CA1057015A - Network structures and methods of making same - Google Patents

Network structures and methods of making same

Info

Publication number
CA1057015A
CA1057015A CA189,852A CA189852A CA1057015A CA 1057015 A CA1057015 A CA 1057015A CA 189852 A CA189852 A CA 189852A CA 1057015 A CA1057015 A CA 1057015A
Authority
CA
Canada
Prior art keywords
main
sheet
ribs
tie
filaments
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA189,852A
Other languages
French (fr)
Inventor
Charles W. Kim
Chia-Seng Liu
Richard Macduff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules LLC
Original Assignee
Hercules LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules LLC filed Critical Hercules LLC
Priority to CA314,904A priority Critical patent/CA1073173A/en
Application granted granted Critical
Publication of CA1057015A publication Critical patent/CA1057015A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D28/00Producing nets or the like, e.g. meshes, lattices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D28/00Producing nets or the like, e.g. meshes, lattices
    • B29D28/005Reticulated structure comprising reinforcements of substantial or continuous length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/423Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/04Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/47Processes of splitting film, webs or sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/108Flash, trim or excess removal

Abstract

Abstract of the Disclosure Methods of making network structures include forming on one side of a sheet of thermoplastic polymer a plurality of parallel continuous m??? ribs and forming on the other side of the sheet in a different direction a plurality of parallel discontinuous tie ribs. The tie ribs are discontinuous in the areas where they cross over the main ribs to eliminate any substantially increased thickness at the cross-over points of the main ribs and tie ribs.
The ribbed sheet thus formed is drawn in either one direction or in two preferably perpendicular directions to open the sheet into a network structure and to orient the main ribs and preferably also to crient the tie ribs.

Description

1~57~.S Kim, Liu and MacDuff Case 1 This invention relates to new and improved network struc-tures and methods for maXing such network structures, and particu-larly to network structures and methods for making them by emboss-ing or forming continuous main ribs in one side of a thermoplastic polymeric sheet and discontinuous tie ribs on the other side of the sheet so as to permit spontaneous fibrillation or opening of the network structure upon drawing in one direction or in two preferably perpendicular directions and to provide a uniform open network structure having desirable strength characteristics.
In the manufacture of networks, it has previously been proposed to form continuous diagonal grooves in one direction in one side of a sheet of plastic material and continuous diagonal grooves in the opposite direction on the other side of the sheet ~o that upon subjecting the sheet to biaxial stretching the thin parts of the sheet, at the crossing points of the grooves, split and form perforations thereby opening the material into a network.
For example, see U.S. patent 3,488,415 to A. G. Patchell et al.
The networks therein disclosed are formed in such a manner as to have thicker masses at the points where the ridges cross, which 20 behave as discrete areas of reinforcement, since on biaxial stretching or drawing of the embossed sheet the thick areas where the ridges cros~ orient only to a limited extent if at all. The tensile strength and tear characteristics of such a network are relatively poor because the presence of the unoriented thick areas weakens the tensile strength and tear resistance of the network 90 prepared, and such a network is not uniform in appearance. U.S.
patent 3,500,627 to Charles W. Kim di~closes making yarn by form-ing on one side of a ribbon of plastic material a plurality of parallel filament forming ribs and on the other side a plurality i 30 of fibril forming cross-ribs arranged at an acute angle to the filament forming ribs. The ribbon is then uniaxially oriented and mechanically fibrillated by means of a toothed fibrillating device to break the fibril forming ribs and form a yarn having fibrils ex-tending laterally therefrom. Use of mechanical fibrillation makes
- 2 - ~

. ,. ~ . . .

-` 1057015 reproducing uniform network structures very difficult.
The subject invention relates to network structures and methods of making network structures by forming on one side of a sheet of thermoplastic polymeric material a plurality of parallel continuous main ribs interconnected by webs of reduced thickness, and forming on the other side of the sheet a plurality of parallel discontinuous tie ribs interconnected by webs of reduced thickness.
Thus, the invention provides a method of making a network structure comprising; forming on one side of a sheet of thermoplastic polymer material a plurality of parallel continuous main ribs interconnected by webs of reduced thickness extending in a first direction; forming on the other side of said sheet a plurality of parallel discontinuous tie ribs extending in a second direction different than said first direction, said tie ribs being formed opposite the webs interconnecting said main ribs and having no substantial part thereof crossing over a main rib; and drawing the sheet in at least one direc-tion to separate the main ribs into continuous main filaments and to separate the tie ribs into tie filaments to form a network structure having main fila-ments thereof being substantially uniformly and continuously oriented.
By forming the tie ribs discontinuously to eliminate substantially increasing the thickness of the main ribs at the cross-over points with the tie ribs, it is possible, among other things, to spontaneously open the ribbed ~ sheet into a network by drawing, and to orient the main ribs continuously and ;l uniformly, thereby making the main ribs very strong. It is this feature which provides a network structure having high tensile strength in the direction parallel to the main ribs. Adtitionally, by having continuous main ribs which are uniformly oriented, the tear strength in the direction across the main ribs is greatly enhanced.
After the main and tie ribs are formed in the plastic sheet the sheet is drawn in a direction to effect orientation of the main ribs continu-ously and uniformly, and may be drawn in two different, preferably perpendicu-~ - 3 -' .. .. . . . .

~(3 57~15 lar, directions to orient both the main and the tie ribs. For example, when the main ribs are formed in the machine direction and the tie ribs are formed in the cross-machine direction a network structure may be formed with only one draw, in this instance in the machine diTection. Alternatively, a more open network structure can be formed by simultaneous or sequential drawing in both the machine and cross-machine directions. In sequential drawing of a sheet having main ribs in the machine direction, the first draw is customarily in the cross-machine direction. Upon drawing, the thinnest areas in the sheet namely the areas where the webs between the main ribs cross the webs between the tie ribs, become oriented and normally open up spontaneously, leaving a uniform pattern of holes or voids in the sheet. Under some conditions and levels of draw the web openings may not - 3a -r occur during the initial draw but may occur only during the subse-quent perpendicular draw. In any event, the web openings occur spontaneously and thus there is no need for mechanical fibrilla- t tion. This spontaneous fibrillation or opening of the webs con-verts or forms the dicontinuous tie ribs into tie filaments and the main ribs into main filaments. Hereinafter, the term tiè ribs shall be used to refex to the tie ribs embossed on the sheet which are ordinarily interconnected by webs. After the webs split or open up, the tie ribs are separated and will be referred to as tie 10 filaments. Likewise, the main ribs are referred to as main ribs while interconnected by webs, but after the webs split or open, the main ribs are separated and will be referred to as main fila-ments. These main filaments are continuous if in the machine direction, or if at an angle to the machine direction, are contin-uous from one edge of the sheet to the other.
It has been found that highly desirable strength character-istics are ohtainable in a network structure having main filaments in one direction crossed by discontinuous tie filaments in another direction 80 that all, or substantially all, of the orientation at 20 the cross-over points of the main and tie filaments is applicable to the main filaments. The tie filaments if desired may be smaller in cross section than the main filaments and are usually oriented to provide sufficient structural integrity for the network struc-; ture, tending to keep it flat and prevent folding, thus maintain-; ing the main filament~ in parallel and uniformly spaced relation.
The single layer pla~tic network structures thus formed are dimen-sionally stable, self-supporting, easy to handle, and have high tensile strength in the direction of the main filaments and high tear resistance in the other direction. Such nets are particularly 30 useful for reinforcing paper products and nonwoven fabrics based on staple fibers and for covering absorbent pads.
Additionally, the network structures so formed may be made into multi-layer fabrics by bonding together two or more layers of network structures having the same or different configurations so ' . . .

~ S7~15 that the main filaments cross in various directions to provide a multi-layered product having certain desired strength characteris-tics. For example, orthogonal cons~ructions can be made wherein the main filaments of one layer cross at 90 to the main filaments of another layer to simulate the appearance and physical proper-ties of woven fabrics and to provide high strength and tear resist-ance in two directions. Diagonal constructions, wherein the main filaments of the two layers cross preferably at about 90 to each other with the main filaments of both layers being at an angle to 10 the machine direction of the fabric, possess stretch and reaovery properties in the machine direction similar to ~hose of knitted fabrics. Fabrics made from three or more layers of networks each having the main filaments in different directions have excellent dimensional stability, high strength and tear resistance in all directions and high burst strength. For example, triaxial con-structions, wherein a diagonal construction is utilized having interposed between the two layers a network having main filaments formed in the machine direction, provide high bursting strength with minimum weight. Isometric constructions, wherein the main 20 fllaments of at least four layers are positioned at about 45 angles to each other, provide strength in all directions with di-mensional ~tability heretofore unattainable in woven, knit or other nonwoven fabric structures with equivalent unit weight.
Additionally, the subject network structures which have main filaments in the machine direction can be made into monofila-ments, tapes or yarns by separating the network structure into strips which may be subsequently fibrillated, and twisted or bulked to entangle the main filaments of the strips. If desired, the strips may also be crimped or false twisted.
Other advantages of the present invention will be apparent from the following detailed description of the invention when con-sidered in conjunation with the following detailed drawings, which drawings form a part of the specification. It is to be noted that ; the drawings illustrate only typical embodiments of the invention 'I

-and are therefore not to be considered limiting of its scope, for the inven-tion may admit to other equally effective embodiments.
~ igure 1 is a perspective schematic view illustrating apparatus for embossing ribs on both sides of an advancing sheet of plastic material in accordance with the principles of this invention.
Figure 2 is an enlarged perspective view of a portion of the embossed sheet shown in Figure 1.
Figure 3 is an enlarged perspective view of the tie rib side of the sheet shown in Figure 2 illustrating the discontinuities in the tie ribs.
Figure 4 is an enlarged perspective view of a portion of the network structure obtained after drawing and orienting the embossed sheet shown in Figures 2 and 3 in two directions.
Figure S is a perspective schematic view illustrating other appara-tus for embossing continuous main ribs on one side of a sheet and discontinu-ous tie ribs on the other side of the sheet.
Figure 6 is an enlarged perspective view of the tie rib side of the embossed sheet made in accordance with the principles of this invention.
Figure 7 shows one side of a portion of the network structure made ater stretching in two directions the sheet shown in Figures 5 or 6.
Figure 8 is a plan view illustrating a portion of a network structure having main filaments in the machine direction and tie filaments in the cross-machine dircction.
Figure 9 is a plan view illustrating a portion of a network struc-ture having main filaments in the cross-machine direction and tie filaments in the machine direction.
Figure 10 is a plan view illustrating a portion of a network struc-ture having main filaments formed at an angle to the machine direction with tie filaments formed in the machine direction.
Figure 11 is a plan view illustrating a portion of a network struc-ture having main filaments formed at an angle to the machine direction with , 1~'' ~

. - - ,- .. . . . . - . .: , . : - . -- ~057015 tie filaments formed perpendicular to the main filaments.
Figure 12 is a perspective schematic view illustrating apparatus for making multi-layer fabric structures in accordance with the principles of the subject invention.
Figure 13 is a perspective schematic view illustrating other appara-tus for making multi-layer fabric structures in accordance with the principles of this invention.
Figure 14 is a plan view illustrating a portion of a three-layer triaxial fabric with one layer having main filaments formed in the cross-machine direction and the other two layers having their main filaments formedat equal opposite angles to the cross-machine direction main filaments.
Figure 15 is a plan view illustrating a portion of two-layer diago-nal fabric formed by bonding together two network structures having their main filaments formed at equal opposite angles to the machine direction and desir-ably, but not necessarily, perpendicular to each other.
Figure 16 is a plan view illustrating a portion of a four-layer iso-metric fabric made by bonding together in any desired order the two layers shown in Figure 12 and the two layers shown in Figure 15.
Figure 17 is a perspective view illustrating apparatus for reinforc-ing paper, foil, nonwoven fabrics or films by utilizing a central network struc-ture mad0 in accordance with the principles of this invention.
Figure 18 is a view il:lustrating apparatus for making network struc-tures into yarns, in accordance with our patent application Serial No. 314,904 ` which is divided from this application.
Figure 19 is an enlarged view of the leasing rods of Figure 18 used to separate or tear the network structure into strips.
Figure 20 is an enlarged plan view of a portion of a strip before fibrillation.
Figure 21 is an enlarged plan view of the strip of Figure 20 after fibrillation illustrating the broken tie filaments.
Figure 22 is a view of a portion of an air jet interlaced multi-filament yarn having protruding side fibers.
_ 7 --,~ .
~ .~

57~5 FIG. 23 is a view of a portion of a bulked entangled multi-filament yarn.
Referring now to FIGS. 1 and 2, there is shown an embossing roll 21 having a plurality of grooves 22 formed therein for form-ing a plurality of transverse main ribs 23 on an advanclng sheet of thermoplastic polymer material 24 with the ribs 23 being inter-connected by webs 25 of reduced thickness. Another embossing roll 26 having a plurality of annular or helical grooves 27 formed therein is positioned opposite roll 21 for forming a plurality of 10 longitudinal tie ribs 28 on the other side of the sheet 24 with the tie ribs being interconnected by webs 30 of reduced thickness.
The embossing rolls 21 and 26 rotate in the directions shown hy the arrows. There are a variety of different ways to effect the double embossin~ described herein. One method is to feed a molten plastic sheet, such as 24, coming directly from an extrusion die into the nip of two counter-rotating embossing rolls, such as 21 and 26, which are urged toward each other by facilities which are not shown. The desired separation between the rolls and ultimately the thickness of the embossed sheet is readily controlled by regu-20 lating the thic~ness of the extruded sheet entering the embossing rolls and the pressure between the two embossing rolls. The roll temperatures typiaally are internally controlled and serve to quench and solidify the molten plastic forming the desired embossed patterns on each side.
Alternatively, a previously cast flat sheet or film may be re-heated to its softening temperature and then advanced through a palr of embossing rolls, such as 21 and 26. Another method may utilize a polymer which i9 in powder form and which is introduced J into the nip between two heated rolls, not shQwn, to permit the 30 heated rolls t~ melt and soften the polymer and form it into a sheet which is then advanced between two embossing rolls such as 21 and 26. An additional method is to pass a previously cast flat sheet or film between two embossing rolls pressed together under a sufficiently high pressure so that the embossed patterns are pressed ~ 5~15 into the sheet without having to melt or soften the sheet. It is evident that many embossing techniques may be utilized to carry ;
out the principles of this invention.
It has been found that by making the tie ribs discontinuous where they cross over the main ribs a network structure can be made having uniformly spaced main filaments oriented uniformly and continuously along their lengths and being quite uniform in cross-section. The discontinuous tie rib configuration eliminates any thick areas where the main filaments and tie filaments cross which 10 would cause those areas to remain either unoriented or only slight-ly oriented on drawing. While the size of the main ribs may be equal to the size of the tie ribs, it has been found desirable to make the main ribs larger than the tie ribs thereby permitting among other things, the main ribs to be drawn and oriented to a greater degree so that most of the strength of the network is attributed to the main ribs. In this instance, most of the poly-mer used in the network is in the main ribs and thus provides most of the s~ructural strength, while the tie ribs provide structural integrity. It has been found that a desirable range of the ratio 20 of the cross-sectional area of the main ribs to the cross-sectional area of the tie ribs is between 1.5:1 to 100:1, with the ratio of the height of the main ribs to the thickness of the webs between the main ribs being at least 3:1 or greater. Thus, as shown in FIG. 2, the cross-sectional area Al of the main ribs and the cross-sectional area A2 Of the tie ribs each includes the web area adja-cent to the base of each respective rib. Also identified in FLG.
2 is the height Tl of the main ribs and the thickness T2 of the webs interconnecting the main ribs.
The cross-sectional shape of the ribs formed may vary. They 30 may be semi-circular, rectangular, triangular, truncated, or any other desiredj shape. Furthermore, the shapes of the main and tie ribs may be the same or different. Likewise, the shape and size of the grooves separating the main or tie ribs is not critical. The grooves may be narrow so that the ribs are close together, or wide _ g _ ~ 057~5 so that the ribs are more widely separated. Furthermore, the tie ribs may be spaced farther apart than the main ribs or vice versa.
The size of the openings in the network structure may be controlled to some degree by controlling the spacing of the main and tie ribs.
Additionally, the direction of the main ribs is not criti-cal. The main ribs may be formed in the machine direction of the sheet, or transverse to the machine direction, i.e., 90 thereto, or at any angle in between. With the main ribs formed in either the machine direction or the transverse direction, orienting the 10 main ribs along their longitudinal axes is easily accomplished by use o either a conventional linear differential speed draw roll device or a conventional tenter. Likewise, if the embossed ribs are diagonal to the machine direction, orientation of the ribs and net formation may be achieved using the same type of equipment. In orienting main ribs which are formed at an angle to the machine direction along their longitudinal axes, it is sometimes advantag-eous to utilize a long draw gap linear drawing unit so that upon drawlng in the machine direction the sheet is permitted to neck down and cause orientation of the main ribs principally along their 20 longitudinal axe9. In drawing in such a manner, it is usually de-sirable that the linear draw be preceded by a cross-machine direc-tion orlentation by passing the sheet through a tenter.
The direction of tha tie ribs on the reverse side of the sheet should be at an angle to that of the main ribs, which in many ca5es is desirably 90, but can also be other angles. Any angle between about 15 and 90 between the directions of the main ribs to the tie ribs is acceptable.
1 Re~erring to FIG. 3, there is shown the tie rib side of the embossed sheet shown in FIG. 2. Note that the tie ribs 28 are 30 discontinuous at 31. The discontinuous tie ribs are formed by either aontrolled embossing to obtain a "cave-in" effect or by us-ing a discontinuous tie rib embossing roll. FIG. 3 illustrates an embogsed sheet having continuous main ribs 23 and discontinuous tie ribs 28 made under selected and controlled embossing conditions ':
3 05~ 5 wherein on the tie rib side of the sheet there are cave-ins or dis-continuities 31 in the tie ribs 28 where they cross the main ribs 23, thereby making the tie ribs 28 discontinuous.
In using grooved embossing rolls such as 21 and 26 shown on FIG. 1, it is possible to control the pattern resulting from con-tact with the main rib and tie rib rolls so as to obtain a "cave-in" effect at the cross-over points of the respective ribs result-ing in discontinuous tie ribs. The factors contributing to this effect are the thickness of the sheet being embossed, the tempera-10 ture of the polymer being embossed, the embossing roll temperatures,the po~ition of first contact of the molten sheet with the emboss-ing rolls, and'the time of contact of the embossed sheet with one roll. Discontinuity development in the tie rib embossed pattern are accentuated by use of thin polymer sheets, by having the molten polymer relatively cool before touching the embossing rolls, by causing the shéet to contact one of the rolls, preferably the one with the larger grooves, for a ~hort distance before entering the nip between the rolls, and by maintaining the embossed sheet in contact with on~ of the rolls, preferably the one with the larger 20 groove pattern, for a distance after leaving the nip between the rolls. The degree of penetration of the polymer into the grooves of the roll with the finer pattern, and shrinkage of the polymer as it c0019 after being embossed in'the nip between the rolls are undoubtedly factors contributing to the unique results of this method. Accordingly, by such controls, the pattern of the grooves 22 of main rib embossing roll 21 will cause formation of continu-OU8 ribs 23 on one side of the sheet, but the embossed tie ribs 28 will be made discontinuous as shQwn in FIG. 3. After orientation, this type of Qmbossed pattern results in a strong and inexpensive 30 network structure, among other reasons,'because it causes a higher proportion of the polymer to be present in the main ribs than when employing other embossing conditions. Additionally, the discon-tinuous tie ribs 28 are further advantageous in that they permit the main ribs 23 to be completely and uniformly oriented since ~ S7~1S
there is essentially no cross-over of the main ribs 23 and the tie ribs 28.
When the embossed sheet having a first pattern of continu-ous main ribs on one side and a second pattern of discontinuous tie ribs on the other side is drawn, the thin areas of the sheet, namely the areas where webs 25 and 30 cross, spontaneously split, forming openings. After the second draw is completed, if desired, a network structur0 such as or similar to that shown in FIG. 4 is achieved. The main ribs 23 of the embossed sheet shown in FIGS.
10 1-3 have been separated into main filaments 53 which are oriented continuously and uniformly. The tie ribs 28 have also been sepa-rated and oriented into tie filaments 54 which interconnect the main filaments 53 and keep them uniformly spaced apart.
Discontinuities in the tie rib embossing pattern can also be obtained in an alternate way, such as by using a continuous main rib embossing roll 61 and a discontinuous tie rib embossing roll 63 a~ shown in FIG. 5. The main rib embossing roll 61 has a plurality of parallel annular grooves 62 formed therein for form-ing main rlbs 67 in a sheet 70. The tie rib embossing roll 63 has 20 a plurality of discontinuous grooves or recesses 64 formed therein parallel to the longitudinal axis of the roll for forming discon-tinuous tie ribs 68. In each row of grooves 64 across the emboss-ing roll 63, each groove or recess 64 is blocked from the adjoin-ing recess by a blocking section 66 of the roll 63. Desirably, the width of the blocking section 66 is equal to or slightly less than the width of the groove 62 of the main rib embossing roll 61. It is to be noted that the tie ribs are not continuous across the em-bossed sheet, but rather are continuous only from one main rib 67 to the ad~oining main rib having a discontinuity at area 6g, as 30 shown clearly in FIG. 6. Because of the configuration of the roll 63, little or no polymer is left on the tie rib side of the ~heet directly opposite the main rib 67. By embossing a sheet 70 in this ; manner, and subsequently drawing in one or two directions, the main ribs can be hi~hly oriented continuously and uniformly. Usipg ;'' , ., , , .

S7~15 embossing roll 63 in this manner assures that little or no polymer is formed across the m~in ribs 67. This allows for high orientation of the main ribs and optimi~es the polymer distribution. In view of the fact that there is little or no substantial mass of polymer crossing over the main ribs when using either the controlled em-bossing method described above to obtain the cave-in effect shown in FIG. 3, or the disaontinuous tie rib forming method as des-cribed above and shown in FIG. 5, the ratio of cross-sectional areas of the main ribs to the tie ribs is not significant. Accord-10 ingly, equal size main and tie ribs will work satisfactorily, aswell as different size main and tie ribs. However, to obtain low unit weights or iner network patterns, e.g., more square yards of net per ounce of pclymer, it may be desirable to use a pattern having more and smaller tie ribs than main ribs. An advantage of the controlled embossing method using two embossing rolls having continuous grooves such as shown in FIG. 1, over the d iscontinuous tie rib forming method using a special roll such as 63 having dis-continuous grooves 64 as shown in FIG. 5, is that there is no need in the former to precisely and accurately register and align the 20 embossing rolls as is required in using the FIG. 5 apparatus.
FIG. 7 shows a portion of a network structure formed after drawing the embossed sheet shown in FIG. 5 in both the cross-machine and the machine directions. Note that the main filaments 71 flatten out somewhat ater drawing, and that the tie filaments 72 uniformly space the main filaments 71 apart. The tie filaments 72 have their ends integrally joined to the main filaments 71, and do not extend across the main filaments 71.
In drawing the embossed sheet, the preferred amount of draw would depend on such factors as the polymer employed, the emboss-3G ing pattern employed, and the degree of separation of the mainfilaments desired in the final network structure. Customarily, the first drawing or orientation step involves drawing the embossed sheet in a direation generally transverse to the direction of the ; main ribs to cause orientation of the thinner areas of plastic . .

S7~1~
material between the main ribs. Referring, for example, to the embossed sheet shown in FIG. 2, since the main ribs 23 are formed in the cross-machine direction, the first draw would normally be, but is not necessarily, in the machine direction. This draw could be effected by using conventional linear differential speed draw rolls. This orientation, which is usually 1.5X or greater, gener-ally results in incipient or actual voids or openings being formed between the main ribs with the formation of small tie filaments spanning the openings between the main, as yet unoriented, ribs or 10 filaments.
As an alternative, it may be desirable to carry out an initial draw such as, for example, up to 2X, in the direction of the main ribs prior to the drawing step transverse to this direc-tion. This initially orients and strengthens the main ribs and tends to prevent any possible distortion or development of cross-orientation of the polymer in the cross-over areas during the transverse orientation.
The second orientation step is normally carried out in a direction generally parallel to the main ribs. Thus, referring 20 again to the embossed sheet shown in FIG. 2, the second orienta-tion would be in the cross-machine direction. This transverse drawing step coul~ be carried out on a conventional tenter. The transverse draw causes orientation of the main ribs along their longitudinal axes and separation of the small, connecting tie filament~. The amount of draw will determine the strength and size of the resulting main filaments. It can vary from as low a~
1.5X to lOX or greater. The maximum draw will depend on the ori-entation characteristics of the polymer employed, among other things. Temperatures for drawing will vary depending upon the 30 polymer employed but generally will be slightly lower than those employed for orienting flat sheets of the same polymer. While reference has been made to first and second sequential drawing steps, both draws may be carried out simultaneously if desired.
The network structures produced by the foregoing methods ;

.

S7~15 contain as desired longitudinal transverse or oblique oriented main filaments interconnected by normall~- lower denier, oriented tie filaments, with the main filaments having orientation contin-uously over their lengths. Examples of the different configura-tions of network structures that can be made are shown in FIGS. 8, 9, 10 and 11. In FIG. 8, a network structure is shown having main filaments 73 extending in the machine direction, the direction ~f the arrow, and tie filaments 74 being formed in the cross-machine direction 90 to the machine direction. In FIG. 9, the main fila-10 ments 75 are formed transverse to the machine direction, indicatedby the arrow, and the tie filaments 76 are formed parallel to the machine direction. In FIG. 10, the main filaments 77 are formed at an angle to the machine direction, shown by the arrow, and the tie filaments 78 are formed parallel to the machine direction.
Alternatively/ the tie filaments may be formed in the cross-machine direction or so they are perpendicular to the main filaments 77 such as shown by tie filaments 56 in FIG. 11. When the main fila-ments 78 are formed at an angle of 75 or less to the machine direction, in order to orient such filaments, it is sometimes de-20 sirable to draw in the machine direction while permitting neckingdown of the network structure. Ordinarily, in making this config-uration, the cross-machine draw in a tenter, if desired, comes first, followed by the machine direction draw allowing neck-down.
It is apparent that many other configurations of network struc-tures may be made in accordance with the principles of this inven-tion, having the main filaments at any desired angle wherein maxi-mum ten~ile strength is desired and the tie filaments formed at an angle relative to the main filaments.
The network structures described herein have good tensile 30 strength in the direction of the main filaments which reflects the degree and uniformity of orientation along the length of these filaments. This strength is lower in the opposite direction be-cause of the smaller size of the interconnecting tie filaments.
The tear-strength is high in the direction transverse to the main .

57(315 filaments because of the strength of t~e main filaments. It is tobe noted that the network structures such as shown in FIGS. 4 and 7 have tie filaments which are discontinuous and integrally join the main filaments, without there being notches at the junctures as is characteristic of many netw~rk structures prepared by previ-ous methods. Such notches at the junctions or cross-overs enable a network to tear easily in either direction.
The subject network structures, while useful as single layer network structures, may also be employed to prepare very 10 useful multi-layer fabric ~tructures. Referring to FIG. 12, there is shown one network structure, generally ~esignated as 81, having main filaments 82 formed in the machine direction and tie fila-ments, not shown, formed in the cross-machine direction being lam-inated or bonded to a second network structure, generally desig-nated as ~3, having main filaments 84 formed in the cross-machine diraction. Tie filaments are not shown in any of the network structures shown in FIGS. 12-17 to facilitate illustration and description of the fa~ric structures. Nevertheless, the tie fila-ments are present in each network and may be assumed to be as 20 shown in FIGS. 8-11 or as previously described. One way of bond-ing the two network~structures 81 and 83 together is to pass them through rolls 79 and 80 into a preheater 95 to heat the networks under tension withcut adversely affecting the orientation thereof and then advance them into the nip of two heated calendar rolls 86 and 87 to bond the plastic materials to each other. Rolls 79 and 80 rotate very slightly slower than rolls 86 and 87 to main-tain the networks 81 and 83 under tension during heating to avoid loss of orientation. Likewise, it is desirable to use a tenter, a series of closely spaced rolls or other means to prevent lateral 30 shrinkage of the networks in this area. This bonding or lamina-tion prccess forms a two-layer fabric which has the appearance and physical properties of a woven fabric having high strength and good tear resistance in both the machine and cross-machine directions. Such a fabric has substantially no stretch in the -- 1~ --, - ,;

-~ ` 1057~5 machine and cross-machine directions/ but does stretch on the bias.
Three or more layer fabrics can also be prepared with the main filaments-of each being formed in different directions to provide fabrics having excellent dimensional stability, high strength in all directions and high burst strength. As shown in FIG. 13, a first layer-or network structure, generally designated as 88, has main filaments 89 formed at an angle to the machine direction which is indicated by the arrow. A second central layer lO or network structure 91 has main filaments 92 formed in the machine directien. A third layer or network structure 93 has main filaments 94 formed at an acute angle to the machine direction opposite that of the angle of layer 88. The three layers pass through the nip of rolls 85 and 90, into a preheater 95 and through the nip of two heated calendar rolls 96 and 97 which bonds the three layers together at their cross-over points. The bonded fabric may then pass through an annealing unit 98 and is taken up on take-up spool 99. If desired, a conventional tenter or other means could be used to maintain tension in the cross-machine direc-20 tion during heating and bonding. Such three or more layer fabrics prcvide strength in all directions and dimensional stability unob-tainable in wcven, knitted or other nonwoven fabric structures with equivalent weight. Such fabrics provide good stretcha~ility in the cross-machine direction.
Referring to FIG. 14, there is shown a similar three layer fabric, except that it has a central layer having its main fila-ments lO0 in the cross-machine direction. Such a fabric has good stretchability in the machine direction. t If the central network layer 91 shown in FIG. 13 is elimi-30 nated, a two-layer fabric such as shown in FIG. 15 is provided having the main filaments 89 on one layer 88 extending at an ~ngle, such as 45 to the machine direction, and the second layer 93 hav-ing main filaments 94 extending oppositely at an equal angle to the mac~ine direction. If the main filaments 89 and 94 are formed ~. -S7~15 45 to the machine direction then main filaments 94 will be perpen-dicular to the main filaments 89. Such a network structure with the central layer 91 eliminated has stretch and recovery properties in the machine and cross-machine directions similar to those of a knitted fabric. That is, the fabric will stretch both in the machine and cross-machine directions.
If desired, the three-layer stnlcture of FIG. 13 could be made into a four-layer isometric fabric structure by bonding or laminating as a top layer, a network structure such as 83 shown in 10 FIG. 12 which has main filaments 84 extending in the cross-machine direction. Such a four-layer isometric fabric is shown in FIG.16.
For the most u~iform properties in such a fabric, it is preferred -that the main filaments 89 and 94 be formed at 45 angles to the machine direction. This fabric is dimensionally stable and has ~ubstantially no stretch in any direction.
Referring to FIG. 17, a single layer plastic network struc-ture, generally designated at 101, having its main filaments 102 formed in the cross-machine direction is bonded between two layers 103 and 104 of paper, film, foil or nonwoven web such as carded, 20 garnetted or air-laid fiber webs, or any combinations thereof by first passing the network structure 101 and the layer 104 through an adhesive applicator 106. Then layer 103 is bonded to the other two layers by curing the adhesive as by passing them through a heated zone such as calender rolls 107 and 108, after which the xeinforced paper, nonwoven fiber webs, film or foil structure is taken up on take-up spool 109.
It can be appreciated that many different multi-layer fabrics can be prepared in accordance with the principles of this invention by taking one network structure having main filaments in 30 one direction and bonding thereto one or more other networks hav-ing main filaments in different directions. Then the layers may be bonded together into a fabric in many ways including applying or spraying an adhesive between the layers and passing them through an oven and calender rolls to bond the layers together, or by ~ - 18 -.

7~ 5 passing the layers only through a pair of heated calender rolls toheat bond them together, or by using ultrasonic bonding, or spot bonding or any other known conventional bonding technique.
Among the many uses of the subject network structures, either as single or multi-layer fabrics, are in sanitary napkins, diapers, incontinence pads, tampons, surgical dressings, surgical sponges, burn dressings and reinforcing material for paper and paper products, films and other nonwovens and woven fabrics. For example, a network may be used to reinforce masking tape or wall-10 paper, thereby contributing increased tensile strength and tearresistance properties. In the case of paper and staple fiber non-wovens, the network ~tructures of the type shown in FIG. 17 having main filaments in the cross-machine direction are particularly ad-vantageous. This is because in preparing or making paper or staple fiber nonwovens the fibers th~rein customarily ~ecome oriented in the machine direction and increased strength in the cross-machine direction as well as increased tear resistance in the machine direction is needed. Ad~itionally, the thermoplastic networks can be used as an adhesive in bonding other materials together under 20 heat and pressure. They are also usable for fusible innerliners in shirts and the like, and can be used in place of cheesecloth for the manufacture and processing of cheeses.
The multi-layer fabrics described above are useful for ap-plications similar to those described for the single layer network ; structures, and particularly useful for those applications in which balanced and high strength and tear resistant properties are de-sired. Multi-layer products are particularly useful, for example, for the preparation of high impact resistant plastic bags, primary and secondary tufted carpet backings, plastic coated fabric, and 30 for other industrial fabric applications. Many other uses are evident for these networks and fabrics which have such properties as not being absorbent, not sticking to wounds or other materials, readily passing li~uids therethrough because of the openings in the network structures, and relatively light weight and high strength.

., ~

DS7~15 While emphasis has been placed on the high tensile strength and high tear resistance of the subject networks, it is of course apparent that network structures may be made in accordance with the principles of this invention without necessarily drawing the main filaments to a high degree so that network structures may have less strength and tear resistance for applications where those characteristics are not important. In certain applica~ions, tex-ture and smoothness may be more significant than strength. An ex-ample of such an application is the use of network structures as 10 a covering in a sanitary napkin wherein it is highly desirable that the network have a soft and smooth texture in order to pre-vent irritation and also have high permeability to permit fluids to pass and be absorbed by the absorbent inner-material of the -napkin.
The subject network structures are very smooth since they do not have any reinforced bosses or thick masses at the cross-o~er points o the main filaments and tie filaments. Such smooth-ness gives the network a soft hand or feel to make it desirable for many uses wherein irritation of the user or wearer may be an 20 important factor. Additionally, the network structures can be drawn in such a manner as to provide relatively flat structures, that iB, a structure having a relatively uniform thickness as measured in the plane perpendicular to the plane of the network.
This may be significant for its use as an adhesive where it may be desired to bond two materials together to provide a laminated or bonded fabric having a uniform thickness.
It i~ also possible to make novel monofilaments or y'arns from certain of the network structures described above. Referring to FIG. 18, there is shown a network structure generally designa-~!' 30 ted as 110 having main filaments 111 extending in the longitudinal or machine direction and tie filaments 112 extending in the cross-machine direction, 90 to the main filamePts 111. Any network structure having its main filaments formed in the machine direc-~ tion and its tie filaments formed at an angle to the machine '' :

S7~15 direction may be utilized in making monofilaments or yarns. The network 110 is advanced by nip rolls 115 through a plurality of lease rods generally designated as 114 to split the network struc-tures into monofilaments or relatively narrow tapes or strips llOa, llOb, llOc, llOd, etc., consisting of single main filaments or a number of main filaments interconnected by tie filaments. The network 110 can easily be split into monofilaments or tapes of any desired width. This is accomplished by initially cutting or tear-ing the leading end of the network 110 into strips of the desired 10 width and feeding adjacent strips differently through the lease rods 114 so that upon advancement the lease rods tear or split the network as desired. For example, as shown in FIGS. 18 and 19, strip llOa, is fed over lease rod 114a, under lease rod 114b, and over lease rod 114c. The adjacent strip llOb is fed or passes under lease rod 114a, over lease rod 114b, and under lease rod 114c. Thus, as strips llOa and llOb advance, the lease rods break the tie filaments interconnecting the adjacent strips. Because of the relative sizes of the main filaments to the tie filaments, the tie filam0nts break easily upon passing through the lease rods as 20 shown, without need for any cutting or slitting elements. lf de-sired, the strips can then be fibrillated to completely or par-tially sever the tie filaments such as by passing the strip over a beater bar 116 cimilar to that described in U.S. patent 3,495,752.
FIG. 20 shows a portion of strip llOa as it looks prior to fibril-lation. Complete fibrillation of the network breaks substantially all of the tie filaments, leaving the main filaments intact there-by forming each strip into a yarn consisting of a plurality of in-dividual main filaments which are not interconnected and have pro-truding portions of tie filaments extending perpendicularly there-" 30 from, or at some other angle if the tie filaments are initially formed at some other angle. FIG. 21 shows a portion of strip llOa after fibrillation with the tie filaments broken. The main fila-ments are pulled through another set of nip rolls 117 and then may pass over a yarn guide 118 for further processing. The fibrillation 1057~
by use of a beater bar 116, or by any other means, converts the strips llOa, llOb, etc. either partially or completely into a series of multi-filaments each with protruding normally smaller side filaments attached. If desired, bulking may be effected by known crimping or false twist methods. Also, bulking may be ef-fected by heat relaxation if the main filaments have been prepared from bi-component polymer sheets. For example, referring again to FIG. 18, the fibrillated strips llOa may be passed from the yarn guide 118 into a heater 119 to provide bulking. If desired, a 10 false twist may be put into the yarns by use of false twisting head 120 after which the yarns are wound on a take-up spool 121.
Alternatively, if zero twist yarns are desired, the unfibrillated or fibrillated strip llOb may be wound directly onto a take-up spool 122 as shown in FIG. lg. Alternatively, if desired, a fibrillated strip llOc may be passed through an air-jet interlacer 123 and then wound on a take-up spool 124. If further desired, the fibrillated strip llOd may pass through a conventional down twister 126 and then be wound on a take-up qpool. Conventional air-jet entangling may be employed to convert the yarns to a form 20 which can be wound and unwound from a package readily. FIG. 22 illuctrates an air-jet entangled or interlaced yarn 128. FIG. 23 ; illu~trates a bulked yarn 129 which is subsequently air-jet en-tangled. Twister take-up packages may also be used to form com-pact, readily handleable yarns. Of course, many combinations of ! these step~ such as fibrillation followed by heat relaxation and twisting may be employed.
The unfibrillated strips or tape networ~s are also useful in untwisted form in weaving or knitting operations where ma~imum coverage in a light weight but strong fabric is desired. ~uch 30 we~ving or knitting operations can be carried out in line with the tape forming operation.
The yarns prepared in accordance with these techniques are unique in that the main filaments have protruding tie filaments which contribute bulk, cover and a desirable appearance. These ~ 7~15 yarns are useful for knitting, weaving, tufting and continuous filament nonwoven applications in general. The presence of the side tie filament portions provide improved adhesion of plastic, rubber or other coatings when fabrics prepared from these yarns are subsequently coated. Furthermore, because of the protruding side tie filament portions the yarns and fabrics have good abra-sion and pilling resistance.
In the preceding discussion of the embossing methods, cus-tomarily one embossing roll drives the other embossing roll through 10 the melt or sheet with each roll rotating at the same speed. How-ever, when using polymers that are relatively difficult to split spontaneously, such as for example, polyesters, polyamides and vinyl polymers, differential speed embossing rolls can be used to t effect incipient splitting of these polymers at the embossing stage. By differential speed, it is meant that the surface speed of the main rib embossing roll i9 different, from a slight differ-ence up to about a 50% difference, either faster or slower, than the surface speed of the tie rib embossing roll. By using differ-ential speed, of the main and tie rib embossing rolls it is pos-20 sible to bring about splitting of the thin web areas of the em-bossed sheet at the embossing stage. This facilitates subsequent splitting or opening up into a uniform network structure upon drawing.
The materials that the above network structures, fabrics and yarns can be formed from include any thermoplastic fiber-forming polymers. Among these are polyethylene, polypropylene homopolymer, random copolymers of propylene containing up to 10%
of another olefin, block copolymers of propylene containing up to 25~ of another olein, nylon-6, nylon-66, polyethylene terephthal-30 ate, other high molecular weight thermoplastic polyesters, and vinyl polymers ~uch as polyvinyl chloride. Conjugate or bicompo-nent plastic sheets in which two or more different polymers are extruded together to form sheets containing layers of separate polymers are also possible. Particularly desirable are conjugate ll - 23 -lC~S7~5 plastics in which a higher melting component, such as nylon or polyester, is used to ~orm the main portion of the main fibers.
For example, two layers of networ~ structures, each having a por-tion thereof made of a relatively high melting point polymer with the remaining portion being made of a lower melting point polymer, ~ -may be bonded together by placing the lower melting point polymers of each layer together and heating. Alternatively, a network structure made of a higher melting point polymer may be bonded to a network structure made of a lower melting point polymer. Fur-10 thermore, a network structure having a portion thereof made of arelatively high melting point polymer, may be bonded to another network structure being made only of a higher melting point poly-mer. Particularly desirable are conjugate plastic in which a higher melting point component, such as nylon or polyester, is used to form the main portion of the main fibers. This permits lamination without adhesive of two layers by bonding with heat and pres~ure or 8elf-bulking by heating the yarns or fabrics prepared from them. Alloys or mixtures of polymers may also be employed.
The principles of this invention are exemplified by the 20 following examples, which are given to illustrate the invention, and are not to be considered limiting in any way.
Example 1 Polypropylene and high density polyethylene, each with a melt flow index of 10 were coextruded at 199C. through a slit die 12 inches long with an opening 15 mils wide. The molten sheet con-sisting of 75~ polypropylene on one side and 25~ polyethylene on the other side was passed between two chrome-plated steel emboss-ing rolls. One roll was 4 inches in diameter, the other 3 inches in diameter, each being 13 inches long. The 4 inch roll had an em-30 bossed pattern consisting of a plurality of grooves extending cir-cumferentially around the roll with a spacing of 48 grooves per inch. This-roll was internally cooled to maintain its temperature at 76C. The other 3 inch roll had a pattern of straight grooves parallel to the axis of the roll having a uniform spacing of lll 57~ls grooves per inch. This 3 inch roll was controlled at 60C. The molten sheet contacted the 4 inch roll one inch before entering the nip between the rolls, the polypropylene side of the molten sheet contacting this roll. The linear rate of the sheet was 19 feet per minute, and the embossed sheet went around the 4 inch roll with 180 contact. The embossed sheet contained 48 main ribs per inch in the longitudinal direction on one side with the ribs being separated by grooves 10 mils wide. On the other sid~ of the t sheet the tie ribs were discontinuous with 111 tie ribs per inch 10 with the tie ribs being separated by grooves 5 mils wide. The tie ribs were discontinuous, not being present in the areas opposite the main ribs on the other side of the sheet. The ratio of the cross-sections of the main ribs to the cross-sections of the tie ribs was about 2:1, and the ratio of the height of the main ribs to the thickness of the webs between the main ribs was about 5:1.
The maximum thickness o the embossed sheet was 11 mi~s.
The embossed sheet was fed into a tenter heated with circu-lating air to 110C. at a speed of 20 feet per minute and it was stretched to twice its width. In this operation, it opened into 20 a uniform network 8tructure. The sheet was then drawn in the linear direction by passing it in frictional contact with a series of 11 steel rolls heated to 120C. and moving at progressively in-creasing speeds. The sheet was fed in at 15 feet per minute and exited at 105 feet per minute, so was drawn seven times its length in the machine direction. The re~ulting network structure had a weight of 0.27 ounces per square yard. The uniformly oriented main filaments were about 40 denier in size. This network struc-ture had a tensile strength of 11 pounds per inch and an elonga-; tion of 10~ in the machine direction. The strength in the cross-30 direction was about 1.0 pounds per inch and the elongation 10%.
The net was very resistant to tearing in the cross-machine direc-tion, giving a value of 32 pounds when tested by the Finch edge tear method, ASTM D-827.

.. ..

57~5 Example 2 Polypropylene and high density polyethylene each with a melt flow of about 10 were coextruded at 207C. into a conjugate sheet at a 50:50 bicomponent ratio using the extrusion equip~ent described in Example-l. The molten sheet was embossed between two rolls, one 6 inches in diameter, containing 75 grooves per inch parallel to the roll axis. The other roll was 4 inches in diam-eter and had 75 grooves per inch extending circumferentially around the roll. The 4 inch diameter roll was internally cooled 10 to maintain its temperature at 60C. and the 6 inch diameter roll wae maintained at 49C. The pressure between the two rolls was about 40 pounds per linear inch. The molten sheet contacted the
4 inch roll 1/2 inch ahead of the nip between the rolls. The sheet pasqed between the two rolls at a rate of 20 feet per n.inute.
The embossed sheet had a maximum thickness of 9 mils and contained 75 main ribs per inch in the longitudinal direction on one side with the ribs being separated by grooves 5 mils wide. On the other side of the sheet discontinous tie ribs were formed with 75 tie ribs per inch with each pair of tie ribs being separated by 20 grooves 5 mils wide. The ratio of the cross-sections of the main ribs to the tie ribs was about 1:1 and the ratio of the height of the main ribs to the thickness of the webs between the main ribs was about 5;1. The tie ribs were not present in the areas oppo-site the main ribs on the other side of the sheet.
The embossed sheet was fed into a tenter heated with circu-lating air to 110C. at a speed of 20 feet per minute and it was stretched to six times its width. In this operation, it opened into a uniform network structure, the sheet was then drawn in the linear direction by passing it in frictional contact with a series 30 of 11 steel rolls heated to 120C. and moving at progressively in-creasing speeds. The sheet was fed in at 15 feet per minute and e~ited at 90 feet per minute, thus was drawn six times its length in the machine directi~n-. The resulting network structure had a weight of 0.2 ounce per square yard. The uniformly oriented ma ~ 1~57~15 filaments were about 40 denier in size. This network structure had a tensile strength of 9 pounds per inch an~ an elongation of 14% in the machine direction. The strength in the cross-direction was about 7 pounds per inch and the elongation 12%. The net was very resistant to tearing in the cross-machine direction, giving a value of 20 pounds when tested by the Finch edge tear method, ASTM D-827.
Example 3 High density polyethylene with a melt index of 6 was ex-10 truded at 232C. through a slit die 18 inches long. The molten sheet was embossed between two rolls, one 6 inches in diameter containing 250 grooves per inch extending 45 to the roll's axis and the other 4 inches in diameter having 75 grooves per inch ex-tending in the circumferential direction. Both rolls were main-tained at a temperature of 66C. The molten sheet contacted the 4 inch roll 1/4 inch from the nip between the rolls. The linear rate of the sheet passing between the embossing rolls was 20 feet per minute and the embossed sheet went around the 4 inch roll with 90 c~ntact. The embossed sheet contained 75 ribs per inch in the 20 machine direction with the ribs being separated by grooves 5 mils wide. On the other side of the sheet discontinuous tie ribs were formed with 250 ribs per inch with the ribs being separated by grooves 1 mil wide. The tie ribs were not present in the areas opposite the main ribs on the other side of the sheet. The ratio of the cross-sections of the main ribs to those of the discontinu-ous tie ribs was about 10:1, and the ratio of the height of the main ribs to the thickness of the webs between the main ribs was 4:1. The maximum thickness of the embossed sheet was 4 mils.
! The embossed sheet was stretched three times its length on 30 linear draw rolls at 120C., and then was stretched 2.5 times its width in a tenter at 90C. during which operation regular voids or openings were formed between the main filaments. The sheet was ~ then drawn llnearly 1.5 times its length by passing it over a ; series of differential speed rolls heated to 120C. The weight of ~ ~7 ~
:.
: . . ., , - ~ :

; ~ ~D57~5 the network structure so formed was 0.25 ounce per square yard.
The uniformly oriented main filaments were about 40 denier in size.
This network structure had a tensile strength of 3.9 pounds per inch in the machine direction and an elongation of 13%. The strength in the cross-machine direction was 0.5 pound per inch and the elongation was 26%. The net had high tear resistance in the cross-machine direction.
Example 4 -Polypropylene with a melt flow index of 7 was extruded at 10 250C. through a slit die 12 inches long with an opening 20 mils wide. The molten sheet was passed into the nip between two em-bossing rollQ maintained at 70C. One roll was 4 inches in diam-eter and contained 40 grooves per inch extending circumferentially around the roll separated by 5 inch wide ridges. The other roll was 6 inches in diameter and contained 125 discontinuous grooves per inch parallel to the roll axis. The discontinuous parallel grooves were 7 mils long with 18 mil discontinuities between the grooves, The discontinuities were in lines extending circumf~r-entially around the roll. The rolls were aligned so that the 20 lines of discontinuity on the 6 inch roll were directly opposite the grooves on the 4 inch roll. The linear speed of the sheet was 25 feet per minute and the embossed sheet was maintained in contact with the 6 inch roll over an angle of 90. The embossed sheet contained 40 ribs per inch on one side separated by webs 5 mils wide. On the other side of the sheet were discontinuous tie ribs with a spacing of 125 ribs per inch. The tie ribs were not present in the areas opposite the main ribs on the other side of ` the embossed sheet. The ratio of the cross-sections of the main ~ ribs to the cross-sections of the tie ribs was about 20:1 and the `~ 30 ratio of the height of the main ribs to the thickness of the webs between the main ribs was 10:1. The maximum thickness of the em-bossed gheet was 15 mils.

The embossed sheet was oriented in the machine direction by passing it in frictional contact with a series of 11 steel rolls '~
~, ,.,.,, ~

, 1Lo57,~15 ` heated to 120 and moving at progressively higher speeds. The sheet was fed in at 15 feet per minute and exited at 150 feet per minute, so was drawn ten times its original length. The-sheet ceparated into a network structure with a weight of 0.5 ounces per square yard. The machine direction filaments were about 80 denier in size separated about 3 mils. The strength in the machine direction was about 20 pounds per inch with 15% elonga-tion. The net had high resistance to tearing in the cross-machine direction, being about 60 pounds when tested by the Finch 10 edge tear method.
It i9 to be understood that the above described embodiments are merely illustrative of applications of the principles of this invention and that ~umerous other arrangements and modifications may be made within the spirit and scope of the invention.

Claims (27)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A method of making a network structure comprising:
forming on one side of a sheet of thermoplastic polymer material a plurality of parallel continuous main ribs intercon-nected by webs of reduced thickness extending in a first direction;
forming on the other side of said sheet a plurality of parallel discontinuous tie ribs extending in a second direction different than said first direction, said tie ribs being formed opposite the webs interconnecting said main ribs and having no substantial part thereof crossing over a main rib; and drawing the sheet in at least one direction to separate the main ribs into continuous main filaments and to separate the tie ribs into tie filaments to form a network structure having main filaments thereof being substantially uniformly and continuously oriented.
2. A method of making a network structure as set forth in claim 1 wherein said sheet is drawn in two different directions to orient both said main filaments and said tie filaments.
3. A method of making a network structure as set forth in claim 2 wherein said sheet is drawn in both said first and second directions to uniaxially orient said main and tie filaments.
4. A method of making a network structure as set forth in claim 3 wherein said sheet is drawn in said first direction at least about 1.5X and wherein said sheet is drawn in said second direction at least about 1.5X.
5. A method of making a network structure as set forth in claim 1 wherein said main ribs and said tie ribs are formed sub-stantially perpendicular to each other.
6. A method of making a network structure as set forth in claim 5 wherein said main ribs are formed substantially parallel to the longitudinal axis of said sheet and said tie ribs are formed substantially perpendicular to the longitudinal axis of said sheet.
7. A method of making a network structure as set forth in claim 5 wherein said main ribs are formed substantially perpen-dicular to the longitudinal axis of said sheet and said tie ribs are formed substantially parallel to the longitudinal axis of said sheet.
8. A method of making a network structure as set forth in claim 1 wherein said main ribs are formed substantially parallel to the longitudinal axis of said sheet.
9. A method of making a network structure as set forth in claim 1 wherein said main ribs are formed at an angle to the longitudinal axis of said sheet.
10. A method of making a network structure as set forth in claim 9 wherein said tie ribs are formed substantially parallel to the longitudinal axis of said sheet.
11. A method of making a network structure as set forth in claim 2 wherein said sheet is first drawn at least 1.5X in a direc-tion between 15° and 90° to said first direction and wherein said sheet is subsequently drawn at least about 1.5X in a direction perpendicular to said first draw direction.
12. A method of making a network structure as set forth in claim 2 wherein said sheet is first drawn at least 1.5 times its width in the cross-machine direction and wherein said sheet is subsequently drawn in the machine direction at least 1.5 times its length.
13. A method of making a network structure as set forth in claim 7 wherein said sheet is first drawn at least 1.5 times its length in the machine direction and wherein said sheet is subse-quently drawn at least 1.5 times its width in the cross-machine direction.
14. A method of making a network structure as set forth in claim 9 wherein said main ribs are formed at an angle of 75° or less to the longitudi-nal axis of said sheet and wherein said sheet is first drawn transverse to the longitudinal axis of said sheet at least 1.5 times and wherein said sheet is subsequently drawn in the machine direction at least 1.5 times.
15. A method of making a network structure as set forth in claim 1 wherein the ratio of the cross-sectional area of said main ribs to said tie ribs is at least 1.5:1, and the ratio of the height of the main ribs to the thickness of the webs between the main ribs is at least 3:1.
16. A method of making a network structure comprising: providing a first embossing roll having a plurality of parallel continuous main grooves formed therein in one direction; providing a second embossing roll positioned oppo-site said first roll and having a plurality of continuous parallel tie grooves formed therein in a second direction different than said first direction;
extruding a sheet of thermoplastic polymer and advancing it while hot into the nip of said first and second embossing rolls; controlling the embossing of said sheet to form a plurality of parallel continuous main ribs interconnected by webs of reduced thickness on one side of said sheet in said first direction and a plurality of parallel discontinuous tie ribs on the other side of said sheet in said second direction, said tie ribs being formed opposite the webs interconnecting said main ribs and having no substantial part thereof cross-ing over a main rib; and drawing said sheet in at least one direction to sepa-rate the main ribs into continuous main filaments and to separate the tie ribs into tie filaments thereby opening the sheet into a network structure, and to substantially uniformly and continuously orient the main filaments.
17. A method of making a network structure as set forth in claim 16, wherein said sheet is drawn in both said first and second directions to sub-stantially uniformly and continuously orient said main filaments along their longitudinal axes and to uniaxially orient said tie filaments.
18. A method of making a network structure as set forth in claim 16 wherein the ratio of the cross-sectional area of said main ribs to said tie ribs is at least 1.5;1 and the ratio of the height of the main ribs to the thickness of the webs between the ribs is at least 3:1.
19. A method of making a network structure as set forth in claim 16 wherein said sheet of thermoplastic material is advanced through the nip of said first and second embossing rolls and is advanced around one of said embossing rolls so that it is in contact therewith at least for an angle of 90°.
20. A method of making a network structure as set forth in claim 16 wherein said first embossing roll rotates at a speed different than said second embossing roll to cause incipient cracking of the embossed sheet in the thin areas thereof.
21. A method of making a network structure as set forth in claim 20 wherein the speed of said first embossing roll varies from within approximately 5-50% of the speed of said second embossing roll.
22. A method of making a nonwoven fabric comprising: forming a first sheet of thermoplastic polymer having a plurality of parallel continuous main ribs interconnected by webs of reduced thickness in a first direction on one side thereof and a plurality of parallel discontinuous tie ribs on the other side thereof extending in a second direction other than said first direction, said tie ribs being formed opposite the webs interconnecting said main ribs and having no substantial part thereof crossing over a main rib; drawing said sheet in at least one direction to separate the main ribs into oriented con-tinuous main filaments having a substantially uniform cross-section and to separate the tie ribs into tie filaments uniformly interconnecting the main filaments, thereby forming a first network structure; forming a second sheet having a plurality of parallel continuous main ribs interconnected by webs of reduced thickness in a third direction other than said first direction on one side thereof and a plurality of parallel discontinuous tie ribs on the other side of said sheet extending in a direction other than said third direction;

drawing said second sheet in at least one direction to separate the main ribs into, oriented continuous main filaments having a substantially uniform cross-section and to separate the tie ribs into tie filaments uniformly interconnect-ing the main filaments thereby forming a second network structure; and bonding said first network structure to said second network structure to provide a fabric having substantially uniform and continuously oriented main filaments formed in both said first and said third directions.
23. A method of making a fabric as set forth in claim 22 wherein said main filaments of said first network structure are formed in the machine direc-tion and the main filaments of said second network structure are formed in the cross-machine direction.
24. A method of making a fabric as set forth in claim 22 wherein said main filaments of said first network structure are formed at an angle to the longitudinal axis of said sheet and the main filaments of said second network structure are formed perpendicular to said first sheet main filaments.
25. A method of making a fabric as set forth in claim 22 including bond-ing at least one other network structure to said first and second network structures wherein said other network structure has its main filaments formed in a direction other than said first and third directions.
26. A method of making a fabric as set forth in claim 25 wherein at least three network structures are bonded together each having their main filaments formed about 60° from each other thereby forming an isometric structure.
27. A method of making a fabric as set forth in claim 25 wherein at least four network structures are bonded together each having their main fila-ments formed about 45° from each other.
CA189,852A 1973-01-16 1974-01-10 Network structures and methods of making same Expired CA1057015A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA314,904A CA1073173A (en) 1973-01-16 1978-10-30 Network structures and methods of making same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US324028A US3922329A (en) 1973-01-16 1973-01-16 Methods of making network structures

Publications (1)

Publication Number Publication Date
CA1057015A true CA1057015A (en) 1979-06-26

Family

ID=23261760

Family Applications (1)

Application Number Title Priority Date Filing Date
CA189,852A Expired CA1057015A (en) 1973-01-16 1974-01-10 Network structures and methods of making same

Country Status (6)

Country Link
US (1) US3922329A (en)
JP (1) JPS5827097B2 (en)
KR (1) KR800000232B1 (en)
CA (1) CA1057015A (en)
IT (1) IT1006924B (en)
ZA (1) ZA74332B (en)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4133310A (en) * 1974-01-11 1979-01-09 Smith & Nephew Research Limited Polymer fabric
US4017659A (en) * 1974-10-17 1977-04-12 Ingrip Fasteners Inc. Team lattice fibers
GB1548865A (en) * 1975-06-16 1979-07-18 Smith & Nephew Res Integral fibrillated net material
GB1531734A (en) * 1975-07-29 1978-11-08 Aspin Shaw Ltd Manufacturers of twine and the like
US4098630A (en) * 1976-08-04 1978-07-04 Kemlite Corporation Process for making decorative resin panels
US4198459A (en) * 1976-12-03 1980-04-15 Brumlik George C Filaments with evolved structure and process of making some
GB1603865A (en) * 1977-07-08 1981-12-02 Smith & Nephew Plastics Production of net
US4331724A (en) * 1978-05-22 1982-05-25 Milliken Research Corporation Fibrillated polyester textile materials
NO152611C (en) * 1978-10-16 1985-10-23 Plg Res PLASTIC NETWORK CONSTRUCTION, PROCEDURE FOR ITS MANUFACTURING AND USE OF THE CONSTRUCTION
US5156495B1 (en) * 1978-10-16 1994-08-30 Plg Res Plastic material mesh structure
US4276336A (en) * 1979-04-23 1981-06-30 Sabee Products, Inc. Multi-apertured web with incremental orientation in one or more directions
US4440709A (en) * 1980-03-27 1984-04-03 Rasmussen O B Method of manufacturing reticular sheet
US4842794A (en) * 1987-07-30 1989-06-27 Applied Extrusion Technologies, Inc. Method of making apertured films and net like fabrics
US5269631A (en) * 1989-09-14 1993-12-14 Netlon Limited Plastics material mesh structures
US5267816A (en) * 1989-09-14 1993-12-07 Netlon Limited Geogrids
US5207962A (en) * 1991-06-25 1993-05-04 Applied Extrusion Technologies, Inc. Method of making apertured film fabrics
US5262107A (en) * 1991-06-25 1993-11-16 Applied Extrusion Technologies, Inc. Method of making apertured film fabrics
JPH07108200B2 (en) * 1992-06-23 1995-11-22 東洋水産株式会社 Fried noodle manufacturing equipment
US5666682A (en) * 1994-09-30 1997-09-16 Bonaddio; Vincenzo A. Mattress pad of adjustable size
MY117643A (en) * 1996-02-29 2004-07-31 Uni Charm Corp Liquid-permeable topsheet for body exudates absorbent article, apparatus and method for manufacturing same
JP3271048B2 (en) * 1996-09-30 2002-04-02 株式会社 塚田螺子製作所 Sheet feed shaft, manufacturing apparatus and manufacturing method thereof
US6277464B1 (en) 1997-05-16 2001-08-21 Pall Corporation Polymeric integral net
US6264872B1 (en) 1997-12-30 2001-07-24 Kimberly-Clark Worldwide, Inc. Method of forming thin, embossed, textured barrier films
USRE45402E1 (en) 1999-07-13 2015-03-03 Stirling Mouldings Limited Flexible material
GB2352208B (en) 1999-07-13 2001-06-13 Stirling Moulded Composites Lt Flexible material
US20060178652A1 (en) * 2005-02-09 2006-08-10 Miller Robert A Iii Incontinence pad and apparel formed therewith
US7470094B2 (en) * 2005-11-10 2008-12-30 Gse Lining Technology, Inc. Geonet for a geocomposite
US20080113143A1 (en) * 2006-10-31 2008-05-15 David Stirling Taylor Flexible Material and Method of Manufacturing the Flexible Material
JP4972384B2 (en) * 2006-11-27 2012-07-11 ユニ・チャーム株式会社 Absorbent articles
JP5054963B2 (en) * 2006-11-27 2012-10-24 ユニ・チャーム株式会社 Absorbent articles
US10499694B2 (en) 2008-08-01 2019-12-10 Nike, Inc. Apparel with selectively attachable and detachable elements
US8898820B2 (en) * 2008-08-01 2014-12-02 Nike, Inc. Layered apparel with attachable and detachable elements
US20100024089A1 (en) 2008-08-01 2010-02-04 Nike, Inc. Apparel With Selectively Attachable And Detachable Elements
US9149084B2 (en) 2009-06-23 2015-10-06 Nike, Inc. Apparel incorporating a protective element and method for making
US8438669B2 (en) 2009-06-23 2013-05-14 Nike, Inc. Apparel incorporating a protective element
US9675122B2 (en) 2009-06-23 2017-06-13 Nike, Inc. Apparel incorporating a protective element
US8438667B2 (en) 2009-09-24 2013-05-14 Nike, Inc. Apparel incorporating a protective element
US8719965B2 (en) 2009-09-24 2014-05-13 Nike, Inc. Apparel incorporating a protective element
US8702895B2 (en) 2010-04-07 2014-04-22 Nike, Inc. Cushioning elements for apparel and other products and methods of manufacturing the cushioning elements
US9505203B2 (en) 2010-11-30 2016-11-29 Nike, Inc. Method of manufacturing dye-sublimation printed elements
US8561214B2 (en) 2011-02-25 2013-10-22 Nike, Inc. Articles of apparel incorporating cushioning elements and methods of manufacturing the articles of apparel
US8764931B2 (en) 2011-05-19 2014-07-01 Nike, Inc. Method of manufacturing cushioning elements for apparel and other products
US9386812B2 (en) 2011-07-25 2016-07-12 Nike, Inc. Articles of apparel incorporating cushioning elements
US10034498B2 (en) 2011-07-25 2018-07-31 Nike, Inc. Articles of apparel incorporating cushioning elements
US20130025036A1 (en) 2011-07-25 2013-01-31 Nike, Inc. Articles Of Apparel Incorporating Cushioning Elements

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1056C (en) * 1911-11-22 1916-02-01 Beran Albert Universal rollers for the production of corrugated cardboard, corrugated sheet iron and the like
US3085292A (en) * 1959-02-13 1963-04-16 Bemis Bros Bag Co Method of producing open mesh sheeting of thermoplastic resin
US3394431A (en) * 1964-09-15 1968-07-30 George S. Nalle Jr. Apparatus for extruding plastic mesh, lace or net fabrics
US3488415A (en) * 1965-07-21 1970-01-06 Smith & Nephew Production of net-like fabrics from plastic material
US3551544A (en) * 1965-12-06 1970-12-29 Tenex Corp Method of continuously forming an elongated cleated runner of plastic material
US3505157A (en) * 1966-05-23 1970-04-07 Du Pont Integrally molded net
US3470594A (en) * 1967-03-30 1969-10-07 Hercules Inc Method of making synthetic textile yarn
US3511901A (en) * 1967-05-17 1970-05-12 Phillips Petroleum Co Fibrillation of plastic film
US3524922A (en) * 1967-11-27 1970-08-18 Stanley E Johnson Radiant heat cable support
GB1260836A (en) * 1968-04-10 1972-01-19 Shell Int Research The manufacture of filaments, fibres and yarns by fibrillation of synthetic organic thermoplastic polymers, and the resulting products
US3500627A (en) * 1968-07-31 1970-03-17 Hercules Inc Synthetic textile yarn
US3719540A (en) * 1970-05-04 1973-03-06 Hercules Inc Preparation of transversely fibrillated film
US3724198A (en) * 1970-07-10 1973-04-03 Hercules Inc Method for preparing spun yarns
US3825391A (en) * 1971-02-16 1974-07-23 R Davis Die for extrusion of lattice structures

Also Published As

Publication number Publication date
IT1006924B (en) 1976-10-20
JPS5849227A (en) 1983-03-23
US3922329A (en) 1975-11-25
JPS5827097B2 (en) 1983-06-07
ZA74332B (en) 1974-11-27
KR800000232B1 (en) 1980-03-22

Similar Documents

Publication Publication Date Title
CA1057015A (en) Network structures and methods of making same
CA1055672A (en) Network structures and methods of making same
US4101358A (en) Method of making network structures
US4188436A (en) Non woven fabrics with pattern of discrete fused areas
US4186781A (en) Network structures and methods of making same
KR101048536B1 (en) High volume composite sheet and its manufacturing method
US3713942A (en) Process for preparing nonwoven fabrics
EP0379763B1 (en) Cross-laminated stretched non-woven fabric and method of making the same
US5789328A (en) Bulky nonwoven fabric and method for producing the same
US4258094A (en) Melt bonded fabrics and a method for their production
US4310594A (en) Composite sheet structure
US8252706B2 (en) Stretchable multiple component nonwoven fabrics and methods for preparing
US5866488A (en) Thermally fusible composite fiber and non-woven fabric made of the same
EP0790336B1 (en) Polytetrafluoroethylene fiber, cotton-like article obtained therefrom, and method for their production
EP0244486B1 (en) Water absorbing material and method for its manufacture
US4207375A (en) Network structures and methods of making same
CA2125948A1 (en) Process for making moldable, tufted polyolefin carpet
JPS5833090B2 (en) Amimekouzobutsuno Seizouhouhou
US4274251A (en) Yarn structure having main filaments and tie filaments
US4144368A (en) Network structures having different cross-sections
CA1073173A (en) Network structures and methods of making same
CA1073174A (en) Tape structures and methods of making same
JPS6316504B2 (en)
DE10352958B4 (en) Use of a highly tear-resistant composite as an entanglement part of a mechanical closure system
EP0043390B1 (en) Composite sheet structure, process for its preparation and laminates comprising said structure