CA1057057A - Synthesis gas production by partial oxidation - Google Patents
Synthesis gas production by partial oxidationInfo
- Publication number
- CA1057057A CA1057057A CA222,035A CA222035A CA1057057A CA 1057057 A CA1057057 A CA 1057057A CA 222035 A CA222035 A CA 222035A CA 1057057 A CA1057057 A CA 1057057A
- Authority
- CA
- Canada
- Prior art keywords
- gas
- mixtures
- hydrocarbonaceous
- group
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 8
- 230000003647 oxidation Effects 0.000 title claims abstract description 8
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000007789 gas Substances 0.000 claims abstract description 83
- 239000000446 fuel Substances 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 26
- 230000008569 process Effects 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 19
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 14
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 13
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 13
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 12
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 8
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 31
- 229910052799 carbon Inorganic materials 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 239000001301 oxygen Substances 0.000 claims description 24
- 229910052760 oxygen Inorganic materials 0.000 claims description 24
- 239000011734 sodium Substances 0.000 claims description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 10
- 238000010791 quenching Methods 0.000 claims description 10
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 230000000153 supplemental effect Effects 0.000 claims description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 238000005201 scrubbing Methods 0.000 claims description 6
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 claims description 5
- 230000006872 improvement Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 238000010924 continuous production Methods 0.000 claims description 4
- 239000010779 crude oil Substances 0.000 claims description 4
- 239000008246 gaseous mixture Substances 0.000 claims description 4
- 150000004677 hydrates Chemical class 0.000 claims description 4
- 125000005609 naphthenate group Chemical group 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 3
- 150000004679 hydroxides Chemical class 0.000 claims description 3
- 239000011368 organic material Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims description 2
- 150000001720 carbohydrates Chemical class 0.000 claims description 2
- 235000014633 carbohydrates Nutrition 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 239000011280 coal tar Substances 0.000 claims description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 claims description 2
- 239000010742 number 1 fuel oil Substances 0.000 claims description 2
- 239000002006 petroleum coke Substances 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 239000010801 sewage sludge Substances 0.000 claims description 2
- 239000003079 shale oil Substances 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 239000011275 tar sand Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 150000001722 carbon compounds Chemical class 0.000 claims 1
- 238000001311 chemical methods and process Methods 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 238000004231 fluid catalytic cracking Methods 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000003915 liquefied petroleum gas Substances 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 230000000171 quenching effect Effects 0.000 claims 1
- 239000004071 soot Substances 0.000 abstract description 13
- 229910052751 metal Inorganic materials 0.000 abstract description 10
- 239000002184 metal Substances 0.000 abstract description 10
- 238000000926 separation method Methods 0.000 abstract description 4
- 230000003247 decreasing effect Effects 0.000 abstract description 2
- 150000002736 metal compounds Chemical class 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 230000036284 oxygen consumption Effects 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910001415 sodium ion Inorganic materials 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001021 Ferroalloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000357437 Mola Species 0.000 description 1
- 101100000210 Mus caroli Orm8 gene Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- -1 crude oil Chemical class 0.000 description 1
- GPWDPLKISXZVIE-UHFFFAOYSA-N cyclo[18]carbon Chemical compound C1#CC#CC#CC#CC#CC#CC#CC#CC#C1 GPWDPLKISXZVIE-UHFFFAOYSA-N 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US463710A US3920579A (en) | 1974-04-24 | 1974-04-24 | Synthesis gas production by partial oxidation |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1057057A true CA1057057A (en) | 1979-06-26 |
Family
ID=23841057
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA222,035A Expired CA1057057A (en) | 1974-04-24 | 1975-03-13 | Synthesis gas production by partial oxidation |
Country Status (14)
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4057510A (en) * | 1975-09-29 | 1977-11-08 | Texaco Inc. | Production of nitrogen rich gas mixtures |
GB2022128A (en) * | 1978-04-03 | 1979-12-12 | Basf Ag | Manufacture of gas containing hydrogen and carbon monoxide |
DE2817835C2 (de) * | 1978-04-24 | 1984-04-05 | Kraftwerk Union AG, 4330 Mülheim | Verfahren zur katalytischen Druckvergasung fester Brennstoffe mit Wasserdampf |
US4277365A (en) * | 1978-10-12 | 1981-07-07 | Texaco Development Corporation | Production of reducing gas |
US4668428A (en) * | 1985-06-27 | 1987-05-26 | Texaco Inc. | Partial oxidation process |
US4952380A (en) * | 1985-06-27 | 1990-08-28 | Texaco Inc. | Partial oxidation process |
US4668429A (en) * | 1985-06-27 | 1987-05-26 | Texaco Inc. | Partial oxidation process |
US4803061A (en) * | 1986-12-29 | 1989-02-07 | Texaco Inc. | Partial oxidation process with magnetic separation of the ground slag |
US5112527A (en) * | 1991-04-02 | 1992-05-12 | Amoco Corporation | Process for converting natural gas to synthesis gas |
DK169614B1 (da) * | 1992-08-13 | 1994-12-27 | Topsoe Haldor As | Fremgangsmåde og reaktor til fremstilling af hydrogen- og carbonmonoxidrige gasser |
DK171528B1 (da) * | 1993-12-10 | 1996-12-23 | Topsoe Haldor As | Fremgangsmåde til sodfri fremstilling af hydrogen- og carbonmonoxideholdig syntesegas |
ES2116795T3 (es) * | 1995-03-10 | 1998-07-16 | Basf Ag | Reutilizacion del gas de dilucion de la oxidacion parcial en fase gaseosa de un compuesto organico. |
US6313361B1 (en) | 1996-02-13 | 2001-11-06 | Marathon Oil Company | Formation of a stable wax slurry from a Fischer-Tropsch reactor effluent |
US5733941A (en) * | 1996-02-13 | 1998-03-31 | Marathon Oil Company | Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid |
US5861441A (en) * | 1996-02-13 | 1999-01-19 | Marathon Oil Company | Combusting a hydrocarbon gas to produce a reformed gas |
US6130259A (en) * | 1996-02-13 | 2000-10-10 | Marathon Oil Company | Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid |
US6201029B1 (en) | 1996-02-13 | 2001-03-13 | Marathon Oil Company | Staged combustion of a low heating value fuel gas for driving a gas turbine |
BR9709857A (pt) * | 1996-06-21 | 2002-05-21 | Syntroleum Corp | processo e sistema de produção de gás de sìntese |
MY118075A (en) * | 1996-07-09 | 2004-08-30 | Syntroleum Corp | Process for converting gas to liquids |
US5950732A (en) * | 1997-04-02 | 1999-09-14 | Syntroleum Corporation | System and method for hydrate recovery |
AU9690298A (en) | 1997-10-10 | 1999-05-03 | Syntroleum Corporation | System and method for converting light hydrocarbons to heavier hydrocarbons withseparation of water into oxygen and hydrogen |
CA2345613A1 (en) * | 1998-11-16 | 2000-05-25 | Frederick C. Jahnke | Removal of soot in a gasification system |
US6794417B2 (en) | 2002-06-19 | 2004-09-21 | Syntroleum Corporation | System and method for treatment of water and disposal of contaminants produced by converting lighter hydrocarbons into heavier hydrocarbon |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2754187A (en) * | 1952-12-02 | 1956-07-10 | Houdry Process Corp | Production of synthesis gas |
US2893941A (en) * | 1955-01-27 | 1959-07-07 | Exxon Research Engineering Co | Removing and preventing coke formation in tubular heaters by use of potassium carbonate |
US3097081A (en) * | 1958-09-23 | 1963-07-09 | Texaco Inc | Production of synthesis gas |
US3520823A (en) * | 1967-04-24 | 1970-07-21 | Texaco Inc | Synthesis gas process |
US3528930A (en) * | 1968-05-29 | 1970-09-15 | Texaco Inc | Production of synthesis gas |
US3607157A (en) * | 1969-07-23 | 1971-09-21 | Texaco Inc | Synthesis gas from petroleum coke |
-
1974
- 1974-04-24 US US463710A patent/US3920579A/en not_active Expired - Lifetime
-
1975
- 1975-03-13 CA CA222,035A patent/CA1057057A/en not_active Expired
- 1975-03-19 JP JP50032523A patent/JPS5844601B2/ja not_active Expired
- 1975-03-24 GB GB1211375A patent/GB1464347A/en not_active Expired
- 1975-03-25 IN IN608/CAL/75A patent/IN143923B/en unknown
- 1975-03-25 ZA ZA00751900A patent/ZA751900B/xx unknown
- 1975-04-02 NL NL7503890A patent/NL7503890A/xx unknown
- 1975-04-09 YU YU909/75A patent/YU39317B/xx unknown
- 1975-04-15 FR FR7511618A patent/FR2268861B1/fr not_active Expired
- 1975-04-16 NO NO751360A patent/NO140627C/no unknown
- 1975-04-16 BE BE155469A patent/BE828010A/xx not_active IP Right Cessation
- 1975-04-17 DE DE2516908A patent/DE2516908C3/de not_active Expired
- 1975-04-22 BR BR3105/75D patent/BR7502442A/pt unknown
- 1975-04-22 SE SE7504654A patent/SE390953B/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
YU90975A (en) | 1982-05-31 |
DE2516908A1 (de) | 1975-11-13 |
DE2516908C3 (de) | 1980-05-08 |
NO751360L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-10-27 |
FR2268861A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-11-21 |
IN143923B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-02-25 |
YU39317B (en) | 1984-10-31 |
NL7503890A (nl) | 1975-10-28 |
AU7966475A (en) | 1976-10-07 |
US3920579A (en) | 1975-11-18 |
NO140627B (no) | 1979-07-02 |
BE828010A (fr) | 1975-10-16 |
BR7502442A (pt) | 1976-03-09 |
GB1464347A (en) | 1977-02-09 |
SE390953B (sv) | 1977-01-31 |
JPS5844601B2 (ja) | 1983-10-04 |
JPS50139803A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1975-11-08 |
DE2516908B2 (de) | 1979-08-30 |
ZA751900B (en) | 1976-07-28 |
NO140627C (no) | 1979-10-10 |
SE7504654L (sv) | 1975-10-27 |
FR2268861B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-01-11 |
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