CA1110039A - Reduction of ferric chloride - Google Patents
Reduction of ferric chlorideInfo
- Publication number
- CA1110039A CA1110039A CA327,370A CA327370A CA1110039A CA 1110039 A CA1110039 A CA 1110039A CA 327370 A CA327370 A CA 327370A CA 1110039 A CA1110039 A CA 1110039A
- Authority
- CA
- Canada
- Prior art keywords
- chloride
- sulphur
- product
- gaseous
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910021578 Iron(III) chloride Inorganic materials 0.000 title claims abstract description 36
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 54
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000005864 Sulphur Substances 0.000 claims abstract description 43
- 239000000460 chlorine Substances 0.000 claims abstract description 36
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 33
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 32
- FWMUJAIKEJWSSY-UHFFFAOYSA-N sulfur dichloride Chemical compound ClSCl FWMUJAIKEJWSSY-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 18
- 229960002089 ferrous chloride Drugs 0.000 claims abstract description 16
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims abstract description 16
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims abstract description 9
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 8
- 239000007789 gas Substances 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 9
- 238000004508 fractional distillation Methods 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 238000006722 reduction reaction Methods 0.000 claims description 7
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 238000005660 chlorination reaction Methods 0.000 abstract description 10
- 238000011084 recovery Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 11
- 238000004821 distillation Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000006298 dechlorination reaction Methods 0.000 description 4
- XDLNRRRJZOJTRW-UHFFFAOYSA-N thiohypochlorous acid Chemical compound ClS XDLNRRRJZOJTRW-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000861718 Chloris <Aves> Species 0.000 description 1
- 101000742346 Crotalus durissus collilineatus Zinc metalloproteinase/disintegrin Proteins 0.000 description 1
- 101000872559 Hediste diversicolor Hemerythrin Proteins 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229910018105 SCl2 Inorganic materials 0.000 description 1
- 101001135436 Urodacus yaschenkoi Antimicrobial peptide scorpine-like-2 Proteins 0.000 description 1
- HYJODZUSLXOFNC-UHFFFAOYSA-N [S].[Cl] Chemical compound [S].[Cl] HYJODZUSLXOFNC-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- -1 ilmenite Chemical compound 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- FNKUJDADVODZOY-UHFFFAOYSA-N sulfanyl thiohypochlorite Chemical compound SSCl FNKUJDADVODZOY-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/45—Compounds containing sulfur and halogen, with or without oxygen
- C01B17/4507—Compounds containing sulfur and halogen, with or without oxygen containing sulfur and halogen only
- C01B17/4538—Compounds containing sulfur and halogen, with or without oxygen containing sulfur and halogen only containing sulfur and chlorine only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/10—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1998878 | 1978-05-16 | ||
| GB19988/78 | 1978-05-16 | ||
| GB19989/78 | 1978-05-16 | ||
| GB1998978 | 1978-05-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1110039A true CA1110039A (en) | 1981-10-06 |
Family
ID=26254352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA327,370A Expired CA1110039A (en) | 1978-05-16 | 1979-05-10 | Reduction of ferric chloride |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS54150392A (de) |
| CA (1) | CA1110039A (de) |
| DE (1) | DE2918944A1 (de) |
| FR (1) | FR2426022A1 (de) |
| IT (1) | IT1116834B (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104609477B (zh) * | 2015-02-03 | 2016-05-11 | 上海拱极化学有限公司 | 一种高纯度无水三氯化铁的制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2852339A (en) * | 1955-01-21 | 1958-09-16 | Texas Gulf Sulphur Co | Process of chlorinating iron sulfide to produce ferrous chloride and sulfur |
| GB1584359A (en) * | 1976-11-17 | 1981-02-11 | Mineral Process Licensing Corp | Recovery of chlorine values from iron chloride by-produced in chlorination of ilmenite and the like |
-
1979
- 1979-05-10 DE DE19792918944 patent/DE2918944A1/de not_active Withdrawn
- 1979-05-10 CA CA327,370A patent/CA1110039A/en not_active Expired
- 1979-05-10 IT IT49001/79A patent/IT1116834B/it active
- 1979-05-10 JP JP5641879A patent/JPS54150392A/ja active Pending
- 1979-05-16 FR FR7912417A patent/FR2426022A1/fr active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2426022A1 (fr) | 1979-12-14 |
| JPS54150392A (en) | 1979-11-26 |
| DE2918944A1 (de) | 1979-11-29 |
| IT1116834B (it) | 1986-02-10 |
| IT7949001A0 (it) | 1979-05-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |