CA1041984A - Catalysts for hydrotreatment of hydrocarbons and process for preparing such catalysts - Google Patents
Catalysts for hydrotreatment of hydrocarbons and process for preparing such catalystsInfo
- Publication number
- CA1041984A CA1041984A CA220,094A CA220094A CA1041984A CA 1041984 A CA1041984 A CA 1041984A CA 220094 A CA220094 A CA 220094A CA 1041984 A CA1041984 A CA 1041984A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- platinum
- carrier
- catalysts
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 116
- 229930195733 hydrocarbon Natural products 0.000 title claims description 19
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052751 metal Inorganic materials 0.000 claims abstract description 39
- 239000002184 metal Substances 0.000 claims abstract description 39
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 22
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052718 tin Inorganic materials 0.000 claims abstract description 20
- 239000011651 chromium Substances 0.000 claims abstract description 18
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 17
- 239000011733 molybdenum Substances 0.000 claims abstract description 17
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 14
- 239000011572 manganese Substances 0.000 claims abstract description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 13
- 150000002367 halogens Chemical class 0.000 claims abstract description 13
- 239000000460 chlorine Substances 0.000 claims abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 8
- 239000011593 sulfur Substances 0.000 claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 5
- 150000002739 metals Chemical class 0.000 claims description 18
- 229910052697 platinum Inorganic materials 0.000 claims description 17
- 235000016768 molybdenum Nutrition 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 238000005470 impregnation Methods 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 239000011148 porous material Substances 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 5
- 238000005987 sulfurization reaction Methods 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 239000011135 tin Substances 0.000 abstract description 19
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 235000010755 mineral Nutrition 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- -1 platinum group metals Chemical class 0.000 abstract description 3
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 abstract 1
- 235000017168 chlorine Nutrition 0.000 abstract 1
- 229940060038 chlorine Drugs 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 12
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- 238000000151 deposition Methods 0.000 description 8
- 230000008021 deposition Effects 0.000 description 8
- 229960000443 hydrochloric acid Drugs 0.000 description 7
- 235000011167 hydrochloric acid Nutrition 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000001508 sulfur Nutrition 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 229910052702 rhenium Inorganic materials 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000002407 reforming Methods 0.000 description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000001119 stannous chloride Substances 0.000 description 2
- 235000011150 stannous chloride Nutrition 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 229910002835 Pt–Ir Inorganic materials 0.000 description 1
- 229910002846 Pt–Sn Inorganic materials 0.000 description 1
- 229910018885 Pt—Au Inorganic materials 0.000 description 1
- 229910018883 Pt—Cu Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- 239000011820 acidic refractory Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Thin Film Transistor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7404895A FR2260382B1 (en, 2012) | 1974-02-13 | 1974-02-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1041984A true CA1041984A (en) | 1978-11-07 |
Family
ID=9134868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA220,094A Expired CA1041984A (en) | 1974-02-13 | 1975-02-13 | Catalysts for hydrotreatment of hydrocarbons and process for preparing such catalysts |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4111841A (en, 2012) |
| JP (1) | JPS50115188A (en, 2012) |
| AT (1) | AT341483B (en, 2012) |
| AU (1) | AU498552B2 (en, 2012) |
