BR9800355A - Process for the hydrogenation of sugars by means of a shelled catalyst. - Google Patents
Process for the hydrogenation of sugars by means of a shelled catalyst.Info
- Publication number
- BR9800355A BR9800355A BR9800355-0A BR9800355A BR9800355A BR 9800355 A BR9800355 A BR 9800355A BR 9800355 A BR9800355 A BR 9800355A BR 9800355 A BR9800355 A BR 9800355A
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogenation
- sugars
- catalyst
- shelled
- raney metal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H3/00—Compounds containing only hydrogen atoms and saccharide radicals having only carbon, hydrogen, and oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
- B01J25/02—Raney nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Saccharide Compounds (AREA)
Abstract
Hydrogenation of 1 or more sugars to sugar alcohols in aqueous solution comprises using hydrogen (H2) at elevated temperature and pressure and a catalyst with an inert core and catalytically active shell of a mixture of pure Raney metal and a Raney metal alloy.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19701440 | 1997-01-17 | ||
DE19720496A DE19720496B4 (en) | 1997-01-17 | 1997-05-16 | Process for the hydrogenation of sugars or sugar mixtures to give sugar alcohols or sugar alcohol mixtures |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9800355A true BR9800355A (en) | 1999-09-08 |
Family
ID=26033166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9800355-0A BR9800355A (en) | 1997-01-17 | 1998-01-19 | Process for the hydrogenation of sugars by means of a shelled catalyst. |
Country Status (9)
Country | Link |
---|---|
US (1) | US5936081A (en) |
EP (1) | EP0854149B2 (en) |
JP (1) | JP3450688B2 (en) |
AT (1) | ATE217003T1 (en) |
AU (1) | AU735009B2 (en) |
BR (1) | BR9800355A (en) |
CA (1) | CA2227319C (en) |
DE (3) | DE19758788B4 (en) |
DK (1) | DK0854149T3 (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999036442A1 (en) | 1998-01-20 | 1999-07-22 | Grain Processing Corporation | Reduced malto-oligosaccharides |
US6919446B1 (en) | 1998-01-20 | 2005-07-19 | Grain Processing Corp. | Reduced malto-oligosaccharides |
DE19929368A1 (en) * | 1999-06-25 | 2000-12-28 | Merck Patent Gmbh | Mannitol preparation, for use in tableting or as a sugar substitute, by continuous hydrogenation of fructose over Raney copper catalyst |
US6380379B1 (en) | 1999-08-20 | 2002-04-30 | Grain Processing Corporation | Derivatized reduced malto-oligosaccharides |
JP2003512508A (en) | 1999-10-20 | 2003-04-02 | グレイン・プロセッシング・コーポレーシヨン | Reduced maltooligosaccharide cleansing composition |
WO2001028325A2 (en) | 1999-10-20 | 2001-04-26 | Grain Processing Corporation | Compositions including reduced malto-oligosaccharide preserving agents |
ATE350158T1 (en) * | 2000-02-18 | 2007-01-15 | Degussa | METHOD FOR PRODUCING CARBOXYLIC ACIDS BY DEHYDRATION OF ALCOHOLS |
US20020038051A1 (en) | 2000-02-18 | 2002-03-28 | Degussa-Huls Ag | Raney copper |
EP1127613A1 (en) * | 2000-02-18 | 2001-08-29 | Degussa AG | Shaped fixed bed copper-Raney catalyst to be used in the dehydrogenation of alcohols |
EP1382595A1 (en) * | 2000-02-18 | 2004-01-21 | Degussa AG | Fixed bed copper Raney catalyst for dehydrogenating alcohols |
WO2002051779A2 (en) * | 2000-12-23 | 2002-07-04 | Degussa Ag | Method for producing alcohols by hydrogenating carbonyl compounds |
