CA1099696A - Catalytic components and catalysts for the polymerization of olefins - Google Patents
Catalytic components and catalysts for the polymerization of olefinsInfo
- Publication number
- CA1099696A CA1099696A CA258,565A CA258565A CA1099696A CA 1099696 A CA1099696 A CA 1099696A CA 258565 A CA258565 A CA 258565A CA 1099696 A CA1099696 A CA 1099696A
- Authority
- CA
- Canada
- Prior art keywords
- ether
- catalyst
- comprised
- forming components
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 19
- 238000006116 polymerization reaction Methods 0.000 title claims description 26
- 150000001336 alkenes Chemical class 0.000 title claims description 5
- 230000003197 catalytic effect Effects 0.000 title description 34
- 229910010061 TiC13 Inorganic materials 0.000 claims abstract description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- 229910010066 TiC14 Inorganic materials 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000004711 α-olefin Substances 0.000 claims abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 49
- -1 aluminium halides Chemical class 0.000 claims description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims description 13
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 229910052782 aluminium Inorganic materials 0.000 claims description 11
- 150000004820 halides Chemical class 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 238000009997 thermal pre-treatment Methods 0.000 claims description 9
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical group CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 238000001228 spectrum Methods 0.000 claims description 8
- 150000002170 ethers Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 claims description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- 150000002902 organometallic compounds Chemical class 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 claims description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000002524 organometallic group Chemical group 0.000 abstract description 4
- 238000012721 stereospecific polymerization Methods 0.000 abstract 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 68
- 239000000306 component Substances 0.000 description 48
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 31
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 31
- 239000000047 product Substances 0.000 description 29
- 239000004743 Polypropylene Substances 0.000 description 15
- 229920001155 polypropylene Polymers 0.000 description 14
- 238000009835 boiling Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 238000000605 extraction Methods 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003638 chemical reducing agent Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229910010062 TiCl3 Inorganic materials 0.000 description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 3
- 229910003074 TiCl4 Inorganic materials 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 230000000707 stereoselective effect Effects 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910016523 CuKa Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- HCTVWSOKIJULET-LQDWTQKMSA-M phenoxymethylpenicillin potassium Chemical compound [K+].N([C@H]1[C@H]2SC([C@@H](N2C1=O)C([O-])=O)(C)C)C(=O)COC1=CC=CC=C1 HCTVWSOKIJULET-LQDWTQKMSA-M 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT26231/75A IT1040379B (it) | 1975-08-08 | 1975-08-08 | Componenti catalitici e catalizzatori per la polimerizzazione delle olefine |
| IT26,231A/75 | 1975-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1099696A true CA1099696A (en) | 1981-04-21 |
Family
ID=11219002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA258,565A Expired CA1099696A (en) | 1975-08-08 | 1976-08-06 | Catalytic components and catalysts for the polymerization of olefins |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS5222082A (en, 2012) |
| AT (1) | AT345549B (en, 2012) |
