CA1077525A - Hydrocarbon synthesis from co and h2 with ru, ni or rh supported on titanium oxide - Google Patents

Hydrocarbon synthesis from co and h2 with ru, ni or rh supported on titanium oxide

Info

Publication number
CA1077525A
CA1077525A CA275,338A CA275338A CA1077525A CA 1077525 A CA1077525 A CA 1077525A CA 275338 A CA275338 A CA 275338A CA 1077525 A CA1077525 A CA 1077525A
Authority
CA
Canada
Prior art keywords
tio2
titanium
nickel
supported
ruthenium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA275,338A
Other languages
English (en)
French (fr)
Inventor
Robert L. Garten
M. Albert Vannice
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/673,356 external-priority patent/US4042614A/en
Priority claimed from US05/673,357 external-priority patent/US4042615A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1077525A publication Critical patent/CA1077525A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA275,338A 1976-04-05 1977-04-01 Hydrocarbon synthesis from co and h2 with ru, ni or rh supported on titanium oxide Expired CA1077525A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US67335876A 1976-04-05 1976-04-05
US05/673,356 US4042614A (en) 1976-04-05 1976-04-05 Hydrocarbon synthesis from CO and H2 using Ru supported on a titanium oxide
US05/673,357 US4042615A (en) 1976-04-05 1976-04-05 Hydrocarbon synthesis from CO and H2 using Ni supported on a titanium oxide

Publications (1)

Publication Number Publication Date
CA1077525A true CA1077525A (en) 1980-05-13

Family

ID=27418266

Family Applications (1)

Application Number Title Priority Date Filing Date
CA275,338A Expired CA1077525A (en) 1976-04-05 1977-04-01 Hydrocarbon synthesis from co and h2 with ru, ni or rh supported on titanium oxide

Country Status (4)

Country Link
JP (1) JPS52122307A (nl)
CA (1) CA1077525A (nl)
DE (1) DE2712909A1 (nl)
FR (1) FR2347326A1 (nl)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4171320A (en) * 1977-10-19 1979-10-16 Exxon Research & Engineering Co. Hydrocarbon synthesis from CO and H2 using Ru supported on group VB metal oxides
ZA783466B (en) * 1978-06-16 1981-07-29 Johnson Matthey Co Ltd Hydrocarbon synthesis
US4339545A (en) * 1981-06-26 1982-07-13 Texaco Inc. Alkanols from synthesis gas
NL8200544A (nl) * 1982-02-12 1983-09-01 Veg Gasinstituut Nv Werkwijze voor de bereiding van methaan uit koolmonoxide bevattende gasmengsels met behulp van nikkel bevattende katalysatoren.
US4477595A (en) * 1982-03-31 1984-10-16 Exxon Research And Engineering Co. Liquid hydrocarbon synthesis using supported ruthenium catalysts
EP0231401B1 (en) * 1984-06-29 1992-09-09 Exxon Research And Engineering Company Ruthenium-rhenium-titania catalysts, and use thereof for fischer-tropsch synthesis
US4992406A (en) * 1988-11-23 1991-02-12 Exxon Research And Engineering Company Titania-supported catalysts and their preparation for use in Fischer-Tropsch synthesis
JPH0724774B2 (ja) * 1988-11-25 1995-03-22 株式会社日本触媒 排ガス処理触媒用担体、その製造方法ならびに該担体を含有してなる排ガス処理用触媒
DK1163955T3 (da) * 2000-06-14 2004-07-19 Kataleuna Gmbh Catalysts Hydrogeneringskatalysator til reducering af funktionelle grupper og fremgangsmåde til dennes fremstilling
DE10124600A1 (de) * 2001-05-21 2002-11-28 Basf Ag Ni/Ti02-Hydrierkatalysator
FR2833253B1 (fr) * 2001-12-12 2004-10-08 Rhodia Elect & Catalysis Procede de preparation d'un oxyde a base de zirconium et de titane, oxydes ainsi obtenus et utilisation de ces oxydes comme catalyseurs

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB624869A (en) * 1945-08-23 1949-06-17 Kellogg M W Co Improvements in or relating to process for hydrogenating carbon oxides
US2637739A (en) * 1948-08-21 1953-05-05 Kellogg M W Co Synthesis of organic compounds
FR1223311A (fr) * 1957-09-27 1960-06-16 Perfectionnements apportés aux procédés de préparation de mélanges d'hydrocarbures gazeux constitués presque totalement d'éthylène

Also Published As

Publication number Publication date
DE2712909A1 (de) 1977-10-13
FR2347326A1 (fr) 1977-11-04
JPS52122307A (en) 1977-10-14
FR2347326B1 (nl) 1983-05-20

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