprising a two-layered composite of metallic tape and organic tape. 제12항에 있어서, 비유기적 테이프는 마이카 폴리에스터 라메네이티이드, 테이프, 마이카 폴리에스터라미네이티이드 테이프, 마이카 유리테이프, 마이카-페이퍼 합성 테이프, 마이카, 페이퍼 라미네이트이드 테이프, 아스베스토테이프, 실란-적용 유리테이프, 알킬화수지니스-적용 유리테이프, 알루미나용융-방적테이프, 실리카 용융-방적테이프, 알루미나 용융-방적 화이터와 유리 화이버의 합성테이프, 실리카용융-방적 화이버와 유리 화이버의 두층 합성테이프, 알루미나-유리 라메네이티이드 테이프의 하나로된 것을 특징으로 하는 방화염 케이블.13. The organic tape of claim 12, wherein the inorganic tape is a mica polyester laminate, a tape, a mica polyester laminate tape, a mica glass tape, a mica-paper synthetic tape, a mica, a paper laminate tape, an asbestos tape, Silane-applied glass tape, alkylated resin-applied glass tape, alumina melt-spun tape, silica melt-spun tape, synthetic tape of alumina melt-spun fiber and glass fiber, double layer synthetic tape of silica melt-spun fiber and glass fiber Flame retardant cable, characterized in that one of the alumina-glass laminating tape. 제10항에 있어서, 케이블이 고온에서 영향을 받기쉬울때 코어 주위에 탄화하기 쉬운 테이프를 감음으로써 형성되는 탄화 테이프층이 코어와 화염 베리어층 사이에 위치하는 것을 특징으로 하는 방화염 케이블.11. The flame retardant cable of claim 10 wherein a carbonized tape layer formed between the core and the flame barrier layer is formed by winding a tape that is liable to carbonize around the core when the cable is susceptible to high temperatures. 제14항에 있어서, 탄화테이프는 크레프트 페이퍼, 아크릴릭화이버천, 레이온, 천, 천연 셀롤로즈 화이버와 실리콘 니스 또는 알킬화수지류 니스로 함유된 이러한 재료들로부터 선택된 재료로 만들어지는 것을 특징으로하는 방화염 케이블.15. The flame retardant according to claim 14, wherein the carbonized tape is made of a material selected from these materials contained in kraft paper, acrylic fiber cloth, rayon, cloth, natural cellulose fiber and silicone varnish or alkylated resin varnish. cable. 제14항에 있어서, 아스베스토, 유리 혹은 세라막화이버로 만들어진 적어도 원피스의 테이프를 감음으로써 형성된 베리어보호층을 기계적으로 열적으로 보호하기 위해 화염베리어층과 의장사이에 위치한 베리어 보호층으로 구성되는 것을 특징으로하는 방화염 케이블.15. The barrier protection layer according to claim 14, comprising a barrier protection layer positioned between the flame barrier layer and the chair for mechanically and thermally protecting the barrier protection layer formed by winding at least one piece of tape made of asbestos, glass, or ceramic film. Featuring flame retardant cable. 제10항에 있어서, 베티어 보호층이 아스베이스, 유리 또는 세라믹 화이버로 만들어진 적어도 원피스의 테이프를 감음으로써 형성되는 베리어보호층이 기계적으로 열적으로 화염베리어층을 보호하기 위해 화염 베리어층과 외장사이에 위치하는 것을 특징으로 하는 방화염 케이블.11. The barrier protection layer of claim 10, wherein the barrier protection layer formed by winding at least one piece of tape made of asbase, glass, or ceramic fibers is mechanically and thermally protected between the flame barrier layer and the sheath. Flame-retardant cable, characterized in that located on. 제7항, 8항 또는 9항에 있어서, 금속성 수산화물은 알루미늄 산화물, 마그네슘 산화물, 칼슘 산화물과 시본 마그네슘 카아보네이트로부터 선택된 재료인 것을 특징으로 하는 방화염케이블.10. The flame retardant cable according to claim 7, 8, or 9, wherein the metallic hydroxide is a material selected from aluminum oxide, magnesium oxide, calcium oxide and carbon magnesium carbonate. 제18항에 있어서, 금속성 수산화물은 지방산, 인을 포함하는 에스테르, 실란커플링 작용물과 티탄산염 커플링 작용물의 하나로 처리된 표면인 것을 특징으로하는 방화염 케이블.19. The flame retardant cable of claim 18, wherein the metallic hydroxide is a surface treated with one of a fatty acid, an ester comprising phosphorus, a silane coupling agent and a titanate coupling agent. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019850001454A 1984-03-07 1985-03-07 Flame-retardant cross-linked composition and flame-retardant cable using same KR930006208B1 (en)

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JP43138 1984-03-07
JP59-43138 1984-03-07
JP59043138A JPS60189114A (en) 1984-03-07 1984-03-07 Flame resistant cable
JP170778 1984-08-16
JP59170778A JPS6149310A (en) 1984-08-16 1984-08-16 Flame resistant cable

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