CA1039170A - Rapid process for producing cemented panes of insulating glass - Google Patents

Abstract

A B S T R A C T
Method and apparatus for producing insulating glass. In the method, two or more glass panes are adhered to a spacer frame optionally containing a dehumidifying agent and the pane edge joints are sealed with a sealing material. The pane edge joints are filled with the sealing material and subsequently the sealing material is heated to 40 - 90°C using capacitive high frequency heating. The apparatus comprises means for supporting at least two panes of glass separated by a spacer located near the lateral edges of the glass, the edges and said spacer being joined by a deposit of uncured thermosetting sealant material; at least two spaced electrodes connected to a high frequency generator adapted to impart heat capacitively to the sealant;
and conveying means moving the sealed glass panes in the space between the electrodes.

Description

1039~70 The present invention relates to an improved method and apparatus for producing insulating glass. Insulating glass is here understood to mean planar double or multiple panes arranged parallel to one another. Due to their better sound and insulation properties they are being increasingly used, so that an improved manufacture thereof is of great importance.
Generally, spacers made from aluminium or iron plate connected to-gether by means of annular brackets are placed in the form of a frame construc-tion between the panes, so that the reciprocal spacing thereof does not change and the edge area is stabilized. In addition, the air gap is hermetically sealed from the ambient. The spacer frames are cemented to the panes by a hot extruded adhesive layer, e.g. of plastic butyl rubber, applied to both sides of the spacer. Misting of the inside of the insulating glass panes is preven-ted by filling the aluminium webs with a dehumidifying agent. The outer joints between the two panes and the aluminium web of the frame construction is then coated with an elastic sealing material which absorbs thermal expan-sions and contractions.
Whereas the tacky butyl rubber sprayed laterally onto the spacer frames remains plastic, the sealing material sprayed or trowelled into the outer joints hardens completely within a particular period of time, i.e.
within several hours, and after being left for a further period its surface becomes non-tacky. In each case the insulating glass manufacturer must care-fully respect this period before the panes are dispatched to ensure that the double or multiple panes do not separate during transportation.
In order to reduce the time required for complete hardening some insulating glass manufacturers store the panes of insulating glass coming from the production line in temperature-controlled rooms at about 40C. An even higher temperature in the rooms would lead to the advantage of a more rapid curing, but would simultaneously lead to the disadvantage that the air between the panes would be expanded to such an extent by the heating that the cement would become detached at the weakest point and air would be blown out .,~r~
- 1 - ~ i 1039i7() at the resulting permanent leakage point.
In a broad aspect, the invention resides in a method of producing insulating glass wherein two or more panes are adhered to a spacer frame con-taining a dehumidifying agent and wherein the pane edge joints are sealed with a thermosetting sealing material which employs as fillers or pigments materials which absorb electrical energy with a dielectric constant~ 200.
The pane edge joints are filled with the sealing material and are subsequently heated by capacitive high frequency heating to 40 - 90 C.
Optionally, before or after the heating the sealing material is covered with aluminium foil as a vapour barrier. Preferably the capacitive high frequency heating is performed in the kHz to MHz range.
The sealing material used should be of the thermosetting type.
Preferably two component systems are used which harden completely accompanied by cross-linkingg e.g. polyurethane or polysulphide sealing materials whereby the cross linking can be greatly accelerated by heating.
The process of the invention can be performed particularly advan-tageously if special sealing materials are used which strongly absorb elec-trical energy, and which contain components and/or additives wherein the dielectric constant and the dielectric loss factor are as large as possible.
Such sealing materials form the objects of my copending application No. 211,675 filed concurrently herewith. The sealing materials obtain the desired properties by using suitable basic polymers and plasticizers and/or by using fillers with a dielectric constant of >200. Titanates, zirconates and stannates of barium, strontium, calcium, magnesium and lead, preferably barium titanate, are particularly suited to act as the fillers. These sealing materials absorb to an increased extent the energy from the alternating electric field which is converted into heat.
In a further broad aspect, the invention resides in an apparatus for producing insulating glass comprising, la) means for supporting at least ~ - 2 -10;~70 two panes of glass separated by a spacer located near the lateral edges of the glass, said edges and said spacer being,joined by a deposit of uncured thermo-setting sealant material;

,~
JJ' 10391~0 (b) at least two spaced electrodes connected to a high frequency generator adapted to impart heat capacitively to said sealant, and ~ c) conveying means moving said sealed glass panes in the space between said electrodes.
In the apparatus, two pairs of electrodes can be arran-ged parallel to one another in such a way that two facing pane edge joints can be simultaneously heated. Frequently, however, it is more advantageous for the pairs of electrodes to be staggered relative to one another in the conveying direction because phase displace-ments could occur as a result of the metal spacer frames in the case of simultaneous capacitive heating of two facing pane edge joints.
The electrodes are preferably arranged in a movable manner so that it is possible to adapt to the particular pane width.
There are various possibilities for the operation of the apparatus. It is firstly possible for the panes of insulating glass, and therefore their edge joints to be discontinuously or pre-ferably continuously passed between stationary high frequency elec-trodes. ~owever, it is also possible for the h.f. electrodes to be passed over the pane edge joints which again implies a discontinuous process.
After heating the sealing material of two facing pane edge joints, the heating of the two remaining joints takesplace.
For this purpose the conveying means should either be constructed in such a way that a 90 direction change of the panes takes place, followed by the panes being passed between furth~r pairs of elec-trodes, or alternatively the conveying direction for the panes of insulating glass can be retained if in the device between the first two and the following two pairs of electrodes a rotary table is arranged which rotates the panes by 90.

1039~70 For the further explanation of the invention, refer-ence should be made to the attached drawings wherein:
Figure 1 is a schematic representation of the perfor-mance of the process according to the invention using the apparatus according to the invention;
Figures 2 - 4 show various arrangements of the h.f.
electrodes for the capacitive heatingJ Figures 2a - 4a being in cross section and Figures 2b - 4b in plan view.
The technical performance of the process can take place in such a way that the panes of insulating glass 21, which in the conventional manner are cemented with a spacer frame 22 which is generally filled with a dehumidifying agent, pass into the apparatus (starting at the left-hand bottom side of Figure 1) on feed rolls or rollers 2, and are aligned by latterally positioned back-up rollers 12. The width of the panes is scanned by a mechanical or photo-electric contact barrier 1 and the value is transmitted to a roller table 3 whose width is adjustable. The width of the Case 2403 1039~70 conveyor is such that the edges of the panes project appro~imately 15-20 cm over the rollers or rolls of table 3 parallel to the conveying direction.
The two components of the sealing material used are combined in a mixing plant 7. By means of a spraying device 8 the sealing material 24 is sprayed on both sides into the edge joints parallel to the conveying direction between the spacer 22 and the two or more panes 21. Excess material is removed with a stripper 9. The sealing material is covered with a thin aluminium foil 10 and pressed down with a roller 11. This outer aluminium layer serves as an effective water vapour diffusion barrier which delays misting of the space between the panes, and simultaneously prevents the sealing material running out during the capacitive heating process.
However, it can also be applied after heating.
The thus prepared edge joints now pass between a pair of electrodes 13 on either side which in each case are connected to a high frequency generator 14 of corresponding capacity and frequency. The length of the electrode rails and the distance between the same and the pane depend on the cross-linking duration of the sealing material, the feed rate for the panes and the electrical capacity of the h.f. generator.
After passing through the first group of electrodes the pane moves into a transverse conveyor 4. After making contact with a contact 5, conveying is briefly interrupted and then conveying continues perpendicular to the conveying direction hitherto used. In this second conveying path in which direction are directed two edge joints not yet filled with sealing Case 2403 1039i70 material, the above-described process stages are repeated, i.e. aligning the pane on the conveyor belt, scanning the pane width, setting the spraying nozzle spacing, filling the joints, stripping the sealing material, covering the sealing material with a strip of aluminium foil and passage through a second group of high frequency electrodes on both sides having an adjustable width.
It must be ensured that the panes of insulating glass are well sealed with sealing material in the corners where the aluminium foils overlap so that the advantage of the water vapour diffusion barrier is not lost through leaks.
Alternatively the conveying direction can be maintained if a rotary table for rotating the panes by 90 is arranged between the first and second feeding and hardening section; the remaining operating members of the apparatus and the process sequence remain substantially unchanged.
Various possibilities exist for the arrangement of the electrodes for capacitively heating the sealing mass in the pane edge joints. Figs. 2-4 show particularly preferred arrangements.
The pane of insulating glass comprises in each case two parallel glass panes 21 of identical size which are separated from one another by a spacer 22. The frame-like spacer 22 is cemented to the glass panes 21 by means of a permanently plastic sealing material 23 having a low water vapour diffusion value. In the edge joint formed by the two glass panes 21 Case 2403 ~039~70 and the metal spacer 22 is located the sealing material 24 which must be completely hardened to give a permanent elastic seal.
According to the embodiment of Fig. 2 the h.f. electrodes 25 and 25' are arranged above and below the pane edge joint of the horizontal insulating glass pane. The pane of insulating glass which passes between the facing electrodes with the aid of the conveyor traverses with its edge area the alternating electric field maintained between the electrodes, so that as a result of the absorption of electrical energy heating of the sealing material 24 takes place.
In the embodiment of Fig. 3 the h.f. electrodes 26 and 26' are arranged sequentially and parallel to the edge of the insulating glass pane.
The metal spacer 22 serves as a bridge for forming the necessary alternating electric field. In this embodiment the panes of insulating glass are once again preferably moved continuously past the electrodes.
A particularly favorable arrangement of the h.f. electrodes is shown in Fig. 4, wherein the h.f. electrodes 27 and 27', arranged above and below the edge joint of the insulating glass pane, are connected in parallel, whilst a lateral central electrode 28 serves as the counter-electrode. In this way a particularly dense alternating electric fieldiS obtained resulting in rapid heating of the sealing material 24. This electrode arrangement is suitable both for a stationary apparatus wherein the insulating glass pane passes through the space between the electrodes and for a movable apparatus which can be moved along the edge joints of an insulating glass pane.

1039~70 The particular advantage of the process according to the invention is that the panes of insulating glass are only heated in the edge area, whereas the air gap between the panes is scarcely heated. For this reason a hardening temperature above 40C, e.g. a temperature of about 70C, can be used without there being any danger of the intermediate air being blown out at the weakest cementing point. Therefore, on leaving the production plant after only standing for a short time the panes can be made ready for despatch which results in a considerable space-saving.
Without passing beyond the scope of the invention it is possible to make numerous changes in the process with horizontal pane conveying as regards the conveying devices, the adjustment of the electrode width and spacings, the filling with the sealing material and the arrangement of the electrode rails of the h.f. generator.
The following Examples serve to further illustrate the invention which by means of model tests illustrate the curing of a self-adhering seal-ing material for insulating glass.

A self-adhering polysulphide sealing material for insulating glass (Terostat 990)* was coated onto a polyethylene cup 12 mm high with a dia-meter of 30 TMm, and with an electrode spacing of 25 mm was heated for 12 sec. by means of a 0.5 kW h.f. generator.

* Trademark Case 2403 1039170 Initial temperature (TI~ = 31.5C
Final temperature (TII~ = 49C
% temperature increase TII - TI 100 = 55 6%
TI
a non-tacky state was reached after 60 minutes.
Shore A hardness after 3 hours - 18 19 Shore A hardness after 6 hours - 37 ........

The freshly mixed sealing material of Example 1 was coated onto polyethylene cups with the same dimensions, and with an electrode spacing of 20 mm was heated for 12 sec. with a 0.5 kW h.f. generator.
Initial temperature (TI~ = 33C
Final temperature (TII~ = 61C
temperature increase TII - TI . 100 = 84.8%
Tl a non-tacky state was reached after 40 minutes.
Shore A hardness after 3 hours - 25-26 Shore A hardness after 6 hours - 36 , _g _ Case 2403 The freshly mixed sealing material of Example 1 was coated onto polyethylene cups with the same dimensions, and with an electrode spacing of 20 mm was heated for 20 sec. with 0.5 kW h.f. generator.
Initial temperature (TI) = 33C
Final temperature (TII) = 83C
Temperature increaSe TII - TI . 100 = 151.5%
TI
a non-tacky state was reached after 6 minutes.
Shore A hardness after 3 hours = 26 Shore A hardness after 6 hours = 36 Without the h.f. heating according to the invention the sealing mass used in the three Examples only reached a non-tacky state after about 6 hours and after 18-20 hours reached 2 Shore A hardness of approximately 28.

Claims (14)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. In the method of producing insulating glass wherein two or more panes are adhered to a spacer frame optionally containing a dehumidifying agent and the pane edge joints are sealed with a thermosetting sealing material, the improvement comprising filling the pane edge joints with a sealing material, which employs as fillers or pigments materials which absorb electrical energy with a dielectric constant > 200, and subsequently heating the sealing material to 40-90°C using capacitive high frequency heating.

2. The method of claim 1 wherein before or after the heating the sealing material is covered by a foil which acts as a water vapor barrier.

3. The method of claim 1 wherein the capacitive high frequency heat-ing is carried out in the kHz to MHz range.

4. The method of claim 1 wherein a sealing material which strongly absorbs electrical energy is used which contains components and/or additives with maximum values for the dielectric constant and dielectric loss factor.

5. An apparatus for producing insulating glass comprising, (a) means for supporting at least two panes of glass separated by a spacer located near the lateral edges of the glass, said edges and said spacer being joined by a deposit of uncured thermosetting sealant material; (b) at least two spaced electrodes connected to a high frequency generator adapted to impart heat capacitively to said sealant, and (c) conveying means moving said sealed glass panes in the space between said electrodes.

6. The apparatus of claim 5 wherein said support means and said con-veying means comprise at least one pair of rollers.

7. The apparatus of claim 5 additionally having means for applying said sealant to said spacer and pane edges.

8. The apparatus of claim 5 wherein said means is adapted to apply said sealant in the form of a spray.

9. The apparatus of claim 5 additionally having means for applying an impermeable foil to the surface of said sealant.

10. The apparatus of claim 5 wherein said electrodes are arranged later-ally of the conveying means such that said pane edges pass continuously between said electrodes.

11. The apparatus of claim 5 wherein said electrodes are movable along the pane edges.

12. The apparatus of claim 5 wherein said conveying means has means for changing the feed direction of said glass panes by 90°.

13. The apparatus of claim 5 wherein said conveying means comprises a rotatable table.

14. The apparatus of claim 5 additionally having means for adjusting the space between said electrodes dependent upon the width of said panes.