TW572878B (en) * | 2001-05-11 | 2004-01-21 | Fushimi Pharmaceutical Co Ltd | Method for production of sugar alcohol |
DE10242062B4 (en) * | 2002-09-11 | 2007-02-15 | Südzucker Aktiengesellschaft Mannheim/Ochsenfurt | Hydrogenated condensed Palatinose, process for their preparation and their use |
WO2007028411A1 (en) * | 2005-09-08 | 2007-03-15 | Evonik Degussa Gmbh | The production and use of supported activated base metal catalysts for organic transformation |
MX2009006724A (en) * | 2006-12-22 | 2009-06-30 | Cargill Inc | A process for the hydrogenation of a sugar or sugar mixture. |
CN101066984B (en) * | 2007-05-28 | 2010-05-19 | 江门量子高科生物股份有限公司 | Preparation process of hydrogenated oligofructos |
DE102008007072A1 (en) * | 2008-01-31 | 2009-08-13 | Südzucker Aktiengesellschaft Mannheim/Ochsenfurt | Process for the production of fermentable drinks |
BR112012015490B1 (en) | 2009-12-23 | 2019-09-24 | Evonik Degussa Gmbh | PROCESS FOR THE PRODUCTION OF A SWEETENER THROUGH THE REACTION OF A CARBOHYDRATE MIXTURE CONTAINING ISOMALTULOSIS AND SACAROSIS |
DE102013226140A1 (en) * | 2013-12-17 | 2015-06-18 | Robert Bosch Gmbh | Air mass measuring device, air mass measurement system and air mass measurement method for a vehicle |
CN106413427A (en) * | 2014-04-10 | 2017-02-15 | 阿彻丹尼尔斯米德兰德公司 | Synthesis of reduced sugar alcohols, furan derivatives |
JP6774494B2 (en) | 2016-02-19 | 2020-10-21 | インターコンチネンタル グレート ブランズ エルエルシー | Process for forming multiple useful streams from a biomass source |
CN117186161B (en) * | 2023-11-06 | 2024-01-16 | 山东百龙创园生物科技股份有限公司 | Isomaltulose alcohol and preparation method thereof |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB430576A (en) * | 1932-12-23 | 1935-06-21 | Du Pont | Improvements in or relating to the manufacture of glycerol and glycols |
GB801732A (en) * | 1955-07-29 | 1958-09-17 | Melle Usines Sa | Improvements in or relating to a process for producing polyalcohols by hydrogenationof corresponding sugars |
GB989532A (en) * | 1960-05-30 | 1965-04-22 | Tervalon Mij Voor Voedingsmidd | Improvements in or relating to bifidus-active substances and bifidus-active food preparations |
DE1693030B1 (en) * | 1967-10-19 | 1971-02-18 | Le Nii Antibiotikow | Process for the production of sorbitol |
US3691100A (en) * | 1970-02-05 | 1972-09-12 | Atlas Chem Ind | Tungsten oxide promoted and supported nickel catalyst |
AU6339073A (en) * | 1972-12-18 | 1975-06-12 | Colonial Sugar Refining | Catalytic hydrogenation |
DE2756270A1 (en) * | 1977-12-16 | 1979-06-21 | Bayer Ag | METHOD FOR PRODUCING LOW MOLECULAR POLYHYDROXYL COMPOUNDS |
DE2831656A1 (en) * | 1978-07-19 | 1980-02-07 | Bayer Ag | METHOD FOR PRODUCING LOW MOLECULAR POLYHYDROXYL COMPOUNDS |
DE2831719A1 (en) * | 1978-07-19 | 1980-01-31 | Bayer Ag | METHOD FOR PRODUCING LOW MOLECULAR POLYHYDROXYL COMPOUNDS |
US4413152A (en) * | 1982-08-25 | 1983-11-01 | Uop Inc. | Hydrogenation in aqueous solutions |
DE3403973A1 (en) * | 1984-02-04 | 1985-08-14 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING A MIXTURE OF (ALPHA) -D-GLUCOPYRANOSIDO-1,6-MANNITE AND (ALPHA) -D-GLUCOPYRANOSIDO-1,6-SORBITE FROM (ALPHA) -D-GLUCOPYRANOSIDO-1,6-FRUCTOSE |
FR2652589B1 (en) * | 1989-10-04 | 1995-02-17 | Roquette Freres | PROCESS FOR THE MANUFACTURE OF XYLITOL AND XYLITOL-RICH PRODUCTS. |
US5162517A (en) * | 1989-10-14 | 1992-11-10 | Bayer Aktiengesellschaft | Process for the preparation of epimer-free sugar alcohols from the group consisting of xylitol, sorbitol (D-glucitol), 4-O-β-D-galactopyranosyl-D-glucitol and 4-O-α-D-glucopyranosyl-D-sorbitol |
