CA1062197A - Method and apparatus to improve the energy yield of a reaction process - Google Patents
Method and apparatus to improve the energy yield of a reaction processInfo
- Publication number
- CA1062197A CA1062197A CA252,088A CA252088A CA1062197A CA 1062197 A CA1062197 A CA 1062197A CA 252088 A CA252088 A CA 252088A CA 1062197 A CA1062197 A CA 1062197A
- Authority
- CA
- Canada
- Prior art keywords
- reaction
- combustion
- frequency
- reactants
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Abstract
ABSTRACT OF THE DISCLOSURE
Method and apparatus to improve the energy yield of a reaction, particularly a combustion process. When used in a heating system in which fuel is burned, a burner sprays fuel and combustion supporting gas, preferably air, into the reaction zone inside a combustion chamber. An electromagnetic radiation of which the frequency is in the range of 1 GigaHertz to 100 GigaHertz preferably 8800 Mc/s ? 20% corresponding to the maximum motion which may be imparted to the reactants of the molecules is directed at the reactants, by an antenna whose axis inter-sects the axis of the burner inside the reaction zone. A
dissociable substance, preferably water with a surface active agent, is used as an additive and injected towards the reaction zone. An electrostatic field is provided around the spray of fuel leaving the burner by a metal ring at a potential of 300 to 25,000 V.
Method and apparatus to improve the energy yield of a reaction, particularly a combustion process. When used in a heating system in which fuel is burned, a burner sprays fuel and combustion supporting gas, preferably air, into the reaction zone inside a combustion chamber. An electromagnetic radiation of which the frequency is in the range of 1 GigaHertz to 100 GigaHertz preferably 8800 Mc/s ? 20% corresponding to the maximum motion which may be imparted to the reactants of the molecules is directed at the reactants, by an antenna whose axis inter-sects the axis of the burner inside the reaction zone. A
dissociable substance, preferably water with a surface active agent, is used as an additive and injected towards the reaction zone. An electrostatic field is provided around the spray of fuel leaving the burner by a metal ring at a potential of 300 to 25,000 V.
Description
1~ 7 .
The present invention relates to a method of improving the energy yields of reactions, particularly combustion.
In reactions such as the combustion of hydrocarbons, it has been known for a long tir.le that the reaction between the combustible or fuel and the combustion supporting gas occurs progressively with the destruction of particles or droplets of the fuel, formation of intermediaries in chains and, normally, the production of unburnt residues. If said production is eliminated by using an excess of the combustion supporting gas, (air) it results in a loss in the energy yiéld.
It is also known, and it makes good sense, that a reaction is more complete and faster when the reactants are mixed better initially. It has been proposed to improve the mixing of the reactants by vlbrations of variable frequency,and ; yet, here again, the complications of the equipment override in ` general the corresponding gain; only simple improvements relat-ive to the shape and arrangements of the tuyeres, for ameliora-ting the turbulence, have really been accepted in practice.
~ or some time it has also been known that it is possible to improve a combustion process by adding a substance in the presence of the fuel which partially dissociates, at a temper-ature below that of the combustion reaction, the products of dissociation recorbiDine in the ' ~:
. , . :
-vicinity of the flame, with themselves and the intermediary ~~ products of combustion. The si~plest such additive is water.
Nevertheles~ the energy gain afforded ~y water is very substan-tially less than might be hoped, therefore hardly compensating for the added complication due to the addition of water;
accordingly, such a ~ethod has not achieved wide acceptance~
The preceding is not only true for a combustion process but also for all other similar reactions.
The idea which was the starting point for the present invention i5 -that additives such as water are far from as effective as they could be because the motion imparted to the molecules of the solid or liquid reactants has been heretofore very small and inadequate to dislodge the particles and droplets to the point of permitting them to react fully w;th the additive.
We have surprisingly and unexpectedly discovered that the maximum thermal or ionic motion imparted to substantially all the substances capable of reacting i5 located in the fre-- quency band of the so-called ~yperfreguenciesUbetween 1 GigaHertz and 100 GigaHertz (that is between 1 and 100 billions of cycles/
second and, prefera~ly in the band of 8800 Mc/s + 20%).
Up until the present day it was not easy to obtain such elevated frequencies, but recently apparatus have been made available enabling the production and transmission of such super high frequencies, in the radar range, economically, at suitable levels of power.
According to one aspect of this invention, there is provided a method of improving the energy yield of a reaction between reactants, comprising providing electromagnetic radiation .~ ~
the frequency of which is in the range of 1 GigaHertz to 100 GigaHertz and substantially corresponds to the maximum thermal or ionic motion of the molecules of said reactants, and directing said electromagnetic radiation towards said reactants while '~
-3- ;
:
.. - . ... . ... .. .. . . . .. .
, , . . .. , . : :. .
tf1 allowing the reaction to proceed. Th~ frequency of the electro-- magnetic radiation is prefera~ly in the band of 88~0 Mc/s + 20~.
According to another aspect of this invention, there is provided an apparatus for improving the energy yield of a com~ustion process compri~ing a com~ustion chamber, a burner extending inside said com~ustion chan~er for spraying fuel and a combustion supporting gas into a reaction zone in said com-bustion chamber, means for supplying fueI and combustion support-ing gas to said burner, means-for generating frequency in the band of 8800 Mc/s + 20% and means for directing said frequency towards said comoustion zone.
~` , .
:
~s, :
,~ .
., , .
,, -. -3a-~
:' ' .
:- , ~ .
.
In the method according to the invention, before react-ing the reactants, possibly with the addition of an additive whose products of dissociation are capable of recombining at least in part with themselves or with the reactants, the react-ants are subjected to an electromagnetic field whose frequency is selected in the band of 8800 Mc/s + 20% which corresponds to a maximum thermal or ionic motion imparted to the reactants.
In case of the combustion of hydrocarbons, the preferred additive is water to which a surface active agent such as 10 "Teepol", a trademarked product distributed by "Compagnie Franc~aise des Produits Chimiques", Shell, Paris, France is added.
When the reaction is principally or secondarily intended for the recovery of heat, for example the burning of fuel in a boiler for heating, the transmission of heat to recovery surfaces, e.g., the walls and tubes of the boiler,is greatly improved by subjecting the reaction zone or area to an electro-static field at a voltage ranging between 300 and 15,000 V.
The effect of such a field is to cause an ionic dispersion, in '- the reaction zone then towards the walls, of the mixture of 20 reactants which has been highly ioniæed due to the simultaneous effect of the electromagnetic field and reaction. ~ potential below 300 V is not very effective, whereas a potential above 15,000 V generates premature and incomplete combustion after a apont6neou6 ' ~ - 4 -ionization~ ln an internal combus,tion engine, potentials may range up to 25 ,ao~ v.
One of the effects of the addition of water in such a case is that since the dielectric constant of the hydrocarbon fuel and combustion supporting gas is- in general even less than about 1/40 that of ~ater, a molecular focusing is brought about by the effect on the rate of propagation of the electro-magnetic wave which'is given by the formula:
v = 1 / ~ E ~
where E is the absolute dielectric constant of the medium and ~ is the magnetic permeability of the medium.
! From another standpoint, the specific heat of the - combustion supporting gases i5 in general very much less than that of water and hydrogen, the presence of water, whether dissociated or not improves the transmission of energy.
The accompanying drawing schematically illustrates a preferred embodiment of the apparatus of the present invention.
Referring to the drawing, a heating system including a - boiler utilizing fuel oil comprises a conventional burner 1 which injects fuel and air into a combustion chamber 2 and an injector 3 which injects water, to which a surface active agent has been added, as a pressurized spray phase. The flow rate of the sprayed water is at most 20% by weight that of the fuel injected.
, A frequency generator set at a central frequency of ,, 8800 Mc/s comprises an isolation voltage transformer 4 which is oonnected via a fixed voltage rectifier S and an oscillating ., . .
. , .
' ' ".. ': ". :'' ~u~æ~
cavity 6 to a horn type waveguide antenna 7 ~hich extends into the combustion chamber to the ~icinity of the burner 50 that its axis 8 intersects the axis of the ~urner in the middle of the flame. The consumption of the frequency-generator is about 215 volt-amperes for domestic use.
An electrostatic generator comprises a special isolation voltage transformer 4a, a special voltage rectifier 9, a voltage and current limiter la, and an insulated metal ring 11 disposed in front of the tip of the burner and having a diameter 15 mm larger than the maximum cross-sectional dimension of the conical spray of combustion reactants in the same plane_ The output voltage is adjustable bet~een 500 and 15,000 V, the current variable between 0.1 and 0 5 milliamps. The power consumed is 17 volt-amperes for domestic use.
Although the preceding example is relative to a boiler of a heating system it is to be noted that the invention is particularly well suited for internal combustion engines where - it is possible to achieve, in addition to an improved energy yield, an appreciable gain in the regularity of combustion and nearly total elimination of unburnt residues.
, - ~ ~ .
"~, -' -.
~ . ,- . .
- . . - . .
~ .
According to a preferred em~odiment of the invention, ~F
the electro-magnetic radlati~on is puls-ed with a frequency between 0.1 Hz and 2 MHz. This embodi`ment permits obtaining a higher peak power with the same effectlve power and particularly improves the evacuation of heat. The length and the form of the pulses are to be determ~ned for each case, the shorter is the percentage of time of emission in each pulse the higher the peak power may be.
As an example, a test has been carried out using a conventional automobile motor functioning with gasoline, with a high frequency generator, regulated at 8875 MHz, pulsed at 12.000 Hz, the radiation being emitted during 1/3 of each pulse period of time. The fuel consumption was reduced by about 20%.
The flow of air with gasoline vapour was subjected to the electro-magnetic radiation do~nstream of the carburetor, in the admission pipes.
.~ . ~
.
.~
. ~
,,, ~ .
., .
.-.
' _7_ ~
The present invention relates to a method of improving the energy yields of reactions, particularly combustion.
In reactions such as the combustion of hydrocarbons, it has been known for a long tir.le that the reaction between the combustible or fuel and the combustion supporting gas occurs progressively with the destruction of particles or droplets of the fuel, formation of intermediaries in chains and, normally, the production of unburnt residues. If said production is eliminated by using an excess of the combustion supporting gas, (air) it results in a loss in the energy yiéld.
It is also known, and it makes good sense, that a reaction is more complete and faster when the reactants are mixed better initially. It has been proposed to improve the mixing of the reactants by vlbrations of variable frequency,and ; yet, here again, the complications of the equipment override in ` general the corresponding gain; only simple improvements relat-ive to the shape and arrangements of the tuyeres, for ameliora-ting the turbulence, have really been accepted in practice.
~ or some time it has also been known that it is possible to improve a combustion process by adding a substance in the presence of the fuel which partially dissociates, at a temper-ature below that of the combustion reaction, the products of dissociation recorbiDine in the ' ~:
. , . :
-vicinity of the flame, with themselves and the intermediary ~~ products of combustion. The si~plest such additive is water.
Nevertheles~ the energy gain afforded ~y water is very substan-tially less than might be hoped, therefore hardly compensating for the added complication due to the addition of water;
accordingly, such a ~ethod has not achieved wide acceptance~
The preceding is not only true for a combustion process but also for all other similar reactions.
The idea which was the starting point for the present invention i5 -that additives such as water are far from as effective as they could be because the motion imparted to the molecules of the solid or liquid reactants has been heretofore very small and inadequate to dislodge the particles and droplets to the point of permitting them to react fully w;th the additive.
We have surprisingly and unexpectedly discovered that the maximum thermal or ionic motion imparted to substantially all the substances capable of reacting i5 located in the fre-- quency band of the so-called ~yperfreguenciesUbetween 1 GigaHertz and 100 GigaHertz (that is between 1 and 100 billions of cycles/
second and, prefera~ly in the band of 8800 Mc/s + 20%).
Up until the present day it was not easy to obtain such elevated frequencies, but recently apparatus have been made available enabling the production and transmission of such super high frequencies, in the radar range, economically, at suitable levels of power.
According to one aspect of this invention, there is provided a method of improving the energy yield of a reaction between reactants, comprising providing electromagnetic radiation .~ ~
the frequency of which is in the range of 1 GigaHertz to 100 GigaHertz and substantially corresponds to the maximum thermal or ionic motion of the molecules of said reactants, and directing said electromagnetic radiation towards said reactants while '~
-3- ;
:
.. - . ... . ... .. .. . . . .. .
, , . . .. , . : :. .
tf1 allowing the reaction to proceed. Th~ frequency of the electro-- magnetic radiation is prefera~ly in the band of 88~0 Mc/s + 20~.
According to another aspect of this invention, there is provided an apparatus for improving the energy yield of a com~ustion process compri~ing a com~ustion chamber, a burner extending inside said com~ustion chan~er for spraying fuel and a combustion supporting gas into a reaction zone in said com-bustion chamber, means for supplying fueI and combustion support-ing gas to said burner, means-for generating frequency in the band of 8800 Mc/s + 20% and means for directing said frequency towards said comoustion zone.
~` , .
:
~s, :
,~ .
., , .
,, -. -3a-~
:' ' .
:- , ~ .
.
In the method according to the invention, before react-ing the reactants, possibly with the addition of an additive whose products of dissociation are capable of recombining at least in part with themselves or with the reactants, the react-ants are subjected to an electromagnetic field whose frequency is selected in the band of 8800 Mc/s + 20% which corresponds to a maximum thermal or ionic motion imparted to the reactants.
In case of the combustion of hydrocarbons, the preferred additive is water to which a surface active agent such as 10 "Teepol", a trademarked product distributed by "Compagnie Franc~aise des Produits Chimiques", Shell, Paris, France is added.
When the reaction is principally or secondarily intended for the recovery of heat, for example the burning of fuel in a boiler for heating, the transmission of heat to recovery surfaces, e.g., the walls and tubes of the boiler,is greatly improved by subjecting the reaction zone or area to an electro-static field at a voltage ranging between 300 and 15,000 V.
The effect of such a field is to cause an ionic dispersion, in '- the reaction zone then towards the walls, of the mixture of 20 reactants which has been highly ioniæed due to the simultaneous effect of the electromagnetic field and reaction. ~ potential below 300 V is not very effective, whereas a potential above 15,000 V generates premature and incomplete combustion after a apont6neou6 ' ~ - 4 -ionization~ ln an internal combus,tion engine, potentials may range up to 25 ,ao~ v.
One of the effects of the addition of water in such a case is that since the dielectric constant of the hydrocarbon fuel and combustion supporting gas is- in general even less than about 1/40 that of ~ater, a molecular focusing is brought about by the effect on the rate of propagation of the electro-magnetic wave which'is given by the formula:
v = 1 / ~ E ~
where E is the absolute dielectric constant of the medium and ~ is the magnetic permeability of the medium.
! From another standpoint, the specific heat of the - combustion supporting gases i5 in general very much less than that of water and hydrogen, the presence of water, whether dissociated or not improves the transmission of energy.
The accompanying drawing schematically illustrates a preferred embodiment of the apparatus of the present invention.
Referring to the drawing, a heating system including a - boiler utilizing fuel oil comprises a conventional burner 1 which injects fuel and air into a combustion chamber 2 and an injector 3 which injects water, to which a surface active agent has been added, as a pressurized spray phase. The flow rate of the sprayed water is at most 20% by weight that of the fuel injected.
, A frequency generator set at a central frequency of ,, 8800 Mc/s comprises an isolation voltage transformer 4 which is oonnected via a fixed voltage rectifier S and an oscillating ., . .
. , .
' ' ".. ': ". :'' ~u~æ~
cavity 6 to a horn type waveguide antenna 7 ~hich extends into the combustion chamber to the ~icinity of the burner 50 that its axis 8 intersects the axis of the ~urner in the middle of the flame. The consumption of the frequency-generator is about 215 volt-amperes for domestic use.
An electrostatic generator comprises a special isolation voltage transformer 4a, a special voltage rectifier 9, a voltage and current limiter la, and an insulated metal ring 11 disposed in front of the tip of the burner and having a diameter 15 mm larger than the maximum cross-sectional dimension of the conical spray of combustion reactants in the same plane_ The output voltage is adjustable bet~een 500 and 15,000 V, the current variable between 0.1 and 0 5 milliamps. The power consumed is 17 volt-amperes for domestic use.
Although the preceding example is relative to a boiler of a heating system it is to be noted that the invention is particularly well suited for internal combustion engines where - it is possible to achieve, in addition to an improved energy yield, an appreciable gain in the regularity of combustion and nearly total elimination of unburnt residues.
, - ~ ~ .
"~, -' -.
~ . ,- . .
- . . - . .
~ .
According to a preferred em~odiment of the invention, ~F
the electro-magnetic radlati~on is puls-ed with a frequency between 0.1 Hz and 2 MHz. This embodi`ment permits obtaining a higher peak power with the same effectlve power and particularly improves the evacuation of heat. The length and the form of the pulses are to be determ~ned for each case, the shorter is the percentage of time of emission in each pulse the higher the peak power may be.
As an example, a test has been carried out using a conventional automobile motor functioning with gasoline, with a high frequency generator, regulated at 8875 MHz, pulsed at 12.000 Hz, the radiation being emitted during 1/3 of each pulse period of time. The fuel consumption was reduced by about 20%.
The flow of air with gasoline vapour was subjected to the electro-magnetic radiation do~nstream of the carburetor, in the admission pipes.
.~ . ~
.
.~
. ~
,,, ~ .
., .
.-.
' _7_ ~
Claims (18)
1. A method of improving the energy yield of a reaction between reactants, comprising providing electromagnetic radiat-ion the frequency of which is in the range of 1 GigaHertz to 100 GigaHertz and substantially corresponds to the maximum thermal or ionic motion of the molecules of said reactants, and directing said electromagnetic radiation towards said reactants while allowing the reaction to proceed.
2. A method according to claim 1, the frequency of said electromagnetic radiation being in the band of 8800 Mc/s ?
20%.
20%.
3. A method according to claim 2, further comprising, before applying said electromagnetic radiation, adding an at least partially dissociable additive at a temperature below the temperature of reaction of said reaction, and allowing the products of dissociation to recombine thereafter.
4. A method according to claim 3, further comprising the products of dissociation recombining with themselves.
5. A method according to claim 3, further comprising the products of dissociation recombining with the products of said reaction.
6. A method according to claim 3, further comprising the products of dissociation recombining during said reaction.
7. A method according to claim 3, further comprising the products of dissociation recombining after said reaction.
8. A method according to claim 3, the additive being a substance the products of dissociation of which are oxygen and hydrogen.
9. A method according to claim 3, the additive being water.
10. A method according to claim 2, further comprising producing an electrostatic field having a potential ranging be-tween 300 and 25,000 V, and applying said electrostatic field to said reactants.
11. A method according to claim 2, said reaction being Combustion and said reactants including at least one hydrocarbon fuel and a combustion supporting gas.
12. An apparatus for improving the energy yield of a combustion process comprising a combustion chamber, a burner extending inside said combustion chamber for spraying fuel and a combustion supporting gas into a reaction zone in said combustion chamber, means for supplying fuel and combustion supporting gas to said burner, means for generating a frequency in the band of 8800 Mc/s ? 20%, and means for directing said frequency toward said combustion zone.
13. An apparatus according to claim 12, wherein said means for directing the frequency is an antenna having an axis intersecting the axis of said burner inside said combustion zone.
14. An apparatus according to claim 13, wherein wave guide means carries the frequency from said means for generating to said antenna.
15. An apparatus according to claim 12, further comprising means for injecting an additive into said combustion zone,
16. An apparatus according to claim 12, further comprising means for producing and applying an electrostatic field in the vicinity of said reaction zone.
17. An apparatus according to claim 16, wherein the last mentioned means include a metal ring arranged inside said combustion chamber and extending round the spray of fuel leaving said burner, and means electrically isolating said metal ring.
18. A method according to claim 1, further comprising pulsing said electro-magnetic radiation with a pulsation frequency between 0 1 Hertz and 2 Mega-Hertz.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA252,088A CA1062197A (en) | 1976-05-10 | 1976-05-10 | Method and apparatus to improve the energy yield of a reaction process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA252,088A CA1062197A (en) | 1976-05-10 | 1976-05-10 | Method and apparatus to improve the energy yield of a reaction process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1062197A true CA1062197A (en) | 1979-09-11 |
Family
ID=4105908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA252,088A Expired CA1062197A (en) | 1976-05-10 | 1976-05-10 | Method and apparatus to improve the energy yield of a reaction process |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1062197A (en) |
-
1976
- 1976-05-10 CA CA252,088A patent/CA1062197A/en not_active Expired
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