BR9802608A - Processo para a separação de ar por meio de retificação criogênica - Google Patents

Processo para a separação de ar por meio de retificação criogênica

Info

Publication number
BR9802608A
BR9802608A BR9802608-9A BR9802608A BR9802608A BR 9802608 A BR9802608 A BR 9802608A BR 9802608 A BR9802608 A BR 9802608A BR 9802608 A BR9802608 A BR 9802608A
Authority
BR
Brazil
Prior art keywords
air
separation
cryogenic rectification
air separation
cryogenic
Prior art date
Application number
BR9802608-9A
Other languages
English (en)
Inventor
John Fredric Billingham
Dante Patrick Bonaquist
James Robert Dray
Original Assignee
Praxair Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Praxair Technology Inc filed Critical Praxair Technology Inc
Publication of BR9802608A publication Critical patent/BR9802608A/pt

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/044Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a single pressure main column system only
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • F25J3/04193Division of the main heat exchange line in consecutive sections having different functions
    • F25J3/04206Division of the main heat exchange line in consecutive sections having different functions including a so-called "auxiliary vaporiser" for vaporising and producing a gaseous product
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04151Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
    • F25J3/04187Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
    • F25J3/04218Parallel arrangement of the main heat exchange line in cores having different functions, e.g. in low pressure and high pressure cores
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04296Claude expansion, i.e. expanded into the main or high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04303Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04412Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/24Processes or apparatus using other separation and/or other processing means using regenerators, cold accumulators or reversible heat exchangers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/902Apparatus
    • Y10S62/909Regeneration

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

"PROCESSO PARA A SEPARAçãO DE AR POR MEIO DE RETIFICAçãO CRIOGêNICA". Um processo é porporcionado para a separação de ar por meio de retificação criogênica compreendendo a compressão de ar de alimentação, a passagem de ar de alimentação comprimido através de um pré-purificador dentro do qual são substancialmente removidas as impurezas do ar, logo depois, o esfriamento do ar limpo dentro de um regenerador esfriado e então a introdução do ar em uma instalação de separação criogênica de ar dentro da qual ocorrre sua separacão em componentes ricos em nitrogênio e ricos em oxigênio.
BR9802608-9A 1997-07-30 1998-07-28 Processo para a separação de ar por meio de retificação criogênica BR9802608A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/902,919 US5802872A (en) 1997-07-30 1997-07-30 Cryogenic air separation with combined prepurifier and regenerators

Publications (1)

Publication Number Publication Date
BR9802608A true BR9802608A (pt) 1999-10-26

Family

ID=25416622

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9802608-9A BR9802608A (pt) 1997-07-30 1998-07-28 Processo para a separação de ar por meio de retificação criogênica

Country Status (7)

Country Link
US (1) US5802872A (pt)
EP (1) EP0895046A3 (pt)
KR (1) KR19990014225A (pt)
CN (1) CN1207491A (pt)
BR (1) BR9802608A (pt)
CA (1) CA2244313C (pt)
ID (1) ID20643A (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19807225A1 (de) * 1998-02-20 1999-08-26 Linde Ag Verfahren und Vorrichtung zur Tieftemperaturzerlegung von Luft
WO1999042773A1 (de) * 1998-02-20 1999-08-26 Linde Aktiengesellschaft Luftreinigung mit regeneratoren und adsorptivbett für wasser
US5968234A (en) * 1998-04-14 1999-10-19 Air Products And Chemicals, Inc. Temperature swing adsorption with regeneration by elevated pressure ASU nitrogen-enriched gas
FR2789162B1 (fr) * 1999-02-01 2001-11-09 Air Liquide Procede de separation d'air par distillation cryogenique
FR2790823B1 (fr) 1999-03-12 2001-06-15 Air Liquide Procede et installation de purification et de separation d'air par voie cryogenique sans pre-refroidissement
FR2793312B1 (fr) * 1999-05-04 2001-07-13 Air Liquide Appareil d'echange thermique a contre-courant et son application aux installations de distillation d'air
FR2823256B1 (fr) * 2001-04-10 2003-07-25 Air Liquide Procede d'alimentation en azote impur de la chambre de combusti0n d'une turbine a gaz combinee a une unite de distillation d'air, et installation de production d'energie electrique correspondante
US6732544B1 (en) 2003-05-15 2004-05-11 Praxair Technology, Inc. Feed air precooling and scrubbing system for cryogenic air separation plant
FR2896861B1 (fr) * 2006-01-31 2008-07-18 Air Liquide Procede de regulation d'un ensemble d'appareils de separation d'air par distillation cryogenique et ensemble d'appareils de separation d'air operant selon ledit procede
FR2949553B1 (fr) * 2009-09-02 2013-01-11 Air Liquide Procede de production d'au moins un gaz pauvre en co2 et d'un ou plusieurs fluides riches en co2
US20130078583A1 (en) * 2011-09-23 2013-03-28 Yu-Po Lee Heat Recycling System for a High-Temperature Exhaust Gas
CN102562302B (zh) * 2012-02-15 2013-11-13 武汉都市环保工程技术股份有限公司 燃气-蒸汽联合循环惰性气体保护控制系统
US8647409B2 (en) * 2012-05-24 2014-02-11 Praxair Technology, Inc. Air compression system and method
CN104132506A (zh) * 2014-05-25 2014-11-05 刘晓 超级空气净化应用系统

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE377118A (pt) * 1929-04-19
US2825212A (en) * 1950-03-25 1958-03-04 Linde Eismasch Ag Process for separating a compressed gas mixture
DE1143526B (de) * 1962-01-12 1963-02-14 Linde Eismasch Ag Verfahren und Einrichtung zur Tieftemperatur-Gaszerlegung, insbesondere Luftzerlegung
US3508412A (en) * 1966-08-12 1970-04-28 Mc Donnell Douglas Corp Production of nitrogen by air separation
IL36741A (en) * 1971-04-30 1974-11-29 Zakon T Method for the separation of gaseous mixtures with recuperation of mechanical energy and apparatus for carrying out this method
DE2557453C2 (de) * 1975-12-19 1982-08-12 Linde Ag, 6200 Wiesbaden Verfahren zur Gewinnung von gasförmigem Sauerstoff
DE2734934C3 (de) * 1977-08-03 1980-07-03 Linde Ag, 6200 Wiesbaden Verfahren zur Tieftemperaturzerlegung von Luft
JPS576282A (en) * 1980-06-14 1982-01-13 Kobe Steel Ltd Air separator
US4557735A (en) * 1984-02-21 1985-12-10 Union Carbide Corporation Method for preparing air for separation by rectification

Also Published As

Publication number Publication date
US5802872A (en) 1998-09-08
CA2244313C (en) 2002-07-16
EP0895046A2 (en) 1999-02-03
EP0895046A3 (en) 1999-07-28
KR19990014225A (ko) 1999-02-25
CA2244313A1 (en) 1999-01-30
ID20643A (id) 1999-02-04
CN1207491A (zh) 1999-02-10

Similar Documents

Publication Publication Date Title
BR9802608A (pt) Processo para a separação de ar por meio de retificação criogênica
BR9801656A (pt) Conjunto de compressão de gás para um sistema de refrigeração e processo de refrigeração.
DE69502328D1 (de) Kryogenisches Rektifikationsverfahren zur Herstellung von Hochdruckstickstoff
AU1937999A (en) Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity
CA2097751A1 (en) Liquefier process
BR9404471A (pt) Processo aperfeiçoado de adsorção por flutuação de pressão para a produção de oxigênio a partir de ar
BR0106171B1 (pt) "processo para a recuperação de dióxido de carbono em alta pressão a partir de uma corrente de baixa pressão".
ZA966433B (en) Process for the production of high purity carbon dioxide.
ATA907898A (de) Verbesserter kaskadenkühlungsprozess zur verflüssigung von erdgas
BR9904954A (pt) Processo e aparelho para produção de dióxido de carbono substancialmente puro a partir de uma alimentação de dióxido de carbono
BR9403176A (pt) Processo para retificação criogênica de ar de alimentação e aparelho de retificação criogênica
BR9801590A (pt) Processo e aparelho para realizar separação criogênica de ar.
BR9801588A (pt) Processo e aparelho para separa-Æo criog-nica de ar
MY119081A (en) Improved cooling process and installation, in particular for the liquefaction of natural gas
MY118753A (en) Air separation method and apparatus for producing nitrogen
DE69505731D1 (de) Kryogenes Rektifikationsverfahren von Luft zur Herstellung von Hochdrucksauerstoff
PT933187E (pt) Processo e aparelho para a producao de um recipiente
BR9105677A (pt) Processo para a separacao criogenica de ar para a producao de oxigenio e nitrogenio de media pressao
BR0005219A (pt) Processo para a produção de nitrogênio gasoso e de oxigênio gasoso por meio de retificação criogênica de ar de alimentação
BR0101474A (pt) Sistema de separação criogênica de ar, núcleo detroca de calor intregrado para separarcomponentes gasosos e proecesso para separarar
MY118100A (en) Apparatus and method for producing nitrogen
TW372258B (en) Ventilating-re-burning type composite cycling power plant
MXPA02001997A (es) Procedimiento y dispositivo para la descomposicion de una mezcla gaseosa con funcionamiento de emergencia.
BR9304299A (pt) Processo para a preparaçao de nitrogeno gasoso de alta pureza a partir de ar
HUP9801083A3 (en) Process for producing (15,4r)- or (1r,4s)-4-[(2-amino-6-chloro-9h-purin)-9-yl]-2-cyclopentene-1-methanol

Legal Events

Date Code Title Description
FF Decision: intention to grant
FG9A Patent or certificate of addition granted
B24C Patent annual fee: request for for restoration

Free format text: REFERENTE A 6A, 7A, 8A, 9A, 10A, 11A, 12A E 13A ANUIDADE(S).

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2257 DE 08/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE AS 6A, 7A, 8A, 9A, 10A, 11A, 12A E 13A ANUIDADES.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2606 DE 15-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.