DE3934457A1 (en) * | 1989-10-14 | 1991-04-18 | Bayer Ag | Prepn. of sorbitol - by hydrogenation of alpha-D-glucose in aq. soln. on unsupported metal catalyst of iron gp. |
IT1256801B (en) * | 1992-01-31 | 1995-12-15 | Novamont Spa | HYDROGENATION CATALYST, PROCEDURE FOR ITS PREPARATION AND USE, IN PARTICULAR FOR THE HYDROGENATION AND / OR HYDROGENOLYSIS OF CARBOHYDRATES AND POLYOLS. |
DE4243722A1 (en) * | 1992-12-23 | 1994-06-30 | Basf Ag | Process for the preparation of polyether glycols |
EP0625578B2 (en) † | 1993-05-06 | 2004-04-28 | Südzucker Aktiengesellschaft Mannheim/Ochsenfurt | Sweetener, process of preparation and use thereof |
DE4345265A1 (en) * | 1993-10-16 | 1995-09-21 | Degussa | Prodn. of shaped Raney metal catalysts for use in a fixed bed |
DE4416115A1 (en) * | 1994-05-06 | 1995-11-09 | Bayer Ag | Process for the preparation of alpha-D-glucopyranosido-1,6-mannitol and sorbitol from alpha-D-glucopyranosido-1,6-fructose |
DE4416408A1 (en) * | 1994-05-10 | 1995-11-16 | Bayer Ag | Continuous prodn. of sugar alcohol(s) used as low calorie sweeteners |
IL110126A (en) † | 1994-06-26 | 2001-01-28 | Gadot Biochemical Ind Ltd | Process for the manufacture of isomaltitol |
JP3793267B2 (en) * | 1995-11-08 | 2006-07-05 | 東和化成工業株式会社 | Raney catalyst, method for producing the same, and method for producing sugar alcohol using the same |
DE19618443A1 (en) * | 1996-05-08 | 1997-11-20 | Klaus Prof Dr Buchholz | Process for the preparation of allitol from sucrose and its use as sweetener |
JP4711471B2 (en) * | 1996-07-05 | 2011-06-29 | 三菱商事フードテック株式会社 | Crystalline maltitol and method for producing honey-containing crystals containing the same |
-
1997
- 1997-05-16 DE DE19758788A patent/DE19758788B4/en not_active Expired - Lifetime
- 1997-05-16 DE DE19720496A patent/DE19720496B4/en not_active Revoked
- 1997-12-31 DK DK97123040T patent/DK0854149T3/en active
- 1997-12-31 AT AT97123040T patent/ATE217003T1/en not_active IP Right Cessation
- 1997-12-31 DE DE59707151T patent/DE59707151D1/en not_active Expired - Lifetime
- 1997-12-31 EP EP97123040.4A patent/EP0854149B2/en not_active Expired - Lifetime
-
1998
- 1998-01-09 US US09/004,800 patent/US5936081A/en not_active Expired - Lifetime
- 1998-01-16 CA CA002227319A patent/CA2227319C/en not_active Expired - Fee Related
- 1998-01-19 BR BR9800355-0A patent/BR9800355A/en not_active Application Discontinuation
- 1998-01-19 JP JP00812598A patent/JP3450688B2/en not_active Expired - Lifetime
- 1998-01-19 AU AU52140/98A patent/AU735009B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
DE59707151D1 (en) | 2002-06-06 |
EP0854149B2 (en) | 2014-11-12 |
ATE217003T1 (en) | 2002-05-15 |
DE19758788B4 (en) | 2007-12-13 |
JPH1129509A (en) | 1999-02-02 |
DE19720496B4 (en) | 2004-10-21 |
US5936081A (en) | 1999-08-10 |
DE19720496A1 (en) | 1998-07-23 |
CA2227319A1 (en) | 1998-07-17 |
EP0854149A1 (en) | 1998-07-22 |
CA2227319C (en) | 2001-10-30 |
DK0854149T3 (en) | 2002-08-19 |
EP0854149B1 (en) | 2002-05-02 |
AU735009B2 (en) | 2001-06-28 |
AU5214098A (en) | 1998-07-23 |
JP3450688B2 (en) | 2003-09-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFERIMENTO DO PRESENTE PEDIDO, TENDO POR BASE OS ARTIGOS 8O E 13 DA LPI 9279 DE 14/05/96 |
|
B12B | Appeal against refusal [chapter 12.2 patent gazette] |