BRPI0908253B1 - CONCENTRATES FOR OIL-BASED SUSPENSION, AS WELL AS THEIR PREPARATION PROCESS AND APPLICATION, AND AGENT - Google Patents

Abstract

CONCENTRATES FOR OIL-BASED SUSPENSION, AS WELL AS THEIR PREPARATION PROCESS AND APPLICATION, AND AGENT. The present invention relates to oil-based suspension concentrates, consisting of at least one compound of formula (1), solid at room temperature, at least one penetration promoter, at least one vegetable oil, at least one non-toxic surfactant. ionic and/or at least one anionic surfactant and, optionally, one or more additives from the groups of emulsifying agents, foam inhibiting agents, preservative agents, antioxidants, colorants and/or inert filler materials, a process for preparing these concentrates for suspension, as well as their use for applying the active substances contained on plants and/or their habitat and for combating insects.

Description

The present invention relates to new oil-based suspension concentrates of cyclic keto-enols of formula (I), to a process for the preparation of these formulations and to their use for the application of cyclic keto-enols of formula (I ) contained therein, to plants and/or their habitat and to combat insects.

It is already known that certain cyclic keto-enols have insecticidal and/or acaricidal properties (see, for example, documents WO 98/05638 and WO 04/007448). Numerous water-free suspension concentrates are also known. Therefore, document number EP-A 0 789 999 describes formulations of this type, which, in addition to the active substance and the oil, comprise a mixture of several surfactants - including surfactants serving as penetration promoters - and also an alum. -hydrophobized stratified silicate as thickening agent. The stability of these preparations is good. However, they have the disadvantage that a thickening agent is necessarily present, and this makes the preparation more complicated. Furthermore, the thickening agent absorbs, in each case, part of the added amount of penetration promoter, which is then not available for its intended purpose.

Document number WO 03/000053 describes formulations of this type which, in addition to the active substance and the oil, comprise a mixture of several surfactants - including surfactants serving as penetration promoters. The described formulations do not require a thickening agent for stabilization. In this publication, the synergistic effect of vegetable oils and penetration promoters is emphasized. Such formulations have the advantage that their preparation is less complicated than the preparation of corresponding formulations comprising thickening agents. However, cyclic keto-enols of formula (I) are not mentioned.

Document number WO 05/084441 describes formulations of this type, which, in addition to certain cyclic and oil keto-enols, comprise a penetration promoter. Here, alkanol ethoxylates are mentioned as particularly preferred penetration promoters. However, these formulations do not comprise a thickening agent.

The oil-based suspension concentrates of cyclic keto-enols described in document number WO 05/084441 have the disadvantage that these formulations have a very high viscosity, in particular at temperatures below 10°C. The advantage of the high viscosity of oil-based suspension concentrates is the fact that, due to the high viscosity, it is possible to avoid sedimentation of the suspension particles in the concentrate. However, as a result of the great increase in low temperatures, products, when used under such conditions, do not flow freely from the packaging. Furthermore, it is problematic to prepare aerosol liquor using highly viscous formulations.

Consequently, it is the object of the present invention to provide storable, stable oil-based suspension concentrates, without the addition of thickening agents, which concentrates, in general and in particular at temperatures below 10°C, which have low viscosity and are, therefore, easy to apply by the user.

New oil-based suspension concentrates have now been developed, comprising: - at least one compound, solid at room temperature, of formula (I): in which: -alkyl in each case optionally substituted with halogen, optionally substituted, saturated cycloalkyl, in which optionally at least one ring atom is replaced by a heteroatom, B represents hydrogen or alkyl, or A and B, together with the hydrogen atom carbon to which they are attached, represent a saturated or unsaturated cycle, unsubstituted or substituted, which eventually contains at least one heteroatom, D represents NH or oxygen, G represents hydrogen (a) or represents one of the groups: in which: E represents a metal ion or an ammonium ion, L represents oxygen or sulfur, M represents oxygen or sulfur, R1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl in each case optionally substituted with halogen, or cycloalkyl optionally substituted with halogen, alkyl or alkoxy, which may be interrupted by at least one heteroatom, phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl in each case eventually substituted, R2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl in each case eventually substituted with halogen or represents cycloalkyl, phenyl or benzyl in each case optionally substituted, R3 represents alkyl optionally substituted with halogen or optionally substituted phenyl, R4 and R5, independently of each other, represent alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio in each case eventually substituted with halogen, or represent phenyl, benzyl, phenoxy or phenylthio in each case eventually substituted and R6 and R7, independently of each other, represent hydrogen, alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl in each case eventually substituted with halogen, represent possibly substituted phenyl, represent possibly substituted benzyl or, together with the nitrogen atom to which they are attached, represent a possibly substituted ring, which is eventually interrupted by oxygen or sulfur, in the form of their mixtures of isomers or their pure isomers, - at least one penetration promoter of formula (II): R8-O-(-OP-)q-(-OE-)p-R9 (II) in which: R8 represents chain alkyl linear or branched with 4 to 20 carbon atoms, R9 represents H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, n-pentyl or n-hexyl, EO represents CH2-CH2 -O-, PO represents p represents numbers from 4 to 8 and q represents numbers from 6 to 10, - at least one vegetable oil, - at least one non-ionic surfactant selected from the group consisting of: - polyethylene oxide - polypropylene oxide - 4-butoxy- butyl ether, - polyethylene glycol ethers of straight-chain alcohols, - reaction products of fatty acids with ethylene oxide and - mixtures of these surfactants mentioned above and/or - at least one anionic surfactant and - optionally one or more additives from from the groups of emulsifying agents, spreading agents, foam-inhibiting agents, preserving agents, antioxidants, coloring agents and/or inert fillers (materials that do not have any effect on the viscosity of the formulation).

Furthermore, it has been found that oil-based suspension concentrates according to the invention can be prepared by mixing the above-mentioned ingredients with each other and then optionally grinding the resulting suspension.

Finally, it was found that the oil-based suspension concentrates according to the invention are highly suitable for applying the compounds of formula (I), comprised therein, to plants and/or their habitat.

Furthermore, it has been found that the oil-based suspension concentrates according to the invention are highly suitable for combating insects.

It is extremely surprising that the oil-based suspension concentrates according to the invention have a considerably lower viscosity, in particular at temperatures below 10°C, compared to prior art formulations of the most similar composition. Based on the prior art described above, this effect was unpredictable. Furthermore, it is very surprising that the biological activity of the oil-based suspension concentrates according to the invention is better than that of the prior art formulations of the most similar composition. Finally, it is also surprising that the compatibility of the formulations with plants has been improved, although the assimilation of the plant-active substances has been increased.

Preferred, spatially preferred, most especially preferred, particularly preferred and emphasized definitions of substituents for compounds of formula (I) are illustrated below: W preferably represents hydrogen, C1-C4-alkyl, C1-C4-alkoxy, chlorine, bromine or fluorine, alkyl, halogen, CrC4-alkoxy or CrC4-haloalkyl, A preferably represents hydrogen or C1-C6-alkyl or C3-C8-cycloalkyl in each case optionally substituted with halogen, B preferably represents hydrogen, methyl or ethyl, A , B and the carbon atom to which they are attached preferably represent C3-C6-saturated cycloalkyl, in which eventually one ring member is replaced by oxygen or sulfur, and which is eventually mono- or disubstituted with C!- C4-alkyl, trifluoromethyl or C1-C4-alkoxy, D preferably represents NH or oxygen, G preferably represents hydrogen (a) or represents one of the groups: in which: E represents a metal ion or an ammonium ion, L represents oxygen or sulfur and M represents oxygen or sulfur, R1 preferably represents Ci-Ci0-alkyl, C2-Cio-alkenyl, Ci-C4-alkoxy-Ci -C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl in each case optionally substituted with halogen or C3-C6-cycloalkyl optionally substituted with fluorine, chlorine, C1-C4-alkyl or C1-C2-alkoxy, represents phenyl optionally substituted with fluorine, chlorine, bromine, cyano, nitro, C1-C4-alkyl, C1-C4-alkoxy, trifluoromethyl or trifluoromethoxy, represents pyridyl or thienyl in each case optionally substituted with chlorine or methyl, R2 preferably represents C1-Cio-alkyl, C2-Cio-alkenyl, Cr C4-alkoxy-C2-C4-alkyl in each case optionally substituted with fluorine or chlorine, represents C5-C6-cycloalkyl optionally substituted with methyl or methoxy or represents phenyl or benzyl in each case optionally substituted with fluorine, chlorine, bromine, cyano, nitro, C1-C4-alkyl, C1-C4-alkoxy, trifluoromethyl or trifluoromethoxy, R3 preferably represents C1-C4-alkyl optionally substituted with fluorine or represents phenyl optionally substituted with fluorine, chlorine, bromine, C1-C4-alkyl, CrC4-alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, R4 preferably represents C1-C4-alkyl, CrC4-alkoxy, C1-C4-alkylamino, Ci- C4-alkylthio in each case optionally substituted with fluorine or chlorine or represents phenyl, phenoxy or phenylthio in each case optionally substituted with fluorine, chlorine, bromine, nitro, cyano, C1-C4-alkoxy, trifluoromethoxy, C1-C4-alkylthio, Ci -C4-haloalkylthio, C1-C4-alkyl or trifluoromethyl, R5 preferably represents C1-C4-alkoxy or C1-C4-thioalkyl, R6 preferably represents C1-Ce-alkyl, C3-C6-cycloalkyl, Cr C6- alkoxy, C3-C6-alkenyl or C1-C4-alkoxy-C1-C4-alkyl, R7 preferably represents C1-C6-alkyl, C3-C6-alkenyl or C1-C4-alkoxy-C1-C4-alkyl , R6 and R7, together, preferably represent a C3-C6-alkylene radical optionally substituted with methyl or ethyl, in which eventually a carbon atom is replaced by oxygen or sulfur, in the form of their mixtures of isomers or their pure isomers. W especially preferably represents hydrogen, methyl, ethyl, chlorine, bromine or methoxy, , especially preferably, represents hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy, A especially preferably, represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl, s-butyl, t-butyl, cyclopropyl, cyclopentyl or cyclohexyl, B especially preferably represents hydrogen, methyl or ethyl, or A, B and the carbon atom to which they are attached, especially preferably represents C5-C6- saturated cycloalkyl, in which optionally one ring member is substituted by oxygen, and which is optionally monosubstituted with methyl, ethyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy, D especially preferably represents NH or oxygen, G especially preferably , represents hydrogen (a) or represents one of the groups: in which: M represents oxygen or sulfur, R1 especially preferably represents Ch-Cs-alkyl, C2-C4- alkenyl, methoxymethyl, ethoxy-methyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl, represents phenyl which is optionally mono- or disubstituted with fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy, represents pyridyl or thienyl in each case optionally substituted with chlorine or methyl, R2 especially preferably represents C1-Ce-alkyl , C2-C4- alkenyl, methoxy-ethyl, ethoxy-ethyl or represents phenyl or benzyl, R6 and R7, independently of each other, especially preferably, represent methyl, ethyl or, together, represent a C5- alkylene radical, in the which the C3-methylene group is replaced by oxygen, in the form of its mixtures of isomers or its pure isomers. W most especially preferably represents hydrogen or methyl, B and the carbon atom to which they are attached, most especially preferably, represent saturated C5-C6-cycloalkyl, in which eventually one ring member is replaced by oxygen, and which is eventually monosubstituted with methyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy, D most preferably represents NH or oxygen, G most preferably represents hydrogen (a) or represents one of the groups in which: M represents oxygen or sulfur, R1 most preferably represents C1-C8-alkyl, C2-C4-alkenyl, methoxymethyl, ethxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl, cyclohexyl or represents phenyl which is optionally monosubstituted with fluorine , chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro, represents pyridyl or thienyl in each case optionally substituted with chlorine or methyl, R2 most especially preferably represents Cj-Ce-alkyl, C2-C4-alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl, R6 and R7, independently of each other, most especially preferably, represent methyl, ethyl or, together, represent a C5-alkylene radical, in which the Ca-methylene group is replaced by oxygen, in the form of its mixtures of isomers or its pure isomers.

Special preference is given to suspension concentrates comprising compounds of formula (I) from the following patents/patent applications cited on page 1, in which the radicals A, B, D, G, W, X, Y, Z , R1, R2, R6 and R7 have the meaning mentioned in the very especially preferred ranges: document numbers WO 98/05638, WO 04/007448.

From these orders, emphasis is placed on using the following compounds of formula (I): for suspension concentrates according to the invention.

Suitable penetration promoters in the present context are certain substances, which are customarily used to improve the penetration of agrochemically active substances into plants. In the present context, penetration promoters are defined by the fact that they penetrate from aqueous aerosol liquor and/or from the aerosol coating on the plant cuticle, thus being capable of increasing the mobility of active substances in the cuticle. The process described below and in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to evaluate this property.

Alkanol alkoxylates of formula (II) are suitable: R8-O-(-PO-)q-(-EO-)p-R9 (II) in which: R8 represents straight or branched chain alkyl with 4 to 20 carbon atoms carbon, R9 represents H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, n-pentyl or n-hexyl, EO represents CH2-CH2-O-, PO represents p represents a number from 4 to 8 and q represents a number from 6 to 10.

In the formulas given above: R8 preferably represents butyl, isobutyl, n-pentyl, isopentyl, neopentyl, n-hexyl, isohexyl, n-octyl, isooctyl, 2-ethylhexyl, nonyl, isononyl, decyl, n-dodecyl, isododecyl, lauryl, myristyl, isotridecyl, trimethylnonyl, palmityl, stearyl or eicosyl and especially preferably represents n-hexyl, isohexyl, n-octyl, iso-octyl, 2-ethylhexyl , nonyl, isononyl or decyl and most especially preferably, represents 2-ethylhexyl.

In the formulas given above: R9 preferably represents H, methyl, ethyl, n-propyl or isopropyl and especially preferably represents H.

In the formulas given above: p preferably represents 5 to 7, most especially preferably represents 6 and q especially preferably represents 7 to 9, most especially preferably represents 8.

Preferably suitable are alkanol alkoxylates of formula (II): R8-O-(-PO-)q-(-EO-)p-R9 (II) in which: R8 represents butyl, isobutyl, n-pentyl, isopentyl, neopentyl, n-hexyl, isohexyl, n-octyl, isooctyl, 2-ethylhexyl, nonyl, isononyl, decyl, n-dodecyl, isododecyl, lauryl, myristyl, isotridecyl, trimethylnonyl, palmityl, stearyl or eicosyl, R9 represents H, methyl, ethyl, n-propyl or isopropyl, EO represents CH2-CH2-O-, PO represents p represents a number from 5 to 7 and q represents a number from 7 to 9.

Furthermore, alkanol alkoxylates of formula (II) are preferably suitable: R8-O-(-PO-)q-(-EO-)p-R9 (II) in which: R8 represents n-hexyl, isohexyl , n-octyl, iso-octyl, 2-ethylhexyl, nonyl, isononyl or decyl, R9 represents H, EO represents CH2-CH2-O-, PO represents p represents a number from 5 to 7 and q represents a number from 7 to 9.

Furthermore, alkanol alkoxylates of formula (II) are preferably suitable: R8-O-(-PO-)q-(-EO-)p-R9 (II) in which: R8 represents n-hexyl, isohexyl , n-octyl, iso-octyl, 2-ethylhexyl, nonyl, isononyl or decyl, R9 represents H, EO represents CH2-CH2-O-, PO represents p represents 6 and q represents 8.

An emphasized example of an alkanol alkoxylate of formula (II), which may be mentioned, is 2-ethylhexyl alkoxylate of formula (11-1): in which EO and PO have the meanings given above and the numbers 8 and 6 are average values.

The above formulas provide general definitions of alkanol alkoxylates. In the case of these substances, mixtures of compounds of the indicated type with various chain lengths are considered. The calculated values for the indices are therefore average values that may also differ from integers.

Alkanol alkoxylates of the indicated formulas are known and are commercially available or can be prepared by known processes.

Suitable vegetable oils are all oils that are obtainable from plants and that are commonly used in agrochemical agents. These are vegetable oils, which are liquid at room temperature. Examples that can be mentioned are sunflower oil, rapeseed oil, corn oil, olive oil and soybean oil. Cottonseed oil, rapeseed oil, coconut oil, peanut oil, almond oil, sesame oil, walnut oil and hemp oil can also be mentioned.

The following oils may be mentioned as being preferred: rapeseed oil, corn oil, soybean oil and sunflower oil.

Very particular preference is given to the following oils: corn oil, soybean oil and sunflower oil.

Sunflower oil is especially preferred.

The oil-based suspension concentrates according to the invention comprise at least one nonionic surfactant and/or at least one anionic surfactant.

Non-ionic surfactants include polyethylene oxide - polypropylene oxide - 4-butoxy-butyl ether, polyethylene glycol ethers of straight-chain alcohols, reaction products of fatty acids with ethylene oxide and mixtures of these surfactants. Preferably, the compositions according to the invention comprise a mixture of 5 to 9 times polyethoxylated (C12-15) fatty alcohol and a propoxylated and ethoxylated 4-butoxybutyl alcohol and at least one other nonionic surfactant. mentioned.

As anionic surfactants, salts of interest, sparingly soluble in vegetable oil, of polystyrene sulfonic acids, salts of polyvinyl sulfonic acids, salts of condensation products from naphthalene sulfonic acid - formaldehyde, salts of condensation products from naphthalene acid - sulfonic, phenol-sulfonic acid and formaldehyde, as well as lignin-sulfonic acid salts. Salts of naphthalene sulfonic acid - formaldehyde condensation products are preferred.

Additives that may be contained in the formulations according to the invention include emulsifiers, spreading agents, foam-inhibiting agents, preservative agents, antioxidants, coloring agents and inert filler materials.

Preferred emulsifiers are ethoxylated nonylphenols, reaction products of alkylphenols with ethylene oxide and/or propylene oxide, ethoxylated arylalkylphenols, in addition, ethoxylated and propoxylated arylalkylphenols, as well as sulfated arylalkylethoxylates or ethoxypropoxylates. or phosphates, with sorbitan derivatives, polyethylene oxide - sorbitan fatty acid esters and sorbitan fatty acid esters being mentioned by way of example. Preferably, polyoxyethylene sorbitol oleate is mentioned.

As a spreading agent, all substances usually used for this purpose in agrochemical agents are of interest. Alkylsiloxanes are preferred.

As foam-inhibiting substances, all substances usually used for this purpose in agrochemical agents are of interest. Silicone oils and magnesium stearate are preferred.

As preservative agents, all substances of this type usually used for this purpose in agrochemical agents are of interest. As examples, Preventol® (Firma Bayer AG) and Proxel are mentioned.

As antioxidants, all substances usually used for this purpose in agrochemical agents are of interest. 2,6-di-t-butyl-4-methyl-phenol is preferred.

As dyes, all substances usually used for this purpose in agrochemical agents are of interest. Examples include titanium dioxide, pigment carbon black, zinc oxide and blue pigments, as well as Permanent Red FGR.

As inert filler materials, all substances usually used for this purpose in agrochemical agents that do not function as thickening agents are of interest. Inorganic particles, such as carbonates, silicates and oxides, are preferred, as well as organic substances, such as urea-formaldehyde condensates. Mentioned by way of example are kaolin, rutile, silicon dioxide, so-called highly dispersed silicic acid, silica gel, as well as natural and synthetic silicates, in addition, talc.

The content in the individual components can be varied within a wide range in the oil-based suspension concentrates according to the invention. Thus, the concentrations: - in the compound of formula (I), are generally between 5 and 30% by weight, preferably between 10 and 25% by weight, especially preferably between 10 and 20% by weight , most particularly preferably, between 10 and 18% by weight, between 5 and 12% by weight, - in penetration promoter, generally between 5 and 30% by weight, preferably between 15 and 25% by weight, especially preferably between 17 and 22% by weight, - in vegetable oil, in general, between 20 and 55% by weight, preferably between 25 and 52% by weight, especially preferably , between 25 and 50% by weight, - in surfactants, they are generally between 1 and 25% by weight, preferably between 1.0 and 15% by weight, very preferably between 1.5 and 5 % by weight, and - in additives, are generally between 0 and 25% by weight, preferably between 0 and 20% by weight.

The preparation of the oil-based suspension concentrates according to the invention takes place in such a way that the components are mixed together in the proportions desired in each case. The sequence in which the components are mixed with each other is irrelevant. Conveniently, the solid components are used in a finely ground state. Therefore, it is also possible to subject the resulting suspension after mixing the components, first to coarse grinding and then to fine grinding, so that the average particle size is below 20 μm. Suspension concentrates in which the solid particles have an average particle size between 1 and 10 μm are preferred.

The temperatures can be varied within a certain range when carrying out the process according to the invention. In general, work is carried out at temperatures between 10°C and 60°C, preferably between 15°C and 40°C. To carry out the process according to the invention, common mixing and grinding apparatus, which are used for the preparation of agrochemical formulations, are of interest.

In the case of the oil-based suspension concentrates according to the invention, these are formulations, which remain stable even after longer storage at elevated temperatures or in the cold, since no crystal growth is observed. They can be converted, by dilution with water, into homogeneous spray liquids. The use of these spray liquids takes place according to usual methods, therefore, for example, by sprinkling, watering or injection.

The application amount of the oil-based suspension concentrates according to the invention can be varied within a wide range. It is directed according to the respective agrochemical active substances and according to the content in the compositions.

The compositions according to the invention are suitable, with good compatibility with plants, with favorable toxicity to warm-blooded animals and with good compatibility with the environment, for the protection of plants and plant organs, for increasing yield harvesting, improving the quality of harvested material and combating animal pests, especially insects, arachnids, helminths, nematodes and molluscs, which occur in agriculture, horticulture, animal husbandry, forests, gardens and food processing facilities. leisure, in the protection of stored products and materials, as well as in the hygiene sector. They can preferably be applied as plant protection agents. They are active against normally sensitive and resistant species, as well as against all developmental stages or individual developmental stages. To the pests mentioned above belong: From the Order Anoplura (Phthiraptera), for example, Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp. From the Arachnida Class, for example, Acarus siro, Acena sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Choríoptes spp., Dermanys - sus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Pa- nonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici. From the Bivalva Class, for example, Dreissena spp. From the Order Chilopoda, for example, Geophilus spp., Scutigera spp. From the Order Coleoptera, for example, Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp. ., Attagenus spp., Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Mi gdolus spp., Monocha - mus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Popillia japonica, Premnotrypes spp., Psylliodes chrysocephala, Ptin us spp., Rhizobius ventralis, Rhizopertha dominica , Sitophilus spp., Sphenophorus spp., Sternechus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp. From the Order of Collembola, for example, Onychiurus armatus. From the Order of Dermaptera, for example, Forficula auricularia. From the Order of Diplopoda, for example, Blaniulus guttulatus. From the Order Diptera, e.g., Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis, Drosophila spp., Fannia spp., Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp., Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinel- la frit , Pegomyia hyoscyami, Phorbia spp., Stomoxys spp., Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.

From the Gastropoda Class, for example, Anon spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.

From the Helminth Class, e.g., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp. ., Cooperia spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp., Strongyloides fuellebomi, Strongyloides stercoralis, S- tronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Native Trichinella, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti.

Furthermore, protozoa such as Eimeria can be combated.

From the Order Heteroptera, e.g., Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurygaster spp., Heliopeltis spp., Hordas nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.

From the Order Homoptera, for example, Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Cameocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis s pp ., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Enosoma spp., Erythroneura spp., Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbrio- lata, Melanaphis sacchari, Metcalfiella spp., Metopolophium dirhodum, Monetta costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp. ., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Perregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae , Pianococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp. ., Unaspis spp., Viteus vitifolii.

From the Order Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the Order of Isopoda, for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber.

From the Order of Isoptera, for example, Reticulitermes spp., Odontotermes spp.

From the Order of Lepidoptera, for example, Acronicta ma jor, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana, Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp., Heliothis spp., Hofmannophila pseudospre tella, Homona magnanima , Hypomeuta padella, laphygma spp., Lithocolletis blancardella, lithophane antennata, loxagrotis al bicosta, lymantria spp. YPIELLA, PHYLLOCNISTIS citrella, Pieris spp., Plutella xylostella, Prodenia spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp.

From the Order of Orthoptera, for example, Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.

From the Order of Siphonaptera, for example, Ceratophyllus spp., Xenopsylla cheopis.

From the Order of Symphyla, for example, Scutigerella immaculate.

From the Order Thysanoptera, for example, Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinot-hnps femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scidoth rips spp., Taeniothrips cardamoni, Th rips spp.

From the Order of Thysanura, for example, Lepisma saccharina.

Plant parasitic nematodes include, for example, Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

The compositions according to the invention are suitable for combating animal pests, especially sucking insects, such as, for example, Thrips spp., Aphids spp., Psylla spp., Skales spp., whiteflies.

The compositions according to the invention may contain, in addition to the previously mentioned agrochemical active substances, as mixing partners, other active substances, such as insecticides, baits, sterilizing agents, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, protectants, fertilizers or semiochemicals.

The active substances, referred to in this specification under their "common name", are known from, for example, "The Pesticide Manual" 13th Ed., British Crop Protection Council 2003, and the website http://www.alanwood. net/pesticides/. Acetyl cholinesterase (AChe) 11-1 inhibitors: II -1 .A carbamates, e.g. alanicarb (II -1 .A-1), aldicarb (II -1 .A-2), aldoxycarb (II -1 . A-3), alixicarb (II -1 .A-4), aminocarb (II -1 .A-5), bendiocarb (II -1 .A-6), benfuracarb (II -1 .A-7) , bufencarb (II -1 .A-8), butacarb (II -1.A-9), butocarboxim (II- 1.A-10), butoxycarboxim (II -1 .A-11), carbaryl (II -1 .A-12), carbofuran (II -1 .A- 13), carbosulfan (II -1 .A-14), chloretocarb (II -1 .A-15), dimethylan (II -1 .A-16), ethiofencarb (II -1 .A-17), fenobucarb (II -1 .A-18), phenothiocarb (II -1 .A-19), formetanate (II -1 .A-20), furatiocarb ( II -1 .A-21), isoprocarb (II -1 .A-22), methamsodium (II- 1.A-23), methiocarb (II -1 .A-24), methomyl (II -1. A-25), metolcarb (II -1 .A-26), o-xamil (II -1 .A-27), pirimicarb (II -1 .A-28), promecarb (II -1 .A-29) , propoxur (II- 1.A-30), thiodicarb (II -1 .A-31), thiophanox (II -1 .A-32), trimetacarb (II -1 .A-33), XMC (II -1 .A-34), xylylcarb (II -1 .A-35),

Antagonists of GABA-ll-2-gated chloride channels: II-2B fiprols (phenylpyrazoles), e.g. acetoprol (II-2B-1), etiprol (II-2B-2), fipronil (II-2B-3) , pyrafluprole (II-2B-4), pyriprole (II-2B-5), vaniliprole (II-2B-6), Sodium channel modulators/voltage-gated sodium channel blockers II-3: II-3 pyrethroids , for example, acrinathrin (II -3-1), allethrin (d-cis-trans, d-trans) (II- 3-2), beta-cyfluthrin (II-3-3), bifenthrin (II-3- 4), bioallethrin (II-3-5), S-cyclopentyl isomer of bioallethrin (II-3-6), bioethanometrin (II-3-7), biopermethrin (II-3-8), bioresmethrin (II-3 -9), clovaportrin (II -3-10), cis-cypermethrin (II-3- 11), cis-resmethrin (II -3-12), cis-permethrin (II -3-13), clocitrin (II - 3-14), cycloprothrin (II -3-15), cyfluthrin (II -3-16), cyhalothrin (II -3-17), cypermethrin (alpha-, beta-, theta-, zeta-) (II -3-18), cyphenothrin (II -3-19), deltamethrin (II-3-20), em-penthrin (1R isomer) (II -3-21), esfenvalerate (II-3-22), etofenprox ( II-3-23), fenfluthrin (II-3-24), fenpropathrin (II-3-25), fenpyrithrin (II-3-26), fenvalerate (II-3-27), flubrocitrinate (II-3-28 ), flucitrinate (II-3-29), flufenprox (II-3-30), flumethrin (11-3-31), fluvalinate (II-3-32), fubfenprox (II-3-33), gamma -cyhalothrin (II-3-34), imiprothrin (II-3-35), kadethrin (II-3-36), lambda-cyhalothrin (II-3-37), methofluthrin (II-3-38), permethrin (cis-, trans-) (II-3-39), phenothrin (1R- trans isomer) (II-3-40), pralethrin (11-3-41), profluthrin (II-3-42), protrifenbut (II-3-43), pyresmethrin (II-3-44), resmethrin (II-3-45), RU 15525 (II-3-46), silafluofen (II-3-47), tau-fluvalinate (II -3-48), tefluthrin (II-3-49), teralethrin (II-3-50), tetramethrin (1R isomer) (II -3-51), tralomethrin (II-3-52), transfluthrin ( II-3-53), ZXI 8901 (II-3-54), pyrethrin (pyretide) (II-3-55), eflusilanate (II-3-56), DDT (II-3-57), methoxychlor (II -3-58), II-4 nicotinergic acetylcholine receptor agonists/antagonists: II-4A chloronicotinils, e.g., acetamiprid (II-4A-1), clothianidin (II-4A-2), dinotefuran (II- 4A-3), imidacloprid (II-4A-4), imidaclotiz (II-4A-5), nitenpyram (II-4A-6), nithiazine (II-4A-7), thiacloprid (II-4A-8), thiamethoxam (II-4A-9), II-4B nicotine (II-4B-1), bensultap (II-4B-2), Cartap (II-4B-3), thiosulfapsodium (II-4B-4), thiocilam (II-4C-4), Acetylcholine receptor allosteric modulators (agonists): II-5 spinosyns, e.g. spinosad (11-5-1), spinetoram (II-5-2) Chloride channel activators: II-6 mectins/macrolides, e.g. , abamectin (11-6-1), emamectin (II-6-2), emamectin benzoate (II-6-3), ivermectin (II-6-4), lepimectin (II-6-5), milbemectin na (II-6-6), II-7A Juvenile hormone analogues, e.g. hydroprene (II-7A-1), quinoprene (II-7A-2), methoprene (II-7A-3), epofenonan (II-7A-4), triprene (II-7A-5), fenoxycarb (II-7B-1), pyriproxyfen (II-7C-1), diofenolan (II-7C-2),

Active substances with unknown or non-specific mechanisms of action: II-8 fumigants, for example, methyl bromide (II-8A-1), chloropicrin (II-8B-1), sulfuryl fluoride (II-8C-1 ), II-9 Selective appetite suppressants, e.g. cryolite (II-9A-1), pymetrozine (II-9B-1), pyrifluquina-zone (NNI0101) (II-9B-2), flonicamid (II-9C -1), II-10 Mite growth inhibitors, e.g. clofentezine (II-10A-1), hexythiazox (II-1OA-2), etoxazole (II-10B-1),

Oxidative phosphorylation inhibitors, ATP disruptors 11-12: II-12A diafenthiuron (II-12A-1), II-12B Organic tin compounds, e.g. azociclotin (11-12B-1), ciexatin (11-12B- 2), fenbutatin oxide (II-12B-3), II-12C propargite (II-12C-1), tetradifon (II-12C-2), Oxidative phosphorylation uncouplers by interrupting the proton gradient H 11-13 chlorofenapyr (II -13-1) binapacril (II -13-2), dinobuton (II -13-3), dinocap (II -13-4), DNOC (II -13-5), Microbial intestinal membrane disruptors of insects: Bacillus thuringiensis strains (11-13-6), Chitin biosynthesis inhibitors: II -15 benzoylureas, e.g. bistrifluron (II -15-1), chlorofluazuron (II -15-2), diflu-benzuron ( II -15-3), fluazuron (II -15-4), flucicloxuron (II -15-5), flufenoxuron (II- 15-6), hexaflumuron (II -15-7), lufenuron II -15-8) , novaluron (II -15-9), novi- flumuron (11-15- II), penfluron (II -15-11), teflubenzuron (II -15-12), triflumuron (II -15-13), 11- 16 buprofezin (II -16-1), Moulting agents: cyromazine (II -17-1)

Ecdysone (II-18) agonists/breakers: II-18A diacylhydrazines, e.g., chromafenozide (II-18A-1), halofenozide (II-18A-2), methoxyfenozide (II-18A-3), tebufenozide ( II-18A-4), JS-118 (II-18A-5), azadirachtin (II-18B-1),

Octopaminergic agonists: e.g. amitraz (II -19-1), II-20 Site II electron transport inhibitors/site II electron transport inhibitors: hydramethylnon (II-20A-1), acequinocil (II-20B -1), fluacripirim (II-20C-1), cyflumetofen (II-20D-1), cyenopirafen (II-20D-2),

Electron transport inhibitors: II -21 Site I electron transport inhibitors: from the METI acaricide groups, for example, fenazaquin (II -21-1), fenpyroximate (11-21-2), pyrimi- diphen (II -21-3), pyridaben (II -21-4), tebufenpyrad (II -21-5), tolfenpyrad (II -21-6), rotenone (II -21-7), II-22 Blockers voltage-gated sodium channels: e.g. indoxacarb (II-22A-1), e.g. metaflumizone (BAS 320I) (II-22B-1), II-23 Fatty acid biosynthesis inhibitors: II-23A Derivatives of tetronic acid: e.g. spirodiclofen (II-23A-1), spiromesifen (II-23A-2), II-23B Tetramic acid derivatives: e.g. spirotetramate (II-23B-1), II-25 Neuronal inhibitors with unknown mechanism of action: bifenazate (11-25-1),

Ryanodine receptor effectors: II-28 diamides, e.g. flubendiamide (11-28-1), (II-28-2); rinaxapir (II-28-3), HGW86 II-29 Active substances with unknown mechanism of action: amidoflumet (II -29-1), benclotiaz (II-29-2), benzoximate (II-29-3), bromopropylate (II-29-4), buprofezin (II -29-5), quinomethionat (II-29-6), chlordimeform (II-29-7), chlorobenzylate (II-29-8), clothiazoben (II-29-9), cycloprene (II-29- 10), dicofol (II -29-11), dicyclanil (II -29-12), fenoxacrim (11-29-13), fentriphanil (11-29-14), flubenzimine (11-29-15), flufenerim ( II -29-16), flutenzin (II -29-17), gossyplure (II -29-18), japonilure (II -29-19), methoxadiazone (II-29-20), petroleum (II -29-21 ), potassium oleate (II-29-22), pyridalyl (II-29-23), sulfluramid (II-29-24), tetrasul (II-29-25), triaratene (II-29-26), verbutin (II-29-27).

The suspension concentrate according to the invention containing an active substance of formula (I-2) mixed with at least one insecticide selected from the above list is preferred.

Most particularly preferably, the suspension concentrate containing an active substance of the formula (I-2) is mixed with insecticides from the group of neonicotinils, selected from imidacloprid (according to EP-A-192 060), thiacloprid (according to EP-A-235 725), acetamiprid (WO 91/04965), nitenpyram (according to EP-A-302 389), thiamethoxam (according to EP-A-580 533), clothianidin (according to EP-A-376 279) and dinotefuran (according to EP-A-649845).

Furthermore, most preferably, the suspension concentrate containing an active substance of the formula (I-2) is mixed with insecticides from the pyrethroid group.

Furthermore, most preferably, the suspension concentrate containing an active substance of the formula (I-2) is mixed with the insecticide flubendiamide (II-28-1).

These active substances are known, for example, from The Pesticide Manual 13th edition.

With the aid of the oil-based suspension concentrates according to the invention, agrochemical active substances can be applied, in a particularly advantageous manner, to plants and/or their habitat. The agrochemical active substances contained exhibit, in this case, a better biological activity (especially a better insecticidal action and/or a better compatibility with crop plants), than in the case of application in the form of the corresponding traditional formulations.

According to the invention, it is possible to treat all plants and parts of plants. Under plants are meant here all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants may be plants, which can be obtained by conventional cultivation or optimization methods or by biotechnological or genetic engineering methods or by combinations of these methods, including transgenic plants and including plant varieties protectable by cultivar protection rights or plant varieties not protectable by cultivar protection rights. Under plant parts should be understood all above-ground and underground plant parts and organs, such as root shoots, leaves, flowers and roots, whereby, for example, leaves, needles, stems, trunks, flowers, etc. are mentioned. fruit bodies, fruits and seeds, as well as roots, tubers and rhizomes. Plant parts also include harvested material, as well as vegetative or germinative propagation material, for example cuttings, tubers, rhizomes, rooted chips and seeds.

The treatment of the plants and parts of plants according to the invention with the plant concentrates takes place directly or by action on their environment, habitat or storage area in accordance with usual treatment methods, e.g. by immersion, spraying, sprinkling, evaporation, misting, brushing, and, in the case of propagation material, especially in the case of seed material, in addition, by wrapping with one or more layers.

As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, plant species and plant cultivars, as well as parts thereof, wild type or obtained by conventional biological cultivation methods, such as crossing or protoplast fusion, are treated. In another preferred embodiment, transgenic plants and plant cultivars, which were obtained by genetic engineering methods, possibly in combination with conventional methods (genetically modified organisms), and parts thereof are treated. The terms "parts" or "plant parts" have been explained above.

Especially preferably, according to the invention, plants of commercially common plant cultivars or those in use are treated. Plant cultivars are understood as plants with new properties ("descriptors"), which have been obtained by conventional cultivation, by mutagenesis or by recombinant DNA techniques. These can be cultivars, bio- or genotypes.

Depending on the plant species or plant cultivars, their location and growing conditions (soils, climate, vegetation period, nutrients), the treatment according to the invention may also result in super additive ("synergistic") effects. Thus, for example, reduced application quantities and/or a broadening of the spectrum of activity and/or a strengthening of the activity of the substances and agents usable according to the invention are possible, improved plant growth, increased tolerance to high temperatures or reduced, increased tolerance against aridity or salt content in water and soil, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and/or higher nutritional value of harvested products , better storage capacity and/or processability of harvested products, which exceed the effects that were actually to be expected.

Transgenic plants (i.e., those obtained by genetic engineering) or preferred plant cultivars to be treated in accordance with the invention include all plants that, through genetic modification, received genetic material, which conferred properties on these plants. especially advantageous valuable ("descriptors"). Examples for such properties are improved plant growth, increased tolerance to high or low temperatures, increased tolerance to aridity or salt content in water or soil, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, better quality and/or higher nutritional value of harvested products, better storage capacity and/or processability of harvested products. Other and particularly emphatic examples for such properties are a better defense of plants against animal and microbial pests, such as against insects, mites, fungi, bacteria and/or phytopathogenic viruses, as well as an increased tolerance of plants against certain herbicidal active substances. As examples of transgenic plants, important crop plants are mentioned, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed, beetroot, sugar cane, as well as orchard plants (with the fruits apples, pears, citrus fruits and wine grapes), with special emphasis on corn, soybeans, potatoes, cotton and rapeseed. As properties ("descriptors"), especially emphasized are increased defense of plants against insects, by toxins that originate in plants, especially those that originate in plants (hereinafter, "Bt plants") by genetic material from Bacillus thuringiensis (for example, by the genes CrylA(a), Cryl-A(b), CrylA(c), CrylIA, CrylllA, CrylllB2, Cry9c, Cry2Ab, Cry3Bb and CrylF, and also their combinations). As properties ("descriptors"), the high defense of plants against fungi, bacteria and viruses by Systemic Acquired Resistance (SAR), systemin, phytoalexin, elicitors, as well as resistance genes and proteins and toxins are also especially emphasized. expressed accordingly. As properties ("descriptors"), in addition, the increased tolerance of plants towards certain herbicidal active substances, e.g. imidazolinones, sulfonylureas, glyphosate or phosphinothricin (e.g. "PAT gene "). The genes, which confer the desired properties ("descriptors") in each case, can also be present in combinations with each other in transgenic plants. As examples for "Bt plants", mention may be made of corn varieties, cotton varieties, soybean varieties and potato varieties, which are marketed under the trade names YIELD GARD® (e.g. corn, cotton, soybean), KnockOut® ( e.g. corn), StarLink® (e.g. corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato). As examples of herbicide-tolerant plants, mention are corn varieties, cotton varieties and soybean varieties, which are marketed under the trade names Roundup Ready® (glyphosate tolerance, e.g. corn, cotton, soybean), Liberty Link® (tolerance to phosphinothricin, e.g. rapeseed), IMI® (tolerance to imidazolinones) and STS® (tolerance to sulfonylureas, e.g. corn). As herbicide-resistant plants (conventionally bred for herbicide tolerance), varieties marketed under the trade name Clearfield® (e.g. corn) should also be mentioned. Obviously, these statements also apply to plant cultivars with these genetic descriptors or genetic descriptors yet to be developed, and which will be developed in the future and/or commercialized in the future.

The mentioned plants can be advantageously treated with the suspension concentrates according to the invention. The preferred ranges, indicated above in the case of suspension concentrates, also apply to the treatment of these plants. Particular emphasis should be placed on treating plants with suspension concentrates specifically mentioned in this text.

Furthermore, it was found that the compositions according to the invention exhibit a high insecticidal action against insects, which destroy technical materials.

By way of example and preferably - without, however, limiting - the following insects are mentioned: Beetles, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticomis, Dendrobium pertinex, Emobius mollis, Priobium carpini , Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus; Hymenoptera, such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur, Termites, such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis , Coptotermes formosanus; Insects with bristle tails, such as Lepisma saccharina.

Under technical materials, in the present context, non-living materials should be understood, such as, for example, plastics, adhesives, gums, paper and cardboard, leather, wood, wood processing products and coating compositions.

Ready-to-use agents may eventually contain other insecticides and, eventually, one or more fungicides.

From the point of view of possible additional mixing partners, reference is made to the insecticides and fungicides mentioned above.

The invention is illustrated by the following examples, without being limited thereby.

Examples Preparation Examples Example 1

For the preparation of a suspension concentrate, 150.0 g of the compound of formula (I-2) 100.0 g of Arlatone T(V) 30.0 g of Atlox 4894 5.0 g of Morwet D 425 0.5 g of Silfoam SC 1132 2.0 g of anhydrous citric acid 2.0 g of Vulkanox BHT are added, under stirring at room temperature, to a mixture of 200.0 g of the compound of formula (11-1) and 510.5 g of sunflower oil.

After the addition has finished, stir for another 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained in which 90% of the solid particles have a particle size below of 6 μm.

Example 2

For the preparation of a suspension concentrate, 150.0 g of the compound of formula (I-2) 100.0 g of Arlatone T(V) 20.0 g of Atlox 4894 5.0 g of Morwet D 425 0.5 g of Silfoam SC 1132 2.0 g of anhydrous citric acid 2.0 g of Vulkanox BHT 10 are added, under stirring at room temperature, to a mixture of 200.0 g of the compound of formula (11-1) and 520, 5 g of sunflower oil.

After the addition has finished, stir for another 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained, in which 90% of the solid particles have a particle size below. of 6 μm.

Example 3

To prepare a suspension concentrate, 150.0 g of the compound of formula (I-2) 100.0 g of Arlatone T(V) 10.0 g of Atlas G 5000 10.0 g of Synperonic A7 5.0 g of Morwet D 425 0.5 g of Silfoam SC 1132 2.0 g of anhydrous citric acid 2.0 g of Vulkanox BHT are added, under stirring at room temperature, to a mixture of 200.0 g of the compound of the formula (11- 1) and 520.5 g of sunflower oil.

After the addition has finished, stir for another 5 to 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained in which 90% of the solid particles have a particle size below 6μm.

Example 4

For the preparation of a suspension concentrate, 150.0 g of the compound of formula (I-2) 100.0 g of Arlatone T(V) 10.0 g of Atlas G 5000 10.0 g of Synperonic A3 5.0 g of Morwet D 425 0.5 g of Silfoam SC 1132 2.0 g of anhydrous citric acid 2.0 g of Vulkanox BHT are added, under stirring at room temperature, to a mixture of 200.0 g of the compound of the formula (11- 1) and 520.5 g of sunflower oil.

After the addition has finished, stir for another 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained in which 90% of the solid particles have a particle size below 6μm.

Comparative Example I (WO 05/084441)

For the preparation of a suspension concentrate, 150.0 g of compound (I-2) 100 g of ArlatoneT(V) 80 g of Zephrym PD 2206 20 g of Borresperse NA 0.5 g of Silfoam SC 1132 2.0 g of anhydrous nitric acid 2.0 g of Vulkanox BHT are added, under stirring at room temperature, to a mixture of 200 g of alkanol alkoxylate of formula (2) CH3-(CH2)t-CH2-O-(-CH2- CH2-O-)u-H (2) in which: t represents a number from 9 to 12 and u represents a number from 7 to 9. 425.5 g of sunflower oil.

After the addition has finished, stir for another 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained in which 90% of the solid particles have a particle size below 6μm.

Comparative Example II (Comparative Example I from WO 05/084441)

To prepare a suspension concentrate, 100 g of the compound (I-2) 100 g of polyoxyethylene sorbitol oleate 80 g of a mixture of polyalkoxylated alcohols (Atlox 4894) 20 g of lignosulfonate (Borresperse NA) 0.5 g of polydimethylsiloxane 2.0 g of anhydrous citric acid 2.0 g of 2-6-di-t-butyl-4-methyl-phenol are added, under stirring at room temperature, to a mixture of 250 g of the compound RO(EO)8(PO)4-H in which: R represents straight or branched chain alkyl with 12 to 15 carbon atoms, 5 EO represents CH2-CH2-O and PO represents 450.1. g of sunflower oil.

After the addition has finished, stir for another 10 minutes at room temperature. The resulting homogeneous suspension in this case is first subjected to coarse grinding and then to fine grinding, so that a suspension is obtained in which 90% of the solid particles have a particle size of - low 6 μm.

In the Examples, the following products are used: Table 1

Application Example I: v iscosity of the formulation as a function of temperature

The complex viscosity of the suspension concentrate is determined on a Bohlin Gemini HR nano viscometer from Firma Malvem 5 Instruments, measurement parameters: frequency of 0.5 Hz and a desired deformation of 0.002. The temperature is initially equilibrated within 200 seconds to 20°C and thereafter reduced towards cooling with a gradient of 1°C/minute. Table 2

Application Example II: determination of biological activity To prepare a suitable preparation solution, 1 part by weight of the formulated substance is diluted with water to the desired concentration. Pear trees, which are heavily infested with Psylla pyri, are treated with the preparation solution at the desired concentration. In this case, "heavily infested" means that 40 insects per shoot (per branch) are present.

After the desired time, mortality in % is determined. In this case, 100% means that all Psylla pyri were killed; 0% means no insects were killed.

In the case of this test, for example, the following formulations according to the invention exhibit superior efficacy compared to formulations known from the prior art: Table 3: test with Psylla pyri in pears

Comparison Example III: determination of biological activity

To prepare a suitable preparation solution, 1 part by weight of the formulated substance is diluted with water to the desired concentration.

Citrus trees, which were heavily infested with scales, are treated 3 times with the preparation solution (with, in each case, an interval of 2 weeks between aerosol treatments), each with 45 g of active substance/ha /m crown height.

After the desired time, the quality of 50 citrus fruits is evaluated. For this, the number of healthy, non-infested fruits was determined.

In the case of this test, for example, the following formulations according to the invention exhibit superior efficacy compared to formulations known from the prior art: Table 4: Scales test in citrus

Application Example IV: determining compatibility with plants

To prepare a suitable preparation solution, 1 part by weight of the formulated substance is diluted with water to the desired concentration.

Pear trees, which are heavily infested by Psylla pyri, are treated with the preparation solution with a concentration of 96 g of active substance/ha/m of crown height.

After the desired time, plant injuries (e.g. necrosis) are determined in %.

In the case of this test, for example, the following formulations according to the invention exhibit superior efficacy compared to formulations known from the prior art: Table 5: Plant compatibility test on pears (cv. Packham's Triumph )

Claims (7)

1. Oil-based suspension concentrates, characterized by the fact that they comprise: - (a) the compound spirotetramate, solid at room temperature, of formula (I-2): (b) the 2-ethylhexyl alkoxylate penetration promoter of formula (II-1): in which EO represents CH2-CH2-O-, PO represents - (c) a vegetable oil, - (d) a nonionic surfactant selected from the group consisting of: - polyethylene oxide - polypropylene oxide - 4-butoxy-butyl ether, - polyethylene glycol ethers of chain alcohols linear, - products of the reaction of fatty acids with ethylene oxide and - mixtures of these surfactants mentioned above and/or - (e) an anionic surfactant, with the content: of the compound of formula (I-2), being between 5 and 30% by weight, - of the penetration promoter of formula (II-1), is between 5 and 30% by weight, - of the vegetable oil, is between 20 and 55% by weight, - of the surfactants, is between 1 and 25 % by weight, and - of the additives, is between 0 and 25% by weight. 2. Suspension concentrates according to claim 1, characterized in that they contain, as vegetable oil, at least one oil selected from sunflower oil, rapeseed oil, corn oil, olive oil and olive oil. soy. 3. Suspension concentrates according to claim 1 or 2, characterized in that they contain, as vegetable oil, sunflower oil. 4. Process for preparing suspension concentrates, as defined in any one of claims 1 to 3, characterized by the fact that the ingredients mentioned in any one of claims 1 to 3, and, optionally, as one or more additives selected from of the groups of emulsifiers, foam-inhibiting agents, preservative agents, antioxidants, colorants and/or inert fillers are mixed with each other, and the resulting suspension is then optionally milled. 5. Application of suspension concentrates, as defined in any one of claims 1 to 3, characterized by the fact that it is for applying the compounds of formula (I-2) to plants and/or their habitat. 6. Application of suspension concentrates, as defined in any one of claims 1 to 3, characterized by the fact that it is for combating insects. 7. Agent, characterized by the fact that it comprises a suspension concentrate, as defined in any one of claims 1 to 3, and extending agents and/or surfactants.