| BE (1) | BE823396A (en, 2012) |
| CA (1) | CA1041984A (en, 2012) |
| CH (1) | CH603238A5 (en, 2012) |
| DE (1) | DE2460560C3 (en, 2012) |
| FR (1) | FR2260382B1 (en, 2012) |
| GB (1) | GB1470917A (en, 2012) |
| IT (1) | IT1027945B (en, 2012) |
| NL (1) | NL168720C (en, 2012) |
| SE (2) | SE418368B (en, 2012) |
| SU (1) | SU923351A3 (en, 2012) |
| ZA (1) | ZA75721B (en, 2012) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4183805A (en) * | 1977-09-14 | 1980-01-15 | Uop Inc. | Hydrocarbon conversion with an attenuated superactive multimetallic catalytic composite |
| FR2453671A1 (fr) * | 1979-04-10 | 1980-11-07 | Catalyse Soc Prod Francais | Nouveaux catalyseurs d'hydroreformage catalytique ou de production d'hydrocarbures aromatiques |
| FR2527098B1 (fr) * | 1982-05-24 | 1986-11-14 | Prod Catalyse Ste Fse | No |
| CN111774048A (zh) * | 2020-07-13 | 2020-10-16 | 沈阳三聚凯特催化剂有限公司 | 一种制备氧化铝载体的方法、重整保护剂及其制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2317683A (en) * | 1941-02-27 | 1943-04-27 | Shell Dev | Cyclization of hydrocarbons |
| US2848510A (en) * | 1954-09-16 | 1958-08-19 | Phillips Petroleum Co | Manganese reforming oxide-containing catalyst |
| US3033780A (en) * | 1954-12-23 | 1962-05-08 | Kellogg M W Co | Hydrocarbon conversion system |
| US2941016A (en) * | 1957-11-05 | 1960-06-14 | Hoechst Ag | Process for preparing aromatic hydrocarbons |
| US3554901A (en) * | 1968-05-10 | 1971-01-12 | Asahi Chemical Ind | Aromatization with a chromium-platinum palladium catalyst |
| FR2031984A5 (en, 2012) * | 1969-02-14 | 1970-11-20 | Raffinage Cie Francaise | |
| US3740328A (en) * | 1969-03-17 | 1973-06-19 | Universal Oil Prod Co | Hydrocarbon conversion process and catalyst therefor |
| US3702294A (en) * | 1971-05-10 | 1972-11-07 | Universal Oil Prod Co | Trimetallic hydrocarbon conversion catalyst and uses thereof |
| BE787953A (fr) * | 1971-08-26 | 1973-02-26 | Franc De Comp | Procede de regulation de la teneur en halogene des catalyseurs de conversion des hydrocarbures |
| US3806446A (en) * | 1972-01-10 | 1974-04-23 | Universal Oil Prod Co | Reforming of hydrocarbons with a platinum-tungsten-germanium catalyst |
| US4048099A (en) * | 1972-01-10 | 1977-09-13 | Uop Inc. | Hydrocarbon conversion with an acidic trimetallic catalytic composite |
| FR2257332B1 (en, 2012) * | 1974-01-10 | 1976-10-08 | Catalyse Soc Prod Francais |
-
1974
- 1974-02-13 FR FR7404895A patent/FR2260382B1/fr not_active Expired
- 1974-12-16 BE BE151542A patent/BE823396A/xx not_active IP Right Cessation
- 1974-12-20 SE SE7416173A patent/SE418368B/xx unknown
- 1974-12-20 DE DE2460560A patent/DE2460560C3/de not_active Expired
- 1974-12-20 IT IT30896/74A patent/IT1027945B/it active
- 1974-12-20 CH CH1713774A patent/CH603238A5/xx not_active IP Right Cessation
- 1974-12-27 AT AT1034274A patent/AT341483B/de not_active IP Right Cessation
-
1975
- 1975-01-09 NL NLAANVRAGE7500264,A patent/NL168720C/xx not_active IP Right Cessation
- 1975-01-14 JP JP50006978A patent/JPS50115188A/ja active Pending
- 1975-02-04 ZA ZA00750721A patent/ZA75721B/xx unknown
- 1975-02-10 AU AU78034/75A patent/AU498552B2/en not_active Expired
- 1975-02-11 SU SU752104498A patent/SU923351A3/ru active
- 1975-02-12 GB GB602675A patent/GB1470917A/en not_active Expired
- 1975-02-13 US US05/549,845 patent/US4111841A/en not_active Expired - Lifetime
- 1975-02-13 CA CA220,094A patent/CA1041984A/en not_active Expired
-
1979
- 1979-06-13 SE SE7905202A patent/SE7905202L/ not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| DE2460560A1 (de) | 1975-08-14 |
| ZA75721B (en) | 1976-01-28 |
| DE2460560C3 (de) | 1980-05-29 |
| AU7803475A (en) | 1976-08-12 |
| ATA1034274A (de) | 1977-06-15 |
| BE823396A (fr) | 1975-06-16 |
| AU498552B2 (en) | 1979-03-15 |
| GB1470917A (en) | 1977-04-21 |
| CH603238A5 (en, 2012) | 1978-08-15 |
| SE418368B (sv) | 1981-05-25 |
| AT341483B (de) | 1978-02-10 |
| SE7905202L (sv) | 1979-06-13 |
| NL7500264A (nl) | 1975-08-15 |
| IT1027945B (it) | 1978-12-20 |
| SE7416173L (en, 2012) | 1975-08-14 |
| FR2260382B1 (en, 2012) | 1978-06-16 |
| NL168720C (nl) | 1982-05-17 |
| SU923351A3 (ru) | 1982-04-23 |
| JPS50115188A (en, 2012) | 1975-09-09 |
| FR2260382A1 (en, 2012) | 1975-09-05 |
| NL168720B (nl) | 1981-12-16 |
| DE2460560B2 (de) | 1979-08-23 |
| US4111841A (en) | 1978-09-05 |
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