BR9908994A - Sìntese de poliésteres de ácido graxo de poliol superior por transesterificação - Google Patents
Sìntese de poliésteres de ácido graxo de poliol superior por transesterificaçãoInfo
- Publication number
- BR9908994A BR9908994A BR9908994-7A BR9908994A BR9908994A BR 9908994 A BR9908994 A BR 9908994A BR 9908994 A BR9908994 A BR 9908994A BR 9908994 A BR9908994 A BR 9908994A
- Authority
- BR
- Brazil
- Prior art keywords
- ingredients
- fatty acid
- polyol
- transesterification
- acid polyesters
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title abstract 5
- 238000005809 transesterification reaction Methods 0.000 title abstract 4
- 235000014113 dietary fatty acids Nutrition 0.000 title abstract 3
- 229930195729 fatty acid Natural products 0.000 title abstract 3
- 239000000194 fatty acid Substances 0.000 title abstract 3
- 229920000728 polyester Polymers 0.000 title abstract 2
- -1 polyol fatty acid Chemical class 0.000 title abstract 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000004615 ingredient Substances 0.000 abstract 4
- 150000003077 polyols Chemical class 0.000 abstract 3
- 239000006227 byproduct Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Saccharide Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Edible Oils And Fats (AREA)
- Fats And Perfumes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Patente de Invenção: <B>"SìNTESE DE POLIéSTERES DE áCIDO GRAXO DE POLIOL SUPERIOR POR TRANSESTERIFICAçãO"<D>. Um processo para a sintetização de poliésteres de ácido graxo de poliol que compreende as etapas de (1) misturar os ingredientes que compreendem (a) um primeiro poliol não esterificado que tenha grupos hidroxila (b) um segundo poliol esterificado com ácidos graxos, (c) um catalisador básico e (d) um agente de emulsificação para formar uma mistura de ingredientes; (2) por em reação a mistura de ingredientes em uma temperatura suficiente para serem obtidos produtos e subprodutos de uma mistura reacional de transesterificação; (3) remover, pelo menos uma parte dos subprodutos a partir da mistura reacional de transesterificação; e (4) aquecer de novo os produtos e ingredientes da reação de transesterificação da etapa (3) em uma temperatura e em um espaço de tempo suficientes para serem esterificados pelo menos cerca de 50% dos grupos hidroxila do primeiro poliol.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7908998P | 1998-03-23 | 1998-03-23 | |
| PCT/US1999/005619 WO1999048946A2 (en) | 1998-03-23 | 1999-03-17 | Synthesis of higher polyol fatty acid polyesters by transesterification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9908994A true BR9908994A (pt) | 2000-12-12 |
Family
ID=22148354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9908994-7A BR9908994A (pt) | 1998-03-23 | 1999-03-17 | Sìntese de poliésteres de ácido graxo de poliol superior por transesterificação |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6504003B1 (pt) |
| EP (1) | EP1066306B1 (pt) |
| JP (1) | JP2002507628A (pt) |
| CN (1) | CN1293678A (pt) |
| AT (1) | ATE240966T1 (pt) |
| AU (1) | AU751699B2 (pt) |
| BR (1) | BR9908994A (pt) |
| CA (1) | CA2325410C (pt) |
| DE (1) | DE69908104T2 (pt) |
| ES (1) | ES2196796T3 (pt) |
| MY (1) | MY120243A (pt) |
| TR (1) | TR200002720T2 (pt) |
| WO (1) | WO1999048946A2 (pt) |
| ZA (1) | ZA992249B (pt) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1066306B1 (en) | 1998-03-23 | 2003-05-21 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters by transesterification |
| CA2474599A1 (en) * | 2002-01-30 | 2003-08-07 | Sigma Coatings B.V. | Polysaccharide esters and their use as binders in coatings |
| US6900310B2 (en) * | 2002-05-28 | 2005-05-31 | The Procter & Gamble Company | Staged synthesis of purified, partially esterified polyol polyester fatty acid compositions |
| US6887947B1 (en) | 2002-05-28 | 2005-05-03 | The Procter & Gamble Company | Synthesis of purified, partially esterified polyol polyester fatty acid compositions |
| US20030228332A1 (en) * | 2002-05-28 | 2003-12-11 | Schaefer Jared John | Purified, partially esterified polyol polyester fatty acid compositions |
| TWI324592B (en) * | 2002-11-28 | 2010-05-11 | Sulzer Chemtech Ag | A method for the esterification of a fatty acid |
| US7659331B2 (en) * | 2003-02-06 | 2010-02-09 | Honeywell International Inc | Shapeable resin compositions |
| US7645819B2 (en) * | 2003-02-06 | 2010-01-12 | Honeywell International Inc. | Extrudable PVC compositions |
| US20050250941A1 (en) * | 2004-05-07 | 2005-11-10 | The Procter & Gamble Company | Synthesis of purified, moderately esterified polyol polyester fatty acid compositions |
| DE602005024029D1 (de) * | 2004-08-10 | 2010-11-18 | Battelle Memorial Inst Columbu | Von pflanzlichen und tierischen ölen und fetten abgeleitete schmiermittel |
| US20060182963A1 (en) * | 2004-08-17 | 2006-08-17 | Bradshaw Howard G | Use of melt plasticizers to enhance processability and mechanical properties of polyolefin articles |
| US8877952B2 (en) | 2005-04-26 | 2014-11-04 | Battelle Memorial Institute | Pre-esterification of primary polyols to improve solubility in solvents used in the polyol process |
| WO2010078493A1 (en) | 2008-12-31 | 2010-07-08 | Battelle Memorial Institute | Solvent-less preparation of polyols by ozonolysis |
| ES2480942T3 (es) | 2005-11-30 | 2014-07-29 | The Nisshin Oillio Group, Ltd. | Composición de éster de ácido graso de trehalosa |
| US8247582B2 (en) | 2006-02-07 | 2012-08-21 | Battelle Memorial Institute | Esters of 5-hydroxymethylfurfural and methods for their preparation |
| CN100390128C (zh) * | 2006-04-16 | 2008-05-28 | 南京红宝丽股份有限公司 | 一种利用菜籽油制备的生物基多元醇 |
| CN100465152C (zh) * | 2006-08-18 | 2009-03-04 | 南京红宝丽股份有限公司 | 一种采用环氧菜籽油制备的生物基多元醇 |
| EP2134822A2 (en) * | 2007-04-09 | 2009-12-23 | Dow Global Technologies Inc. | Capped polyester polyol lubricant composition |
| CN101423472B (zh) * | 2008-10-29 | 2011-06-15 | 湖南省林业科学院 | 一种提高油脂与低碳醇酯交换反应速率的方法以及组合物 |
| CA2748622C (en) | 2008-12-31 | 2016-11-01 | Battelle Memorial Institute | Preparation of esters and polyols by initial oxidative cleavage of fatty acids followed by esterification reactions |
| MX2011006961A (es) | 2008-12-31 | 2011-09-27 | Battelle Memorial Institute | Uso de acidos grasos como material de alimentacion en el proceso de poliol. |
| EP2406357B1 (en) | 2009-03-13 | 2016-04-27 | Battelle Memorial Institute | Process for producing modified vegetable oil lubricants |
| US8658580B2 (en) | 2012-03-01 | 2014-02-25 | Uchicago Argonne, Llc | Superabsorbing gel for actinide, lanthanide, and fission product decontamination |
| FR3024981B1 (fr) * | 2014-08-22 | 2016-09-09 | Univ Montpellier 2 Sciences Et Techniques | Derives polyesters d'acides gras de polyglycosides |
| CN109891025A (zh) | 2016-09-01 | 2019-06-14 | Hs制造集团有限责任公司 | 纤维质表面的生物基衍生化的方法 |
| WO2020056124A1 (en) | 2018-09-12 | 2020-03-19 | Sm Technology Holdings Llc | Biobased barrier coatings |
| WO2020106799A1 (en) | 2018-11-21 | 2020-05-28 | Sm Technology Holdings Llc | Novel aqueous adhesives using saccharide fatty acid esters |
| JP7784304B2 (ja) | 2019-01-25 | 2025-12-11 | グリーンテック・グローバル・プライベート・リミテッド | ポリオール脂肪酸エステル担体組成物 |
| CN114040917B (zh) | 2019-03-06 | 2024-10-25 | 绿色科技全球私人有限公司 | 酰基卤的液体分散体 |
| CN114402108B (zh) | 2019-07-31 | 2023-12-22 | 绿色科技全球私人有限公司 | 含半纤维素的涂料 |
| US20210347999A1 (en) | 2020-05-08 | 2021-11-11 | Greentech Global Pte. Ltd. | Methods for biobased derivatization of cellulosic and synthetic materials and articles obtained therefrom |
| CN116635309A (zh) | 2020-11-05 | 2023-08-22 | 绿色科技全球私人有限公司 | 改善的纤维素纳米纤丝(cnf) |
| US20230265614A1 (en) | 2021-11-19 | 2023-08-24 | Greentech Global Pte. Ltd. | Water insoluble, high melting point saccharide fatty acid esters (sfae) |
| CN114806132B (zh) * | 2022-06-09 | 2023-07-04 | 山东滨州金盛新材料科技有限责任公司 | 一种高亲水性聚甘油脂肪酸酯-蔗糖脂肪酸酯组合物的制备方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3174144A (en) * | 1960-11-21 | 1965-03-16 | Richard J O'neill | Digital read-out and display unit |
| NL145278B (nl) | 1966-04-06 | 1975-03-17 | Nebraska State | Werkwijze ter uitvoering van een heresteringsreactie tussen een vloeibare polyhydrische alcohol en een hydrofobe ester van een vetzuur met lange keten. |
| US3600186A (en) * | 1968-04-23 | 1971-08-17 | Procter & Gamble | Low calorie fat-containing food compositions |
| US3714144A (en) | 1969-05-29 | 1973-01-30 | Us Agriculture | Process for the production of sucrose esters of fatty acids |
| GB1399053A (en) | 1973-03-16 | 1975-06-25 | Tate & Lyle Ltd | Process for the production of surface active agents comprising sucrose esters |
| US3963699A (en) | 1974-01-10 | 1976-06-15 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters |
| IE50028B1 (en) | 1979-12-19 | 1986-02-05 | Tate & Lyle Plc | Process for the production of a surfactant containing sucrose esters |
| US4517360A (en) | 1983-06-23 | 1985-05-14 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters using carbonate catalysts |
| US4861613A (en) | 1986-07-25 | 1989-08-29 | Arco Chemical Technology, Inc. | Non-digestible fat substitutes of low-caloric value |
| DD262663A1 (de) * | 1987-07-24 | 1988-12-07 | Adw Ddr | Verfahren zur herstellung grenzflaechenaktiver polyolester-gemische |
| US5175323A (en) | 1988-08-01 | 1992-12-29 | Arco Chemical Technology, L.P. | Preparation of esterified propoxylated glycerin by transesterification |
| US4983329A (en) | 1988-08-26 | 1991-01-08 | Arco Chemical Technology, Inc. | Preparation of esterified propoxylated glycerin from free fatty acids |
| US4927920A (en) | 1988-11-15 | 1990-05-22 | Nebraska Department Of Economic Development, State Of Nebraska, U.S.A. | Sugar ester synthesis |
| US4983731A (en) | 1989-03-17 | 1991-01-08 | Nebraska Department Of Economic Development | Separation and purification of sugar esters |
| CA2073868A1 (en) | 1990-01-16 | 1991-07-17 | Kevin S. Dobson | Low caloric fat substitutes, precursors of such substitutes and methods of making same |
| US5273772A (en) | 1991-10-25 | 1993-12-28 | Arco Chemical Technology, L.P. | Food compositions containing esterified alkoxylated polysaccharide fat substitutes |
| US5387429A (en) | 1992-05-20 | 1995-02-07 | Arco Chemical Technology, L.P. | Reduced calorie cocoa butter substitutes |
| US5288884A (en) | 1992-10-22 | 1994-02-22 | Arco Chemical Technology, L.P. | Process for producing a reduced calorie fat mimetic composition |
| US5298637A (en) | 1992-10-22 | 1994-03-29 | Arco Chemical Technology, L.P. | Process for producing a reduced calorie lipid composition |
| US5304665A (en) * | 1993-04-05 | 1994-04-19 | Arco Chemical Technology, L.P. | Process for the preparation of highly esterified alkoxylated polyol compositions |
| US5399728A (en) | 1993-04-05 | 1995-03-21 | Arco Chemical Technology, L.P. | Process for the preparation of highly esterified alkoxylated polyol compositions |
| US5399729A (en) | 1993-08-31 | 1995-03-21 | Arco Chemical Technology, L.P. | Esterified alkoxylated polyol fat substitutes having high primary ester content |
| US5362894A (en) | 1993-11-12 | 1994-11-08 | Arco Chemical Technology, L.P. | Process for producing an esterified alkoxylated polyol |
| US5427815A (en) | 1993-12-10 | 1995-06-27 | Arco Chemical Technology, L.P. | Linked esterified alkoxylated polyols useful as reduced calorie fat substitutes |
| US5374446A (en) | 1993-12-10 | 1994-12-20 | Arco Chemical Technology, L.P. | Linked esterified alkoxylated polyols useful as reduced calorie fat substitutes |
| US5466843A (en) | 1994-04-29 | 1995-11-14 | Arco Chemical Technology, L.P. | Process for preparing a C12 -C24 saturated fatty acid esterified alkoxylated polyol |
| EP0708075B1 (en) * | 1994-10-21 | 1999-07-14 | ARCO Chemical Technology, L.P. | Process for the preparation of fatty acid-esterified propoxylated glycerin |
| US5597605A (en) | 1995-02-09 | 1997-01-28 | Arco Chemical Technology, L.P. | Reduced calorie fat component |
| US5589217A (en) | 1995-05-11 | 1996-12-31 | Arco Chemical Technology, L.P. | Reduced calorie fat component |
| US5935631A (en) | 1995-12-20 | 1999-08-10 | Cpc International, Inc. | Reduced calorie fried snacks having a cooling sensation when placed in the mouth |
| US5767257A (en) * | 1996-07-19 | 1998-06-16 | The Procter & Gamble Company | Methods for producing polyol fatty acid polyesters using atmospheric or superatmospheric pressure |
| EP1066306B1 (en) | 1998-03-23 | 2003-05-21 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters by transesterification |
-
1999
- 1999-03-17 EP EP99914912A patent/EP1066306B1/en not_active Expired - Lifetime
- 1999-03-17 US US09/646,295 patent/US6504003B1/en not_active Expired - Lifetime
- 1999-03-17 JP JP2000537921A patent/JP2002507628A/ja active Pending
- 1999-03-17 WO PCT/US1999/005619 patent/WO1999048946A2/en not_active Ceased
- 1999-03-17 AT AT99914912T patent/ATE240966T1/de not_active IP Right Cessation
- 1999-03-17 ES ES99914912T patent/ES2196796T3/es not_active Expired - Lifetime
- 1999-03-17 BR BR9908994-7A patent/BR9908994A/pt not_active IP Right Cessation
- 1999-03-17 CA CA002325410A patent/CA2325410C/en not_active Expired - Lifetime
- 1999-03-17 TR TR2000/02720T patent/TR200002720T2/xx unknown
- 1999-03-17 DE DE69908104T patent/DE69908104T2/de not_active Expired - Lifetime
- 1999-03-17 AU AU33551/99A patent/AU751699B2/en not_active Ceased
- 1999-03-17 CN CN99804197A patent/CN1293678A/zh active Pending
- 1999-03-22 MY MYPI99001064A patent/MY120243A/en unknown
- 1999-03-23 ZA ZA9902249A patent/ZA992249B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2196796T3 (es) | 2003-12-16 |
| ZA992249B (en) | 1999-09-23 |
| WO1999048946A2 (en) | 1999-09-30 |
| AU3355199A (en) | 1999-10-18 |
| MY120243A (en) | 2005-09-30 |
| CA2325410A1 (en) | 1999-09-30 |
| AU751699B2 (en) | 2002-08-22 |
| ATE240966T1 (de) | 2003-06-15 |
| JP2002507628A (ja) | 2002-03-12 |
| CA2325410C (en) | 2004-10-12 |
| TR200002720T2 (tr) | 2000-12-21 |
| CN1293678A (zh) | 2001-05-02 |
| DE69908104T2 (de) | 2004-04-01 |
| DE69908104D1 (de) | 2003-06-26 |
| EP1066306B1 (en) | 2003-05-21 |
| US6504003B1 (en) | 2003-01-07 |
| WO1999048946A3 (en) | 1999-11-11 |
| EP1066306A2 (en) | 2001-01-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 5A,6A, 7A E 8A ANUIDADES |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1907 DE 24/07/2007. |