FR2347326A1 - Procede perfectionne de synthese d'hydrocarbures a partir de l'oxyde de carbone et de l'hydrogene en presence de ruthenium, de nickel ou de rhodium sur un support d'oxyde de titane - Google Patents

Procede perfectionne de synthese d'hydrocarbures a partir de l'oxyde de carbone et de l'hydrogene en presence de ruthenium, de nickel ou de rhodium sur un support d'oxyde de titane

Info

Publication number
FR2347326A1
FR2347326A1 FR7710106A FR7710106A FR2347326A1 FR 2347326 A1 FR2347326 A1 FR 2347326A1 FR 7710106 A FR7710106 A FR 7710106A FR 7710106 A FR7710106 A FR 7710106A FR 2347326 A1 FR2347326 A1 FR 2347326A1
Authority
FR
France
Prior art keywords
catalyst
tio2
rhodium
ruthenium
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7710106A
Other languages
English (en)
Other versions
FR2347326B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/673,356 external-priority patent/US4042614A/en
Priority claimed from US05/673,357 external-priority patent/US4042615A/en
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of FR2347326A1 publication Critical patent/FR2347326A1/fr
Application granted granted Critical
Publication of FR2347326B1 publication Critical patent/FR2347326B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
FR7710106A 1976-04-05 1977-04-04 Procede perfectionne de synthese d'hydrocarbures a partir de l'oxyde de carbone et de l'hydrogene en presence de ruthenium, de nickel ou de rhodium sur un support d'oxyde de titane Granted FR2347326A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US67335876A 1976-04-05 1976-04-05
US05/673,356 US4042614A (en) 1976-04-05 1976-04-05 Hydrocarbon synthesis from CO and H2 using Ru supported on a titanium oxide
US05/673,357 US4042615A (en) 1976-04-05 1976-04-05 Hydrocarbon synthesis from CO and H2 using Ni supported on a titanium oxide

Publications (2)

Publication Number Publication Date
FR2347326A1 true FR2347326A1 (fr) 1977-11-04
FR2347326B1 FR2347326B1 (fr) 1983-05-20

Family

ID=27418266

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7710106A Granted FR2347326A1 (fr) 1976-04-05 1977-04-04 Procede perfectionne de synthese d'hydrocarbures a partir de l'oxyde de carbone et de l'hydrogene en presence de ruthenium, de nickel ou de rhodium sur un support d'oxyde de titane

Country Status (4)

Country Link
JP (1) JPS52122307A (fr)
CA (1) CA1077525A (fr)
DE (1) DE2712909A1 (fr)
FR (1) FR2347326A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2406618A1 (fr) * 1977-10-19 1979-05-18 Exxon Research Engineering Co Procede catalytique de synthese d'hydrocarbures
FR2434793A1 (fr) * 1978-06-16 1980-03-28 Johnson Matthey Co Ltd Procede de synthese d'hydrocarbures
EP0086538A1 (fr) * 1982-02-12 1983-08-24 Veg-Gasinstituut N.V. Procédé pour la préparation de méthane
EP0231401A1 (fr) * 1984-06-29 1987-08-12 Exxon Research And Engineering Company Catalyseurs ruthénium rhénium oxyde de titane et leur utilisation pour des sythèses Fischer-Tropsch
EP0370523A1 (fr) * 1988-11-25 1990-05-30 Nippon Shokubai Co., Ltd. Support pour un catalyseur de traitement de gaz procédé pour sa fabrication et catalyseur de traitement de gaz contenant ledit support
EP0370757A1 (fr) * 1988-11-23 1990-05-30 Exxon Research And Engineering Company Catalyseurs contenant de l'oxyde de titane, leur préparation et utilisation dans la synthèse de fischer-tropsch
WO2002094434A1 (fr) * 2001-05-21 2002-11-28 Basf Aktiengesellschaft Catalyseur d'hydrogenation ni/tio2

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4339545A (en) * 1981-06-26 1982-07-13 Texaco Inc. Alkanols from synthesis gas
US4477595A (en) * 1982-03-31 1984-10-16 Exxon Research And Engineering Co. Liquid hydrocarbon synthesis using supported ruthenium catalysts
DK1163955T3 (da) * 2000-06-14 2004-07-19 Kataleuna Gmbh Catalysts Hydrogeneringskatalysator til reducering af funktionelle grupper og fremgangsmåde til dennes fremstilling
FR2833253B1 (fr) 2001-12-12 2004-10-08 Rhodia Elect & Catalysis Procede de preparation d'un oxyde a base de zirconium et de titane, oxydes ainsi obtenus et utilisation de ces oxydes comme catalyseurs

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB624869A (en) * 1945-08-23 1949-06-17 Kellogg M W Co Improvements in or relating to process for hydrogenating carbon oxides
US2637739A (en) * 1948-08-21 1953-05-05 Kellogg M W Co Synthesis of organic compounds
FR1223311A (fr) * 1957-09-27 1960-06-16 Perfectionnements apportés aux procédés de préparation de mélanges d'hydrocarbures gazeux constitués presque totalement d'éthylène

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB624869A (en) * 1945-08-23 1949-06-17 Kellogg M W Co Improvements in or relating to process for hydrogenating carbon oxides
US2637739A (en) * 1948-08-21 1953-05-05 Kellogg M W Co Synthesis of organic compounds
FR1223311A (fr) * 1957-09-27 1960-06-16 Perfectionnements apportés aux procédés de préparation de mélanges d'hydrocarbures gazeux constitués presque totalement d'éthylène

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2406618A1 (fr) * 1977-10-19 1979-05-18 Exxon Research Engineering Co Procede catalytique de synthese d'hydrocarbures
FR2434793A1 (fr) * 1978-06-16 1980-03-28 Johnson Matthey Co Ltd Procede de synthese d'hydrocarbures
EP0086538A1 (fr) * 1982-02-12 1983-08-24 Veg-Gasinstituut N.V. Procédé pour la préparation de méthane
EP0231401A1 (fr) * 1984-06-29 1987-08-12 Exxon Research And Engineering Company Catalyseurs ruthénium rhénium oxyde de titane et leur utilisation pour des sythèses Fischer-Tropsch
EP0370757A1 (fr) * 1988-11-23 1990-05-30 Exxon Research And Engineering Company Catalyseurs contenant de l'oxyde de titane, leur préparation et utilisation dans la synthèse de fischer-tropsch
EP0370523A1 (fr) * 1988-11-25 1990-05-30 Nippon Shokubai Co., Ltd. Support pour un catalyseur de traitement de gaz procédé pour sa fabrication et catalyseur de traitement de gaz contenant ledit support
WO2002094434A1 (fr) * 2001-05-21 2002-11-28 Basf Aktiengesellschaft Catalyseur d'hydrogenation ni/tio2
US7408086B2 (en) 2001-05-21 2008-08-05 Basf Aktiengesellschaft Ni/TiO2 hydrogenation catalyst

Also Published As

Publication number Publication date
DE2712909A1 (de) 1977-10-13
CA1077525A (fr) 1980-05-13
JPS52122307A (en) 1977-10-14
FR2347326B1 (fr) 1983-05-20

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Legal Events

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DR Decision of the appeal court due to an appeal at law against decisions of the director of the inpi, except decision of lapse
ST Notification of lapse