CA1039802A - Lithium iodine battery having improved energy density - Google Patents
Lithium iodine battery having improved energy densityInfo
- Publication number
- CA1039802A CA1039802A CA238,554A CA238554A CA1039802A CA 1039802 A CA1039802 A CA 1039802A CA 238554 A CA238554 A CA 238554A CA 1039802 A CA1039802 A CA 1039802A
- Authority
- CA
- Canada
- Prior art keywords
- iodine
- current collector
- lithium
- cathode
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YFXWODPYUNGUEE-UHFFFAOYSA-N [I].[Li] Chemical compound [I].[Li] YFXWODPYUNGUEE-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 90
- 239000011630 iodine Substances 0.000 claims abstract description 90
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 88
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 25
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 12
- 239000004020 conductor Substances 0.000 claims description 7
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 5
- 239000011365 complex material Substances 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 2
- 239000008188 pellet Substances 0.000 abstract description 18
- 239000010406 cathode material Substances 0.000 abstract description 14
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract description 7
- 210000004027 cell Anatomy 0.000 description 42
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000011368 organic material Substances 0.000 description 4
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 230000000747 cardiac effect Effects 0.000 description 2
- 210000003850 cellular structure Anatomy 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000208140 Acer Species 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 229920001780 ECTFE Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- -1 iodine ions Chemical class 0.000 description 1
- ZFTKWAVDJBKFCS-UHFFFAOYSA-N iodine;pyridine Chemical compound [I].C1=CC=NC=C1 ZFTKWAVDJBKFCS-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/182—Cells with non-aqueous electrolyte with solid electrolyte with halogenide as solid electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/539,730 US3944433A (en) | 1975-01-09 | 1975-01-09 | Lithium iodine battery having improved energy density |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1039802A true CA1039802A (en) | 1978-10-03 |
Family
ID=24152418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA238,554A Expired CA1039802A (en) | 1975-01-09 | 1975-10-29 | Lithium iodine battery having improved energy density |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3944433A (OSRAM) |
| CA (1) | CA1039802A (OSRAM) |
| DE (1) | DE2550541A1 (OSRAM) |
| FR (1) | FR2297498A1 (OSRAM) |
| GB (1) | GB1525866A (OSRAM) |
| NL (1) | NL7600058A (OSRAM) |
| SE (1) | SE7600082L (OSRAM) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4072803A (en) * | 1976-08-20 | 1978-02-07 | Catalyst Research Corporation | Lithium halide cell |
| US4164070A (en) * | 1975-09-29 | 1979-08-14 | Eleanor & Wilson Greatbatch Foundation | Method of making a lithium-bromine cell |
| US4105833A (en) * | 1976-09-16 | 1978-08-08 | Eleanor & Wilson Greatbatch Foundation | Lithium-bromine cell |
| US4182798A (en) * | 1978-03-13 | 1980-01-08 | Medtronic, Inc. | Preformed polymer sheet in combination with the anode of electrochemical cells |
| US4315975A (en) * | 1979-08-15 | 1982-02-16 | Matsushita Electric Industrial Co., Ltd. | Solid-state lithium-iodine primary battery |
| US4278745A (en) * | 1980-02-25 | 1981-07-14 | Medtronic, Inc. | Cathode materials for electrochemical cells |
| US4267244A (en) * | 1980-03-28 | 1981-05-12 | Union Carbide Corporation | Layered charge transfer complex cathodes or solid electrolyte cells |
| US4340651A (en) * | 1980-11-12 | 1982-07-20 | Medtronic, Inc. | Cathode material and high capacity lithium-iodine cells |
| US5209994A (en) * | 1990-12-13 | 1993-05-11 | Medtronic, Inc. | Lithium-iodine electrochemical cells with improved end of life characteristics |
| JP5091573B2 (ja) * | 2007-07-17 | 2012-12-05 | 富士重工業株式会社 | 蓄電デバイス |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3653966A (en) * | 1969-05-08 | 1972-04-04 | Mallory & Co Inc P R | Separator and high energy cell having an organic charge transfer complex cathode |
| US3660163A (en) * | 1970-06-01 | 1972-05-02 | Catalyst Research Corp | Solid state lithium-iodine primary battery |
| US3723183A (en) * | 1971-02-04 | 1973-03-27 | Greatbatch Ltd | Lithium battery enclosure |
| US3773557A (en) * | 1972-03-01 | 1973-11-20 | Wurlitzer Co | Solid state battery |
| US3817791A (en) * | 1973-01-31 | 1974-06-18 | Greatbatch W Ltd | Lithium iodine battery |
| CA996631A (en) * | 1973-01-31 | 1976-09-07 | Wilson Greatbatch Ltd. | Enclosure for lithium-iodine cell and method of making the same |
| US3874929A (en) * | 1973-03-05 | 1975-04-01 | Wilson Greatback Ltd | Lithium-iodine battery |
| US3957533A (en) * | 1974-11-19 | 1976-05-18 | Wilson Greatbatch Ltd. | Lithium-iodine battery having coated anode |
-
1975
- 1975-01-09 US US05/539,730 patent/US3944433A/en not_active Expired - Lifetime
- 1975-10-29 CA CA238,554A patent/CA1039802A/en not_active Expired
- 1975-11-11 DE DE19752550541 patent/DE2550541A1/de not_active Withdrawn
- 1975-11-19 FR FR7535320A patent/FR2297498A1/fr active Granted
- 1975-11-25 GB GB48415/75A patent/GB1525866A/en not_active Expired
-
1976
- 1976-01-05 NL NL7600058A patent/NL7600058A/xx not_active Application Discontinuation
- 1976-01-07 SE SE7600082A patent/SE7600082L/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL7600058A (nl) | 1976-07-13 |
| US3944433A (en) | 1976-03-16 |
| FR2297498A1 (fr) | 1976-08-06 |
| SE7600082L (sv) | 1976-07-12 |
| GB1525866A (en) | 1978-09-20 |
| FR2297498B1 (OSRAM) | 1980-04-04 |
| DE2550541A1 (de) | 1976-07-15 |
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