CA1047516A - Process for the preparation of titanium thio-derivatives - Google Patents
Process for the preparation of titanium thio-derivativesInfo
- Publication number
- CA1047516A CA1047516A CA227,219A CA227219A CA1047516A CA 1047516 A CA1047516 A CA 1047516A CA 227219 A CA227219 A CA 227219A CA 1047516 A CA1047516 A CA 1047516A
- Authority
- CA
- Canada
- Prior art keywords
- ticp2
- titanium
- thio
- preparation
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010936 titanium Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 8
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims abstract description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 125000003118 aryl group Chemical group 0.000 claims abstract description 3
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims abstract 2
- 239000012442 inert solvent Substances 0.000 claims description 5
- 150000003608 titanium Chemical class 0.000 claims description 4
- 239000002685 polymerization catalyst Substances 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- TZOVOULUMXXLOJ-UHFFFAOYSA-N 1-methyl-4-[(4-methylphenyl)disulfanyl]benzene Chemical compound C1=CC(C)=CC=C1SSC1=CC=C(C)C=C1 TZOVOULUMXXLOJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT22868/74A IT1012477B (it) | 1974-05-17 | 1974-05-17 | Processo per la preparazione di tio derivati del titanio |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1047516A true CA1047516A (en) | 1979-01-30 |
Family
ID=11201358
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA227,219A Expired CA1047516A (en) | 1974-05-17 | 1975-05-16 | Process for the preparation of titanium thio-derivatives |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4039566A (e) |
| JP (1) | JPS50157338A (e) |
| BE (1) | BE829182A (e) |
| CA (1) | CA1047516A (e) |
| DE (1) | DE2521923A1 (e) |
| FR (1) | FR2271206B1 (e) |
| GB (1) | GB1471243A (e) |
| IT (1) | IT1012477B (e) |
| LU (1) | LU72488A1 (e) |
| NL (1) | NL7505841A (e) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4605751A (en) * | 1984-01-17 | 1986-08-12 | The Board Of Regents Acting For And On Behalf Of The University Of Michigan | Bimetallic cluster catalysts |
| DE3800760A1 (de) * | 1988-01-13 | 1989-07-27 | Koepf Maier Petra | Cytostatisch wirksame titanocen-derivate und diese enthaltende arzneimittel |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3030395A (en) * | 1961-09-12 | 1962-04-17 | American Cyanamid Co | Cyclopentadienyl (hydrocarbo-thio) titanium compounds |
| US3361777A (en) * | 1963-10-25 | 1968-01-02 | Du Pont | Neutral chelates having a transition metal attached to one to three-sc(cf3)=c(cf3)s-groups |
| GB1220506A (en) * | 1968-06-18 | 1971-01-27 | Ici Ltd | Transition metal compounds |
-
1974
- 1974-05-17 IT IT22868/74A patent/IT1012477B/it active
-
1975
- 1975-04-29 US US05/572,649 patent/US4039566A/en not_active Expired - Lifetime
- 1975-05-15 GB GB2072875A patent/GB1471243A/en not_active Expired
- 1975-05-16 CA CA227,219A patent/CA1047516A/en not_active Expired
- 1975-05-16 FR FR7515521A patent/FR2271206B1/fr not_active Expired
- 1975-05-16 LU LU72488A patent/LU72488A1/xx unknown
- 1975-05-16 BE BE156445A patent/BE829182A/xx unknown
- 1975-05-16 NL NL7505841A patent/NL7505841A/xx not_active Application Discontinuation
- 1975-05-16 DE DE19752521923 patent/DE2521923A1/de active Pending
- 1975-05-16 JP JP50057489A patent/JPS50157338A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| BE829182A (fr) | 1975-09-15 |
| FR2271206B1 (e) | 1978-09-22 |
| JPS50157338A (e) | 1975-12-19 |
| NL7505841A (nl) | 1975-11-19 |
| IT1012477B (it) | 1977-03-10 |
| DE2521923A1 (de) | 1975-11-20 |
| LU72488A1 (e) | 1975-08-28 |
| GB1471243A (en) | 1977-04-21 |
| FR2271206A1 (e) | 1975-12-12 |
| US4039566A (en) | 1977-08-02 |
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