CA1042066A - Sodium-aluminum halide, sulfur battery - Google Patents
Sodium-aluminum halide, sulfur batteryInfo
- Publication number
- CA1042066A CA1042066A CA249,142A CA249142A CA1042066A CA 1042066 A CA1042066 A CA 1042066A CA 249142 A CA249142 A CA 249142A CA 1042066 A CA1042066 A CA 1042066A
- Authority
- CA
- Canada
- Prior art keywords
- sodium
- molten
- positive
- reactant
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Sodium-aluminum halide Chemical class 0.000 title claims abstract description 33
- 229910052717 sulfur Inorganic materials 0.000 title claims description 27
- 239000011593 sulfur Substances 0.000 title claims description 27
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 26
- 239000000376 reactant Substances 0.000 claims abstract description 47
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 46
- 239000011734 sodium Substances 0.000 claims abstract description 46
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 37
- 239000003792 electrolyte Substances 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 10
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 7
- 239000011780 sodium chloride Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 150000001649 bromium compounds Chemical class 0.000 claims description 4
- 150000001805 chlorine compounds Chemical class 0.000 claims description 4
- 239000000155 melt Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 230000010287 polarization Effects 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000005297 pyrex Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910000792 Monel Inorganic materials 0.000 description 2
- 229910020275 Na2Sx Inorganic materials 0.000 description 2
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 150000004673 fluoride salts Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000004694 iodide salts Chemical class 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-N sodium polysulfide Chemical compound [Na+].S HYHCSLBZRBJJCH-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- WMEKSYHDIDMJMC-UHFFFAOYSA-L [Na+].[Na+].[S-]SSS[S-] Chemical compound [Na+].[Na+].[S-]SSS[S-] WMEKSYHDIDMJMC-UHFFFAOYSA-L 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- COOGPNLGKIHLSK-UHFFFAOYSA-N aluminium sulfide Chemical compound [Al+3].[Al+3].[S-2].[S-2].[S-2] COOGPNLGKIHLSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- YQCIWBXEVYWRCW-UHFFFAOYSA-N methane;sulfane Chemical compound C.S YQCIWBXEVYWRCW-UHFFFAOYSA-N 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/585,021 US3969138A (en) | 1975-06-09 | 1975-06-09 | Sodium-aluminum halide, sulfur battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1042066A true CA1042066A (en) | 1978-11-07 |
Family
ID=24339743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA249,142A Expired CA1042066A (en) | 1975-06-09 | 1976-03-30 | Sodium-aluminum halide, sulfur battery |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3969138A (enExample) |
| JP (1) | JPS51150030A (enExample) |
| BR (1) | BR7602143A (enExample) |
| CA (1) | CA1042066A (enExample) |
| DE (1) | DE2613901A1 (enExample) |
| FR (1) | FR2314590A1 (enExample) |
| GB (1) | GB1493783A (enExample) |
| SE (1) | SE7602996L (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1533853A (en) * | 1975-02-14 | 1978-11-29 | Chloride Group Ltd | Electric storage batteries |
| CA1149865A (en) * | 1979-08-22 | 1983-07-12 | Margaretha J. Nolte | Electrolyte for an electrochemical cell, and an electrochemical cell including the electrolyte |
| SE8008330L (sv) * | 1979-12-05 | 1981-06-06 | Western Electric Co | Elektrolytisk cell |
| ZA837601B (en) * | 1982-10-20 | 1984-06-27 | South African Inventions | Electrochemical cell |
| GB8314235D0 (en) * | 1983-05-23 | 1983-06-29 | Ind Distributors Shannon Ltd | Electrochemical cell |
| JP2594973B2 (ja) * | 1987-09-14 | 1997-03-26 | 株式会社日立製作所 | 流動型溶融塩電池 |
| US10020543B2 (en) | 2010-11-05 | 2018-07-10 | Field Upgrading Usa, Inc. | Low temperature battery with molten sodium-FSA electrolyte |
| US10056651B2 (en) | 2010-11-05 | 2018-08-21 | Field Upgrading Usa, Inc. | Low temperature secondary cell with sodium intercalation electrode |
| US10224577B2 (en) | 2011-11-07 | 2019-03-05 | Field Upgrading Usa, Inc. | Battery charge transfer mechanisms |
| KR102069150B1 (ko) * | 2013-03-26 | 2020-01-23 | 에스케이이노베이션 주식회사 | 이차전지용 집전체 및 이를 포함하는 이차전지 |
| WO2014197813A1 (en) | 2013-06-06 | 2014-12-11 | Ceramatec, Inc. | Low viscosity/high conductivity sodium haloaluminate electrolyte |
| US8980459B1 (en) | 2014-01-02 | 2015-03-17 | Dynantis Corporation | Secondary metal chalcogenide batteries |
| US10734686B2 (en) | 2015-04-17 | 2020-08-04 | Field Upgrading Usa, Inc. | Sodium-aluminum battery with sodium ion conductive ceramic separator |
| US10601062B2 (en) * | 2015-10-01 | 2020-03-24 | Dynantis Corp. | Sodium metal batteries with intercalating cathode |
| CN105958045B (zh) * | 2016-06-07 | 2018-08-24 | 浙江大学 | 一种用于锂硫电池的正极材料及其制备方法 |
| US20230242030A1 (en) * | 2020-10-02 | 2023-08-03 | Magtec Alaska, LLC | Transportable slurry box system |
| US12077362B2 (en) | 2021-08-06 | 2024-09-03 | Ryan Peterkin | Transportable self contained cutting box |
| US11772884B2 (en) | 2021-08-06 | 2023-10-03 | Ryan Peterkin | Pressure vessel device |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3463670A (en) * | 1967-05-26 | 1969-08-26 | Mallory & Co Inc P R | High energy density thermal cell |
| US3679480A (en) * | 1969-05-08 | 1972-07-25 | Dow Chemical Co | Electrical cell assembly |
| US3635765A (en) * | 1970-06-05 | 1972-01-18 | Nasa | Method of making e m f cell |
| FR2115522A5 (en) * | 1970-11-23 | 1972-07-07 | Accumulateurs Fixes | Sodium-sodium halide cell - using aluminium chloride-sodium halide complexes |
| US3751298A (en) * | 1971-05-21 | 1973-08-07 | Union Carbide Corp | Thermal, rechargeable electrochemical cell having lithium monoaluminide electrode and lithium tetrachloroaluminate electrolyte |
| US3718505A (en) * | 1971-12-07 | 1973-02-27 | Esb Inc | Sodium-sulfur battery having aluminum sulfide or aluminum polysulfide in the electrolyte |
| US3879224A (en) * | 1974-04-05 | 1975-04-22 | Gen Electric | Sealed primary sodium-halogen cell |
| US3877984A (en) * | 1974-04-24 | 1975-04-15 | Esb Inc | Alkali metal-metal chloride battery |
-
1975
- 1975-06-09 US US05/585,021 patent/US3969138A/en not_active Expired - Lifetime
-
1976
- 1976-03-03 SE SE7602996A patent/SE7602996L/xx unknown
- 1976-03-11 JP JP51026587A patent/JPS51150030A/ja active Pending
- 1976-03-24 FR FR7608538A patent/FR2314590A1/fr active Granted
- 1976-03-30 CA CA249,142A patent/CA1042066A/en not_active Expired
- 1976-03-31 DE DE19762613901 patent/DE2613901A1/de not_active Withdrawn
- 1976-04-08 BR BR7602143A patent/BR7602143A/pt unknown
- 1976-05-28 GB GB22204/76A patent/GB1493783A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE7602996L (sv) | 1976-12-10 |
| BR7602143A (pt) | 1977-05-10 |
| FR2314590A1 (fr) | 1977-01-07 |
| GB1493783A (en) | 1977-11-30 |
| JPS51150030A (en) | 1976-12-23 |
| DE2613901A1 (de) | 1976-12-30 |
| US3969138A (en) | 1976-07-13 |
| FR2314590B1 (enExample) | 1980-06-13 |
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