CA1125731A - Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition therefor - Google Patents
Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition thereforInfo
- Publication number
- CA1125731A CA1125731A CA294,517A CA294517A CA1125731A CA 1125731 A CA1125731 A CA 1125731A CA 294517 A CA294517 A CA 294517A CA 1125731 A CA1125731 A CA 1125731A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- catalyst
- copper
- bismuth
- hydrogen sulphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 40
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 46
- 239000002912 waste gas Substances 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 title claims description 9
- 230000003197 catalytic effect Effects 0.000 title description 7
- 239000010949 copper Substances 0.000 claims abstract description 34
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 29
- 229910052802 copper Inorganic materials 0.000 claims abstract description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 19
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 29
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000012876 carrier material Substances 0.000 claims description 5
- 229960003903 oxygen Drugs 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- 239000005864 Sulphur Substances 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 description 20
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 239000000969 carrier Substances 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 101100379067 Caenorhabditis elegans anc-1 gene Proteins 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- -1 niekel Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000010269 sulphur dioxide Nutrition 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/843—Arsenic, antimony or bismuth
- B01J23/8437—Bismuth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biomedical Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Incineration Of Waste (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75753177A | 1977-01-07 | 1977-01-07 | |
| US757,531 | 1977-01-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1125731A true CA1125731A (en) | 1982-06-15 |
Family
ID=25048172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA294,517A Expired CA1125731A (en) | 1977-01-07 | 1978-01-06 | Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition therefor |
Country Status (13)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3280104D1 (de) * | 1982-02-02 | 1990-03-15 | Union Oil Co | Katalysator und verfahren zum oxydieren von schwefelwasserstoff. |
| FR2631854A1 (fr) * | 1988-05-26 | 1989-12-01 | Norsolor Sa | Procede de purification catalytique d'un effluent aqueux |
| JP2000515807A (ja) * | 1996-07-26 | 2000-11-28 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 触媒組成物、その調製、及び接触灰化におけるその使用 |
| EP0914193B1 (en) * | 1996-07-26 | 2001-07-04 | Shell Internationale Researchmaatschappij B.V. | Catalytic incineration process and catalyst composition useful therefor |
| JP3847712B2 (ja) | 2000-10-18 | 2006-11-22 | 日揮株式会社 | 硫化水素、メルカプタン、炭酸ガス、芳香族炭化水素を含むガス中の硫黄化合物の除去方法およびその装置 |
| IT1403545B1 (it) * | 2011-02-02 | 2013-10-31 | Eonsudenergia Srl | Catalizzatore per la termolisi di rifiuti |
| EP3799854A1 (en) | 2019-10-01 | 2021-04-07 | Stefan Johannes Fellner | Extract of organic humified materials |
| CN113117517B (zh) * | 2019-12-31 | 2022-10-11 | 中国石油化工股份有限公司 | 一种高浓度含硫有机废气的处理方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1900751A (en) * | 1928-02-27 | 1933-03-07 | Ig Farbenindustrie Ag | Purification of gases |
| GB319396A (en) * | 1928-06-20 | 1929-09-20 | Ig Farbenindustrie Ag | Improvements relating to the purification of gas containing sulphuretted hydrogen |
| FR1070681A (fr) * | 1953-02-06 | 1954-08-05 | Bataafsche Petroleum | Procédé de préparation du soufre à partir de l'hydrogène sulfuré |
-
1977
- 1977-12-08 DE DE2754762A patent/DE2754762C2/de not_active Expired
- 1977-12-29 BE BE1008616A patent/BE862443A/xx not_active IP Right Cessation
-
1978
- 1978-01-05 JP JP5678A patent/JPS5377873A/ja active Granted
- 1978-01-05 FR FR7800205A patent/FR2376686A1/fr active Granted
- 1978-01-05 RO RO7892830A patent/RO76367A/ro unknown
- 1978-01-05 BR BR7800064A patent/BR7800064A/pt unknown
- 1978-01-05 ZA ZA00780050A patent/ZA7850B/xx unknown
- 1978-01-05 NL NLAANVRAGE7800126,A patent/NL190357C/xx not_active IP Right Cessation
- 1978-01-05 AR AR270636A patent/AR212728A1/es active
- 1978-01-05 GB GB368/78A patent/GB1558656A/en not_active Expired
- 1978-01-05 AU AU32198/78A patent/AU510872B2/en not_active Expired
- 1978-01-06 CA CA294,517A patent/CA1125731A/en not_active Expired
-
1981
- 1981-12-30 MY MY349/81A patent/MY8100349A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7800126A (nl) | 1978-07-11 |
| MY8100349A (en) | 1981-12-31 |
| AU510872B2 (en) | 1980-07-17 |
| NL190357C (nl) | 1994-02-01 |
| AU3219878A (en) | 1979-07-12 |
| JPS6120342B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-05-21 |
| JPS5377873A (en) | 1978-07-10 |
| NL190357B (nl) | 1993-09-01 |
| FR2376686A1 (fr) | 1978-08-04 |
| DE2754762A1 (de) | 1978-07-13 |
| FR2376686B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-05-07 |
| BE862443A (nl) | 1978-06-29 |
| GB1558656A (en) | 1980-01-09 |
| ZA7850B (en) | 1978-12-27 |
| BR7800064A (pt) | 1979-01-02 |
| RO76367A (ro) | 1981-11-04 |
| DE2754762C2 (de) | 1987-02-05 |
| AR212728A1 (es) | 1978-09-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3859416A (en) | Scrubbing a gas stream containing so' ' and o' ' with an absorbent containing a reducing agent | |
| US4346063A (en) | Desulfurization of hot gas with cerium oxide | |
| EP0078690B2 (en) | Process for the reduction of the sulfur content in a gaseous stream | |
| EP0242006B1 (en) | A process for recovering sulfur from sulfur-containing gases | |
| US4382912A (en) | Selective combusting of hydrogen sulfide in carbon dioxide injection gas | |
| US5384301A (en) | Catalyst for elemental sulfur recovery process | |
| CA1300117C (en) | Catalyst for the selective oxidation of sulfur containing compounds | |
| US4001375A (en) | Process for the desulfurization of flue gas | |
| US4012486A (en) | Process for reducing the total sulfur content of Claus off-gases | |
| US5700440A (en) | Selective oxidation of hydrogen sulfide in the presence of iron-based catalysts | |
| EA001069B1 (ru) | Катализатор для селективного окисления соединений серы до элементарной серы, способ получения такого катализатора и способ селективного окисления соединений серы до элементарной серы | |
| CA1232429A (en) | Process for the oxidation of hydrogen sulphide to elemental sulphur and/or sulphur dioxide | |
| CA1125731A (en) | Process for the catalytic incineration of hydrogen sulphide-containing waste gases and a catalyst composition therefor | |
| AU737471B2 (en) | Process for treating hydrogen sulfide lean streams with partial combustion of feed stream | |
| US5653953A (en) | Process for recovering elemental sulfur by selective oxidation of hydrogen sulfide | |
| JP2930409B2 (ja) | 硫化物含有ガスの精製法 | |
| CA2237744A1 (en) | Catalyst and process for oxidation of sulphur dioxide | |
| EP0218302A2 (de) | Verfahren zum Reinigen von Schwefelwasserstoff und Schwefeldioxid enthaltendem Abgas | |
| US4735788A (en) | Process of removing of COS and CS2 compounds contained in an industrial gas | |
| US3728433A (en) | Continuous process for scrubbing sulfur dioxide from a gas stream | |
| EP0669854B1 (en) | Process for removing sulphur dioxide from a sulphur dioxide-containing gas stream | |
| JPH06228573A (ja) | 石炭ガス化プラントのテールガス処理法 | |
| EP0636107B1 (en) | Process and use of an apparatus for recovering sulphur from a gas stream containing hydrogen sulphide | |
| US5958359A (en) | Process for treating H2 S-lean streams, with recycle of SOx from burner | |
| US3764653A (en) | Continuous process for scrubbing so{11 {11 from a gas stream with h{11 {11 regeneration |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |