BRPI1104602A2 - polÍmero em emulsço de multiestÁgios, mÉtodos para formar um polÍmero em emulsço de multiestÁgicos e para prover um revestimento, partÍcula compàsita, e, composiÇço aquosa de revestimento - Google Patents
polÍmero em emulsço de multiestÁgios, mÉtodos para formar um polÍmero em emulsço de multiestÁgicos e para prover um revestimento, partÍcula compàsita, e, composiÇço aquosa de revestimento Download PDFInfo
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- BRPI1104602A2 BRPI1104602A2 BRPI1104602-3A BRPI1104602A BRPI1104602A2 BR PI1104602 A2 BRPI1104602 A2 BR PI1104602A2 BR PI1104602 A BRPI1104602 A BR PI1104602A BR PI1104602 A2 BRPI1104602 A2 BR PI1104602A2
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- weight
- monomer
- emulsion polymer
- acid
- multistage
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- 239000004908 Emulsion polymer Substances 0.000 title claims abstract description 104
- 238000000576 coating method Methods 0.000 title claims abstract description 73
- 239000011248 coating agent Substances 0.000 title claims abstract description 51
- 239000008199 coating composition Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 30
- 239000011246 composite particle Substances 0.000 title claims abstract description 20
- 239000000178 monomer Substances 0.000 claims abstract description 173
- 239000002253 acid Substances 0.000 claims abstract description 74
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000839 emulsion Substances 0.000 claims abstract description 47
- 229920000642 polymer Polymers 0.000 claims abstract description 32
- 239000000203 mixture Substances 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 34
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 125000005395 methacrylic acid group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 63
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 47
- -1 acryloxy, methacryloxy, styryl Chemical group 0.000 description 41
- 239000002131 composite material Substances 0.000 description 32
- 239000013543 active substance Substances 0.000 description 21
- 239000004408 titanium dioxide Substances 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 20
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- 238000002156 mixing Methods 0.000 description 19
- 239000010408 film Substances 0.000 description 18
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- 239000003085 diluting agent Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 229920002125 Sokalan® Polymers 0.000 description 10
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 239000003999 initiator Substances 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
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- 241001093575 Alma Species 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 239000003139 biocide Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
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- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
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- 239000003638 chemical reducing agent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
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- 150000002148 esters Chemical class 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
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- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
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- 229910021529 ammonia Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
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- 239000013530 defoamer Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 2
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- 125000004356 hydroxy functional group Chemical group O* 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
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- FVEFRICMTUKAML-UHFFFAOYSA-M sodium tetradecyl sulfate Chemical compound [Na+].CCCCC(CC)CCC(CC(C)C)OS([O-])(=O)=O FVEFRICMTUKAML-UHFFFAOYSA-M 0.000 description 2
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- AZGLQACAXHUAOK-TYYBGVCCSA-N (e)-but-2-enedioic acid;phosphono dihydrogen phosphate Chemical compound OC(=O)\C=C\C(O)=O.OP(O)(=O)OP(O)(O)=O AZGLQACAXHUAOK-TYYBGVCCSA-N 0.000 description 1
- QULBNKHMPKDBJG-UHFFFAOYSA-N 1-[2-[(2-hydroxy-3-prop-2-enoxypropyl)amino]ethyl]imidazolidin-2-one Chemical compound C=CCOCC(O)CNCCN1CCNC1=O QULBNKHMPKDBJG-UHFFFAOYSA-N 0.000 description 1
- VJMVRFXCVYILRL-UHFFFAOYSA-N 1-ethenoxy-2-methylpropan-2-amine Chemical compound CC(C)(N)COC=C VJMVRFXCVYILRL-UHFFFAOYSA-N 0.000 description 1
- VSDMVRFSCLVCOF-UHFFFAOYSA-N 1-ethenoxybutan-2-amine Chemical compound CCC(N)COC=C VSDMVRFSCLVCOF-UHFFFAOYSA-N 0.000 description 1
- GSSDUXHQPXODCN-UHFFFAOYSA-N 1-phenylethenylphosphonic acid Chemical compound OP(O)(=O)C(=C)C1=CC=CC=C1 GSSDUXHQPXODCN-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
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- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
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- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
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- BTFPHODXQGLBMA-UHFFFAOYSA-N 2-methylprop-2-enoic acid;urea Chemical compound NC(N)=O.CC(=C)C(O)=O BTFPHODXQGLBMA-UHFFFAOYSA-N 0.000 description 1
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- JPVNTYZOJCDQBK-UHFFFAOYSA-N 3-ethenoxypropan-1-amine Chemical compound NCCCOC=C JPVNTYZOJCDQBK-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
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- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Graft Or Block Polymers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
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| US40277110P | 2010-09-03 | 2010-09-03 |
Publications (1)
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|---|---|
| BRPI1104602A2 true BRPI1104602A2 (pt) | 2013-01-15 |
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| EP (1) | EP2426155B2 (OSRAM) |
| JP (2) | JP2012067283A (OSRAM) |
| KR (1) | KR101310639B1 (OSRAM) |
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| AU (1) | AU2011213895B2 (OSRAM) |
| BR (1) | BRPI1104602A2 (OSRAM) |
| CA (1) | CA2749419C (OSRAM) |
| ES (1) | ES2440797T5 (OSRAM) |
| MX (1) | MX348804B (OSRAM) |
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| AU2012355548B2 (en) * | 2011-12-19 | 2016-01-14 | Rohm And Haas Company | Sulfur acid functionalized latex polymer |
| AU2013215275A1 (en) | 2012-01-31 | 2014-08-07 | Rohm And Haas Company | Dispersion of adsorbing emulsion polymer particles |
| EP2928934B1 (en) * | 2012-12-05 | 2018-10-24 | Rohm and Haas Company | Stable aqueous dispersion of particle polymers containing structural units of 2-(methacryloyloxy)ethyl phosphonic acid and composites thereof |
| US8895658B2 (en) * | 2012-12-18 | 2014-11-25 | Columbia Insurance Company | Grafted pigment dispersing polymeric additive and paint employing the same with improved hiding |
| EP2762502B1 (en) * | 2013-02-04 | 2020-07-29 | Rohm and Haas Company | Acrylic latex binder and method of preparation |
| EP2986677A4 (en) * | 2013-04-15 | 2016-11-02 | Rohm & Haas | POLYMER PARTICLES ADSORBED BY SULFATE PROCESS STITAIDE |
| KR102144306B1 (ko) | 2014-06-20 | 2020-08-13 | 다우 글로벌 테크놀로지스 엘엘씨 | 다단계 라텍스 폴리머, 이의 제조 방법, 및 이로 제조된 코팅 조성물 |
| CN106459716B (zh) * | 2014-06-27 | 2019-10-18 | 罗门哈斯公司 | 用于制造玻璃纤维产品的经含亚磷酸单体的乳液聚合物改性的脲-甲醛树脂组合物 |
| US9475932B2 (en) * | 2014-08-08 | 2016-10-25 | Rohm And Haas Company | Composition comprising a latex and a HEUR thickener |
| CN107109088B (zh) | 2014-11-03 | 2019-09-20 | 本杰明·摩尔公司 | 用于提高的遮盖的添加剂及包含其的漆组合物 |
| CA2912294C (en) * | 2014-12-01 | 2023-01-03 | Dow Global Technologies Llc | Phosphorus acid functionalized opaque polymer |
| CA2913351A1 (en) * | 2014-12-19 | 2016-06-19 | Rohm And Haas Company | Polyvinyl acetate latex |
| BR102016004995A2 (pt) | 2015-03-24 | 2017-01-24 | Rohm & Haas | látex bimorfológico |
| CA2940732C (en) | 2015-09-17 | 2023-10-03 | Rohm And Haas Company | Pigmented paint formulation with a phosphorus acid functionalized latex binder and an associative thickener |
| CN108602924A (zh) | 2015-12-02 | 2018-09-28 | 阿科玛股份有限公司 | 乳液聚合物及由其制备的低voc涂料组合物 |
| ES2996808T3 (en) | 2015-12-02 | 2025-02-13 | Arkema Inc | Emulsion polymers and stain resistant coating compositions made therefrom |
| MX388406B (es) | 2015-12-18 | 2025-03-19 | Rohm & Haas | Composiciones polimericas en emulsion de multi-etapas acuosas para usarse en aplicaciones de ebanisteria. |
| WO2017172411A1 (en) * | 2016-03-28 | 2017-10-05 | Dow Global Technologies Llc | Compositions, aqueous coating compositions, and methods for improving the freeze/thaw stability of aqueous coating compositions |
| WO2017191167A1 (en) | 2016-05-04 | 2017-11-09 | Basf Se | Process for preparing an aqueous polymer latex |
| US20190169458A1 (en) * | 2016-08-08 | 2019-06-06 | Asahi Kasei Kabushiki Kaisha | Coating composition dispersion, aqueous dispersion of composite particles and method for producing aqueous dispersion of composite particles |
| CA2977989C (en) | 2016-09-22 | 2025-09-02 | Rohm And Haas Company | ON-SITE PREPARATION OF BIOMORPHOLOGICAL LATEX PRIMED BY OXIDATION-REDUCTION |
| WO2018065574A1 (en) | 2016-10-07 | 2018-04-12 | Basf Se | Latex paint containing titanium dioxide pigment |
| CN109804026A (zh) | 2016-10-07 | 2019-05-24 | 巴斯夫欧洲公司 | 含二氧化钛颜料的乳胶漆 |
| WO2018120527A1 (zh) * | 2016-12-30 | 2018-07-05 | 常州大学 | 乳液聚合室温制备支化聚合物的方法 |
| CN111315832B (zh) | 2017-11-10 | 2025-06-17 | 巴斯夫欧洲公司 | 水性聚合物分散体 |
| KR102262503B1 (ko) | 2018-12-17 | 2021-06-08 | 주식회사 엘지화학 | 아크릴계 에멀젼 수지의 제조 방법 |
| CN110294960B (zh) * | 2019-07-30 | 2022-01-28 | 高碑店市隆泰丰博石墨烯有限公司 | 冰点在-20℃以下防冻型水性石墨烯电热浆及制备方法 |
| BR112022011769A2 (pt) | 2019-12-16 | 2022-08-30 | Basf Se | Uso de um látex de polímero aquoso, composição aquosa de revestimento, e, látex de polímero aquoso |
| CA3188871A1 (en) * | 2020-08-14 | 2022-02-17 | Sudhir M. Mulik | High acid acrylic or styrene acrylic emulsion copolymer modified urea formaldehyde binders for mineral fibers |
| EP3957659A1 (en) * | 2020-08-19 | 2022-02-23 | Evonik Operations GmbH | Functionalized polymers |
| US20230312972A1 (en) | 2020-09-03 | 2023-10-05 | Arkema Inc. | Coating composition with improved block and humidity resistance, direct to metal adherence and low voc content |
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| US4325856A (en) | 1980-01-02 | 1982-04-20 | The Dow Chemical Company | Sequential emulsion polymerization process |
| DE3017543A1 (de) | 1980-05-08 | 1981-11-26 | Bayer Ag, 5090 Leverkusen | Waessrige dispersionen auf basis von (meth)acrylsaeurealkylester-polymerisaten mit zwei ausgepraegten, praktisch sich nicht ueberlappenden maxima in der teilchengroessenverteilung innerhalb spezieller teilchengroessenbereiche, sowie verfahren zu ihrer herstellung und ihre verwendung |
| DE3319340A1 (de) | 1983-05-27 | 1984-11-29 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung bi- oder polymodaler waessriger kunststoffdispersionen |
| DE3443964A1 (de) | 1984-12-01 | 1986-06-12 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von polymer-dispersionen, die blockfeste filme bilden |
| US4814373A (en) | 1984-12-20 | 1989-03-21 | Rohm And Haas Company | Modified latex polymer composition |
| GB8504726D0 (en) | 1985-02-23 | 1985-03-27 | Standard Telephones Cables Ltd | Integrated circuits |
| US4733005A (en) | 1986-04-21 | 1988-03-22 | The Dow Chemical Company | Phosphinyl-containing ethylenically unsaturated compounds |
| US5087665A (en) | 1989-12-20 | 1992-02-11 | Mobay Corporation | Toughened, hydrolysis resistant polycarbonate/polyester blends |
| US5385960A (en) * | 1991-12-03 | 1995-01-31 | Rohm And Haas Company | Process for controlling adsorption of polymeric latex on titanium dioxide |
| US6080802A (en) | 1991-12-03 | 2000-06-27 | Rohm And Haas Company | Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide |
| DE19750618A1 (de) | 1997-11-14 | 1999-05-20 | Basf Ag | Pigmenthaltige Zubereitungen auf der Basis wässriger Polymerisatdispersionen |
| AU782594B2 (en) * | 2000-11-21 | 2005-08-11 | Rohm And Haas Company | Polymer-pigment composites |
| US6545084B2 (en) | 2001-02-23 | 2003-04-08 | Rohm And Haas Company | Coating composition |
| AU785282B2 (en) | 2001-06-20 | 2006-12-21 | Rohm And Haas Company | Coating with improved hiding, compositions prepared therewith, and processes for the preparation thereof |
| US7179531B2 (en) * | 2002-09-12 | 2007-02-20 | Rohm And Haas Company | Polymer particles having select pendant groups and composition prepared therefrom |
| EP1496091A1 (en) * | 2003-07-08 | 2005-01-12 | Rohm And Haas Company | Aqueous polymer composition |
| US7285590B2 (en) | 2003-11-13 | 2007-10-23 | Hexion Specialty Chemicals, Inc. | Aqueous dispersions containing multi-stage emulsion polymers |
| EP1574533B1 (en) | 2004-03-09 | 2007-11-14 | Rohm And Haas Company | Aqueous dispersion of polymeric particles |
| FR2867478B1 (fr) | 2004-03-10 | 2006-04-28 | Cray Valley Sa | Dispersion aqueuse de polymere pour revetement barriere |
| US20050222299A1 (en) | 2004-04-01 | 2005-10-06 | Alain Garzon | Aqueous coating composition |
| AU2006203398B2 (en) * | 2005-08-19 | 2011-09-29 | Rohm And Haas Company | Aqueous dispersion of polymeric particles |
| NZ553410A (en) | 2006-03-02 | 2008-06-30 | Rohm & Haas | Scrub and stain-resistant copolymer coating composition |
| US7695770B2 (en) * | 2006-09-21 | 2010-04-13 | Rohm And Haas Company | Coating binder polymer and coatings |
| US8877852B2 (en) | 2006-12-15 | 2014-11-04 | Rohm And Haas Company | Phosphorous-containing organic polymer and compositions and processes including same |
| JP4792052B2 (ja) | 2007-04-30 | 2011-10-12 | ローム アンド ハース カンパニー | 水性コポリマー分散体およびコーティング組成物 |
| EP2077301B1 (en) * | 2008-01-02 | 2016-10-19 | Rohm and Haas Company | Scrub and stain-resistant coating |
-
2011
- 2011-08-17 EP EP11177867.6A patent/EP2426155B2/en active Active
- 2011-08-17 JP JP2011178307A patent/JP2012067283A/ja active Pending
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| EP2426155B1 (en) | 2013-10-16 |
| CN102417560B (zh) | 2015-11-25 |
| MX348804B (es) | 2017-06-28 |
| ES2440797T5 (es) | 2017-10-31 |
| KR101310639B1 (ko) | 2013-09-25 |
| JP2014194035A (ja) | 2014-10-09 |
| JP5837961B2 (ja) | 2015-12-24 |
| AU2011213895B2 (en) | 2013-11-21 |
| EP2426155A1 (en) | 2012-03-07 |
| MX2011009238A (es) | 2012-03-29 |
| CA2749419A1 (en) | 2012-03-03 |
| US20120058277A1 (en) | 2012-03-08 |
| CA2749419C (en) | 2014-09-30 |
| ES2440797T3 (es) | 2014-01-30 |
| EP2426155B2 (en) | 2017-06-28 |
| KR20120024501A (ko) | 2012-03-14 |
| CN102417560A (zh) | 2012-04-18 |
| JP2012067283A (ja) | 2012-04-05 |
| US9447215B2 (en) | 2016-09-20 |
| AU2011213895A1 (en) | 2012-03-22 |
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Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2529 DE 25-06-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |