BR9909042B1 - composições e métodos para inibição da polimerização de monÈmero aromático de vinila. - Google Patents

composições e métodos para inibição da polimerização de monÈmero aromático de vinila.

Info

Publication number
BR9909042B1
BR9909042B1 BRPI9909042-2A BR9909042A BR9909042B1 BR 9909042 B1 BR9909042 B1 BR 9909042B1 BR 9909042 A BR9909042 A BR 9909042A BR 9909042 B1 BR9909042 B1 BR 9909042B1
Authority
BR
Brazil
Prior art keywords
inhibiting
compositions
methods
vinyl aromatic
aromatic monomer
Prior art date
Application number
BRPI9909042-2A
Other languages
English (en)
Other versions
BR9909042A (pt
Inventor
Graciela B Arhancet
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BR9909042A publication Critical patent/BR9909042A/pt
Publication of BR9909042B1 publication Critical patent/BR9909042B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C07C17/42—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C07C25/28—Halogenated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/12—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing sulfur and oxygen
    • C09K15/14—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing sulfur and oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
BRPI9909042-2A 1998-03-25 1999-02-10 composições e métodos para inibição da polimerização de monÈmero aromático de vinila. BR9909042B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/047,551 US6024894A (en) 1998-03-25 1998-03-25 Compositions and methods for inhibiting vinyl aromatic monomer polymerization
PCT/US1999/002926 WO1999048996A1 (en) 1998-03-25 1999-02-10 Compositions and methods for inhibiting vinyl aromatic monomer polymerization

Publications (2)

Publication Number Publication Date
BR9909042A BR9909042A (pt) 2000-12-05
BR9909042B1 true BR9909042B1 (pt) 2009-05-05

Family

ID=21949626

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9909042-2A BR9909042B1 (pt) 1998-03-25 1999-02-10 composições e métodos para inibição da polimerização de monÈmero aromático de vinila.

Country Status (10)

Country Link
US (1) US6024894A (pt)
EP (1) EP1086192B1 (pt)
KR (1) KR100713764B1 (pt)
AR (1) AR017985A1 (pt)
BR (1) BR9909042B1 (pt)
CA (1) CA2323870C (pt)
DE (1) DE69933558T2 (pt)
ES (1) ES2270584T3 (pt)
TW (1) TW539681B (pt)
WO (1) WO1999048996A1 (pt)

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KR20010079776A (ko) * 1998-09-09 2001-08-22 칼 에이. 로월드 장애 히드록실아민을 이용한 비닐 모노머 중합반응 억제방법
AU2968300A (en) * 1999-01-19 2000-08-01 Angus Chemical Company Sterically-hindered alkyl hydroxylamines for scavenging of free radicals
US6685823B2 (en) 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US6689926B2 (en) 2002-02-12 2004-02-10 Fina Technology, Inc. Process for purifying styrene monomer feedstock prior to polymerization
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US6926820B2 (en) * 2002-09-20 2005-08-09 G.E. Betz, Inc. Inhibition of viscosity increase and fouling in hydrocarbon streams including unsaturation
US20060163539A1 (en) * 2003-03-17 2006-07-27 Junichi Nakajima Polymerization inhibitor for aromatic vinyl compounds and method for inhibiting the polymerization of the compounds
US7128826B2 (en) * 2003-07-31 2006-10-31 General Electric Company Polymerization inhibitor for styrene dehydrogenation units
US7651635B1 (en) * 2009-02-05 2010-01-26 Nalco Company Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US8298440B2 (en) 2010-06-03 2012-10-30 General Electric Company Methods and compositions for inhibiting vinyl aromatic monomer polymerization
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
US8884038B2 (en) 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9206268B2 (en) 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
US8901362B2 (en) * 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
JP6043937B2 (ja) * 2012-08-16 2016-12-14 株式会社片山化学工業研究所 ビニル芳香族モノマーの重合を抑制するための組成物
SG11201500774WA (en) 2012-08-24 2015-02-27 Dorf Ketal Chemicals India Private Ltd Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof
TW202005938A (zh) 2018-07-13 2020-02-01 美商藝康美國公司 具有胺穩定劑之聚合抑制劑及阻滯劑組合物
US10869444B2 (en) * 2018-07-13 2020-12-22 Ecolab Usa Inc. Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers
WO2020068735A1 (en) 2018-09-28 2020-04-02 Ecolab Usa Inc. Amino-quinone antipolymerants and methods of using
TW202114976A (zh) * 2019-10-11 2021-04-16 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2022182612A1 (en) * 2021-02-26 2022-09-01 Bl Technologies, Inc. Composition and method for inhibiting the formation and growth of popcorn polymers

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US2965685A (en) * 1958-06-24 1960-12-20 Monsanto Chemicals Polymerization inhibitor
DE2028183B2 (de) * 1969-06-10 1975-09-11 Rohm And Haas Co., Philadelphia, Pa. (V.St.A.) Verfahren zur Inhibierung der Polymerisation von Acrylsäure bei der Destillation
GB1346774A (en) * 1970-10-05 1974-02-13 Bp Chem Int Ltd Stabilisation of acrylonitrile
US3733326A (en) * 1971-03-10 1973-05-15 Sankyo Co Inhibition of the polymerization of vinyl monomers
US4003800A (en) * 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4040911A (en) * 1976-01-02 1977-08-09 Gulf Research & Development Company Process for inhibiting the polymerization of styrene
US4105506A (en) * 1977-02-24 1978-08-08 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4237326A (en) * 1979-05-30 1980-12-02 Mitsubishi Petrochemical Company Limited Method of inhibiting polymerization of styrene
US4376678A (en) * 1982-07-29 1983-03-15 American Hoechst Corporation Method of inhibiting polymerization of vinyl aromatic compounds
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4434307A (en) * 1982-12-27 1984-02-28 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4466905A (en) * 1983-04-11 1984-08-21 Cosden Technology, Inc. Polymerization inhibition process for vinyl aromatic compounds
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
DE3611764A1 (de) * 1986-04-08 1987-10-15 Bernd Kellner Vakuum-sonnenkollektor
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US5545786C1 (en) * 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
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US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators

Also Published As

Publication number Publication date
TW539681B (en) 2003-07-01
DE69933558T2 (de) 2007-06-21
WO1999048996A1 (en) 1999-09-30
BR9909042A (pt) 2000-12-05
AR017985A1 (es) 2001-10-24
CA2323870C (en) 2005-11-08
KR100713764B1 (ko) 2007-05-07
ES2270584T3 (es) 2007-04-01
KR20010034636A (ko) 2001-04-25
DE69933558D1 (de) 2006-11-23
EP1086192A4 (en) 2005-02-09
EP1086192A1 (en) 2001-03-28
EP1086192B1 (en) 2006-10-11
CA2323870A1 (en) 1999-09-30
US6024894A (en) 2000-02-15

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 05/05/2009, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 20A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2500 DE 04-12-2018 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.