CA1133177A - Adhesive composition and process for bonding - Google Patents
Adhesive composition and process for bondingInfo
- Publication number
- CA1133177A CA1133177A CA309,188A CA309188A CA1133177A CA 1133177 A CA1133177 A CA 1133177A CA 309188 A CA309188 A CA 309188A CA 1133177 A CA1133177 A CA 1133177A
- Authority
- CA
- Canada
- Prior art keywords
- adhesive composition
- composition according
- rosin
- vinyl ester
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 59
- 239000000853 adhesive Substances 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 21
- 229920001567 vinyl ester resin Polymers 0.000 claims abstract description 52
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 38
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 38
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 38
- -1 polyethylene Polymers 0.000 claims abstract description 27
- 239000004698 Polyethylene Substances 0.000 claims abstract description 22
- 229920000573 polyethylene Polymers 0.000 claims abstract description 22
- 229920003023 plastic Polymers 0.000 claims abstract description 21
- 239000004033 plastic Substances 0.000 claims abstract description 21
- 235000007586 terpenes Nutrition 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 15
- 150000003505 terpenes Chemical class 0.000 claims abstract description 15
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 12
- 239000005011 phenolic resin Substances 0.000 claims abstract description 11
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims description 15
- 239000000155 melt Substances 0.000 claims description 6
- 230000035515 penetration Effects 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims description 2
- 229930006722 beta-pinene Natural products 0.000 claims description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 2
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 150000003097 polyterpenes Chemical class 0.000 claims description 2
- 239000003784 tall oil Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 claims 2
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 claims 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims 1
- 239000007859 condensation product Substances 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 9
- 239000001993 wax Substances 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004831 Hot glue Substances 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000011417 postcuring Methods 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229930003642 bicyclic monoterpene Natural products 0.000 description 1
- 150000001604 bicyclic monoterpene derivatives Chemical class 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Chemical class O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004616 structural foam Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J191/00—Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
- C09J191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US848,286 | 1977-11-03 | ||
| US05/848,286 US4167433A (en) | 1977-11-03 | 1977-11-03 | Adhesive composition and process for bonding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1133177A true CA1133177A (en) | 1982-10-05 |
Family
ID=25302887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA309,188A Expired CA1133177A (en) | 1977-11-03 | 1978-08-11 | Adhesive composition and process for bonding |
Country Status (10)
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4500661A (en) * | 1977-11-03 | 1985-02-19 | Gulf Oil Corporation | Adhesive composition |
| US4247428A (en) * | 1979-08-16 | 1981-01-27 | The Goodyear Tire & Rubber Company | Adhesive for polyesters and polyolefins |
| US4248748A (en) * | 1980-02-04 | 1981-02-03 | Minnesota Mining And Manufacturing Company | Heat-activated adhesive |
| US4293473A (en) * | 1980-07-25 | 1981-10-06 | E. I. Du Pont De Nemours And Company | Polyvinyl alcohol - crystalline solvent system based compositions modified with ethylene polymer |
| CA1167992A (en) * | 1980-08-11 | 1984-05-22 | Timothy T. Schenck | Filled thermoplastic compositions based on mixtures of ethylene interpolymers |
| US4581392A (en) * | 1984-05-24 | 1986-04-08 | Owens-Corning Fiberglas Corporation | Hot melt glass fiber coating |
| US4567102A (en) * | 1984-05-24 | 1986-01-28 | Owens-Corning Fiberglas Corporation | Hot melt size |
| GB2162191B (en) * | 1984-07-27 | 1987-07-08 | Eschem Ltd | Alkene-vinyl acetate copolymer adhesives |
| US4772650A (en) * | 1985-04-12 | 1988-09-20 | Minnesota Mining And Manufacturing Co. | Polymeric coating for container induction innerseal |
| US4874804A (en) * | 1987-06-19 | 1989-10-17 | National Starch And Chemical Corporation | Hot melt adhesives based on ethylene-n-butyl acrylate |
| US4816306A (en) * | 1987-06-19 | 1989-03-28 | National Starch And Chemical Corporation | Hot melt adhesives based on ethylene-n-butyl acrylate |
| US5310803A (en) * | 1988-05-04 | 1994-05-10 | Minnesota Mining And Manufacturing Company | Hot-melt composition that have good open time and form creep-resistant bonds when applied in thin layers |
| US5635261A (en) * | 1989-10-10 | 1997-06-03 | Viskase Corporation | Thermoplastic film incorporating high melt index resins |
| US5034216A (en) * | 1990-01-24 | 1991-07-23 | Revlon, Inc. | Anhydrous cosmetic product containing a particular gel phase |
| US5183841A (en) * | 1991-12-24 | 1993-02-02 | Avery Dennison Corporation | Removable pressure-sensitive adhesives for recyclable substrates |
| JPH062746U (ja) * | 1992-06-10 | 1994-01-14 | アルプス電気株式会社 | 多層印刷配線基板 |
| US5401791A (en) * | 1992-12-03 | 1995-03-28 | Exxon Chemical Patents Inc. | Bookbinding adhesives; processes for production of bookbinding adhesives; and methods of bookbinding |
| US5331033A (en) * | 1993-02-23 | 1994-07-19 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesive |
| US5670566A (en) * | 1995-01-06 | 1997-09-23 | National Starch And Chemical Investment Holding Corporation | Cool-applied hot melt adhesive composition |
| US5500472A (en) * | 1995-02-17 | 1996-03-19 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| US7019060B1 (en) * | 1999-11-12 | 2006-03-28 | National Starch And Chemical Investment Holding Corporation | Low application temperature hot melt adhesive |
| US7013818B2 (en) | 2001-10-18 | 2006-03-21 | Guangdong Esquel Textiles Co. Ltd. | Wrinkle free garment and method of manufacture |
| US6765054B1 (en) * | 2002-04-24 | 2004-07-20 | H. B. Fuller Licensing & Financing Inc. | Ethylene-vinyl acetate hot melt adhesive composition and article and method incorporating the same |
| US20040045666A1 (en) * | 2002-09-06 | 2004-03-11 | Lie-Zhong Gong | Hot melt adhesive and use thereof |
| US20050031878A1 (en) * | 2003-08-04 | 2005-02-10 | Vasanthakumar Narayanan | Adhesion promoter concentrates |
| US7892391B2 (en) * | 2004-01-29 | 2011-02-22 | E. I. Du Pont De Nemours And Company | Compositions of ethylene/vinyl acetate copolymers for heat-sealable easy opening packaging |
| US20070209757A1 (en) * | 2006-03-10 | 2007-09-13 | Hengel James F | Method for attaching tubes using an adhesive |
| KR101605906B1 (ko) * | 2006-12-07 | 2016-03-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 블록 공중합체와 아크릴 접착제의 블렌드 |
| JP5396584B1 (ja) * | 2012-10-03 | 2014-01-22 | 東洋インキＳｃホールディングス株式会社 | ホットメルト型接着剤、紙ラベル及び紙ラベル付きプラスティック容器 |
| AT518537B1 (de) * | 2016-06-09 | 2017-11-15 | Avl List Gmbh | Brennkraftmaschine |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD83829A (US06174465-20010116-C00003.png) * | ||||
| US3175986A (en) * | 1963-04-01 | 1965-03-30 | Atlantic Refining Co | Carton board coating composition |
| US3448178A (en) * | 1967-09-22 | 1969-06-03 | Nat Starch Chem Corp | Hot melt adhesives comprising ethylene/vinyl acetate copolymers and alpha-pinene/phenol condensation products |
| US3626026A (en) * | 1968-08-01 | 1971-12-07 | Hitachi Ltd | Hotmelt adhesive compositions |
| US3615106A (en) * | 1969-04-04 | 1971-10-26 | Nat Starch Chem Corp | Manufacture of hard covered books |
| US3654207A (en) * | 1970-07-22 | 1972-04-04 | Shell Oil Co | Block-resistant heat sealable wax composition |
| US3704157A (en) * | 1970-11-23 | 1972-11-28 | Du Pont | Coated article and method of making same |
| US3734798A (en) * | 1970-12-21 | 1973-05-22 | Borden Inc | Hot melt package coating method |
| JPS4869839A (US06174465-20010116-C00003.png) * | 1971-12-25 | 1973-09-21 | ||
| JPS5729501B2 (US06174465-20010116-C00003.png) * | 1972-02-02 | 1982-06-23 | ||
| JPS5133596B2 (US06174465-20010116-C00003.png) * | 1972-02-26 | 1976-09-20 | ||
| JPS48103636A (US06174465-20010116-C00003.png) * | 1972-04-14 | 1973-12-26 | ||
| JPS508847A (US06174465-20010116-C00003.png) * | 1973-05-26 | 1975-01-29 | ||
| AR204760A1 (es) * | 1974-05-29 | 1976-02-27 | Schlegel Engineering | Procedimiento para la soldadura continua por solapamiento de laminas o placas de termoplastico y dispositivo para ilevarlo a cabo |
-
1977
- 1977-11-03 US US05/848,286 patent/US4167433A/en not_active Expired - Lifetime
-
1978
- 1978-08-04 EP EP78300289A patent/EP0001878B1/en not_active Expired
- 1978-08-04 DE DE7878300289T patent/DE2861082D1/de not_active Expired
- 1978-08-11 CA CA309,188A patent/CA1133177A/en not_active Expired
- 1978-08-18 AU AU39051/78A patent/AU3905178A/en active Pending
- 1978-10-02 FI FI782990A patent/FI782990A/fi unknown
- 1978-10-19 NO NO783547A patent/NO783547L/no unknown
- 1978-11-01 JP JP13383978A patent/JPS5472239A/ja active Granted
- 1978-11-02 IT IT29367/78A patent/IT1101286B/it active
- 1978-11-02 DK DK489878A patent/DK489878A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2861082D1 (en) | 1981-12-03 |
| JPS5472239A (en) | 1979-06-09 |
| IT1101286B (it) | 1985-09-28 |
| DK489878A (da) | 1979-05-04 |
| EP0001878A2 (en) | 1979-05-16 |
| AU3905178A (en) | 1980-02-21 |
| FI782990A (fi) | 1979-05-04 |
| NO783547L (no) | 1979-05-04 |
| JPS6247223B2 (US06174465-20010116-C00003.png) | 1987-10-07 |
| EP0001878B1 (en) | 1981-09-16 |
| IT7829367A0 (it) | 1978-11-02 |
| US4167433A (en) | 1979-09-11 |
| EP0001878A3 (en) | 1979-05-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |