CA1085945A - Method for producing selected alignment in liquid crystal cells - Google Patents
Method for producing selected alignment in liquid crystal cellsInfo
- Publication number
- CA1085945A CA1085945A CA287,105A CA287105A CA1085945A CA 1085945 A CA1085945 A CA 1085945A CA 287105 A CA287105 A CA 287105A CA 1085945 A CA1085945 A CA 1085945A
- Authority
- CA
- Canada
- Prior art keywords
- plasma
- substrate
- free radicals
- alignment
- liquid crystal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract 5
- 210000002858 crystal cell Anatomy 0.000 title claims description 5
- 239000000758 substrate Substances 0.000 claims abstract description 70
- 239000001301 oxygen Substances 0.000 claims abstract description 39
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 39
- 150000003254 radicals Chemical class 0.000 claims abstract description 36
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 32
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 19
- 239000011737 fluorine Substances 0.000 claims abstract description 19
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011521 glass Substances 0.000 claims abstract description 14
- 239000007789 gas Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 3
- 238000011065 in-situ storage Methods 0.000 claims abstract 2
- 210000004027 cell Anatomy 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052786 argon Inorganic materials 0.000 claims description 4
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 claims description 4
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 150000003606 tin compounds Chemical class 0.000 claims description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 20
- -1 oxygen radicals Chemical class 0.000 abstract description 14
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 abstract description 13
- 229910003437 indium oxide Inorganic materials 0.000 abstract description 11
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 229910052681 coesite Inorganic materials 0.000 abstract description 10
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 10
- 239000000377 silicon dioxide Substances 0.000 abstract description 10
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 10
- 229910052682 stishovite Inorganic materials 0.000 abstract description 10
- 229910052905 tridymite Inorganic materials 0.000 abstract description 10
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 9
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052710 silicon Inorganic materials 0.000 abstract description 5
- 239000010703 silicon Substances 0.000 abstract description 5
- 238000010849 ion bombardment Methods 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 230000001427 coherent effect Effects 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 239000010408 film Substances 0.000 description 14
- 229920002120 photoresistant polymer Polymers 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 238000005530 etching Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- WLPATYNQCGVFFH-UHFFFAOYSA-N 2-phenylbenzonitrile Chemical group N#CC1=CC=CC=C1C1=CC=CC=C1 WLPATYNQCGVFFH-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000003961 organosilicon compounds Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- VDWPNEQMDFISMS-UHFFFAOYSA-N 2-pentyl-6-phenylbenzonitrile Chemical group CCCCCC1=CC=CC(C=2C=CC=CC=2)=C1C#N VDWPNEQMDFISMS-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000364027 Sinoe Species 0.000 description 1
- XRWSZZJLZRKHHD-WVWIJVSJSA-N asunaprevir Chemical class O=C([C@@H]1C[C@H](CN1C(=O)[C@@H](NC(=O)OC(C)(C)C)C(C)(C)C)OC1=NC=C(C2=CC=C(Cl)C=C21)OC)N[C@]1(C(=O)NS(=O)(=O)C2CC2)C[C@H]1C=C XRWSZZJLZRKHHD-WVWIJVSJSA-N 0.000 description 1
- FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 1
- 229940126142 compound 16 Drugs 0.000 description 1
- 229940125961 compound 24 Drugs 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- KCWYOFZQRFCIIE-UHFFFAOYSA-N ethylsilane Chemical compound CC[SiH3] KCWYOFZQRFCIIE-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 208000013651 non-24-hour sleep-wake syndrome Diseases 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 101150095744 tin-9.1 gene Proteins 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0227—Pretreatment of the material to be coated by cleaning or etching
- C23C16/0245—Pretreatment of the material to be coated by cleaning or etching by etching with a plasma
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
- C23C16/40—Oxides
- C23C16/401—Oxides containing silicon
- C23C16/402—Silicon dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
- C09K2323/021—Inorganic, e.g. glass or silicon oxide
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Nonlinear Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Plasma & Fusion (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US724,439 | 1976-09-20 | ||
| US05/724,439 US4038439A (en) | 1976-09-20 | 1976-09-20 | Method for producing selected alignment in liquid crystal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1085945A true CA1085945A (en) | 1980-09-16 |
Family
ID=24910445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA287,105A Expired CA1085945A (en) | 1976-09-20 | 1977-09-20 | Method for producing selected alignment in liquid crystal cells |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4038439A (OSRAM) |
| JP (1) | JPS5339148A (OSRAM) |
| CA (1) | CA1085945A (OSRAM) |
| DE (1) | DE2740384A1 (OSRAM) |
| FR (1) | FR2365139A1 (OSRAM) |
| GB (1) | GB1542372A (OSRAM) |
| IT (1) | IT1114122B (OSRAM) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4105298A (en) * | 1977-04-11 | 1978-08-08 | Rca Corporation | Electro-optic devices |
| US4188426A (en) * | 1977-12-12 | 1980-02-12 | Lord Corporation | Cold plasma modification of organic and inorganic surfaces |
| GB1601601A (en) * | 1978-01-18 | 1981-11-04 | Standard Telephones Cables Ltd | Liquid crystal display cells |
| DE2824798A1 (de) * | 1978-06-06 | 1979-12-13 | Siemens Ag | Fluessigkristallzelle |
| US4252838A (en) * | 1978-09-11 | 1981-02-24 | Honeywell Inc. | Glow discharge fabrication of transparent conductive coatings |
| US4261650A (en) * | 1978-12-18 | 1981-04-14 | International Business Machines Corporation | Method for producing uniform parallel alignment in liquid crystal cells |
| US4456638A (en) * | 1981-04-06 | 1984-06-26 | Polytronix, Inc. | Polymer packaging material for liquid crystal cell |
| US5215677A (en) * | 1985-09-27 | 1993-06-01 | Sanyo Electric Co., Ltd. | Liquid crystal display device |
| JPH02246358A (ja) * | 1989-03-20 | 1990-10-02 | Fujitsu Miyagi Electron:Kk | リードフレーム |
| JPH03241767A (ja) * | 1990-02-20 | 1991-10-28 | Matsushita Electric Ind Co Ltd | リードフレームの製造方法 |
| DE4015869A1 (de) * | 1990-05-17 | 1991-11-21 | Nokia Unterhaltungselektronik | Hochaufloesende passiv angesteuerte fluessigkristallanzeige |
| JPH04246852A (ja) * | 1991-02-01 | 1992-09-02 | Nec Corp | 半導体装置用パッケージ |
| EP1111441B1 (en) * | 1997-06-12 | 2009-12-02 | Sharp Kabushiki Kaisha | Vertically-aligned (VA) liquid crystal display device |
| US6660341B2 (en) * | 2001-06-07 | 2003-12-09 | International Business Machines Corporation | Tilted vertical alignment of liquid crystals employing inorganic thin film composition and ion beam treatment |
| RU2317313C2 (ru) * | 2004-10-28 | 2008-02-20 | Самсунг Электроникс Ко., Лтд | Способ получения жидкокристаллической полимерной пленки |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1408852A (en) * | 1972-03-08 | 1975-10-08 | Seiko Instr & Electronics | Liquid crystal display device and a method of making the same |
| JPS5343058B2 (OSRAM) * | 1972-03-08 | 1978-11-16 | ||
| US3834792A (en) * | 1972-04-10 | 1974-09-10 | Ncr | Alignment film for a liquid crystal display cell |
| JPS529146B2 (OSRAM) * | 1972-05-25 | 1977-03-14 | ||
| JPS5222249B2 (OSRAM) * | 1972-07-15 | 1977-06-16 | ||
| JPS5438908B2 (OSRAM) * | 1973-05-11 | 1979-11-24 | ||
| US3938242A (en) * | 1973-09-27 | 1976-02-17 | Rca Corporation | Fabrication of liquid crystal devices |
| FR2248529B1 (OSRAM) * | 1973-10-19 | 1978-02-17 | Thomson Csf | |
| US3941901A (en) * | 1974-02-15 | 1976-03-02 | Hoffmann-La Roche Inc. | Surface alignment method for liquid crystal cells and production of polarizers therefor |
| US3966305A (en) * | 1974-10-10 | 1976-06-29 | American Micro-Systems, Inc. | Liquid crystal cell with improved alignment |
| JPS5284760A (en) * | 1976-01-07 | 1977-07-14 | Hitachi Ltd | Formation of electrode for liquid crystal display element |
-
1976
- 1976-09-20 US US05/724,439 patent/US4038439A/en not_active Expired - Lifetime
-
1977
- 1977-07-26 FR FR7723833A patent/FR2365139A1/fr active Granted
- 1977-08-26 IT IT26988/77A patent/IT1114122B/it active
- 1977-08-31 JP JP10373577A patent/JPS5339148A/ja active Granted
- 1977-09-08 DE DE19772740384 patent/DE2740384A1/de not_active Withdrawn
- 1977-09-13 GB GB7738154A patent/GB1542372A/en not_active Expired
- 1977-09-20 CA CA287,105A patent/CA1085945A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2365139B1 (OSRAM) | 1980-09-05 |
| GB1542372A (en) | 1979-03-21 |
| FR2365139A1 (fr) | 1978-04-14 |
| JPS6242254B2 (OSRAM) | 1987-09-07 |
| DE2740384A1 (de) | 1978-03-23 |
| JPS5339148A (en) | 1978-04-10 |
| IT1114122B (it) | 1986-01-27 |
| US4038439A (en) | 1977-07-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |