CA1063055A - Desulfurization of petroleum hydrocarbons - Google Patents
Desulfurization of petroleum hydrocarbonsInfo
- Publication number
- CA1063055A CA1063055A CA253,936A CA253936A CA1063055A CA 1063055 A CA1063055 A CA 1063055A CA 253936 A CA253936 A CA 253936A CA 1063055 A CA1063055 A CA 1063055A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- calculated
- cobalt
- catalyst
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003208 petroleum Substances 0.000 title claims abstract description 13
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 8
- 238000006477 desulfuration reaction Methods 0.000 title description 5
- 230000023556 desulfurization Effects 0.000 title description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 46
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 19
- 239000011593 sulfur Substances 0.000 claims abstract description 19
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 7
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 13
- 239000010941 cobalt Substances 0.000 claims description 12
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000003209 petroleum derivative Substances 0.000 claims description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 2
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 2
- 229960005349 sulfur Drugs 0.000 claims 4
- 235000001508 sulfur Nutrition 0.000 claims 4
- 150000004706 metal oxides Chemical class 0.000 claims 1
- AXFKVYBBROZOGA-UHFFFAOYSA-N [P].[Mo].[Co] Chemical compound [P].[Mo].[Co] AXFKVYBBROZOGA-UHFFFAOYSA-N 0.000 abstract description 4
- CKQGJVKHBSPKST-UHFFFAOYSA-N [Ni].P#[Mo] Chemical compound [Ni].P#[Mo] CKQGJVKHBSPKST-UHFFFAOYSA-N 0.000 abstract description 2
- WYWPWLUDBKATGV-UHFFFAOYSA-N [P].[Mo].[Ni].[Co] Chemical compound [P].[Mo].[Ni].[Co] WYWPWLUDBKATGV-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 15
- 239000003921 oil Substances 0.000 description 9
- 235000014786 phosphorus Nutrition 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000003009 desulfurizing effect Effects 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 208000036366 Sensation of pressure Diseases 0.000 description 2
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
- 229910000001 cobalt(II) carbonate Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000006187 pill Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000000727 fraction Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- -1 hydrogen - Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- DWAHIRJDCNGEDV-UHFFFAOYSA-N nickel(2+);dinitrate;hydrate Chemical compound O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DWAHIRJDCNGEDV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59095875A | 1975-06-27 | 1975-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1063055A true CA1063055A (en) | 1979-09-25 |
Family
ID=24364435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA253,936A Expired CA1063055A (en) | 1975-06-27 | 1976-06-02 | Desulfurization of petroleum hydrocarbons |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS525807A (enrdf_load_stackoverflow) |
| CA (1) | CA1063055A (enrdf_load_stackoverflow) |
| DE (1) | DE2628531A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2315533A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1514671A (enrdf_load_stackoverflow) |
| IT (1) | IT1069975B (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2904242B1 (fr) * | 2006-07-28 | 2012-09-28 | Inst Francais Du Petrole | Procede d'hydrodesulfuration de coupes contenant des composes soufres et des olefines en presence d'un catalyseur supporte comprenant des elements des groupes viii et vib |
| WO2020083945A1 (en) | 2018-10-22 | 2020-04-30 | Total Marketing Services | Deep desulphurization of low sulphur content feedstock |
| CN109529899A (zh) * | 2018-12-04 | 2019-03-29 | 宁波中科远东催化工程技术有限公司 | 重油加氢复合催化剂及其制备方法和使用方法 |
-
1976
- 1976-06-02 CA CA253,936A patent/CA1063055A/en not_active Expired
- 1976-06-04 GB GB2324376A patent/GB1514671A/en not_active Expired
- 1976-06-18 FR FR7618714A patent/FR2315533A1/fr active Granted
- 1976-06-22 IT IT5006576A patent/IT1069975B/it active
- 1976-06-24 DE DE19762628531 patent/DE2628531A1/de active Pending
- 1976-06-25 JP JP51075404A patent/JPS525807A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS525807A (en) | 1977-01-17 |
| GB1514671A (en) | 1978-06-21 |
| IT1069975B (it) | 1985-03-25 |
| DE2628531A1 (de) | 1976-12-30 |
| JPS5348206B2 (enrdf_load_stackoverflow) | 1978-12-27 |
| FR2315533A1 (fr) | 1977-01-21 |
| FR2315533B1 (enrdf_load_stackoverflow) | 1981-09-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4568449A (en) | Hydrotreating catalyst and process | |
| US4255282A (en) | Hydrotreating catalyst and process for its preparation | |
| US6037300A (en) | Catalyst containing boron and silicon and its use for hydrotreating hydrocarbon feeds | |
| US4886594A (en) | Hydrotreating catalyst and process | |
| US4652545A (en) | Catalyst for hydroconversion of heavy oils and method of making the catalyst | |
| US6531054B1 (en) | Process for effecting deep HDS of hydrocarbon feedstocks | |
| US4513097A (en) | Hydrotreating catalyst and a method for preparing the catalyst | |
| US5370788A (en) | Wax conversion process | |
| CA1253839A (en) | Hydrocracking catalyst of improved activity | |
| US4568450A (en) | Hydrocarbon conversion process | |
| US4540483A (en) | Hydrotreating process | |
| EP0310165B1 (en) | Process for hydrocracking of a hydrocarbon feedstock | |
| CA1182769A (en) | Two-bed catalytic hydroprocessing for heavy hydrocarbon feedstocks | |
| US4446248A (en) | Hydrotreating catalyst | |
| US3425934A (en) | Catalytic refining with hydrogen | |
| CA1063055A (en) | Desulfurization of petroleum hydrocarbons | |
| CA1048952A (en) | Desulphurisation catalysts and their use | |
| EP0158997B1 (en) | A method for the hydrogenation treatment of a heavy hydrocarbon oil | |
| CA1272153A (en) | Single-stage hydrotreating process | |
| US3931048A (en) | Hydrocarbon conversion catalytic composite | |
| US5914290A (en) | Distillate hydrofining catalyst and a process for the preparation of the same | |
| US4758544A (en) | Catalyst composition and hydroprocessing of oils using same | |
| US5116484A (en) | Hydrodenitrification process | |
| CA1304348C (en) | Process for preparing hydrotreating catalysts from hydrogels | |
| EP0024199A1 (en) | Catalyst having low volume of large pores and hydrocarbon hydroconversion process using same |