CA1058155A - Heating device comprising a heat accumulator - Google Patents

Heating device comprising a heat accumulator

Info

Publication number
CA1058155A
CA1058155A CA226,161A CA226161A CA1058155A CA 1058155 A CA1058155 A CA 1058155A CA 226161 A CA226161 A CA 226161A CA 1058155 A CA1058155 A CA 1058155A
Authority
CA
Canada
Prior art keywords
heat
reservoir
transport medium
accumulating material
closed space
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA226,161A
Other languages
French (fr)
Inventor
Matthias L. Hermans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke Philips NV
Original Assignee
Philips Gloeilampenfabrieken NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philips Gloeilampenfabrieken NV filed Critical Philips Gloeilampenfabrieken NV
Application granted granted Critical
Publication of CA1058155A publication Critical patent/CA1058155A/en
Expired legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/04Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02GHOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00Hot gas positive-displacement engine plants
    • F02G1/04Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F02G1/053Component parts or details
    • F02G1/055Heaters or coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/025Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being in direct contact with a heat-exchange medium or with another heat storage material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Abstract

ABSTRACT:

A heating device provided with a reservoir which is arranged within a closed space and in which in operation a heat-accuumulating material is present for exchanging heat with an evaporable medium in the closed space, the reservoir also containing an evaporable medium for pressure equalization on both sides of the reservoir walls.

Description

10~155 The invention relates to a heating device for supplying heat to a heat user, comprising a closed space with-in which one or more closed reservoirs are arranged which in operation contain a heat-accumulating material which can be heated by means of at least one primary heat source, the said heat-accumulating material being adapted to act as a secondary heat source for exchanging heat, via one or more heat-transmit-ting reservoir walls, with a heat transport medium which is present in the closed space and which transports heat from the reservoirs to the heat user by an evaporation/condensation cycle.
Heating devices of the kind set forth are known from Canadian Patents 944,742 and 958,290.
The heat-accumulating material may be a material which remains in the solid state in any operating condition ~for example, A1203; BeO; TiO, MgO2; SiO2), so that only sensible heat is stored, or a material in which the storage of hea~ is achieved mainly by utilizing the transition from the solid to the liquid phase (melting heat). Examples of the latter materials are: LiF; CaF2; SrF2; NaCl and other metal salts or mixtures thereof.
If a plurality of reservoirs are present for the heat-accumulating material, they may be arranged to be in-dependent of each other or be connected in series with or parallel to each other by way of one or more common filling and/or discharge ducts.

~ cjJ

Because the heating device is operated over a wide temperature range (from room temperature to temperatures beyond 1500C), the reservoirs cannot be completely filled, because the fact that the volume of the heat-accumulating S material increases as the temperature increases should be taken into account.
The volume increase of melting heat-accumulating metal salts generally amounts to 20% to 30%, going from room temperature to operating temperature.
In practice, this fact is usually taken into account by choosing a suitable filling degree for the reservoir, even though other solutions are also feasible, for e~ample, the use of an overflow reservoir for liquid metal salt.
The following problem occurs in the known heating devices.
In order to ensure that the evaporation/
condensation process of the heat transport medium ln the closed space can properly taken place, this space is normally evacuated. A substantial vacuum then prevails in the closed space at room temperature. As the operating temperature of the device increases, the vapour pressure of the heat transport medium in the closed space strongly increases. This means that the reservoir walls on the outside are subject to strongly varying pressures, the largest pressure occurring at the highest operating temperature.
Inside the partly filledreservoires however, usually a very low pressure prevails, because the reservoirs are e usually also evacuated after provision of the h~at-i(~51~155 accumulating material and before closing, notably to prevent oxidation of theheat-accumulating material by oxygen present in the air.
As the temperature of the heat-accumulating material increases, the pressure inside the reservoir remains constantly low. This i9 not only applicable to solid heat-accumulating materials, but also to materials which change over to the liquid phase when heated. This is because the vapour pressures of the commonly used heat-accumulating metal salts in liquid form are very low at the temperature levels occurring (below 1 Torr (= 1 mm mercury pressure)).
As a result, the reservoir walls are subjected to strongly varying and large mechanical stresses, because of the variable pressure difference between the variable heat transport medium pressure in the closed space on the one side, and the substantially constant, very low pressure in the reservoir on the other side.
The reservoir walls must thus be thick, since they have to be capable of withstanding the largest pressure differences occurring at the highest operating temperatures. Thick reservoir walls, however, have a high thermal resistance and lead to a heavy construction of the device.
The present invention provides an improved heating device in which the described dra~backs have been eliminated in a simple manner.
The invention provides a heating device for supplying heat to a heat user, comprising a closed space, at least one closed reservoir having one or more heat transmitting walls being arranged in the closed space and adapted to contain a heat-accumulating material, means for heating the heat-accumulating material, and an evaporable heat transport medium in the closed space for the transfer of heat from the heat-accumulating material to the heat user, wherein an evaporable heat transport medium is also present in each said reservoir for equalizing or substantially equalizing the pressure in said reservoir and the pressure in the closed space outside of the said reservoir, chemical reaction between the said heat-accumulating material and the said evaporable heat transport medium in each said reservoirs being avoided.

105~5 Substantially the same temperature prevails on both sides of the reservoir walls in any operating condltion. Because a quantity of heat transport medium has also been added to the reservoirs, the vapour pressure on both sides of the reservoir walls is also substantially the same at any temperature. The reservoir walls may now be thin walls having a low thermal resistance, which on the one hand reduces the weight of the device and makes it cheaper, whilst on the other hand there exists improved transfer of heat between the heat-accumulating material in the reservoirs and the heat trans-port medium outside the reservoir in the closed space.
This is achieved without special aids (for example, a pressure control device reacting to the pressure in the closed space) being used.
It may occur that the heat transport medium added to the reservoir tends to enter into a chemical reaction with the heat-accumulating material, so that the proper operation of the device might be disturbed.
In order to avoid such a possibility, a preferred embodiment of the heating device according to the invention is characterized in that in each of the reservoirs, a flexible, movable partition is provided between the heat-accumulating material and the evaporable heat transport medium.
The partition may be, for example, a metal foil which is made~ for example, of the same material as the reservoir walls.

.l ri ~

The invention furthermore relates to a hot-gas reciprocating machine, such as a hot-gas engine and a hot-gas turbine, comprising a working medium which performs a thermodynamic cycle in a closed working space, heat being applied to the said working medium from without. According to the invention, the hot-gas reciprocating machine is provided with a heating device as described.
The invention will be described in detail hereinafter with reference to the drawing which is diagrammatic and not to scale.
Figure 1 is a longitudinal sectional view of a~-heating device in which a small quantity of heat transport medium is present above the heat-accumulating material in the res-ervoir.
Figure 2 is a longitudinal sectional view of a heating device in which the heat transport medium and the heat-accumulating material inside the reservoir are separated from each other by a flexible, movable partition.
Fig. 3 is a longitudinal sectional view of a hot-gas reciprocating engine, comprising a heating device which is equipped with three reservoirs for heat-accumulating material The reference 1 in Fig. 1 denotes a closed ~ube which bounds a closed space 2 in which a closed reservoir 3 is arranged which is mainly filled with a heat-accumulating material 4, for example, a mixture of the metal salts NaF
and MgF2. Heat can be applied to this meltable salt mixture by means of the electrical heating elements 5 and 6 which are connected in series in the present embodiment and which comprise electrical supply wires 7 and 8 which are passed through the wall of tube l.
The reservoir 3 comprises heat-transmitting walls 3a-3b-3c wherethrough the heat-accumulating material can exchange heat with a heat transport medium 9, for example, sodium, in the closed space 2. The inner walls of tube l and the outer sides of the reservoir walls 3a-3b-3c are covered with a capillary structure lO, which is formed, for;
example, by one or more layers of metal gauze. Tube l furthermore comprises a heat-transmitting wall ll, wherethrough heat can be transferred to a heat user not shown. The ~-remainder of tube 1 is thermally ~nsulated from the surround-ings by means of a thermal-insulating material layer 12.
During operation, when the heat-ac~umulating material 4 has been "charged" by the heating elements 5 and 6 as the primary heat source, this material transfers heat as a secondary heat source, via the reservoir walls 3a-3b-3c, to heat transport medium 9 in space 2 which, consequently, evaporates and flows in the vapour phase to the heat-trans-mitting wall 11, because a lower temperature and pressure prevail at this wall. The heat transport medium vapour condenses on wall 11 while giving off heat thereto. The condensate is subsequently returned to reservoir 3 through the capillary structure 10 because of capillary forces while utilizing the surface tension of the condensate, the condensate subsequently spreading over the entire surface of the walls 3a-3b-3c via the capillary structure. Complete and uniform wetting of the reservoir walls is thus ensured.
At the start of the heat transport to the wall 11, when the heat-accumulating material 4 in the reservoir 3 and the heat transport medium 9 ln space 2 are both at their highest and mutually substantially equal temperature, the vapour pressure in space 2 also has its highest value. The vapour pressure of the mixture of metal salts in the reser-voir, however, ls then still below l Torr. In order to ensure that at any temperature the pressures on both sides of the reservoir walls 3a-3b-3c are equal or substantially equal, a quantity of evaporable heat transport medium, denoted by the reference numeral 9', has also been added to reservoir 3. At any temperature level of reservoir 3 and space 2, this heat transport medium 9' produces a vapour pressure which is equal to the vapour pressure of heat transport medium 9 occurring at the relevant tempera-ture level. Because of the negligibly small partial vapour pressure of the heat-accumulating material 4, this means that in substantially any operating condition substantially equal operating pressures prevail on both sides of the res-ervoir walls 3a-3b-3c. The said walls are thus constantly subjected to a low load (only the weight of the heat-accumu-lating material is of importance in this respect), so that the reservoir walls are thin and represent low thermal resistances in the heat exchange process.
The heating device shown in Fig. 2 comprises a tube 20 having a heat-transmitting wall 21, and a heat insulating layer 22. Inside the tube 20 there is arranged a reservoir 23 having heat-transmitting walls 23a-23b-23c which communicate, by way of a capillary structure 24, with tube wall 21. Space 25 inside tube 20 again contains a quantity of evaporable heat transport medium 26, in this case calcium. Inside reservoir 23 there is arranged a heating element 27 as a primary heat source in heat-accumu-lating material 28, in this case NaF, which is separated from a quantity of evaporable calcium 29 by a thin metal wall 30 which is connected to the inner wall of reservoir 23 along its circumference, but which is constructed to be flexible such that the contraction and expansion of the NaF can be comp~etely followed. Thus on both sides of the partition 30 always the same pressure prevails. The partition ensures that the calcium cannot react with the sodium fluoride to form calcium fluoride and free sodium.
The operation of the device is the same as that of the device dèscribed with reference to Fig. 1.

Fig. 3 shows a combination of ahot-gas engine and a heating device.
Tube 40 bounds a closed space 41 in which on the one s~de three reservoirs 42, 43 44 are arranged, and on the other side the heater parts 45 of a hot gas engine 46, are arranged.
The walls of tube 40 are covered on the inside with a capillary structure 47, whilst the heat-transmitting walls of the reservoirs 42, 43, and 44 are covered with a capillary structure 47 on the outer side. Inside the reservoirs a heat-accumulating material 48 is present, and above this material a small quantity of evaporable heat transport medium 49 is provided, the said medium being of the same kind as the heat transport medium present in space 41 (not shown).

The reservoirs 42, 43 and 44 are in open communic~tion with each other and are connected to a common filling and discharging duct 50 which is closed by means of a valve 51.
For the primary heat source use is made of an electrical heating element 52 which applies heat to heat accumulating material 48 directly as well as by way of evaporation of the heat transport medium in space 41. When this material gives off heat to the heat transport medium in space 41 via the heat-transmitting reservoir walls, the heat trans-port medium evaporates, flows to the heater pipes 45 and condenses thereon while giving off heat through the heater pipe walls to the working medium in the engine which flows through these pipes (for example, helium or hydrogen). The condensate formed on the heater pipes is returned, via the capillary structure 47, to the reservoirs 42, 43 44 so as to be evaporated again.
The heat transport medium 49 inside the reservoirs 42, 43, 44 again ensures that at~any operating temperature the pressure level in the reservoirs is at least substan-tially equal to that in the space 41.

Claims (2)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A heating device for supplying heat to a heat user, comprising a closed space, at least one closed reservoir having one or more heat trans-mitting walls being arranged in the closed space and adapted to contain a heat-accumulating material, means for heating the heat-accumulating material, and an evaporable heat transport medium in the closed space for the transfer of heat from the heat-accumulating material to the heat user, wherein an evaporable heat transport medium is also present in each said reservoir for equalizing or substantially equalizing the pressure in said reservoir and the pressure in the closed space outside of the said reservoir, chemical reaction between the said heat-accumulating material and the said evaporable heat transport medium in each said reservoirs being avoided.
2. A heating device as claimed in claim 1, wherein the heat-accumulat-ing material and the evaporable heat transport medium in the reservoirs show chemical affinity for each other, and in each reservoir said chemical reaction is avoided by the provision of a flexible, movable partition separating the heat-accumulating material from the evaporable heat transport medium.
CA226,161A 1974-05-03 1975-05-02 Heating device comprising a heat accumulator Expired CA1058155A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7405947A NL7405947A (en) 1974-05-03 1974-05-03 HEATING DEVICE EQUIPPED WITH A HEAT ACCUMULATOR.

Publications (1)

Publication Number Publication Date
CA1058155A true CA1058155A (en) 1979-07-10

Family

ID=19821293

Family Applications (1)

Application Number Title Priority Date Filing Date
CA226,161A Expired CA1058155A (en) 1974-05-03 1975-05-02 Heating device comprising a heat accumulator

Country Status (8)

Country Link
JP (1) JPS5712952B2 (en)
BE (1) BE828688A (en)
CA (1) CA1058155A (en)
DE (1) DE2517080C3 (en)
FR (1) FR2280049A1 (en)
GB (1) GB1506283A (en)
NL (1) NL7405947A (en)
SE (1) SE7504984L (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2717933A1 (en) * 1977-04-22 1978-10-26 Dornier System Gmbh LATENTHEAT STORAGE
US4220196A (en) * 1977-05-05 1980-09-02 U.S. Philips Corporation Heat storage device
GB2160965B (en) * 1984-06-13 1987-06-17 Electricity Council Thermal storage device
US4753072A (en) * 1987-02-11 1988-06-28 Stirling Power Systems Corporation Stirling engine heating system
IL130545A0 (en) * 1999-06-18 2000-06-01 Yeda Res & Dev Safety system for storage of high temperature heat
DE102005059029B4 (en) * 2005-12-10 2010-09-23 Juhl, Karsten, Dipl.-Ing. (FH) Method and device for long-term storage of heat
DE102007005331A1 (en) * 2007-01-29 2008-07-31 Kba-Metalprint Gmbh & Co. Kg Heat accumulator, has two accumulator elements, where hot medium rinsing stream withdrawing from one of hot ends of one of accumulator elements enters into another hot end of another element over rinsing path in loaded condition

Also Published As

Publication number Publication date
JPS50146959A (en) 1975-11-25
DE2517080C3 (en) 1979-09-20
BE828688A (en) 1975-11-03
GB1506283A (en) 1978-04-05
NL7405947A (en) 1975-11-05
FR2280049B1 (en) 1980-03-07
SE7504984L (en) 1975-11-04
DE2517080B2 (en) 1979-01-18
DE2517080A1 (en) 1975-11-20
JPS5712952B2 (en) 1982-03-13
FR2280049A1 (en) 1976-02-20

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