| AU (1) | AU513230B2 (en, 2012) |
| BE (1) | BE844951A (en, 2012) |
| CA (1) | CA1099696A (en, 2012) |
| DE (1) | DE2635163C2 (en, 2012) |
| ES (1) | ES450554A1 (en, 2012) |
| FR (1) | FR2320308A1 (en, 2012) |
| GB (1) | GB1553232A (en, 2012) |
| IT (1) | IT1040379B (en, 2012) |
| NL (1) | NL7608629A (en, 2012) |
| NO (1) | NO762686L (en, 2012) |
| SE (1) | SE7608697L (en, 2012) |
| SU (1) | SU843709A3 (en, 2012) |
| ZA (1) | ZA764722B (en, 2012) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5049606A (en, 2012) * | 1973-09-04 | 1975-05-02 | ||
| EP0000998B1 (en) | 1977-08-31 | 1982-03-24 | Imperial Chemical Industries Plc | Titanium trichloride compositions, preparation thereof, catalyst system containing them and polymerisation of olefins using this system |
| DE2861357D1 (en) * | 1977-08-31 | 1982-01-28 | Ici Plc | Titanium trichloride compositions, preparation thereof, catalyst system containing them and polymerisation of olefins using this system |
| DE2860737D1 (en) * | 1977-08-31 | 1981-09-03 | Ici Plc | Titanium trichloride compositions, preparation thereof, catalyst system containing them, and polymerisation of olefins using this system |
| US4295991A (en) * | 1978-09-26 | 1981-10-20 | Exxon Research & Engineering Co. | Titanium trichloride catalyst component and the process for the production thereof |
| CN110628010B (zh) * | 2019-10-18 | 2022-09-27 | 辽宁奥克医药辅料股份有限公司 | 一种催化剂组合物及其应用于制备中等分子量聚乙二醇的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL227164A (en, 2012) * | 1957-04-27 | |||
| CH543546A (fr) * | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| GB1408620A (en) * | 1972-12-04 | 1975-10-01 | Shell Int Research | Isoprene polymerization and catalyst therefor |
| JPS5074594A (en, 2012) * | 1973-11-02 | 1975-06-19 | ||
| ES435000A1 (es) * | 1974-03-20 | 1977-03-01 | Hoechst Ag | Procedimiento para la obtencion de un catalizador. |
| US3984350A (en) * | 1974-05-09 | 1976-10-05 | Standard Oil Company (Indiana) | Catalyst component comprising brown titanium trichloride |
| DK81375A (da) * | 1975-01-30 | 1976-07-31 | Hoechst Ag | Fremgangsmade til fremstilling af en katalysator |
| JPS51123796A (en) * | 1975-04-23 | 1976-10-28 | Mitsubishi Chem Ind Ltd | Preparation process of solid titanium trichloride catalyst |
-
1975
- 1975-08-08 IT IT26231/75A patent/IT1040379B/it active
-
1976
- 1976-08-03 NO NO762686A patent/NO762686L/no unknown
- 1976-08-03 SE SE7608697A patent/SE7608697L/xx not_active Application Discontinuation
- 1976-08-03 NL NL7608629A patent/NL7608629A/xx unknown
- 1976-08-04 FR FR7623842A patent/FR2320308A1/fr active Granted
- 1976-08-05 GB GB32661/76A patent/GB1553232A/en not_active Expired
- 1976-08-05 ZA ZA764722A patent/ZA764722B/xx unknown
- 1976-08-05 DE DE2635163A patent/DE2635163C2/de not_active Expired
- 1976-08-05 AT AT582276A patent/AT345549B/de not_active IP Right Cessation
- 1976-08-06 SU SU762388804A patent/SU843709A3/ru active
- 1976-08-06 BE BE169609A patent/BE844951A/xx unknown
- 1976-08-06 CA CA258,565A patent/CA1099696A/en not_active Expired
- 1976-08-07 ES ES450554A patent/ES450554A1/es not_active Expired
- 1976-08-07 JP JP51093603A patent/JPS5222082A/ja active Pending
- 1976-08-09 AU AU16695/76A patent/AU513230B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2635163A1 (de) | 1977-02-24 |
| ATA582276A (de) | 1978-01-15 |
| JPS5222082A (en) | 1977-02-19 |
| FR2320308A1 (fr) | 1977-03-04 |
| IT1040379B (it) | 1979-12-20 |
| AU513230B2 (en) | 1980-11-20 |
| NO762686L (en, 2012) | 1977-02-09 |
| NL7608629A (nl) | 1977-02-10 |
| FR2320308B1 (en, 2012) | 1979-09-28 |
| ZA764722B (en) | 1977-07-27 |
| GB1553232A (en) | 1979-09-26 |
| SE7608697L (sv) | 1977-02-09 |
| BE844951A (fr) | 1977-02-07 |
| AT345549B (de) | 1978-09-25 |
| SU843709A3 (ru) | 1981-06-30 |
| ES450554A1 (es) | 1978-01-01 |
| AU1669576A (en) | 1978-02-16 |
| DE2635163C2 (de) | 1984-12-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |